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Rubber Processing and Molding Overview

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72 views16 pages

Rubber Processing and Molding Overview

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timanorov039
Copyright
© All Rights Reserved
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Presentation on theme: "Lecture # 3 RUBBER PROCESSING

TECHNOLOGY"— Presentation transcript:


1 Lecture # 3 RUBBER PROCESSING TECHNOLOGY
Rubber Processing and ShapingManufacture of Tires and Other Rubber ProductsProduct Design
Considerations

2 Overview of Rubber Processing


Many of the production methods used for plastics are also applicable to rubbersHowever, rubber
processing technology is different in certain respects, and the rubber industry is largely separate
from the plastics industryThe rubber industry and goods made of rubber are dominated by one
product: tiresTires are used in large numbers on automobiles, trucks, aircraft, and bicycles

3 Two Basic Steps in Rubber Goods Production


Production of the rubber itselfNatural rubber (NR) is an agricultural cropSynthetic rubbers is based
on petroleumProcessing into finished goods:CompoundingMixingShapingVulcanizing

4 The Rubber IndustriesProduction of raw NR is an agricultural industry because latex, the starting
ingredient, is grown on plantations in tropical climatesBy contrast, synthetic rubbers are produced by
the petrochemical industryFinally, processing into tires and other products occurs at processor
(fabricator) plants, commonly known as the rubber industry

5 Production of Natural Rubber


Natural rubber is tapped from rubber trees (Hevea brasiliensis) as latexIn Southeast Asia and other
parts of the worldLatex is a colloidal dispersion of solid particles of the polymer polyisoprene in
waterPolyisoprene (C5H8)n is the chemical substance that comprises NR, and its content in the
emulsion is about 30%

6 Recovering the RubberPreferred method to recover rubber from latex involves coagulation -
adding an acid such as formic acid (HCOOH)Coagulation takes about 12 hoursThe coagulum, now
soft solid slabs, is then squeezed through rolls which drive out most of the water and reduce
thickness to about 3 mm (1/8 in)The sheets are then draped over wooden frames and dried in
smokehouses for several days

7 Grades of Natural Rubber


The resulting rubber, now in a form called ribbed smoked sheet, is folded into large bales for
shipment to the processorIn some cases, the sheets are dried in hot air rather than smokehouses,
and the term air-dried sheet is usedThis is considered a better grade of rubberA still better grade,
called pale crepe rubber, involves two coagulation steps, followed by warm air drying

8 Synthetic RubberMost synthetic rubbers are produced from petroleum by the same polymerization
techniques used to synthesize other polymersUnlike thermoplastic and thermosetting polymers,
which are normally supplied to the fabricator as pellets or liquid resins, synthetic rubbers are
supplied to rubber processors in the form of large balesThe rubber industry has a long tradition of
handling NR in these unit loads

9 CompoundingRubber is always compounded with additivesCompounding adds chemicals for


vulcanization, such as sulfurAdditives include fillers that either enhance the rubber's mechanical
properties (reinforcing fillers) or extend the rubber to reduce cost (non-reinforcing fillers)It is through
compounding that the specific rubber is designed to satisfy a given application in terms of properties,
cost, and processability

10 Carbon Black in RubberThe single most important reinforcing filler in rubber is carbon black, a
colloidal form of carbon obtained by thermal decomposition of hydrocarbons (soot)It increases
tensile strength and resistance to abrasion and tearing of the final rubber productCarbon black also
provides protection from ultraviolet radiationMost rubber parts are black in color because of their
carbon black content

11 Other Fillers and Additives in Rubber


China clays - hydrous aluminum silicates (Al2Si2O5(OH)4) reinforce less than carbon black but are
used when the color black is not acceptableOther polymers, such as styrene, PVC, and
phenolicsRecycled rubber added in some rubber products, but usually 10% or lessAntioxidants;
fatigue- and ozone-protective chemicals; coloring pigments; plasticizers and softening oils; blowing
agents in the production of foamed rubber; mold release compounds

12 MixingThe additives must be thoroughly mixed with the base rubber to achieve uniform
dispersion of ingredientsUncured rubbers have high viscosity so mechanical working of the rubber
can increase its temperature up to 150C (300F)If vulcanizing agents were present from the start of
mixing, premature vulcanization would result - the “rubber processor's nightmare”

