Scribd
Upload
31 views17 pages

Organic All Chapters in Short Form

Organic chemistry tricks short cut method

Uploaded by

haya.aty01
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
31 views17 pages

Organic All Chapters in Short Form

Organic chemistry tricks short cut method

Uploaded by

haya.aty01
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
Chotackeristics ob alkane | [> Jabali senderen an (ydrogeaion) >Jaturaled > Aliphatic > Aligyelic > Q,Manea > Sp? Hybridization > 104.5° (Telrahedral) 3 + C=C 154 Pm > C—H — 109-SPm Physical Propeslies > Cu- C2 Colousless Salas} : i > Non-polas miromolecslesy> als ~¢- Ingoluble in water degen ton > Bept xin no of tarbon i ley > [Link] a Lor > LOF of Molecular Jize ‘rane > Mpt no of carbon > Exption:. odd. no alane have. SR ne tess Meek then al ss one CaTON-/ C3 rC > ce HCH dmchy uSf Hs Kolb’ eleclrolutic me) iG} Naf sal 0} Hit a > GHC, > Coloorless beset TS tic > Cs—Cy > Loloutls le ids] | Salurale d_mandeasboryie acid ‘Only Jorn symmetrical altar 9 Te B -aCOs rai Bert L>By worlz Bn: ‘Whajgnt chain S, Branch, Ea on Sonn 7 alkene tian a) for 100% S ymeneitical ge_x ant els anlar + -K 8) Fox_asyeneebiea_fikanes aban pt. wept > Dnsly erro (“aay 3] Hence carnal besspeed Qridaion_Leactrons Lengo i ‘Sag yea pre Oe Sethtt Stead stint 0 coe tous OF O3t- * +0,—> C0. + Ha0+ Heat CeO ajmaare pare CH One COs + eO+Heatt ‘oyaane fone 10 Jn Tiled On: Yocom xian) (es He) CHla+ 0 —> (0 + Had +Heat . Tie dome causes carbsornornide Pois 2) Calalyic oxidation 2" > HOO » bones is Jamed because i Co. ‘rnax oxidelion Sale +4 - Free Radical lubstition pectin tae 0. — Fras aw > Mlha = po. rf i} > ty Pipa hea Drmore by yee adic > eant+ts—4V > tn 4 mie vs rosa a nee i AF ya Nelere in baa = - iin PREACH I eae! = ea) thay oe ysis raking aes Yorn Feotopie arintvre pan bagen aR Say ces z e RTE. mglgpain-y Alene + Charack OL Cycloatkane Siliecki = ip? Hybrid > dye ae 151m > CaHan > C-H > 108Pm Nomen 3} Aone => P Pree Ladied) dubstitstion Reaction is the raracle > Welodttanes resemble alkanes in Cucloalkane ut chemiea) behavior Exeopt {clopropane and ydobukme, In CYclopropane and cyclobutane => Butane 2 CycloButane => Pantane = tyclopmnlane eqetoatane | the axrtent o} | overappi is not —> lyclopropane and cyclabetance smatimums because 6} the High angle. tin occure addition Reaction Gains while other tannot + 4o Jom eyeloalane Angle Jtal al The change in band angle. = Jalualed uompds athich an ge > Can Cy > boasts than ap ld a e> addition Beacon - > ls-Ca> liquids i a ® Oyen eeesine -> Non polar 7 oe > Insoluble in usdtey = Beptox Molecolarmass x zona (yelocitiane > OPencnen Bem ee Ue into}. odd-no oe Nile) “hen Jus thn ha mech Gag