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13 views9 pages

Chem Module PPDF

Best questions of chemistry

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simranagrawal035
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© All Rights Reserved
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ee XERCISE # 0-1 IONIC BOND (Only one option is correc) \K The compound which contains ionic as well as covalent bonds és (A) GHCh, (8) CHI (© KCN OHO, CBO ‘A bond formed between two like atoms cannot be (A) ionic (B) covalent ({C) coordinate (D) metallic cBOD ‘An ionic bond 4°B™ is most likely to be formed when : (A) the ionization energy of A is high and the electron gain enthalpy of B is low (B) the ionization energy of A is low and the electron gain enthalpy of B is high (C) the ionization energy of A and the electron gain enthalpy of B both are high (D) the ionization energy of A and the electron gain enthalpy of B both are low BONN COVALENT BOND , CO-ORDINATE BOND & LEWIS STRUCTURE 4 Which of the following species are hypervalent? (1) PCL, (2) BF,, (3) XeF, , (4) CO,> (A) 1,2,3 (B) 1,3 (34 ()1,2 : CBO00 5, The types of bond present in N,Os,, are (A) only covalent (B) only ionic (C) ionic and covalent (D) covalent & coordinalt Which of the following molecule does not have coordinate bonds? a (A) CH-NC (By CO ©, (©) co? -CBOOONE 7. Which of the following Lewis dot diagrams is(are) incorrect ? ee ®) X10 Ge (©C)2)H-N-H i V.B.T., HYBRIDISATION & capone! $. Which of the following has a geometry different fon ae Peel a three species (having the (A) BE, (B) SO; (Ox ‘ (D) PH; 9. — Maximum bond energy is in iS (A) Fy ®)N, ©o, cao (D) equal 110: e “J uh 1 in Re 16. 1, Ig, I, Ey 300001 300002 BO0003 BO0004 ordinate Chemical Bonding he nybridisation and shape of BrF, molecu (4) pi and bent T' shape (B) sp*d? and tetragonal )spid and bent 3 (D) none of these CBON010 The shape of methyl cation (CH) is likely to be (a)linear (B) pyramidal (C) planar (D) spherical CBOOOIL 2, The structure of XeF, involves hybridization of the type (a sp’ (B) sp* (C) sp'd (D) sp*d? CBOOOI2 fi Which of the following has been arranged in increasing order of length of the hybrid orbitals ? (A)spsp?> sp (B) sp>>sp?>sp — (C) sp? > sp> sp? (D) sp? < sp < sp? cBOO01s 8 When 2s-2s, 2p-2p and 2p-2s orbitals overlap, the bond strength decreases in the order P (A)p-p>s-s>p-s (B)p—p>p-s>s-s ()s-s>p—p>p—s (D)s-s>p-s>p-p cBOOOIS Carbon atoms in C,(CN), are: (A) sp-hybridized (B) sp?-hybridized. (©) sp- and sp? hybridized (D) sp, sp? and sp*- hybridized CBO0016 ‘The structure of XeF, in vapour phase is ‘A) pentagonal bipyramidal (B) trigonal bipyramidal ri bipyramidal (© capped octahedron (D) square bipy ae CBO0017 BENT'S RULE AND DRAGO'S RULE 4 CH bond distance is the longest in: (A) CH. (B) GA (C2 Hy PUSH A oe CBOOOIS 4, .f oxygen in ether (CH,OCH,) is : bridization of oxy: p a bond angle at oxygen a ot : ae (© 110°, (©) 109°28, sp" OCS ae Ces CBONOI9 inged in order of decreasing bond length ? which of the following has been arranes “B) P_O > $-0 > CLO ‘“)P-O>CLO>S-0 {D) CLO > S-O> P-O So .cLo> Po CBO0020 i —— 2 21, hemistry ALLEY: Select the CORRECT set of statements. As the s-character of a hybrid orbital decreases (1) The bond angle decreases: (ID) The bond strength increases (LI) The bond length increases, (AV) Size of orbital inereases : (A), (UD and (TY) (B) ID, (ID and (IV) (C) () and (ID (D) All are CORRECT BOON Among the