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Chemical Process Industries Course Overview

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26 views5 pages

Chemical Process Industries Course Overview

Uploaded by

rohithelango328
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© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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COIMBATORE INSTITUTE OF TECHNOLOGY

(Government Aided Autonomous Institution Affiliated to Anna University)

Coimbatore - 641 014

DEPARTMENT OF CHEMICAL ENGINEERING

SUBJECT : CHEMICAL PROCESS INDUSTRIES

SUBJECT CODE : 19CH62

FACULTY IN-CHARGE : Dr. P. SIVAKUMAR

Department of Chemical Engineering, CIT, Coimbatore Page 1


COURSE DESCRIPTION

ACADEMIC YEAR : 2023-24


SEMESTER : VI
COURSE / BRANCH : [Link]. Chemical Engineering
NAME OF THE FACULTY : Dr. P. SIVAKUMAR, Assistant Professor
FACULTY ROOM NO : Dept. of Chemical Engineering
LECTURE HOURS : Monday : 11.05 am to 12.00 noon
Wednesday : 09.00 am to 09.55 am
Thursday : 09.55 am to 10.50 am
CONSULTING HOURS : Monday Afternoon
SUBJECT CODE / NAME : 19CH62 / Chemical Process Industries

(i) COURSE OUTCOME

CO1: Identify the contemporary technologies in water treatment and label the process
economics in salt and sulphur based industries.
CO2: Design the production methodology of oil industries and analyse the efficiency of the
products.
CO3: Formulate the chemical processes and economics involved in the carbohydrate
industries.
CO4: Describe the flowsheets of manufacture process of pulp based, leather industries and
engineering problems faced in the industries.
CO5: Evaluate the surface coating & cement industry processes to justify their appropriate
production techniques and their handling processes.

(ii) Once the student has successfully complete this course, he/she must be able to
answer the following questions or perform/demonstrate the following:

1. Students are able to understand the fundamental knowledge in solving the chemical
reactions and technology involved.
2. Students are able to apply the knowledge in solving the problems faced in the chemical
industry.
3. Students are able to improve the design and perform the experiments in small scale;
subsequently to large scale.
4. Students should be able to find the difficulties in interpreting the experimental results and
able to sort it out.
5. Students are able to apply the knowledge in formulating new ideas to be implemented in
chemical technology.
6. Students are able to troubleshoot the problems like design and production of chemicals
and also increasing the yield efficiency.

Department of Chemical Engineering, CIT, Coimbatore Page 2


7. Students are able to understand the recent analytical instruments/equipment available
for the production units.
8. Students are able to understand the safety, health and environmental issues and to sort
out the issues.

(iii) Topic/Unit/Chapter Layout

NITROGEN, PHOSPHOROUS AND SULPHUR BASED INDUSTRIES


Nitrogen, Ammonium nitrate, Ammonium sulphate and Urea. Phosphorus, Phosphoric acid,
Ammonium phosphates, Sodium phosphates, Nitrophosphate& Phosphate esters. Mixed
fertilizers (NPK Mixtures). Manufacture of Sulphur and Sulphuric acid. Materials for handling,
storage and transportation. (11)

OIL AND ALLIED INDUSTRIES


Vegetable oil extraction methods. Refining of vegetable oils. Hydrogenation of Oils. Soaps
and Candle. Detergents and Glycerine. Materials for handling, storage and transportation. (7)

CARBOHYDRATES AND FERMENTATION INDUSTRIES


Manufactureof Starch, Dextrin, Glucose and sucrose and manufacture of Ethyl alcohol, Acetic
acid, Citric acid, Oxalic acid and Antibiotics (Penicillin). Materials for handling, storage and
transportation. (9)

PULP AND LEATHER INDUSTRIES


Production of Pulp. Conversion to paper. Production of Viscose, Acetate and
Cuprammonium rayons and Cellulose [Link] of Dimethyl sulphite and Dimethyl
sulphoxide from wood liquor. Manufacture of leather from hides and skins. Manufacture of Glue
and Gelatin. Materials for handling, storage and transportation. (9)

