(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

EXERCISE-I 14. The highest probability of finding the electron in an orbital having values of quantum numbers n =
GENERAL INTRODUCTION
3, l = 1 and m = −1 .
1. Which of the following pairs of the species are isoelectronic as well as isotopic?
(A) In between any two axis out of three
(Atomic number of Ca = 20, Ar = 18, K = 19, Mg = 12, Fe = 26, Na = 11 )
(B) On any two axis simultaneously, perpendicular to each other
40
(A) Ca+2 , 40
Ar (B) 39
K +, 40
K+ (C) 24
Mg 2+ , 25
Mg (D) 23
Na , 24
Na+
(C) On any one axis out of the three at a time
2. Which among the following is an example of pure element?
(D) On all the three axis simultaneously at a time
(A) Steel (B) Air (C) Brass (D) Graphite
15. Find the group of orbitals in which atleast one common nodal plane is present:
3. Identify the set of isoelectronic species:
(A) 2px , 3 dxy , 4 dyz (B) 2py , 3 dxy , 4 dyz
(A) N 3− , O2− , F (B) N, O, F (C) H, H+ , H− (D) H − , Li, Be
(C) 2pz , 3 dxy , 4 dyz (D) 4dx 2 −y 2 , 5dz 2
4. An atom has 8 electron, 10 neutron and 8 protons. Which is the isotope of given atom?
16. The electrons, identified by quantum number n and l :
(A) 9 F 19 (B) 6 C14 (C) 8 F18 (D) None of these
(i) n = 3: l = 0 (ii) n = 5: l = 2 (iii) n = 2: l = 1 (iv) n = 4: l = 3
5. Which of the following set of compound is isoelectronic?
Can be placed in order of increasing energy from the lowest to highest as:
(A) NO+ −
2 &NO2 (B) CO−2 +
3 &NO2 (C) CO2 &NO+
2 (D) HCO− −
3 &HSO4
(A) (iii) < (i) < (iv) < (ii) (B) (i) < (iii) < (iv) < (ii)
6. Which of the following pair is isoster?
(C) (ii) < (iii) < (iv) < (i) (D) (ii) < (iv) < (i) < (iii)
(A) N2 O&H2 O (B) CO2 &H2 O (C) N2 O&CO2 (D) NO&CO
17. Which of the following orbital have nodal plane in yz plane?
7. Which of the following can not be isoelectronic?
(A) pz (B) py (C) dxy (D) dyz
(A) two different cations (B) two different anions
18. Total number of orbitals in a shell are 16, find total no. of orbitals which have m = 0 in that shell.
(C) different cation & anion (D) two different atoms
76 (A) Four (B) Two (C) Eight (D) Six
8. An isotone of 32 Ge is?
79 77 73 19. Assume the set of four quantum no. for last electron of an element X in ground state is n = 4 ,
(A) 34 Se (B) 33 As (C) 31 Ga (D) None of these
l = 1, m = 1& s = −1/2 . and spin multiplicity of element X in its ground state is 4. Identify the
9. Find the total number of exchanges in d configuration:- 7
element X.
(A) 7 (B) 10 (C) 6 (D) 11 (A) Ga (B) Ge (C) As (D) Se
10. Total number of degeneracies in N shell in Li+2 ion are:- 20.
1
If an electron has spin quantum number of + and magnetic quantum number is -1 it cannot be
2
(A) 16 (B) 9 (C) 3 (D) 6 present in
(A) f-orbital (B) d-orbital (C) p-orbital (D) s-orbital
QUANTUM NUMBER
11. Which of the following pair of electron is excluded from an atom 21. Calculate the total number of electron for Mn having n + l + m = 2 .
1 1 (A) 3 (B) 4 (C) 5 (D) 6
(A) n = 2, l = 1, m = +1, s = + & n = 2, l = 1, m = −1, s = −
2 2
1 1
EFFECTIVE NUCLEAR CHARGE (𝐙eff )
(B) n = 2, l = 0, m = 0, s = + & n = 2, l = 0, m = 0, s = + 22. Which of the following has maximum value of Zeff :
2 2
1 1
(C) n = 1, l = 0, m = 0, s = + & n = 1, l = 0, m = 0, s = − (A) F (B) Cl (C) Br (D) All equal
2 2
1 1 23. If Zeff of F(Z = 9) is X and Zeff of Li(Z = 3) is Y then find the value of |X − Y|
(D) n = 3, l = 2, m = −2, s = + & n = 3, l = 0, m = 0, s = +
2 2
(A) 4.90 (B) 3.90 (C) 2.90 (D) 1.90
12. Which one of the following represents an acceptable set of quantum numbers for an electron in an
atom? (arranged as n, l, m/ and ms ) 24. Which of the following element is having same value of Zeff for electrons of 3 d and 4 s orbital.
(A) Sc (B) Cr (C) Co (D) Ni
(A) 5,4, −5,1/2 (B) 1,0,0,1/2 (C) 2,2, −1, −1/2 (D) 3,3,3,1/2
25. If Zeff of N(Z = 7) is X and Zeff of C(Z = 6) is Y then find the value of X + Y
13. Which quantum number determines the energy of an electron in a hydrogen atom?
(A) 4.90 (B) 7.15 (C) 2.90 (D) 1.90
(A) l (B) n (C) n and l both (D) mi
APNI KAKSHA 21 APNI KAKSHA 22
(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