following, the CORRECT statement (A) Between NH, and PH,, NH, isa better electron donor because the lone pair of electrons occupies spherical 's orbital (B) Between NH, and PH, PH, is a better electron donor because the lone pair of electrons occupies sp ‘orbital and is more directional (©) Between NH, and PH,, NH, isa better electron donor because the lone pair of electrons occupies sp orbital and is more directional (D) Between NH, and PH,, PH, is a better electron donor because the Jone pair of electrons occupies spherical 's orbital and is less directional ul is less directional cBONI2 In which of the following molecule C—C bond length will be highest ? (A) CE, — CF, (8) F,CH-CHF, (€) FCH,-CH.F —(D) CH-CF, BONE Tn BCIBr I molecule the maximum % s-character provided from the central atom is in bond ‘ (A)B-1 (B) B~Cl (©) B-Br (D) Can not predict CBOO024 Which of the following order is CORRECT for increasing p-character in orbital used for bonding by central atom fA) SiH, > CH, (B) H,S > H,0 (C) PH; > PH, (D) NH, > PH, CBO0025 MOLECULE DOES NOT EXIST PCI, exists but NCI, does not because (A) Nitrogen has no vacant 2d-orbitals (B) NCI, is unstable (©) Nitrogen atom is much smaller than P (D) Nitrogen is highly inert CBO Which of the following molecules do not exist. (A) BEE (B) NCI, (©) NOR, (D) XeRz S io Select non existing species oa (A) PH, (B) PH, (CPR (D) None of these Among the fluorides below, the one which does not exist is - we (A) XeF, B) BeF, a (B) BeF, (©) SF, cr, 4 Which of the following compound exist - oe (A) XeHH, (8) CIF, 7 (C) PH, (p) Ic, cBo0 Tee Mo) h Which of the folie he mae & HYDROGEN noNDING WOHCl> CHES cH, ree F Bedin order of decreasing dipole moment? (© CH,CI > CH,Br > CHI cue (B) CH, aP > CH,Cl > CH,Br > CHI CT (D) CHF > CH,CI > cI 1 > CH,Br 90021 99 The experimental value of the dipole mom B00031 1215 A. The percentage of ionic character in Her cg oo ee TH lath of the H-C1 bond is cwnies | ys ast ter in HCI is nearly : © (D)7 cupies B02 4. Ethanol has a higher boiling poi 7 Tee ng Pointthan dimethyl ether though they have the same molecular weight. ‘cupies : : (A) resonance (B) coordinate bonding cupies | (0) hydrogen bonding (D) ionic bonding 00022 Gone M. Which of the following compounds would have significant intermolecular hydrogen bonding ? HF, CH,OH, N,O,, CH, 00023 | (4) HF, N,O, (B) HF, CH,, CH,OH (C) HF, CH,OH —(D) CH,OH, CH, ‘CBO0034 8. For H,0,, HS, H,O and HF, the correct order of decreasing strength of hydrogen bonding is Od (A) H,0 > HF > H,0, > HS (B) HF > H,0, > H,0 > HS ondit (©) HE > H,0 > HO, > H,S (D) H,0, > H,0 > HF > H,S CBO0035 00025 |* Which one of the following does not have intermolecular H-bonding? : (A) Ho (B) o-nitro phenol (C) HF ane, (CBO0036 2. The order of strength of hydrogen bonds is: one (0026 (A) NH...N > OH... > FH..F (D) NH...N < OH...O > FH...F (© NH...N > OH..O < FHF CBO0037 ted as 00027 4™ the 17 tond in solid He" ean be best rep jue oe ws sil ise ()H-F..H-F.