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10. Identify the products obtained when direct nitration of aniline is carried out,
a) Only p-Nitroanitine
b) Only o-Nitranniline
¢}.A mixture of ortho and para nitroaniline
4) A mixture of ortho, meta and para nitrosniline
Read the given passage and answer the questions that folkiw:
Amines constitute an important class of organic compounds derived by replacing one
‘or more hydrogen atoms of ammonia molecule by alkyliaryl groups, Arines are usually
formed from nitro compounds, halides, amides, ete. They exhibit hydrogen bonding
which influences their physical properties. Alkyl amines are found to be stronger bases
than ammonia, In aromatic amines, electron releasing and withdrawing groups,
respectively increase and decrease their basie character. Reactions of amines are
governed fy availability of the unshared pair of electrons on nitrogen. Influence of the
number of hydrogen atoms at nitregen atom on the type of reactions and nature of
products is responsible for identification and distinction between primary, secondary
cand tertiary amines. Reactivity of aromatic amines enn be controlled by acylation
process.
11. Why does aniline not give Friedel-Crafts reaction?
12, Arrange the following in the increasing order of their pK values in aqueous
phase;
CoHSNHz, NH5, (CHsNEs, (CHskN
13, How ean you distinguish between CHsCH3NHz and (CH;CH:)NH by
Hinsberg’s test? 14, Assertion: Reaction with iron scrap and hydrochloric acid is preferred for the
reduction of Nitrobesrene to Aniline.
Reason: Only a small amount of HCI is required to initiate the reaction as
FeCl: formed gets hydrolysed tor release hydrochloric acid during the
reaction.
a) Both assertion and reason are correct statements, and reason is the correct
explanation of the assertion
b) Both assertion and reson are correct statements, but reason is not the correct
explanation of the assertion.
¢) Assertion is correct, but reason is wrong statement,
a) Assertion is wrong, but reason is correct stiternent,
15, Assertion: Butnn-I-amine is more soluble in water than Butan--ol,
Reason: Alcobols are more polar than amines and form stronger intermolecular
hydrogen bonds than amines.
a) Both assertion and reason are correct statements, and reason is the correct
explanation of the assertion.
b) Both assertion and reason are correct statements, but reason is not the comect
explanation of the assertion.
¢) Assertion is correct, but reason is wrong statement,
.d) Assertion is wrong, but reason is correct statement.
16, Assertion: In aqueous phase, secondary amines are more basic than primary amines.
Reason: Alkyl group is electron donating.
a) Both assertion and reason are correct statements, and reason is the correct
explanation of the assertion.
b) Both assertion and reason are: correct statements, but reason is not the correct
explanation of the assertion,
c) Assertion is correct, but renson is wrong statement,
«d) Assertion is. wrong, but reason is correct statement,