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epsession. Ay freeain Pofint
The terperedore al Which. Vapour pressore o the
colt Comes quad -to Lhe get is
alled. ad. The Preeging Point,
VP T
“Desimentall - th ts hound thet epresston.
in i ean Pala rs
dlsictly Pr Postional te the 0 Daolalltty
Th -The Ate
SAE xm [ATE = ke xm|
Ke = Molal cleperisston Constant ™= Molaltty,
eeler ae Pragieg temp ieien
Tp = Hreeging temp 4] Solution.\y = (VXM
Q } 1g ol
mol U
se
le latend Heat, Me tah
Glocce is dissoived My 1 Kg i( Gen
OK wsay,
d
dind &: Pof the Son
U
AT6 = KgxM
[Link]]
OT6- G.o8rk.
Té = (004273 - 333,
T+ 0.082,
Ata - Te- 75
G.0s2 = T% - 323
©. 682 + 333-7%
6-428 « T%. Lng
£& Tf boy. 4 mass, Qa Sol
Ufc blaine ind
in “shod Point 7
ATé. « Ak box 4
Ao.s2 x ily
ution. 4 brea.
- thell elevate.
the Solution
© Hoos
O52 ¥ Jog 25
Me
At. 13.r |
Greaphteal te presentatton, Pra . fe
zor
Ne,
Vapor
Pressore.
Xn > fracfon™ |
aro: oaolefrect(o ee
Laltigatce Prope sy
Relative ae ap tapaor Pressure.
Dating -o} Non=\olatile. Solute into \elottte, Solvent
bet beef I a] ae rn
rE 9 Tnihiall nity dhe wo toed 4 hin ihe vesceS fe (Solver
wine’ _LXe6 dy Vapoox_/ pressure Pa. ony =
\when a Non 1 pe Volatile _ Solute eB fg is_dlissalved. in thy
\tolatile _Selwent Au Sere of oh Molecules. of B
Gcquine,_ the positron . at Se of
odin due, to etch eer 4f atthe Safer
non- “realatiie, Solu
Co peabbes. as Bis.
“tec fore ft cdl exvest no pressere. at the. Sua
but’ the molecules. of A tot (ontinve. to
Pret the pressure. 0. Henre Vapour Pressuxe. ht
the. Solution Stat? att be Lees. Compared
b the pressure {w the. pore State,
k |oo
ip> a Xa
tye itn Ce]
fae Pp ~ PRY * PR - Py Xp ~
=Pa apa = fh vg
Pap Pa = Xp
Pe, :
Elevatfon. tn sing pot nt fits]
Bot i Point = The temp ak which the ling
—pressuxe an Se6stance
7 _ toy. _becambas. ny St
a —Cr#onea atm. presence
Called sri point
‘ Mapex —
Pressure,
a “Temperate OT pute
When @ pon=\olatile. Slut? Ts cligsalved an
Sod" then the ecppouY _pkessure cleeseares. hente.
Wn _oxdey te attaty the artmas rhe rf _yDoessur?-
Gx boiling Pt higher tenn ts eq C733 fr.
sader_4to 6074 the puxe Solvent Usser femp i
Seq... This oli\) 6fus the. Atco _tennja_ig — —
the BR levation in Sotliing __ point. ‘fe Sim eke
ATAU = Te
Rapetiventoly 74 was fetne, aberved tha Plevation
in ening Pt fs dived’ proportianal ta the.
molarit
vo ATR xm
ATR = kor
K+ Molar Elevotion Conct. / €bushiaceasaFe
Constant.
ont t Wg .
Kelvin = Kd mol
KS
Ké= kelytn Kg
mol
Ko kamor!
Wher ome Mote of Selure fe mined. fr kq of Salurng
the €levadion. ta Y Rotting petit net isl Caled
os Kb Cmolay elevator Con tem.
Kew Ry [7e Je
1OC0 K Ae evap
Re has fonct
T= Billing temp g Solvent Tic]
Ms Molarit race Of Solvent
Ars enthalpy 9 fapouri'sati an.Which \npouy pressure {g veduced.
Rxticd Pecsure due to prtoein 4 odifleent
Types of sobstance. ( :
dh Volatile Solvent ust a volattle Solote.
According to Rautt's (aus the. pasttal presore.
eeexted. by ary ee is diveetly.