EXERCISE-II
EXERCISE – II
ELECTRONIC CONFIGURATION
GENERAL INTRODUCTION
26. The percentage of orbitals occupied by electron out of total orbitals present upto the outermost shell
35
1. Which among the following are isodiapher with 17 Cl :-
of Fe atom:
39 19 27
(A) 19 K (B) 9 F (C) 13 Al (D) 3 Li7
(A) 50% (B) 70% (C) 25% (D) 35%
2. Which of the following is/are heterogeneous mixture?
27. The total number of unpaired electrons in the element (Z = 24) in its lowest energy states?
(A) Blood (B) Milk (C) Air (D) Tap water
(A) 1 (B) 5 (C) 4 (D) 6
QUANTUM NUMBER
28. Which of the following is violation of (n + l) rule.
3. Which of the following statement (s) is/are correct about the element having atomic No. 24:
(A) (B)
(A) l = 2 is possible for an electron in this atom
(B) Total number of electrons having value of magnetic quantum number |m| = 2 are two.
(C) (D)
(C) Total number of electrons having |m| = 1 are ten.
29. Which electronic configuration represents CORRECT ground state electronic configuration:
(D) n = 4, l = 0, m = 0, s = +1 is impossible set of quantum number for outermost electron.
(A) 1s 2 , 2s1 , 2p6 , 3s1 (B) 1 s 2 , 2 s 2 , 3 s 2 , 3p2
4. Which of the following set(s) of quatum number is/are invalid for any electron in the ground state
(C) (D)
electronic configuration of all the elements upto atomic number 18?
n l m s
30. The electronic configuration of a carbon 1 s 2 , 2 s 2 , 2p2 and consider the following three
(A) 3 2 −1 +1/2
arrangements of the 2p electrons. Which arrangements have lowest energy?
(B) 2 2 +1 −1/2
(A) (B) (C) (D) (C) 4 0 0 +1/2
(D) 4 1 −1 +1/2
31. Which electronic configuration represents a violation of Hund's rule and Pauli's rule both for an 5. All the obitals of a given subshell have the same value of:
atom in its ground state? (A) principle quantum number (n) (B) azimuthal quantum number (l)
(C) magnetic quantum number (m) (D) none of these
(A) (B)
6. For an electron magnetic quantum number = +2. The electron may be present in:
(A) 4 s-orbital (B) 4p-orbital (C) 4 d-orbital (D) 4f-orbital
(C) (D)
7. Which of the set of quantam number is/are not correct for any electron in ground state electronic
32. Number of elements/ions given below which contains only one electron in their outer most shell? configuration of the elements upto atomic no. 30?

