Presentation on theme: "Lecture # 3 RUBBER PROCESSING
TECHNOLOGY"— Presentation transcript:
1 Lecture # 3 RUBBER PROCESSING TECHNOLOGY
Rubber Processing and ShapingManufacture of Tires and Other Rubber ProductsProduct Design
Considerations
2 Overview of Rubber Processing
Many of the production methods used for plastics are also applicable to rubbersHowever, rubber
processing technology is different in certain respects, and the rubber industry is largely separate
from the plastics industryThe rubber industry and goods made of rubber are dominated by one
product: tiresTires are used in large numbers on automobiles, trucks, aircraft, and bicycles
3 Two Basic Steps in Rubber Goods Production
Production of the rubber itselfNatural rubber (NR) is an agricultural cropSynthetic rubbers is based
on petroleumProcessing into finished goods:CompoundingMixingShapingVulcanizing
4 The Rubber IndustriesProduction of raw NR is an agricultural industry because latex, the starting
ingredient, is grown on plantations in tropical climatesBy contrast, synthetic rubbers are produced by
the petrochemical industryFinally, processing into tires and other products occurs at processor
(fabricator) plants, commonly known as the rubber industry
5 Production of Natural Rubber
Natural rubber is tapped from rubber trees (Hevea brasiliensis) as latexIn Southeast Asia and other
parts of the worldLatex is a colloidal dispersion of solid particles of the polymer polyisoprene in
waterPolyisoprene (C5H8)n is the chemical substance that comprises NR, and its content in the
emulsion is about 30%
6 Recovering the RubberPreferred method to recover rubber from latex involves coagulation -
adding an acid such as formic acid (HCOOH)Coagulation takes about 12 hoursThe coagulum, now
soft solid slabs, is then squeezed through rolls which drive out most of the water and reduce
thickness to about 3 mm (1/8 in)The sheets are then draped over wooden frames and dried in
smokehouses for several days
7 Grades of Natural Rubber
The resulting rubber, now in a form called ribbed smoked sheet, is folded into large bales for
shipment to the processorIn some cases, the sheets are dried in hot air rather than smokehouses,
and the term air-dried sheet is usedThis is considered a better grade of rubberA still better grade,
called pale crepe rubber, involves two coagulation steps, followed by warm air drying
8 Synthetic RubberMost synthetic rubbers are produced from petroleum by the same polymerization
techniques used to synthesize other polymersUnlike thermoplastic and thermosetting polymers,
which are normally supplied to the fabricator as pellets or liquid resins, synthetic rubbers are
supplied to rubber processors in the form of large balesThe rubber industry has a long tradition of
handling NR in these unit loads
9 CompoundingRubber is always compounded with additivesCompounding adds chemicals for
vulcanization, such as sulfurAdditives include fillers that either enhance the rubber's mechanical
properties (reinforcing fillers) or extend the rubber to reduce cost (non-reinforcing fillers)It is through
compounding that the specific rubber is designed to satisfy a given application in terms of properties,
cost, and processability
10 Carbon Black in RubberThe single most important reinforcing filler in rubber is carbon black, a
colloidal form of carbon obtained by thermal decomposition of hydrocarbons (soot)It increases
tensile strength and resistance to abrasion and tearing of the final rubber productCarbon black also
provides protection from ultraviolet radiationMost rubber parts are black in color because of their
carbon black content
11 Other Fillers and Additives in Rubber
China clays - hydrous aluminum silicates (Al2Si2O5(OH)4) reinforce less than carbon black but are
used when the color black is not acceptableOther polymers, such as styrene, PVC, and
phenolicsRecycled rubber added in some rubber products, but usually 10% or lessAntioxidants;
fatigue- and ozone-protective chemicals; coloring pigments; plasticizers and softening oils; blowing
agents in the production of foamed rubber; mold release compounds
12 MixingThe additives must be thoroughly mixed with the base rubber to achieve uniform