13 Mixers in Rubber Processing


(a) Two-roll mill and (b) Banbury-type internal mixer

14 Two-Stage MixingTo avoid premature vulcanization, a two-stage mixing process is usually


employedStage 1 - carbon black and other non-vulcanizing additives are combined with the raw
rubberThis stage 1 mixture is called the master batchStage 2 - after stage 1 mixing is completed,
and cooling time has been allowed, stage 2 mixing is carried out in which vulcanizing agents are
added

15 Filament Reinforcement in Rubber


Many products require filament reinforcement to reduce extensibility but retain the other desirable
propertiesExamples: tires, conveyor beltsFilaments include cellulose, nylon, and
polyesterFiber-glass and steel are also used (e.g., steel-belted radial tires)Continuous fiber materials
must be added during shaping; they are not mixed like the other additives

16 Shaping and Related Processes for Rubber Products


Four basic categories of shaping processes:ExtrusionCalenderingCoatingMolding and castingSome
products require several basic processes plus assembly work (e.g., tires)

17 Extrusion Screw extruders are generally used


The L/D ratio of the extruder barrel is less than for thermoplasticsTypical range 10 to 15Reduces risk
of premature cross-linkingDie swell occurs in rubber extrudatesThe highly plastic polymer exhibits
“memory”The rubber has not yet been vulcanized

18 CalenderingRubber stock is passed through a series of gaps of decreasing size by a stand of


rotating rollsRubber sheet thickness is slightly greater than final roll gap due to die swell

19 Roller Die ProcessCombination of extrusion and calendering that results in better quality product
than either extrusion or calendering alone

20 Coating or Impregnating Fabrics with Rubber


Important industrial process for producing tires, conveyor belts, inflatable rafts, and waterproof cloth

21 Molded Rubber Products


Molded rubber products include shoe soles and heals, gaskets and seals, suction cups, and bottle
stopsAlso, many foamed rubber parts are produced by moldingIn addition, molding is an important
process in tire production
22 Molding Processes for Rubber
Principal molding processes for rubber areCompression moldingTransfer moldingInjection
moldingCompression molding is the most important because of its use in tire manufacture

23 Molding Processes for Rubber


Curing (vulcanizing) is accomplished in the mold in all three molding processesThis represents a
departure from previous shaping methodsOther shaping methods use a separate vulcanizing step

24 What is Vulcanization?The treatment that accomplishes cross-linking of elastomer


moleculesMakes the rubber stiffer and stronger but retain extensibilityThe long-chain molecules
become joined at certain tie points, which is reduces the ability to flowSoft rubber has 1 or 2
cross-links per 1000 mersAs the number of cross-links increases, the polymer becomes stiffer (e.g.,
hard rubber)

25 Effect of Vulcanization on Rubber Molecules


(1) raw rubber, and (2) vulcanized (cross-linked) rubber: (a) soft rubber and (b) hard rubber

26 Vulcanization Chemicals and Times


When first invented by Goodyear in 1839, vulcanization used sulfur (about 8 parts by weight of S
mixed with 100 parts of NR) at 140C (280F) for about 5 hoursVulcanization with sulfur alone is no
longer used, due to long curing timesVarious other chemicals (e.g., zinc oxide, stearic acid) are
combined with smaller doses of sulfur to accelerate and strengthen the treatmentResulting cure time
is 15-20 minutes

27 Tires and Other Rubber Products


Tires are about 75% of total rubber tonnageOther important
products:FootwearSealsShock-absorbing partsConveyor beltsHoseFoamed rubber productsSports
equipment

28 Pneumatic TiresFunctions of pneumatic tires on vehicle :Support the weight of the vehicle,
passengers, and cargoTransmit the motor torque to propel the vehicleAbsorb road vibrations and
shock to provide a comfortable rideTires are used on automobiles, trucks, buses, farm tractors, earth
moving equipment, military vehicles, bicycles, motorcycles, and aircraft

29 Tire Construction About 50 for a passenger car tire


A tire is an assembly of many componentsAbout 50 for a passenger car tireLarge earthmover tire
has as many as 175The internal structure of the tire, known as the carcass, consists of multiple
layers of rubber-coated cords, called pliesThe cords are strands of nylon, polyester, fiber glass, or
steel, which provide inextensibility to reinforce the rubber in the carcass