SURFACE COATING, CEMENT AND GLASS INDUSTRIES


Constituents of paints & varnishes and their functions. Paint mixing process. Manufacture of
pigments such as White lead, Zinc oxide and Titanium dioxide. Cements: Introduction, types of
cements, properties and applications. Manufacture of Portland cement. Beneficiation &
Production of Hydrated lime. Raw materials for Glass Industries. Production of glass by tank
furnace - shaping and forming of articles from glass. (9)
TOTAL : 45
TEXT BOOKS:
1. Gopala Rao, M. & Marshall Sittig. : Dryden's Outlines of Chemical Technology, (3 rd
Ed.), Affiliated East-West Press, New Delhi, (2004).
2. Austin, G.T.: Shreve's Chemical Process Industries, (5th Ed.), McGraw Hill (ISE), (1984).
3. Shukla, S.D. Pandey, G.N. : A Text Book of Chemical Technology, Vol.I, Vikas, New
Delhi, (1994).

REFERENCES:
1. CHEMTECH - III, Chemical Engineering Education Development Centre, I.I.T., Madras,
1977.

Department of Chemical Engineering, CIT, Coimbatore Page 3


2. CHEMTECH - IV, Chemical Engineering Education Development Centre, I.I.T., Madras,
1979.
3. Kent, A.J.: Riegel's Handbook of Industrial Chemistry, Van Nostrand - Reinhold, New
York, (1974).
4. Stephenson, R.M.: Introduction to Chemical Process Industries, Van Nostrand, New
Jersy, (1966).
5. Furnas, C.C.(Editor): Roger's Manual of Industrial Chemistry, Vol. I, (6th Ed.), Van
Nostrand, New Jersy, (1942).

(iv) Evaluation Scheme

Assessment Methods:
Number of Credits :3

Evaluation Scheme
Internal Assessment = 40 Marks
Terminal Examination = 60 Marks
Total = 100 Marks

 Internal Assessments are based on Mid-Sem Tests (2), Assignments (5)

 Mid-Sem Tests are conducted as per the Instructions of the Principal and Head of the
Department organized centrally.

 Assignments as follows:
 Questions on five modules given for assignment
 Each Assignment was evaluated for 20 Marks

 End Semester Examination is conducted by the Controller of Examinations.

Department of Chemical Engineering, CIT, Coimbatore Page 4


(v) a) Weekly Lesson Plan:

Week CONTENTS
Production of Nitrogen, Ammonium nitrate, Ammonium sulphate and
1
Urea
Phosphorus, Phosphoric acid, Ammonium phosphates, Sodium
2
phosphates, Nitrophosphate& Phosphate esters
Mixed fertilizers (NPK Mixtures). Manufacture of Sulphur and Sulphuric
3
acid
Vegetable oil extraction methods.
4
Refining of vegetable oils.
Hydrogenation of Oils.
5
Soaps, Candle
Detergents and Glycerine.
6
Materials for handling, storage and transportation.
Manufacture of Starch, Dextrin,
7
Glucose and sucrose.
8 Manufacture of Ethyl alcohol, Acetic acid and Vinegar
Citric acid, Oxalic acid and Antibiotics (Penicillin).
9
Materials for handling, storage and transportation.
Production of Pulp. Conversion to paper.
10
Production of Viscose, Acetate
Cuprammonium rayons Cellulose acetate.
11 Production of Dimethyl sulphite and Dimethyl sulphoxide from wood
liquor.
Manufacture of leather from hides and skins.
12 Manufacture of Glue and Gelatin.
Materials for handling, storage and transportation.
Paints, Varnishes, Paint mixing process. Manufacture of pigments such
13
as White lead, Zinc oxide and Titanium dioxide.
Cements: Introduction, types of cements, properties and applications.
14
Manufacture of Portland cement.
Beneficiation & Production of Hydrated lime. Raw materials for Glass
15 Industries .Production of glass by tank furnace - shaping and forming of
article from glass.