dispersion of ingredientsUncured rubbers have high viscosity so mechanical working of the rubber
can increase its temperature up to 150C (300F)If vulcanizing agents were present from the start of
mixing, premature vulcanization would result - the “rubber processor's nightmare”
13 Mixers in Rubber Processing
(a) Two-roll mill and (b) Banbury-type internal mixer
14 Two-Stage MixingTo avoid premature vulcanization, a two-stage mixing process is usually
employedStage 1 - carbon black and other non-vulcanizing additives are combined with the raw
rubberThis stage 1 mixture is called the master batchStage 2 - after stage 1 mixing is completed,
and cooling time has been allowed, stage 2 mixing is carried out in which vulcanizing agents are
added
15 Filament Reinforcement in Rubber
Many products require filament reinforcement to reduce extensibility but retain the other desirable
propertiesExamples: tires, conveyor beltsFilaments include cellulose, nylon, and
polyesterFiber-glass and steel are also used (e.g., steel-belted radial tires)Continuous fiber materials
must be added during shaping; they are not mixed like the other additives
16 Shaping and Related Processes for Rubber Products
Four basic categories of shaping processes:ExtrusionCalenderingCoatingMolding and castingSome
products require several basic processes plus assembly work (e.g., tires)
17 Extrusion Screw extruders are generally used
The L/D ratio of the extruder barrel is less than for thermoplasticsTypical range 10 to 15Reduces risk
of premature cross-linkingDie swell occurs in rubber extrudatesThe highly plastic polymer exhibits
“memory”The rubber has not yet been vulcanized
18 CalenderingRubber stock is passed through a series of gaps of decreasing size by a stand of
rotating rollsRubber sheet thickness is slightly greater than final roll gap due to die swell
19 Roller Die ProcessCombination of extrusion and calendering that results in better quality product
than either extrusion or calendering alone
20 Coating or Impregnating Fabrics with Rubber
Important industrial process for producing tires, conveyor belts, inflatable rafts, and waterproof cloth
21 Molded Rubber Products
Molded rubber products include shoe soles and heals, gaskets and seals, suction cups, and bottle
stopsAlso, many foamed rubber parts are produced by moldingIn addition, molding is an important
process in tire production
22 Molding Processes for Rubber
Principal molding processes for rubber areCompression moldingTransfer moldingInjection
moldingCompression molding is the most important because of its use in tire manufacture
23 Molding Processes for Rubber
Curing (vulcanizing) is accomplished in the mold in all three molding processesThis represents a
departure from previous shaping methodsOther shaping methods use a separate vulcanizing step
24 What is Vulcanization?The treatment that accomplishes cross-linking of elastomer
moleculesMakes the rubber stiffer and stronger but retain extensibilityThe long-chain molecules
become joined at certain tie points, which is reduces the ability to flowSoft rubber has 1 or 2
cross-links per 1000 mersAs the number of cross-links increases, the polymer becomes stiffer (e.g.,
hard rubber)
25 Effect of Vulcanization on Rubber Molecules
(1) raw rubber, and (2) vulcanized (cross-linked) rubber: (a) soft rubber and (b) hard rubber
26 Vulcanization Chemicals and Times
When first invented by Goodyear in 1839, vulcanization used sulfur (about 8 parts by weight of S
mixed with 100 parts of NR) at 140C (280F) for about 5 hoursVulcanization with sulfur alone is no
longer used, due to long curing timesVarious other chemicals (e.g., zinc oxide, stearic acid) are
combined with smaller doses of sulfur to accelerate and strengthen the treatmentResulting cure time
is 15-20 minutes
27 Tires and Other Rubber Products
Tires are about 75% of total rubber tonnageOther important
products:FootwearSealsShock-absorbing partsConveyor beltsHoseFoamed rubber productsSports
equipment
28 Pneumatic TiresFunctions of pneumatic tires on vehicle :Support the weight of the vehicle,
passengers, and cargoTransmit the motor torque to propel the vehicleAbsorb road vibrations and
shock to provide a comfortable rideTires are used on automobiles, trucks, buses, farm tractors, earth