Rb+, Sr+2 , H, Cr, Hg+, Mn+2 , P+3 , N +4 n l m s

(A) 4 0 0 +1/2
(A) 1 (B) 2 (C) 5 (D) 4 (B) 3 2 −2 −1/2
33. Select the correct ground state electronic configuration of the element with atomic number 47 is: (C) 3 1 +2 +1/2
(A) [Ar]3d9 4s 2 (B) 1s 2 , 2s2 , 2p6 , 3s2 , 3p6 , 3d10 , 4s2 (D) 4 1 −2 +1/2
8. Which of the following is/are a valid set of four quantum number (n, l, mb , ms ) :-
(C) [Ar] (D) [Kr]4d10 5s1
1 1 1 1
(A) 3,2, −2, + (B) 2,0,0, − (C) 3,3, −1, + (D) 4,3, −3, −
2 2 2 2
1
34. In Mn, the minimum number of electrons having ms = − is –
2
9. Select the INCORRECT statement (s):
(A) 10 (B) 12 (C) 13 (D) 15
(A) In dx 2 −y 2 orbital, 2 nodal planes are in xz and yz plane
35. If Aufbau rule is not followed, K − 19 will be placed in
(B) dxy and pz has one common nodal plane
(A) s-block (B) p-block (C) d-block (D) f-block
(C) m = −2 for 4 d subshell is not possible as n = 4
(D) number of electrons in subshell = 2(2ℓ + 1)
APNI KAKSHA 23 APNI KAKSHA 24
(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

10. Which of the following statement(s) is/are CORRECT? 19. Using the slater's rule, choose the incorrect statements among the following.

(A) Total number of maximum electrons which can have n = 5, s = +1/2 and n = 5, s = −1/2 are (A) Value of σ (shielding constant) for d-electrons of penultimate shell of Sc, Y, La are equal.
same. (B) Zeff for d-electrons of penultimate shell of Sc, Y, La are equal.
(B) In H-like atoms, the shells and subshells of a shell have same energies. (C) Value of σ increases by a factor of 0.3 in the second period from left to right.
(C) The energy order of subshells in only multielectronic atom is decided by (n + l) rule. (D) Value of Zeff increases by a factor of 0.35 in the second period from left to right.
(D) The energy order of subshells in single electron species is decied by (n + l) rule. 20. Select the correct relationship ( Zeff for the last electron):
ELECTRONIC CONFIGURATION (A) Zeff (Na+ ) < Z eff (Mg +2 ) (B) Zeff (He) < Z eff (Be+2 )
11. Total number of vacant orbitals in the valency shell of that atom which have total s electrons and (C) Zeff (Mg) = Z eff (Ca) (D) Zeff (Al+3 ) < Z eff (Na+ )
total p electrons are in same number in its ground state electronic configuration.
(A) Zero (B) Five (C) Four (D) Eight
12. Which of the following subshells are involved for 6 th period elements in periodic table?
(A) 4f (B) 5 d (C) 6 s (D) 5p
13. Which electronic configuration represents an atom in its ground state configuration and having
completed 3rd principle energy level?
(A) 2 − 8 − 6 − 2 (B) 2 − 8 − 10 − 2
(C) 2 − 8 − 18 − 8 − 1 (D) 2 − 8 − 18 − 3

14. Which of the following statement (s) is/are INCORRECT?

(A) Number of electrons having l = (0) is 10 in Pd.
(B) Number of electron in d subshell of Cr and Mn are the same.
(C) Multiplicity of Fe is equal to that of Ni2+
(D) Value of l/n for last electron of element having atomic number 57 is 0.4.
15. Which of the following order of paramagnetism is/are INCORRECT?
(A) Cr > Fe > Ni > Cu (B) Cr > Ni > Fe > Cu
(C) Mg < Al < O < N (D) N < O < Al < Mg

16. Which of the following pair(s) of species is/are having different value of magnetic moment?
(A) Mn2+ &Na+ (B) Co3+ &Fe3+ (C) Zn2+ &Cl (D) Zn2+ &Na+

EFFECTIVE NUCLEAR CHARGE (𝐙𝐞𝐟𝐟 )

17. Effective nuclear charge in As(Z = 33) is 6.30. Which of following is/are correct:
(A) 4 s electron (B) 4p electron (C) 3 d electron (D) Outermost electron