E -E-oe speToaBkane “having one goss 7 sathon- 5 <0 e- ita OK Cy>esKCeder Reactivity ig 2 atpe* Hep eect g te ~ Dansity wrdeeatar dine (PC fafa é rey (Les then wiater) > Caled oleqine - Form oly Tayer > Altyene ag > Acyclic > unsatraed. > GnHan > Aliphatic Crthomer 9} “eyctontkane |> Elechophilie additidn reaction is charactenittic Ren o} Alcene~ 120" > Spttkbsiiaed. C=C > 134Pin > C= H->108Prn| > In_lonjugatic C-C > 148Pm iy Ain poston 6 = bd SEE Gone Boban © Nomber 6} altky! =" C3) 2 . Shy sea, J+ Hability ‘el ) cha CH= Oy AG ay WY Wo Bois fs ia abil hen to ai oe 10 double bonded. }> Tans is Sable tren Gi beok sects Sw exe =Cnu Reese R+t-H agar Sap choigie eich” SY azn fg oot td nen Bree enn ela twp) tle has to yma Co tore sd alc onpge toy ge = Oridation_Pm of filrene ss > Combustion df abvenes- CaH+ 0s ——> COs! coreg Sorramtattere> % sed > Catalytic vic xine “ < pee ee ban eta ‘ery Fd himatiine 7 Soe faimae | om 2s she 28 on iD ee bee ee ea mie THebantalion oh tenes fogs e fo dentiyication 4] "Neca, nd ee e=0) Stine ema Mt ha ur Yo (atte lsne 01 costae Sait rink * eat ato ed =n gene ni 1 = Eleclroptilie. addition Bn of Alene Ou ination of Alkanes 3 Tt yt F: Nt er C4 BiB-DicHondielhy sai (wasted bis) iaihy Roiwreos eedavlgehs Way Used in Obrinalion of at ebtenas vail MT SDoleh iqoid test of lower Ready 7 1 Hy alin 3) Bien Bede) ntl nuit td " . tk ‘@ Hydrohalogination of Alkenes s- : ae chiaty-4-afpa03 “> May 01 Hag nok be anartanizo’,asiton @© Polymerization of. tenes ‘Deeare in tower aenes ¢ ent f>Chovaclenstes wo OE MANES hy Bi ols le > felie > daltan-2 > 180° SP Mbit > C=C >114Pin 2 C-H> 406Pm 9 C5 Cia > liquids > Ca — Cu» >dalids ->18pox 4 in no of eaibon- > Bp 2) Termina) cigee < non- teil Non-polar go insolbble in water > Dansity of Molecslar dine ("eis { etafive shability of Altre =| > Stabilo Pauiten 0} Ariple bond - > Nop-terminal) S Terminal - feiily ot ot 1 ™ fo op eavbon > Acidity g-chatractes-of exbon > a Valve of s-Aephe is lous thon Ka wold? of Ha hanes 4-Aikyne is lass _aiditic Yhan_waler ‘ecko onsator isa i gexec d z nydrohalogenation of —>| Riocina) dihdlides- x y t pend aie © t 4 vee Me -nlantts 2 cxe-Fiie on alaty eogatic eae 7 ‘> tomburtion of Aikynes tare Hen bree ans 40s 2 CODA Trory-aciglre 20% foe > Hydroxylatio of picynere “hoa j—> > delat ees oN FT Ask is Yor dokcton of 2) bond. eye 2a Fy Sm eam ar Etectophilic adailion Pen of nikynes ation) 2) Adaition of HX = Cee Heese tH PH-€ ie! i oD Pe iybaton ogee Yt eee neeabw 4 fl cache wc elhynide, faint) D jenation | Aliyines- Roc mc —y NOm? | <4 Ter ue ebb 1 i Hedlogenation ¢)_Adeynes {Simple Aiiten) rane Chiorination:- q Hoxe-H +0 HM ou-oat-vtel aad ue El re © © Brominalion- a Bromine