HP0y3- CH3CHIOHS COO

CaHOy

WB e CA
When

CA

604
(b)
(a)
2 57 x 10-13
4 07 x 10:4 (d)
.

(C)

CA weak acid
B

↑
acid =

↓ PH

Acetic acid
Phosphate dad
 N # equivalence
=

L soln .

# =9 solute
eq .

Wt
eq
.
.

Wt =
MM
eq .
.

% cysteine
g salute o
1 =

100%
.

=6 459
100 %
.

80 1 .
+

6 .

459
=4 45 . % cysteine

2 .
10 8mL ethanol
.

p
0 789g/m) (ethanol)
=

[Link] so In .

P soln .
=

0 982
.

g/mL

a volume % =

10 m2 CHaCHeOH
%
.

x 100
100 mL solution
=10 0 .
%

b % 10 m) 0 789 g ethanol
=

. mass .

1mL
x 100 %
100 m) 0 . 982 g so In
x

1 mL

= 8 03. %

C mole fraction nethano

:

n total

=10 m)
x
0 789
. gethanol ,
I mol

1mL 46 .

0489
(100m) xg)
0 9829
I
0 / mol
(10m) x 1899x
.
.

x +

ImL 1 m2 46 .

0489
=0 0304 .
- ethanol

d molarity
mute
=

=10 mc x
0 .
4899 x
I mol
1 mL 46 0489.

100 m) I L
x

1000 mL
=
1 71.
mol/L
 I
3 M 119 mol
=

x
20 04 .

9
-

100 x 10 L

1 83.
M

H .
M =

mol solute

I soln

=1 .

659 x I mol

110 .

39
11 1 . x 10-3 L
/

1 331 M
=

N =

M n :

1 31 M .
x 2

2 463 N
=

34 09 1189 12 0 M
1000
5 . .
mL I mol I
.
-

X x X

100 1m) 36 59
9
.

7 .
C, V, =
CeVe
15 .
04 M)(x) =

10 840 M) (250 mL)

.

X
=

42 7 ML .

dilute to
=

250 mL

dilute with 250-42 7

=

8 .
9 .
 antilog 19
i
Part III 5 a .

.
.
41-9 .

23) =

pH pKa+log
A4
3
=
.

1 51 mol
.

primary sodium borate

* I mol boric acid

AsPOy =
/HePOn] THOYE DOY

21 tordium
b
antilog (4 80 9
-
.
.

pKa=-log Kaz
=-10g(6 20 x10
-

5)
our aare
.

=
7 21 .

4 21 =1
109
pH
it
3 84
=
. +
.
:

8 98 . !1

7 03 -
good buffer
=
.

8 .
buffer name depends on the conjugate buffer
pH
=

pKa+ good buffer

Buffer preparation :

!
1 PH pa+10g base weak acid
1 ratio of conjugate
=

to
.
.

s
log(mos
=3 74 . +

CH3 COO Na

=
antilog (5
0 -4 14)
y el
.
.

3 85 000-]
82
Mo e
(CH , 1.
=

--

[CHg C00H]
log
i
2
pH pKa +
=
:

c .
total theoretical moles of buffer
searched

55+
log
8 00 6 2 82
=

. .
.

3 .
total actual moles of buffer

antlog/000ing -i wo
e 0 300M
mo
. .
=

X 0 15 moles
=

4 actual moles weak acid

of conjugate base and
(A] CHA]
theoretical
:ob
94 47 .

mol
-
-actual
-(182 7 10 . I
*
=

5 moves

x =
0 097.

mol CH3COONA

total -

A- =

0 15-0 094
. .

=0 053 . mol CHICOOH

 5 moles
- mil 9
07
.
.

antilog(5-4 74)
094 mox
Nas
0 .
1 L 0 323L . .
=

0 3 mol .
CHs200 Na

0 053 mOl
.
x
1L = 0 194 L
.

1 82 mol
.
=
(NaOAe]
0 3 mol CH3COOH
.
I mol (Ho Ac]

② . total theoretical

Total volume 0 323 0 174= 0 5 L 82 moles

1 81 1
+
=
.
. .
.
+ =

2 .

7 .
① (A) ③ total actual
/AA] 0 .
100 M = x mol

0 5 L
.

antilog (4 4-4 20) .

.
=

(8uHs COONa] x
=
0 05 mol
.

[CoHs COOH]
④ theoretical =
actual

3 14. mol CGH5 COO

I mol CGH5 COOH A =
X

2 82
.
0 05 moles
.

② 3 12
. + 1 =

4 14.

X = 0 03.
NaOAC
0 05-0 03
.
.
=

0 02 .
HoAC

③ 0 200 M .
=

x mol

0 . 2 L ⑤ (A) =

0 03 mol
.

x
=

2 .

469
x = 0 04 . moles total

④ 3 16 .
A
-
X mol 95g CH3COOH
X
1 .

04989soIn x
1000 m2
X
/mol CH3COOH
12 60 0529
4 16 total
.
0 .
04 100
g so In 1 mL .

x
=

0 03 .

mol CuHsCOONd =16 21 M .

0 . 84-0 . 03 =

0 01 .

CaH5COOH
[AA] =

0 02 moles
.

⑬ mol
mol ,

95 % W/w =

16 G M .
=

0 02
. moles

0 08 L X

inmos
> 0 02 0 0012
X 0 15
molx
.

= .
.
.
=

0 01.
mol x 122 .

139 x =
1mL

mol

1 <
09 w
.

179 10 .

not
possible to
prepare
 0 . 10-0 10 .
=

I I
10 A
OH
.

HePOn-
. -

-
OH
APOy
=
HgPOy = POy3
0 10

-
.

0 28 .

0 3
-

OH 0
0 10-0 10
.
=
.
,

D 0 3-0 20.
. =0 10

I
.
.

/In
2
H3POn = =
-

He
0 .
20 0 10,

0 4-0 2 0 20
=
.
.
.

0 20-0 20
=

0
&
.
.

# HePOy- APOn2
HPOy
0 20 0 20
0 20
. .

-
20
0
0
0
not buffer
 0 . 10-0 10 .
=

I I
10 A
OH
.

HePOn-
. -

-
OH
APOy
=
HgPOy = POy3
0 10

-
.

0 28 .

0 3
-

OH 0
0 10-0 10
.
=
.
,

D 0 3-0 20.
. =0 10

I
.
.

/In
2
H3POn = =
-

He
0 .
20 0 10,

0 4-0 2 0 20
=
.
.
.

0 20-0 20
=

0
&
.
.

# HePOy- APOn2
HPOy
0 20 0 20
0 20
. .

-
20
0
0
0
not buffer