18. Which of the following option is CORRECT ?

Element/ion Zeff Element/ion Zeff
+2
(A) 55 Cs 2.2 (B) 21 Sc 18
(C) 9 F 5.20 (D) 10 Ne 4.15

APNI KAKSHA 25 APNI KAKSHA 26

(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

EXERCISE-III
EXERCISE – III EXERCISE-IV
EXERCISE – IV

Integer Answer Type (0 to 9): PARAGRAPH FOR QUESTION NUMBER 1 TO 2

1. What is the minimum value of n (principal quantum number) is possible for magnetic quantum Three quantum numbers are required to define an orbital while four quantum numbers are required
1 to describe an electron.
number m = −2 and s = + ?
2
1. (n + l) is maximum and minimum for which of the following orbitals: 6 s, 5p, 4 d, 2p, 3 s, 2 s?
2. Find the total number of electron in Cr which have (n × l) = zero.
4 (A) 4 d and 1 s (B) 6 s and 2 s (C) 5p and 3 s (D) 6s and 2p
3. Total number exchange are possible for 3 d electronic configuration.
2. Which of the following statement is correct for H atom?
4. Find the total number of orbital(s) in iron having |m| < 1 and atleast one electron is present in
(A) H atom can be placed both in group 1 and group 18.
orbital.
(B) H atom can be placed both in Group 1 and Group 17.
5. Find the sum of total numbers of 5f-electrons in Th and Ac.
(C) H atom produces smallest anion in reality.
6. Total number of electrons in Zn (atomic number = 30 ) for which n + l + m = 0
(D) 2 s, 2p, 3 s orbitals are not available in H atom
7. Find the number of electron having (n × l + m) = 3 for Kr atom (Atomic number = 36)
PARAGRAPH FOR QUESTION NUMBER 3 TO 4
8. The Zeff on the last electron of Zr 3+ ion is
Repulsion force by innershell electrons on outer most shell electrons is called shielding effect. Due
9. In the following species, the number of them having same magnetic moment value is
to shielding effect valence shell electron experiences less force of attraction by nucleus. (i.e. total
__________ Fe3+ , Co3+ , Ni2+ , Mn3+ , Cu+, Zn2+ , Cd2+ , Cu2+ , Ag+
attraction force experienced by valence electron is called effective nuclear charge) Zeff. = Z − σ
10. An element ′ X ' has its electronic configuration of ' K ' shell is (n − 5)s 2 and it has total number of
Where : Zeff. = effective nuclear charge Z = atomic number
electrons in its outermost, penultimate and antipenultimate shell are 2, 8 and 25 respectively, then
σ = shielding constant
find out total number of unpaired electrons in element ' X ' in their ground state.
3. Select the correct effective nuclear charge on outermost electron in C.
11. Find the total number of orbitals in which electron density is not observed along any axis
(A) 2.75 (B) 2.40 (C) 3.25 (D) 0.85
(x, y or z). PX , Py , Pz , dyz , dxz , dx 2 −y 2 , d2z , dxy
1
4. Calculate the screening constant for 4 s electron of Zn ?
12. Find the maximum number of electrons in Cr atom which have m = −1 and s = + but n ≠ 2 .
2 (A) 4.6 (B) 21.5 (C) 25.65 (D) 5.6
13. Find minimum possible values of missing digits (X, Y, Z) in following set of quantum numbers and
PARAGRAPH FOR QUESTION NUMBER 5 TO 6
calculate sum of X, Y and Z.
Many elements and compounds exhibit magnetic property because of presence of unpaired
n l | m| s
1 electrons.
Set (I) = 5 2 X −
2
1 5. Which of the following species is diamagnetic in nature?
Set (II) = Y 3 0 +
2