moving equipment, military vehicles, bicycles, motorcycles, and aircraft
29 Tire Construction About 50 for a passenger car tire
A tire is an assembly of many componentsAbout 50 for a passenger car tireLarge earthmover tire
has as many as 175The internal structure of the tire, known as the carcass, consists of multiple
layers of rubber-coated cords, called pliesThe cords are strands of nylon, polyester, fiber glass, or
steel, which provide inextensibility to reinforce the rubber in the carcass
30 Three Tire constructions: (a) diagonal ply, (b) belted bias, and (c) radial ply
31 Tire Production Sequence
Tire production is summarized in three steps:Preforming of componentsBuilding the carcass and
adding rubber strips to form the sidewalls and treadsMolding and curing the components into one
integral pieceVariations exist in processing depending on construction, tire size, and type of vehicle
32 Preforming of Components
Carcass consists of multiple components, most of which are rubber or reinforced rubberThese
components and others are produced by continuous processesThey are then pre-cut to size and
shape for subsequent assemblyOther components include: bead coil, plies, inner lining, belts, tread,
and sidewall
33 Building the CarcassPrior to molding and curing, the carcass is assembled on a building drum,
whose main element is a cylindrical arbor that rotates
34 Molding and Curing(1) Uncured tire placed over expandable diaphragm, (2) split mold is closed
and diaphragm is expanded to force uncured rubber against cavity with tread pattern; mold &
diaphragm are heated to cure rubber
35 Other Rubber Products: Rubber Belts
Widely used in conveyors and pulley systemsRubber is ideal for these products due to its flexibility,
but the belt must have little or no extensibilityAccordingly, it is reinforced with fibers, commonly
polyester or nylonFabrics of these polymers are usually coated by calendering, assembled together
to obtain required number of plies and thickness, and subsequently vulcanized by continuous or
batch heating processes
36 Other Rubber Products: Hose
Two basic types:Plain hose (no reinforcement) is extruded tubingReinforced tube, which consists
of:Inner tube - extruded of a rubber compounded for particular liquid that will flow through
itReinforcement layer - applied to inner tube as fabric, or by spiraling, knitting, braidingOuter layer –
compounded for environment and applied by extrusion
37 Other Rubber Products: Footwear
Rubber components in footwear: soles, heels, rubber overshoes, and certain upper partsMolded
parts are produced by injection molding, compression molding, and certain special molding
techniques developed by the shoe industryThe rubbers include both solid and foamedFor low
volume production, manual methods are sometimes used to cut rubber from flat stock
38 Processing of Thermoplastic Elastomers
A thermoplastic elastomer (TPE) is a thermoplastic polymer that possesses the properties of a
rubberTPEs are processed like thermoplastics, but their applications are those of an elastomerMost
common shaping processes are injection molding and extrusionGenerally more economical and
faster than the traditional processes for rubbers that must be vulcanized
39 TPE ProductsMolded products: shoe soles, athletic footwear, and automotive components such
as fender extensions and corner panelsExtruded items: insulation coating for electrical wire, tubing
for medical applications, conveyor belts, sheet and film stockNo tires of TPE
40 Product Design Considerations
Economic Production Quantities:Rubber parts produced by compression molding (the traditional
process) can often be produced in quantities of 1000 or lessThe mold cost is relatively low compared
to other molding methodsAs with plastic parts, injection molding of rubber parts requires higher
production quantities to justify the more expensive mold
41 Product Design Considerations
Draft:Draft is usually unnecessary for molded parts of rubber, because its flexibility allows it to
deform for removal from the moldShallow undercuts, although undesirable, are possible with rubber
molded parts for the same reasonThe low stiffness and high elasticity of the material permits
removal from the mold
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