wcttey 4 dost ye" Alyn Recsc-u + By, WO 5 whe, 4 yt I Brown Gro. Baa 1 corte 2 Polymerization: o} moneys BCS i ee (ee) i Taser D> aH-cac—y Mach Hayne: eo yoo it E05 4 Coenen blames 8 a >Fiom_ arelytene mElecropniic agent Peco” (Analy cae) > Aromatic compre [ere © Hydhoginations- P > Ce arg ceyiaaon Bieeme-n MS or Coen, UMMM S BSE ome [> Sp Hy ridin 120" Fionn phenolt-(Peduction): egal noch Nal halgeatir) ‘€- caste i-C> 108R on O20 Oe3a as be maga > hig dame bond angi | aemanien Cogan) _pUlehoptilc Jatt Sait sae tnd Fl Nibalion o} Benzene hesdtaneg? Bond! order = as 4. me Hpbride-> Pf bond = O [ra catia igor | ieve-> von =6 st Linelve-> Pietecton = 6__ Et = aertion op x Pes > Bontene aie close iqaids| i aot etal gaa, na tea ** Wk Jit has ar Sea ond boing Deon —— oar sive tee Density i o 884) aa den Dt ah oom my he te eee catalytic oxidation 0} Bergen Fl te ne Grex Mes Or®eux =enk Non- polar Oho Me —F—" do eeoatto Paras neg = 153,anmo ‘ i @ Friedel eat aro! ¢ : : = § ie! x A, or eax -o samt, GylLeene or etemamt ty, Ook saturn > dnienend. Peagen! (oor Fiow adore» gl naga hai > & Gana Sp Mabrdized. | ety, — a> cher vats cnet y-Te ny “ak ie tlhese foe 7 Fiom_aultene & (elrohaleganston) C3-X> Gtts— _y at ae ede tea [fiom aloha: > Paclon 4 Ga onder ts - " & Uihen GR veaed with, achive ae onsite hen Gah Ro Ong HK —> P= Kind rp etal a. Beohol with thiany/ chlside My > BH + [EeSeisaer Shaan eet S Bp ot No ob. tatbon CR ete rasteB-ct 180-9 —> RH Bp x diz halogen akan 4 ah {oR wih comps MGaranmasins) atl wth phoxphan tina 3. fa Pend oy Eon Insoluble in wates 30-Ol1+ Pls > 30-xallpo, erro oe SMP EEE | Aley| Htosride and abl4t chtoride fp Alechol usth phog enka dz? "hide es ide and ater todide. i re denier thon wet poe > Fe — ie pale Basic 7 ME > Anyelones GR noc! 205 5*pleshel be SNi-Mechanison GY]. GNa- Mechanism @]€, -mechanivon @ | €2-mecheris} : aera is Lighter thon water P- OH + Pts ——>R-X+9-K+ PY, DBI with Leber eompoonds (FES A [> Gonpae in-2-sleps RCT TCT Premplle in a-Tlept Fete TEP [> bal Spr age deste Ppa rb zip Ee depoad any natal Sbetend co a testa Ins) bo ealect furan tu] [> Rate of {isbshale} | sPltale and. ba fe mokedani = rhea ede > Pate hatte med Kes oR [aeons sda Patron Base $7 2 S223 11 apehi i J Pater aprotic: Jong nyeleaphite ata Pro fe decond dey Jmx> 420 A Kd tanation State elfen d Nok inns TP imed_ 7 No =A ined P Moleslaity § ofdered. 