1 (A) Fe2+ (B) Zn2+ (C) Fe3+ (D) Co3+
Set (III) = 3 Z 1 −
2
6. Which species has the same spin multiplicity as that of Mn2+ ?
14. Number of unpaired electrons in Mn+7 = a
(A) Cr + (B) Fe3+ (C) Co4+ (D) All of these
Number of d-subshell electrons in Cr = b
Number of f-subshell electron in Hf (Atomic number = 72) = c PARAGRAPH FOR QUESTION NUMBER 7 TO 8
Find the value of c − b + a ? In a hypothetical system all the known concept of shell, subshell, orbitals etc. exist in the same way
15. How many subshells are possible in N-shell? as in our system except that the (n + l) rule is modified to (n − l) rule for deciding the subshell
16. Find the number of exchanges of electrons associated to l = 2 in nickel. energy. In case of equal value of (n − l), the higher value of ' n ' gives the higher energy.
7. In this hypothetical system S(Z = 16) will be a
[Write your answer as sum of digits till you get the single digit answer]
x (A) p-block element
17. The spin only magnetic moment of Mn+2 is √x B.M. .The value ( ) of
7
(B) s-block element
18. Find the number of sets of isosters
(C) d-block element
(N2 , CO), (N2 O, CO2 ), (HF, OH− ), (B3 N3 H6 , C6 H6 )
(D) f-block element
APNI KAKSHA 27 APNI KAKSHA 28
 (CHEMISTRY) GENERAL CHEMISTRY
(CHEMISTRY) GENERAL CHEMISTRY
JEE –Main
EXERCISE JEE-MAIN
1. The electrons identified by quantum numbers n and ℓ :-
8. For n ≤ 3 ; the subshell having maximum energy for the above hypothetical system will be:
[JEE-1999, JEE-MAIN, (ONLINE)-2012]
(A) 2 s (B) 3 d (C) 3p (D) 3 s
MATRIX MATCH TYPE (a) n = 4, ℓ = 1 (b) n = 4, ℓ = 0 (c) n = 3, ℓ = 2 (d) n = 3, ℓ = 1
9. Column I Column II Can be placed in order of increasing energy as
(A) 2(2l + 1) (P) number of orbitals in subshell. (A) (a) < (c) < (b) < (d) (B) (c) < (d) < (b) < (a)
(B) n 2 (Q) value of shell in an atom (C) (d) < (b) < (c) < (a) (D) (b) < (d) < (a) < (c)
(C) n (R) number of electron in subshell. 2. Which of the following paramagnetic ions would exhibit a magnetic moment (spin only) of the
order of 5 B.M.? [JEE-MAIN, (ONLINE)-2012]
(D) (2l + 1) (S) number of orbitals in shell
(T) number subshell in shell. (At. No: Mn = 25, Cr = 24, V = 23, Ti = 22 )
10. Column I Column II (A) V 2+ (B) Ti2+ (C) Mn2+ (D) Cr 2+
37
(A) Isobars (P) 17 Cl & 21 Sc 45 3. In an atom how many orbital (s) will have the quantum numbers; n = 3, l = 2 and ml = +2 ?
(B) Isoelectronics (Q) 40 40 [JEE-MAIN, (ONLINE)-2013]
18 Ar & 20 Ca
(C) Isodiaphers (R) 24 23
12 Mg & 11 Na (A) 1 (B) 5 (C) 3 (D) 7
(D) Isotones (S) SiO−4 −2
4 & SO 4 4. The numbers of protons, electrons and neutrons in a molecule of heavy water are respectively
11. Column I Column II [JEE-MAIN, (ONLINE)-2013]
(Elements) (𝐙𝐞𝐟𝐟 experienced by outer most electron)
(A) 10,10,10 (B) 8,10,11 (C) 10,11,10 (D) 11,10,10
(A) C (P) 5.85
5. Given
(B) O (Q) 2.2 (A) n = 5, ml = +1 (B) n = 2, l = 1, ml = −1, ms = −l/2
(C) Na (R) 3.25 The maximum number of electron(s) in an atom that can have the quantum numbers as given in (A)
(D) Ne (S) 4.55 and (B) are respectively: [JEE-MAIN, (ONLINE)-2013]
(A) 8 and 1 (B) 25 and 1 (C) 2 and 4 (D) 4 and 1
6. The correct set of four quantum numbers for the valence electrons of rubidium atom (Z = 37) is:
[JEE-MAIN, (ONLINE)-2014]
1 1 1 1
(A) 5,1,1 + (B) 5,0,1 + (C) 5,0,0 + (D) 5,1,0 +
2 2 2 2