(vi) Mapping of Course Outcomes with Programme Outcomes:

Cos Program Outcomes/Program Specific Outcomes (Pos/PSOs)


PO1 PO2 PO3 PO4 PO5 PO6 PO7 PO8 PO9 PO10 PO11 PO12 PSO1 PSO2
CO1 2 3 1 1 1
CO2 3 1 1 1 2 1
CO3 3 3 1 2 2 3 2
CO4 1 2 1 1 1 1 1
CO5 3 3 1 1 2 1 3 1

Department of Chemical Engineering, CIT, Coimbatore Page 5

Common questions

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The significance lies in the ability to systematically analyze and address discrepancies in experimental data, ensuring accurate, reliable, and reproducible results. Engineering problem-solving involves identifying key variables, understanding process limitations, and using scientific principles to refine methodologies and equipment. This process is crucial in troubleshooting issues related to chemical yield, reaction efficiency, and scaling, ultimately leading to improved technology and process optimization .

Advancements in analytical instrumentation, such as enhanced chromatographic techniques, mass spectrometry, and spectroscopic methods, increase process control accuracy, allowing for real-time monitoring of chemical reactions. This understanding enables rapid identification of impurities, optimization of reaction conditions, and immediate troubleshooting, directly leading to increased efficiency, reduced waste, and improved product quality .

Refining of vegetable oils involves the removal of impurities such as free fatty acids, phospholipids, pigments, and odoriferous compounds to improve quality and stability. This typically includes degumming, neutralization, bleaching, and deodorization. Hydrogenation, on the other hand, involves the addition of hydrogen to unsaturated fats to convert them into saturated fats, altering the melting point and oxidative stability. While refining improves purity and shelf-life, hydrogenation primarily affects the texture and solidification properties of products, such as margarine, impacting their usability and efficiency in specific applications .

Dimethyl sulfite and dimethyl sulfoxide are both derived from the processing of wood liquor. Dimethyl sulfite is typically produced through the reaction of sulfur dioxide with methanol while dimethyl sulfoxide is obtained through oxidation. Although related, their preparation methods define their distinct functional properties and industrial applications. Dimethyl sulfoxide serves as a solvent with significant penetrative abilities, while dimethyl sulfite has applications in solvent production and as an intermediate in chemical synthesis .

The primary challenges in glass production via a tank furnace include maintaining high temperatures, achieving homogeneous melting, and avoiding defects like bubbles and striae. These challenges are addressed by precise control of temperature zones, including proper insulation and burner design, and employing stirring mechanisms. Additionally, the quality of raw materials and careful control of batch feed rates are crucial to maintain consistent glass quality .

Key engineering considerations include ensuring homogeneity, controlling viscosity, and preventing air entrapment during the mixing process. The choice of mixer, speed, and sequence of ingredient addition are vital to achieve uniform distribution of pigments and other components. These factors are important as they affect the final product’s appearance, consistency, drying characteristics, and application properties, impacting both performance and consumer satisfaction .

Phosphorus is primarily produced through the thermal reduction of phosphate rock, whereas phosphoric acid is obtained via the reaction of the rock with sulfuric acid in the wet process. Ammonium phosphates are synthesized by reacting ammonia with phosphoric acid. The techniques for application include soil direct application for agriculture, providing essential nutrients for plant growth. The production method impacts the purity and reactivity of the compound, crucial for efficient fertilizer formulations and subsequent agricultural yield .

The production of penicillin involves cultivating Penicillium mold in large fermentation tanks under controlled conditions, which integrates biotechnology for optimizing yield and purity. Effective material handling is critical to ensure that nutrients and the mold are mixed uniformly while maintaining sterile conditions to prevent contamination. Automation in feeding, temperature control, and harvesting integrates biochemical processes with robust engineering designs to enhance productivity and scalability in pharmaceutical manufacturing .

Contemporary water treatment technologies include advanced oxidation processes, membrane filtration, and ion exchange systems. These technologies enhance the economic efficiency of salt and sulfur-based industries by ensuring high purity and reducing waste and environmental impact, thereby lowering long-term operational costs. The use of these technologies streamlines production processes and often leads to reduced chemical consumption, which can also minimize the need for disposal of hazardous waste, enhancing overall economic feasibility .

The flowsheet of pulp-based industries involves processes like wood chipping, pulping through chemical or mechanical means, bleaching, and conversion to paper. Engineering challenges include managing energy consumption during pulping, treatment of effluents and emissions, maintaining fiber quality, and reducing environmental impact. Bleaching, for instance, involves handling chemicals that can pose safety hazards and require efficient waste treatment systems to minimize pollution .

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