30 Three Tire constructions: (a) diagonal ply, (b) belted bias, and (c) radial ply

31 Tire Production Sequence


Tire production is summarized in three steps:Preforming of componentsBuilding the carcass and
adding rubber strips to form the sidewalls and treadsMolding and curing the components into one
integral pieceVariations exist in processing depending on construction, tire size, and type of vehicle

32 Preforming of Components
Carcass consists of multiple components, most of which are rubber or reinforced rubberThese
components and others are produced by continuous processesThey are then pre-cut to size and
shape for subsequent assemblyOther components include: bead coil, plies, inner lining, belts, tread,
and sidewall

33 Building the CarcassPrior to molding and curing, the carcass is assembled on a building drum,
whose main element is a cylindrical arbor that rotates
34 Molding and Curing(1) Uncured tire placed over expandable diaphragm, (2) split mold is closed
and diaphragm is expanded to force uncured rubber against cavity with tread pattern; mold &
diaphragm are heated to cure rubber

35 Other Rubber Products: Rubber Belts


Widely used in conveyors and pulley systemsRubber is ideal for these products due to its flexibility,
but the belt must have little or no extensibilityAccordingly, it is reinforced with fibers, commonly
polyester or nylonFabrics of these polymers are usually coated by calendering, assembled together
to obtain required number of plies and thickness, and subsequently vulcanized by continuous or
batch heating processes

36 Other Rubber Products: Hose


Two basic types:Plain hose (no reinforcement) is extruded tubingReinforced tube, which consists
of:Inner tube - extruded of a rubber compounded for particular liquid that will flow through
itReinforcement layer - applied to inner tube as fabric, or by spiraling, knitting, braidingOuter layer –
compounded for environment and applied by extrusion

37 Other Rubber Products: Footwear


Rubber components in footwear: soles, heels, rubber overshoes, and certain upper partsMolded
parts are produced by injection molding, compression molding, and certain special molding
techniques developed by the shoe industryThe rubbers include both solid and foamedFor low
volume production, manual methods are sometimes used to cut rubber from flat stock

38 Processing of Thermoplastic Elastomers


A thermoplastic elastomer (TPE) is a thermoplastic polymer that possesses the properties of a
rubberTPEs are processed like thermoplastics, but their applications are those of an elastomerMost
common shaping processes are injection molding and extrusionGenerally more economical and
faster than the traditional processes for rubbers that must be vulcanized

39 TPE ProductsMolded products: shoe soles, athletic footwear, and automotive components such
as fender extensions and corner panelsExtruded items: insulation coating for electrical wire, tubing
for medical applications, conveyor belts, sheet and film stockNo tires of TPE

40 Product Design Considerations


Economic Production Quantities:Rubber parts produced by compression molding (the traditional
process) can often be produced in quantities of 1000 or lessThe mold cost is relatively low compared
to other molding methodsAs with plastic parts, injection molding of rubber parts requires higher
production quantities to justify the more expensive mold

41 Product Design Considerations


Draft:Draft is usually unnecessary for molded parts of rubber, because its flexibility allows it to
deform for removal from the moldShallow undercuts, although undesirable, are possible with rubber
molded parts for the same reasonThe low stiffness and high elasticity of the material permits
removal from the mold

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The drying method significantly affects the quality grade of natural rubber. Smoke drying, which imparts certain physical and chemical characteristics to rubber by curing with smoke, results in ribbed smoked sheets, a common form for export and processing . An alternative is hot air drying which produces an air-dried sheet, considered of better quality due to a purer color and less contamination . Pale crepe rubber, an even higher grade, uses warm air drying following a dual coagulation process . These methods impact industry standards by influencing rubber’s physical properties, market value, and application suitability. Higher grade rubber fetches premium pricing and is often required for high-precision industries, necessitating stringent control of drying conditions to maintain product integrity .

Natural rubber production is based on agricultural methods where latex is tapped from rubber trees, mostly grown on plantations in tropical climates . This agricultural aspect makes it distinct because it relies heavily on environmental conditions and agricultural practices. In contrast, synthetic rubber is derived from petroleum through industrial polymerization processes similar to those used in producing other types of polymers . This industrial aspect requires different expertise and infrastructure, typically in petrochemical facilities . Consequently, the rubber industry is divided into sectors that deal separately with agricultural, industrial, and manufacturing operations, impacting the logistics, production planning, and market approach .