7. If the principal quantum number n = 6 , the correct sequence of filling of electrons will be:-
[JEE-MAIN, (ONLINE)-2015]
(A) ns → (n − 1)d → (n − 2)f → np (B) ns → np → (n − 1)d → (n − 2)f
(C) ns → (n − 2)f → (n − 1)d → np (D) ns → (n − 2)f → np → (n − 1)d

8. The total number of orbitals associated with the principal quantum number 5 is:
[JEE-MAIN, (ONLINE)-2016]
(A) 25 (B) 5 (C) 20 (D) 10
9. The 71st electron of an element X with an atomic number of 71 enters into the orbital:
[JEE-MAIN, (ONLINE)-2019]
(A) 6p (B) 6 s (C) 5 d (D) 4f
10. The value of magnetic quantum number of the outermost electron of Zn+ion is _________ .
[JEE-MAIN – 2021]
APNI KAKSHA 29 APNI KAKSHA 30
 (CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

23. Consider the following set of quantum numbers [JEE-MAIN – 2022]

11. Ge(Z = 32) in its ground state electronic configuration has x completely filled orbitals with m𝑙 =
n 1 m1
0. The value of x is _______ . [JEE-MAIN – 2021]
+ (A) 3 3 -3
12. The Azimuthal quantum number for the valence electrons of Ga ion is ____ . [JEE-MAIN – 2021]
(B) 3 2 -2
(Atomic number of Ga =31)
(C) 2 1 +1
13. Which one of the following species doesn't have a magnetic moment of 1.73BM, (spin only value)?
(D) 2 2 +2
[JEE-MAIN – 2021]
The number of correct sets of quantum numbers is ________ .
(A) O+
2 (B) CuI (C) [Cu(NH3 )4 ]Cl2 (D) O−
2
3+ 2+ 3+ 24. Consider the following statements : [JEE-MAIN – 2022]
14. The spin only magnetic moments (in BM ) for free Ti , V and Sc ions respectively are (At. No.
(A) The principal quantum number ' n ' is a positive integer with values of ' n ' = 1,2,3, ….
Sc : 21, Ti: 22, V: 23) [JEE-MAIN – 2021]
(B) The azimuthal quantum number ' l ' for a given ' n ' (principal quantum number) can have
(A) 3.87,1.73,0 (B) 1.73,3.87,0 (C) 1.73,0,3.87 (D) 0,3.87,1.73
values as ′ l′ = 0,1,2, … . n
15. The number of orbitals with n = 5, m1 = +2 is ________ . [JEE-MAIN – 2021]
(C) Magnetic orbital quantum number ' ml ' for a particular ' l ' (azimuthal quantum number) has
(Round off to the Nearest Integer).
(2l + 1) values.
16. What is the spin-only magnetic moment value (BM) of a divalent metal ion with atomic number 25,
(D) ±1/2 are the two possible orientations of electron spin.
in it's aqueous solution? [JEE-MAIN – 2021]
(E) For l = 5 , there will be a total of 9 orbital.
(A) 5.92 (B) 5 (C) zero (D) 5.26
Which of the above statements are correct?
17. A certain orbital has n = 4 and mL = −3. The number of radial nodes in this orbital is (Round off
(A) (A), (B) and (C) (B) (A), (C), (D) and (E)
to the Nearest Integer). [JEE-MAIN – 2021]
(C) (A), (C) and (D) (D) (A), (B), (C) and (D)
18. In the ground state of atomic Fe(Z = 26) , the spin-only magnetic moment is × 10−1 BM. (Round off
to the Nearest Integer). [JEE-MAIN – 2021] 25. Which of the following statements are correct? [JEE-MAIN – 2022]
[Given : √3 = 1.73, √2 = 1.41] 5 1
(A) The electronic configuration of Cr is [Ar]3d 4𝑠
19. A certain orbital has no angular nodes and two radial nodes. The orbital is: [JEE-MAIN – 2021] (B) The magnetic quantum number may have a negative value.
(A) 2 s (B) 3 s (C) 3p (D) 2p (C) In the ground state of an atom, the orbitals are filled in order of their increasing energies.

