UNITI (24 ME I0)
Med
chemistks
rodlgmenis [Link]
roerisaticn -cHy-Cly
cthete (rolyethee)
of
olassiftcalo of olgmests
toriqin igsyeo
thetic : polgthehe
-inea polgmeg
-Brarchad polyimer
elosslinka polgme
Cogerkotton
Additin polg nerktoion
polgmeriestion, condencahon polynestsofo
twth oct eltmitaibg smu moecae like Hy0,NH
Addition fcimerisotion.
s cated Hi0, NH t
smal moecales 1ike
Cauled
lastomess
Fibres:
Molecuc fortes/
Thertroetic a C,
Rabber
Thamoseting
ostic
E: ekalite
’ Themo platt o Thetmo acf tenirg plastC
7Thatro Tttirg NosiC (a) thr mo fasiceig plastic
Functional ity ot
’The oof functiora Arocs eset in a
is Knoon as
For Exane
functichity.
thestyTere oleCuk form
bifuntional morome'
(HOCO-CHh-CoOt).(Mabni Aid)
(ClCH- CHO (ethyere glycol)
Mono fuctionol monoters
Ctt O).CMettard)
CHy Coo (Aetic acld)
Ti functino monomers
(H-CHyCH{O}-CtoH)
(Giyero)
Totro tfurctional oromeis
cHiOH
Ch o CH, OH
( Fenta eryttol)
furticraity
CH-CH-oH
eroup
Guetiorcl
-OH-CH-ct)-oH
cOOH--Co
fetiora
thratehol
cthylee
compou Melonic
acid acid
Acetic
8ycol
S-No
3.
Plastic&
tdetcdoc ceigtt tohich Cas be mouded
ahy desied form tunder het and erweintofh
FVesence of catalytt oe caukd lastics
NDtererce
(M)
bln Therro phtic ad
Thevro [etirg as.
\:The
Themcpiasts Therroge tting tiate
Nastics ohich e The
Soften on heatina and lastes tohch ae
hoding en coolithq ose harcening on beating
and cahnt he soft b.
Caled Therrnoplacttic
appling teat ard pesi
oR caed Thern0tfirg
1The aoe fommed by Plastic.
cddition polytrerteatio They ae
2
se tormedby
3
plasticits is leverble condensctior poyrerato
4Theyoe sctabe ln oronik plasticits is Ireverkk
ets They eihokable in
cqaic solvents
5 They can beechimed
from the coaste
5 They canrot e
adoni
fronm the ciaste.
6 Thelyote
lireorchapolynen 6. Thes oe d-dinerii onl
CKoS-linked polge
1:They 0se softiecko lest qThey
brrttle ae fasd,ctrong
more ttle
OoTe teld tcqethen b
te Vaderca for ces CoYoet bonds.
q- Eg: vC, polgtthere Eq: Nylon 6 6, arelite
Io8|24
60-&0
cH=CH HC CH)H
HqsCit
ACete lee
nCH CH fcty-tt
vingichlok
pYOpertias:
’ Me (Eirq Poist 48e
’ Ihoable in ergont ctolverts
througt Aete eye t 60-&C" in the prescNe ct
’ It is peposed by the free thdico Aolrerela
bengd petide cor ) Hydroger peroude
prtperties
tetra bylofoon
’Ithas oses hich oten ing pont t48c &
pOstes qveotert iffheds.
Actien
iqid ve (or) unbetiibel Vc
STt &tod tor toa~itg shectC, dafety be l'orts
tyesetc
>Tt is uted for ackitq tal Coots, tohk c
insestr. like &oo\tches, Scoith boordc,
Sorkettt etcd
akelt PRpartion
Bekatte iu Neosei by the condercot icn
polgureriation of thenol fortrald-hyk tnth
Raence of cidic hedin Tt invoves hih,
Shap Fomotion of o-tycioy hety phaa
LHM) tyiog tettyt pherol
ot
4t
pherl fomoldehyde
ott OH.
CHOH cHOH
CH2 Cth
(sbralac]
canbe
te3 Novalac is fcisuhk oich
coNorted {nto
bq [Link] tetaonlor
Rkolite
cH2
Ott
Act
(Rakelte
PYOFerties
ercelat electvcal inSalating
’ They pOses
choacteT
auotea esistane, infetible,
’They coe
Vigid {nsOuble colids
’ They
Yesistant to non ordisibg acid
They asd mary oihes Cahic colverts.
Calts
attacked by alkalis betaute of
’They oJe
+fe. pYeSete Ot-OH gocpS.
Ttey
esins in cate fteig
’ Fer. Nakta electrical inglccter
cots like
Saoitches ,Nug ete
They ase ato (uled for making trcaldod
articlea lke TV, Tebthote
Bio degradabe polgnes etc....
POg Hydtexq becterccte (H8)
MONOTer hydroxy´btorolc aCtd
Wed
CH -CH-CH,-oH
à-hydroy butaoic ccid
PHB Pretoroaic
’Tt s epooted by the fernertotich ot
eheabe rao matetic
CHs-C-CHy -0
>ba the tgdroty bectotok acid ee qt the
strurttre of PHR bu the less of
cacenoecae
CHy
Jh
3-hydrosg tdarc
acid
1t
actirity
poutiaulg cnftaie raterel ath
igh Nelting goltt
It i stiff and britle.
ApNicatiohs
’ n medicite PHB & sed as sorgcal implant
as eam thecds tor the healing of cooands
Sood veslels orttopedic devices.
’In pharmacolagy , PHBi sed as a microcapSule
’ne nonomesT ttee nease in C is tOpol4
tnoTe thon monome s Caaed co-polge
Prepvoction
-tyirory tortarac acid and 3-tgdroy
pentaroc acd
4a-hioxy pertocc acd.
hHaf-gHqt--9+D HÇ-CHy-CH-cH-C-69
3tycoy ktarde acid 3-+tyaroxy etanoc acid
+0-H-cHy--0-CH-CH J
MoRetes thermajatt pogestot
>PHBV is ann- togic , sio Comfactbi lity
>when Cormeoed HA Northo
Has bottex physical olye,PHB
ropesrties
co-i
such as
cEitfnecs, resistaNe, flexbilty
ArplicatiONS:
>It is caed in peciaug packoqing ckrcas,
ortropedc deees ad conttol eleaect det
Ra- otedere CMoromer)
Na
Na- Nalccteist
N Ntile
&-Stgrehe Monoe)
usbtediee Styere
Buna-t
RanaS. doastG ettt oact Ckth dlschem
BuNaN itt cot roact
e tytfetic tuhber .