Carbon black serves as the most significant reinforcing filler in rubber, enhancing tensile strength and resistance to abrasion and tearing while also providing ultraviolet radiation protection . This makes it a vital component in improving the durability of rubber products. Other fillers, such as China clays, hydrate aluminum silicates, and recycled rubber, are used to adjust mechanical properties and reduce production costs . These fillers are chosen based on the desired product characteristics, such as color, flexibility, and cost-effectiveness, thus allowing manufacturers to tailor rubber properties for specific applications .

In rubber processing, calendering involves passing rubber stock through rotating rolls to create sheets with uniform thickness, ideal for products like rubber belts and coated fabrics . It provides precision in thickness control, consistent surface texture, and is conducive to high-volume production . Extrusion uses screw extruders to shape rubber by forcing it through a die, creating continuous profiles like tubing and wire coatings . This method allows for complex cross-sections and is economical for producing long lengths of uniform profiles . Both techniques offer advantages in specific applications, with calendering suitable for flat surfaces and extrusion ideal for continuous profiles, both providing high efficiency and scalability .

Different tire structural designs significantly affect performance qualities such as vehicle handling, durability, and ride comfort. Diagonal (or bias) ply tires provide flexibility and a smooth ride due to their cross-layered plies but are less durable at high speeds . Belted bias combines cross-ply construction with reinforcing belts, offering improved handling and durability over standard bias ply . Radial ply tires have plies arranged radially from the tire center, offering better fuel efficiency, ride comfort, and longevity due to reduced rolling resistance and heat buildup . These structural designs require distinct manufacturing techniques, influencing production complexity and cost .

Thermoplastic elastomers (TPEs) differ from traditional vulcanized rubber in that they can be processed like thermoplastics, allowing for easier and more economical shaping via methods like injection molding and extrusion . This processing efficiency translates into faster production cycles and lower costs, making TPEs attractive for high-volume applications . TPEs find use in products requiring elastomeric properties without the need for vulcanization, such as shoe soles and automotive parts . Their recyclable nature also adds environmental benefits compared to rubber. However, TPEs generally lack the heat and chemical resistance of vulcanized rubber, limiting their use in certain demanding environments. Hence, TPEs might be preferred where process speed, cost, and recyclability outweigh the need for extreme durability .

Historical developments in rubber processing, such as Goodyear's vulcanization discovery in 1839, laid the foundation for modern rubber manufacturing by enabling the production of more durable and versatile rubber products . These advancements allow for diverse applications that were not feasible before, such as automotive tires and industrial belts. Over the years, improvements in compounding, shaping, and curing processes have enhanced production efficiency and material properties, optimizing costs and expanding market capabilities . Current methods leverage historical techniques, incorporating modern technology for quality control and scalability, influencing economic considerations by reducing production costs and improving material utilization . This evolution highlights the industry's reliance on historical methods to drive innovation and operational efficiency .

A two-stage mixing process is employed to prevent premature vulcanization, which would otherwise occur due to the high temperatures generated during mixing . In the first stage, known as the master batch, carbon black and non-vulcanizing additives are dispersed into raw rubber, allowing for temperature control without triggering vulcanization . After cooling, the vulcanizing agents are added in the second stage, thereby ensuring full control over when vulcanization occurs . This process addresses the challenge of maintaining rubber's uncured state during production, which is critical to ensuring quality and process integrity .

Vulcanization introduces cross-links between elastomer molecules in rubber, enhancing its durability and strength while maintaining elasticity . Specifically, this process increases stiffness and decreases flow ability by bonding long-chain molecules at tie points, thereby converting soft rubber into more resilient forms like hard rubber . Vulcanization is critical as it determines the performance and lifespan of rubber products, making them suitable for demanding applications such as in tires and industrial belts .

Filament reinforcement critically reduces the extensibility of rubber products while maintaining other desired properties, such as flexibility and strength, especially in applications like tires and conveyor belts . Common materials used for reinforcement include cellulose, nylon, polyester, fiberglass, and steel, each selected for specific properties like tensile strength, flexibility, and resistance to environmental factors . Polyester and nylon are preferred for their lightweight and robust nature, while steel provides exceptional strength for heavy-duty applications like steel-belted radial tires . This reinforcement technique significantly extends product durability and performance under stress, highlighting its essential role in high-load and dynamic applications .

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