-H-F 0028 iE pS va S aa © hr (Qu 002? CBO0038 a caer ro J JEE-Chemistry EXERCISE # 0-2 ' TONIC BOND COVALENT BOND & COORDINATE BOND | 1... Which of the fotlowing compounds contain lonie, covalent and co-ordinate bonds? (A) NUCL {B) KCN (C) NaBP, (D) NaOH CBO0053 ments is/are true? 2. Which of the following (A) Covalent bonds are directional (B) onic bonds are nondirectional (©) A polar bond is formed between two atoms which have the same electronegativity value. (D) The presence of polar bonds in a polyatomic molecule suggests that it has zero dipole moment BONS able 3. To which of the following species octet rule is not app! (A) BrF, (B) SF, (C) IF, (D) CO. cans | * LEWIS STRUCTURE & BOND LENGTH 4. O(ozone) molecule can be equally represented by the structures I and II shown below which of the following values of x are not correct nw (A) 148 pm (B) 121 pm. (C)less than 121 pm (D) more than 148 pm. CBO: 5. Select the correct statement - (A) C-O bond length of CO molecule is higher than the C-O bond length of CO. (B) C-0 bond length of CO molecule is lower than the C-O bond length of CO,_ (©) N-O bond length of NO, ion is higher than the N-O bond length of No (D) N-O bond length of NO, ion is lower than the N-O bond length of NO, ae Boos? ————— Sea | ALE VBT, HYBRIDISATION & VSEPR THEORY 6, _ Which of the following statement(s) is/are not correct? (A) Hybridization is the mixing of atomic orbitals of large enersy difference. (B) sp*-hybrid orbitals are formed from two p - atomic orbitals and one s- atomic orbital (©) sp'e2-hybrid orbitals are all at 90° to one another (D) sp'-hybrid orbitals are directed towards the corners of & regular tetrahedron CBO0058: Which of the following species are linear ? (a) Ic Bi (Ny () clo; CBO0059 8%. Which of the following molecules have bent shape. Where A is central atom , B is surrounding atom and E is lone pair - (A) ABE, (B) ABLE (© ABE (D) AB, CBO0060 In which of the following process(s) hybridisation of underlined atom does not change ~ 5 (A) NH, + BF, > H,[Link],, (B) SIF, + 2F° —> [SiF,]? (©) BH, + ts HB | (D) HBO, 4 [B(OR),- CBO0061 Which of the following ‘d' orbital(s) participate in the hybridistaion for Xe in the cationic part of XeF (8) > wad, (B) day 4, © 4, Select the CORRECT statement if internuclear axis is y-axis >= (Ad, and d,, orbital of two atoms form: bond B)p, “and p, orbital of two atoms form a-bond 056 | (©) dys_,p and d,s_y2 otbital of wo atoms form bond (©) p, and d,, orbital of two atoms form r-bond 4 os : €RO0063 2 Whats the hybridisation state of Cl in cationic part of solid ClO, ? (A) sp" @) or (D) sd CBO006S —— 14 INCORRECT order of bond angle is: (D) NF, > NH, (A) 0, > SF, (B) H,0 > OF ‘ BOOS | 2. 14, Select the CORRECT statement(s) ? (A) Bond angle onder | CH, > CF, (B) Bond length onder = d, (NO, ) SO,’ , (D) Bond angle order : NH, < PH, CBO0066 ue MOLECULE DOES NOT EXIST 18. Which of the following molecules do not exist ? (A) Br. (B) SF, (C) NCI, (D) OF, ( CBO0067 ( 16. Which of the following do not exists ? ( (A) SH, (B) HFO, (©) sicl,* (D) HCIO, ae BOON s 17. Which of the following molecule exist- ¢ (A) SF, (B) IH, (©) SH, (D) PCI, ‘ CBO00? 18, Which of the following molecules does not exist and non-existence reason is same as that of SHy « (A) OF, (B) SH, ©) PBK (D) XeH, a cBoo7? DIPOLE: MOMENT & HYDROGEN BOND z* 19. Which of the following compounds possesses zero dipole moment? @ (A) Water (B) Benzene « (C) Carbon tetrachloride (D) Boron wifluoride W 20. Which of the following statements are correct ¥ (A) The crystal lattice of ice is formed by covalent ay well as hydrogen bonds (B) The density of water increases when heated from 0°C 04°C oe e (C) Above 4° C the thermal agitation of water molecules increases, Therefore, intermolecular a distance increases and water starts expanding G (D) The density of water decreases from 0” Ctoa maximum at 4° C caw? 398 —$S

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