20. Consider the following pairs of electrons [JEE-MAIN – 2022] (D) The total number of nodes are given by 𝑛 − 2.
1 1 Choose the most appropriate answer from the options given below :
(A) (a) n = 3,1 = 1, ml = 1, ms = + (b) n = 3, l = 2, m1 = 1, ms = +
2 2
1 1
(A) (A), (C) and (D) only (B) (A) and (B) only
(B) (a) n = 3,1 = 2, m1 = −2, ms = − (b) n = 3, l = 2, m1 = −1, ms = −
2 2 (C) (A) and (C) only (D) (A), (B) and (C) only
1 1
(C) (a) n = 4,1 = 2, m1 = 2, ms = + (b) n = 3, l = 2, m1 = 2, ms = + 26. Which of the following sets of quantum numbers is not allowed ? [JEE-MAIN – 2022]
2 2
The pairs of electron present in degenerate orbitals is/are: 1 1
(A) n = 3, l = 2, m1 = 0, s = + (B) n = 3, l = 2, m1 = −2, s = +
2 2
(A) Only A (B) Only B (C) Only C (D) (B) and (C) 1 1
(C) n = 3, l = 3, m1 = −3, s = − (D) n = 3, l = 0, m1 = 0, s = −
2 2
21. The pair, in which ions are isoelectronic with Al3+ is :- [JEE-MAIN – 2022]
(A) Br − and Be2+ (B) Cl− and Li+ 27. The correct decreasing order of energy, for the orbitals having, following set of quantum numbers:
2− + 2− 2+ (A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0 [JEE-MAIN – 2022]
(C) S and K (D) O and Mg
(C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1
22. The number of radial and angular nodes in 4 d orbital are. respectively [JEE-MAIN – 2022]
(A) (D) > (B) > (C) > (A) (B) (B) > (D) > (C) > (A)
(A) 1 and 2 (B) 3 and 2 (C) 1 and 0 (D) 2 and 1
(C) (C) > (B) > (D) > (A) (D) (B) > (C) > (D) > (A)

APNI KAKSHA 31 APNI KAKSHA 32

(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY
28. The number of subshells associated with n = 4 and m = - 2 quantum numbers is JEE-ADV
EXERCISE – JEE-ADVANCE
[JEE-MAIN – 2020] 1. The electronic configuration of an element is 1s 2 2s 2 2p6 3s 2 3p6 3d5 4s1 . This represents its:
(A) 2 (B) 8 (C) 4 (D) 16 [JEE- 2000]
29. Consider the hypothetical situation where the azimuthal quantum number, I, takes value 0,1, 2, …n (A) excited state (B) ground state
+ 1, where n is the principal quantum number. Then, the element with atomic number (C) cationic form (D) none
[JEE-MAIN – 2020] 2. The maximum number of electrons that can have principal quantum number, n = 3 , and spin
(A) 9 is the first alkali metal (B) 6 has a 2 p-valence subshell quantum number, ms = −1/2 , is [JEE- 2011]
(C) 8 is the first noble gas (D) 13 has a half-filled valence subshell 1
3. In an atom, the total number of electrons having quantum numbers n = 4, | mℓ | = 1 and ms = −
2
30. In the sixth period, the orbitals that are filled are [JEE-MAIN – 2020]
is: [JEE Advanced- 2014]
(A) 6s, 4f, 5d, 6p (B) 6s, 5d, 5f, 6p
4. Not considering the electronic spin the degeneracy of the second excited state (n = 3) of H-atom is
(C) 6s, 6p, 6d, 6f (D) 6s, 5f, 6d, 6p
9, what will be the degeneracy of the second excited state of H − is [JEE Advanced- 2015]
1
31. The number of oribtals associated with quantum number n = 5, m s = + [JEE-MAIN – 2020]
2