2 Alkylalian 0} amoroniae— Characteristics HONM HR — yi apt crivies ammanig Re “eae” adi HR R-N-e > ie can tridined. > 4107-5° Ss Tater. Guonelty RRW rR nr Bok -f-8 42-x fe fpeewe} e-ive hm tre Bin with larbonyl cenpand (ee [> y naa ide) dhape > Posses romani like sell > Higher “i then abicane > ving Hydrogen bond. hw them- > Bi tii cov, ym) Hebb with, eobsrcat Hh Hb with water ‘ RCN ate) ates fy wal E> ReducHer Of mitvoalkane |__> No, Stalnt Intel eal arin —> 2>1°3° ‘sgonation STE tie 2 ca gies en hy Dae” a Tae ee Trsaaiied ie aerate et ins Ara et ed pep re RG once FRAT) fs an 4 (Sah penned wih HE] mai fo-nsenFha ON-H 4Nand, sel 7 i fs + " ia spuds + Ay deg " sie 3) (allylic ordain 6 otto, Salis 222 1° Cy bi fos Set enfin pate in = Jf i i H+ alg a. = Ba dad- +H-0H ee 9p d tue ee ro gruth conc acd 1 (Estetifleaon) oo ht a iss lien &) eenbonyt Bont Shae San roars, (Deeqyellon oF ea _ 12-35) —e 1S emo Gil > Nise re in {nel ae 08 ort e-g-a SE atl mn) a FSIS ce PaE PIE ede _cate, at pnes Mcohot loetatcacs sent ait c= “Eee a tee chiar Neola Fone fritecget eth ety. ach tc sta Boia ack rs pace one et IS yy 7° pitts ied ~o =o Stbagion 2} Alcohol with Pha and. Phe = 3 Sess — ap xr tts Baty ts en PS teacher ama Gh ing Poh sa- a (Oi 6) abtohol with a +502 +2-C) eae ia Pitre ten dos acy natin oboe ra siphalee 2 ALmoderate id she sp een met a they. Pee I82) far eer tee i oe ied 2 bh (Pam sdf —>01Hdaon 0} “Blohol pend olde oa oie ea fatad Iipend Pp 6 raps piled a] aft ete 8 Wt#0 hy-o4 eate-08 Cty cfnm ono emir tt rts ig pane > UWs-on Cots ‘ath —“OHlengt on, | >a quits Lied d ap etso+ HTOn L> -OWK H-OH io = [7 Laverakidohoresobble Poincar] M=p—p-# + Hoy —> anne altthel coaiet - To a Sa bas DSN e ON he PHO (ods aa May be moro and ional \nteona) sing “angie a *) £-0 + 136pm-c-H->46p, (¢-0) <@e-o) Ta ss ds oR 8 eysleinetlids haracenite Bicone [Fiom ack iad wh > bets 3 (ais Same pes phanaion 3} jer” rey Mote Joluble in usater then x rol | yaw. sox —> a __"Aeahol al Silogeaton 32 = “& : : pease raga Sitinam Grea oye We Laeoueh 0) ae heat & & * & & ane ga eansls (ricart fat 30) . a Reo > Pl Satter> Reto) Xe GT" ey 1 a, or col dol fgets he uate pet) @ Oxidation o} phenol = Sree & bat -Benaoqoiare 8) Lin o} Phenol with Jornnaldehyder— on AMEHANA) )(attse ) a an tHee-w 5 Avene sf ee oath epee ae a 96 rf : ofan n &: onl HakT $ en as oy g cy. on Chavaclassties of Ethers > Bartthers dard race us, Bases > achive R-D-R ,R- 0-PhR- ‘omnethots motels soxidizing and teduct erect eng pn en Totes in . a8 ao 9 wy fi J Ht B-onk te p2e— Sis aa. ae—GNat te Newer he fen oxoniue dab ih ce fide 1 Boe paR— ON 5 ap-0-R42Nak 4 fc iE is gpmmerscg) P= O-Ph ther] NBRSK Formation 3} oroniam Salts NE R-0-R’er R-0-eh then -O-estene-a$6s—$§$> le-d-e iy it is ungynmessiced - ; Neonyateane f» By Infermolesar dehycation Alcohol J) Foramall Fos tage L 2- on on RH"_, po -estho Group, tay woe. Basie in natuie hake ty a yowniom Pov 4H-asos 9 e-oststh9 > eawage 9 other si ee An a Mestage a elber Linkage « a eA gsonse-EX eve