Mol
nl Fos gt
Pa of XA
Pas Pa LWA
pa- PPB Ve
P= Pa Pe
sy Pa nnd rs x8.
| af Ty a Container foo moles of Is eal
with, — three mo led B tf _ Absaste-
preseore- Based dve wo KE ff B ave
ysorm™ 6
Ka Find.
lgoram
te anddual sobetanee at this . -mofneng 8
idl ar the Absolote pressuy, a
6),
Calle
clenoted q ced.
Ine Substance f% pure the
Note -. 4 @ a
Pressure TS Said to be Mapex
Pressure At pore Serge
Faaticl Preswetm .
the. Pressuie ‘eoceate say _Spect te
Qos: | Moree
tt hein:
i otal. Page teadse koe Ages
‘on which =Vawouy reat se beg
ohgkd doesn cot depend on the.:Shape’ eb ‘eifatinn
oh. Bt od epetd_on the nature Gf. ional
ahs Pressure —frveysty [od to the
aries Ottsaction. (ehween the motéculet,
ra _ \lapovy Psene vt
Jovce 6 “Ghvottion.
feted! the moleci}eh
-Puo.< Petyon. el od
v1! Because’ of Qntey Molece —
Cayse’ \
soil Oe. Me abcd et: if
I \lapoby Preceure,
I
Golution -
dt isq home: pie mixtore. | DQ as more
Soéstance wihtch: loose tt thet tdent
anducan. not. bes eee Physteat
means. ‘ Ghevety 3¢ t id
Tem peratore Andependen
Te mpesatove Depend ent =
1M \atefg bn [votiene- 7 fe rn wash wrefginct |ssretght
ab \tolume [volume forty at er Molaktty, e
al, molastty. ab ema mote fraction
\lq ba Pressure.
“The poasore cated Ave to the _Vapoors, fx.
Calle ax the. Joa pour Preseor'e.
TL " 2
The cpmoment: ait cobich® wate'o evaporation
vbocdrneas equal tothe vate ~—9 Condition.
the Va po ov pressure mease~ ed ontme 20- =\ 0.0,
‘gu
aan
\tel_ af Sol =\ loog,
(
denstiy <“ Maas hol = 1.202 = Loo
J Vol,
\rolume = loo mol = 83,7,
Maas“ of X= [Prase of Nurmi
H ‘Mass 4 total pixtore-Mase of total pfoctoxe. = 224107 = Va
Mess 7, of Serene = ye Kloot = 16.997
Tay
Mass 7% 9] (hy - SADR yoo “= Yar.
sf
,
ona
let Mags 1 Sol” be loogmn,
Tass "tof ey oa = Boqm
Pass ope
pSet | Rengenee Bo s0.89.
Molet of ely = » ost mae,
se
Moles fraction, (Bengeta 20.39 AOE
“7O.Z9TOUS
tagh
= Mass of Selute, 1 x foo0 A
CR gol”
a msl = ;
s molecvlar mags.” ”
= BO y lowe = Os024M,
2a 4308 ,myry = Mave
we} feet Rod) = Lia) [S061
ey My 60.03")
‘ ‘
molarity. | Hy Soy = 0.03,
seta
6.25 Mole 4 . Ged Present iw Xa of r
Moles +f Uxea= 6.28 Mole.
Macs Solvent = ) Ka. = looeg
Meloy ORS = bo Sel. y
0-25 Mole of Urea =0.28¥ fy mol = 164
“Total. mase of S049 = oot ISq, = Is
= 1.0 =
| 015 i f Sol" Contain. Urea.
I66) 5 2.8g, Sol” yaty “Yequtve u
=y is gy 9, =
wt iat > ee ag. Aua
faleotate the
Molatt of
acta Cetigtoony la ty! 1 Qe ot nor ©
Ren gene.
A
Molay masa of Coty 21D Xd 41x4 ise
maebes CyHyO, =2+Sy
beqmot”
mass of Gengene. 1a Kg.2 8g /tabog Ke”
= 78 ae .
Lc _™Mo lal. ie Can Ct
< 0.04 17 mods!
Golestate- Co. mola? oe esgirt _€I me a
feacrton. en a the — = do nox
[Pras / mas) aque lug Ke ts Lo 79 rat
+ Toemutle, —-y d= Mass. -
met solute
Yotome \l Solvation. Ce}
molality se Deo te ML RL.
MBolvent 6 KATH.