(A) 25 (B) 30 (C) 50 (D) 35

32. The number of s-electrons present in an ion with 55 protons in its unipositive state is ___________ .
[JEE-MAIN – 2023]
(A) 8 (B) 9 (C) 12 (D) 10
33. How many of the following metal ions have similar value of spin only magnetic moment in gaseous
state? [JEE-MAIN – 2023]
(Given: Atomic number : V, 23; Cr, 24; Fe, 26; Ni, 28)
V 3+ ⋅ Cr 3+ , Fe2+ , Ni3+
34. Maximum number of electrons that can be accommodated in shell with n = 4 are:
[JEE-MAIN – 2023]
(A) 16 (B) 32 (C) 50 (D) 72
35. Arrange the following orbitals in decreasing order of energy? [JEE-MAIN – 2023]
(A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0
(C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1
The correct option for the order is : [JEE-MAIN – 2023]
(A) B > D > C > A (B) D > B > C > A
(C) A > C > B > D (D) D > B > A > C
36. Which one of the following sets of ions represents a collection of isoelectronic species?
(Given : Atomic Number : F: 9, Cl: 17, Na = 11, Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21 )
[JEE-MAIN – 2023]
+ + 2+ 2+ 2+ 2+ 2+
(A) Li , Na , Mg , Ca (B) Ba , Sr , K+, Ca
(C) N 3− , O2− , F−, S2− (D) K + , Cl− , Ca2+ , Sc3+

APNI KAKSHA 33 APNI KAKSHA 34

(CHEMISTRY) GENERAL CHEMISTRY (CHEMISTRY) GENERAL CHEMISTRY

Answer key
ANSWER KEY EXERCISE # JEE-MAIN
1. (C) 2. (C) 3. (A) 4. (A) 5. (A) 6. (C) 7. (C)
DO YOUR SELF – 1
8. (A) 9. (C) 10. (0) 11. (7) 12. (0) 13. (B) 14. (B)
1. (C) 2. (A) 3. (C) 4. (D) 5. (B)
15. (3) 16. (A) 17. (0) 18. (49) 19. (B) 20. (B) 21. (D)
DO YOUR SELF – 2
22. (A) 23. (B) 24. (C) 25. (D) 26. (C) 27. (A) 28. (B)
1. (B) 2. (A) 3. (A) 4. (D) 5. (D) 6. (A) 7. (A)
29. (D) 30. (A) 31. (A) 32. (D) 33. (2) 34. (B) 35. (B)
DO YOUR SELF – 3
36. (D)
1. (A) 2. (B) 3. (B) 4. (D) 5. (B) 6. (C) 7. (B)
EXERCISE # JEE-ADVANCE
DO YOUR SELF – 4
1. (BC) 2. (9) 3. (6) 4. (3)
1. (D) 2. (A) 3. (A) 4. (B) 5. (B)
EXERCISE–I
1. (B) 2. (D) 3. (A) 4. (D) 5. (C) 6. (C) 7. (D)
8. (B) 9. (D) 10. (A) 11. (B) 12. (B) 13. (B) 14. (C)
15. (B) 16. (A) 17. (C) 18. (A) 19. (C) 20. (D) 21. (B)
22. (C) 23. (B) 24. (A) 25. (B) 26. (A) 27. (D) 28. (B)
29. (D) 30. (C) 31. (B) 32. (D) 33. (D) 34. (A) 35. (C)
EXERCISE–II
1. (ABCD) 2. (ABD) 3. (ABCD) 4. (AB) 5. (AB)
6. (CD) 7. (CD) 8. (ABD) 9. (ABC) 10. (AC) 11. (AD)
12. (ABC) 13. (CD) 14. (AC) 15. (BD) 16. (ABC) 17. (ABC) 18. (AC)
19. (ACD) 20. (ABC)
EXERCISE–III
1. (3) 2. (7) 3. (6) 4. (7) 5. (0) 6. (0) 7. (6)
8. (4) 9. (4) 10. (7) 11. (3) 12. (2) 13. (4) 14. (9)
15. (4) 16. (4) 17. (5) 18. (4)
EXERCISE–IV
1. (B) 2. (B) 3. (C) 4. (C) 5. (B) 6. (D) 7. (C)
8. (D)
9. (A) → 𝐑; (B) → 𝐒; (C) → 𝐐, 𝐓; (D) → 𝐏
10. (A) → Q; (B) → 𝐒; (C) → 𝐏; (D) → 𝐑;
11. (A) → 𝐑; (B) → 𝐒; (C) → 𝐐; (D) → 𝐏

APNI KAKSHA 35 APNI KAKSHA 36