o-e vison 8 a satee thers ot ei a , a et ae qa i A : Sicuids aith Plewant odours [pete sa te syns aca x te | Syermettical aan eters ie i Ethers ave high {pam Jam unsymneltical nen syenenehia — 2 OFM for is Jule Sable vith ef. ; inqlammabe | lis Jor which orm zip I roHim in is behave patcsn see lows bat iat tren | elena onpnci tml” oor en & untdie aih T alicohol ; Lg fight en wag, SPH eB -arb > jefe bond ; ’ . is gis thon alkene yorms tbelezen nem ae e Foun Rydrogen bond. wih |, stare ets |> from Sip FOF 2-8-P +18 > Pshe sh, erates = se ;. Reeth > 4 =. Hea a ] ! 3-2 —> ede ely 5 5 oRb. e-bace [rye]a® # R +] t beg on+R-T Lemar. gunan sat slabe in | adhe. —>e- 0-0 294k 4 denser ke usdler eet ea “ a ~ioptial Kewweho SNOT Gharaclarisfies of Aldchyde/yelorpOzonalysis 0} Alene @. auAily ane ~ dj sis _, ae lerboritt neup (ys = ontain omy se) oon wien ty Aten adie ie Nt 7 a : ‘ Lasoo ebon is $6 bbsioton oye “se, Oxygen ig also Sp Hybuid- > bod Jen Bkydeand ve Bae, | 7 eijriocer] ; > lerplele Reduction. tapbon ® 1 aire reread cacy ye gy yet. FM ghanin 2 i \20°2 igen) lptnner | ere OVERS md Mey || «eC g zat, ie ia! iehipepe Oxidation c) alcohol s-~——W atet =) By wolf Beshney -f if > ali - >Yory Toueraeyles have Hdharptsionke- £7 : aon raed Leer Eorgent odsur eshere guides E bt alors aldehyle and. velore ae Fearn Mundie oo dou» Formac ave ga ak temp ushile other are Zotouslers diquids . Formmaldohyte. aia Sr and used as Yo" acyoou tatted Sowmnaiin= Solut DEY Grindlen Reagents Rechane aid ctnermentbers [ixatayad nan aat [peep wen f rite CHRO} Ketone. gerles are colowefrg wT Fema AE ina i> ie Siquide dune fer | Brewis t + dehyde 211g tS intrude rig "Cy Aldohyde and ketone are pot ttiaam Ce? Pawo 4!) \ tame gt lie Worndel ; PB 9H wil i Atal ye phe bp the Akane and infin 0} of wih eae = me PBA auch Sint ga se Nol foray Hub ash aol | ee em we Form Hb with Lee i [cnn Heidole eo deniers ae Po * wv ak «od ston Set 5 be, gecait MO Mog 1 ilk Te e-onpHiati ce ob lacetadl ie, a a [=> Reduction by "N” nucleophile _twmpound:- uld_Qewtaing _agents- . LF mucleophie. addition” yosming an ynilable Whew’ Mild oxidizing agent can ovidize aldehydes - eghl t Radu which then loses udder ‘only mot toh tea 7 ought iss wach Oxidi eed ton oxidized. indentation The egidensation product = swig eels ta) Of Iramie dial Eases Paget > eal fag tin Boni ston au a gf qeanou) bs sble) 2)Aliphatic aukyde Ha, oni sia, a “i # sge,t tho ea a) Aromatic aldehyde We 4) ti len _Roagente— terwerica) sototion fans - Jae +H Ne R Sree sults’ ——> Ug oe )a) 490 , eS een enna ers so sit a £— +H20 tog Ta caenlond Py), Nose ° mente Oni pole — Ea suche LE to en soe eta (iat clo seat Perle wo: > yew cas te Siler Mies ~ teu jae he hin =ositation Oxidation oackions o}. Carbortyt Com « mck-wefquotiat Apr B-onk tet sg? > Jtrong Oxidizin, ot ont tan Gxidize a * pybuidation ze atdehyle by fel Sten ed f Jf aldehyde tte ; Gin ane otro + bres Oligan ents a ecbue Ba conelicwses(eida rete A> Ass Ne Pnabion xeninOy SS KaGn0,S¢ toned, ici ir Ol Oridathion Oni id pw i tle tape wted for Ten en apidehyde pines ae ay a=nieyoe 7 aN , “ teat Characleriaies Ot lie Reid | Deivalives o} (aibouyficacid Prepaialioh 0} dayborylie a ne one Te e fe Waid alee Sy aid Garbonahion oO} dxtignasd. Reagents De baat erin musi) Tala ie* by “yl HTL eng Hat oH ent Se Eaeo ne 1 tog mse Ae fon set Caan 2 P-CooR iy eae lavas Nii : ON is Spa hybrid. Imananoy) 2h Stein partaoy) = 1 SN Ben is tates pen, [ilo 23- lee seaioutl] ——> &- E+ ‘Altanoie acid 2¢=c >12apm ides 3 > AUeaNe cama La +NS, * tata ® R= CaN 4+ Had + Nad R-c-0Na thew sso anes Hl Oe alk yale sidation ol. imaty Hechl:- : hows +8sonAnee Loelween of andd cma onkguitoton ol any Met Gen 2 O=1a0% carbory i tas Pena, - _ Poy LL Remo HL e-& tophitc. kay (Néhanamiie, 6 AB Propanamie. ids " lon ion o}- abide ia a EAE > Al aanale “ te a HCOOH —>Pomnie qeid. —> 1 >" Hy Sel —pe-2. Reptane °F” by "ale. i Caianyiony- [Oxidation acOOH —> acl acid. —» 2g? e-l-o-e [etertog= london Yee genanes- Sia tommon mame 0 a ~ "OH sHsCOOH > ropionio acid. 3 fet Ratan OTB) yee ode HyCOK —> Botysie acid —u + bates oe asda 07 iP S a Hq (OH —> Valeri eid —> > vd piso ee Acidity 07 Cenbonylie acid ‘ 7 Pieper ‘as fe-order» 4 oi ‘Nie phatal Perera a goer hl OCT > baal o i ey ~ Same side drawing Circa Diquid —>Pendrating adorn | SA Side Dith side ut Rng Bias Carta tos volte Ma, ARTE Geet) tel 2 b gli eld feat al 1%. ys ie ook | ani Pm ag bea No a} witb Group water and tailed ie, |Nitviles?-—> Alecane nitrile [sites ia 4 Fela oie* by senile Paeacad fat) QE of witht GR Lomiotith Sragestam |) oa pawns of Euston il ne dno ee Pde gata et [etch Deg taerp 100 Bay > Fan Wo with tretelf and water a. % t aaa Cotega- boa feo Solsbitil in water decoy + mance ; Lonversition a {ston Ned dovvalves ~rlenwewion to heyl tabider, 40-2 on +46 ——>-9-!t cra oye %0- Laas Pas —_> 9_ ch + POC; +H Cemersion do acid Onhyénidess— 4 t 4 Re-otror—p-2 Wn kb L-e 4 — b-aror-6-e =e Lette domertin blo Bsrerss- tats Lonansign 40 aoriides ° 2—C—aranut; tat > pS sae 210 4 4 2—C—K ants —> ott, Eh -nua tk ° i Cis 6- 4 ly —> Cyne +0 gug S { > belo ol stl ideo * a WE deeatoxplation eadion fs FR Sin ena 89 ea tlds 92a i_.i ' Rd -o- 8 enon seed! ar a ; 2-bot tye tec ith i — oa He Raction 0} mnidtiless- Tifa (lt eit) 2. Redchl6) (Binary amine) 3+ Beduction with vig teen) i! 4 . ° Cts €—0- city 4Ns > ete 8 tae chs 4

You might also like