Diagnostic cum Scholarship Tests

SAMPLE PAPER
For Students of Class XII
Paper 2 Other Engineering Entrance Exam & JEE Main

Duration : 90 minutes
Paper Code: 1112-2 Maximum Marks : 192

Please read the instructions and guidelines carefully :

Important Note : Please ensure to accurately input the details for the Question Paper Code as indicated at the top of this
sheet (Side 2) into the corresponding columns / fields on the OMR sheet before proceeding with the paper. Incorrectly filled
information regarding the class or paper may result in inaccurate outcomes or results.

“This paper has been scientifically designed to evaluate your potential – manifested
and hidden for the target examinations mentioned in various sections of the paper.
Thus, your adherence to the instructions is critical in the evaluation of the same”

1. This Question paper consists of 2 sections.

2. Student should devote allotted time for each section. If a section is easy, then it is easy for everyone & was meant to be like that with
a goal in mind. Do not switch over to another section if you find the section to be easy. If a section is tough, then it is tough for
everyone. You are advised to spend 45 Minutes on Section-I & 45 Minutes on Section-II. Dedicating the required time to finish
each section successfully is essential. Opening the next section before completing the allotted time for the preceding section is
not permitted. This adherence is crucial for assessing your true potential, as each section is meticulously crafted to evaluate
your potential for the corresponding competitive examinations.
3. Candidate should open the seal of Section-II only after devoting 45 minutes on Section-I.
4. Sheets will be given to each candidate for rough work. Candidate must fill all details on the rough sheet and submit the same
to invigilator along with OMR sheet. Candidate must mention the Question No. while doing the rough work in the sheet.
5. Please note candidates are not allowed to bring any prohibited items into the exam hall such as electronic devices, mobile
phones, smart watch, earphones, calculators, books, notes, formula sheets, and bags.
6. Marking scheme is given in table below:

Question Marking Scheme for each question

Section Subject
no. Correct answer Wrong answer

PHYSICS (PART-A) 1 to 4 +4 –1

CHEMISTRY (PART-B) 5 to 8 +4 –1
SECTION – I (Other Engineering
MATHEMATICS (PART-C) 9 to 12 +4 –1
Entrance Exam)
PHYSICS (PART-D) 13 to 16 +4 –1
Time Allotted: 45 Minutes
CHEMISTRY (PART-E) 17 to 20 +4 –1

MATHEMATICS (PART-F) 21 to 24 +4 –1

PHYSICS (PART-A) 25 to 28 +4 –1

CHEMISTRY (PART-B) 29 to 32 +4 –1

SECTION – II (JEE Main) MATHEMATICS (PART-C) 33 to 36 +4 –1

Time Allotted: 45 Minutes PHYSICS (PART-D) 37 to 40 +4 –1

CHEMISTRY (PART-E) 41 to 44 +4 –1

MATHEMATICS (PART-F) 45 to 48 +4 –1

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 Section – I
Time: 45 Minutes

PHYSICS – (PART – A)
This part contains 4 Multiple Choice Questions number 1 to 4. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

1. Find the acceleration of blocks of mass m. Assume pulleys are massless and frictionless.
m

2m

(A) g/3 (B) 2g/3

(C) g/2 (D) g/6
   
2. What is the value of linear velocity, if ω = 3 i - 4jˆ + kˆ and r = 5 i - 6jˆ + 6kˆ ?

(A) 6 i + 2jˆ - 3kˆ (B) -18 ˆi - 13i + 2kˆ
 
(C) 4 i - 13jˆ + 6kˆ (D) 6 i - 2jˆ + 8kˆ

3. There are blocks A and B of masses m and 2 m respectively. These are held at rest such that the
spring is in natural length. Find out the accelerations of both the blocks just after release.

m A B 2m
g g
(A) g , g  (B) , 
3 3
(C) 0,0 (D) g , g 

4. A force ‘F’ is applied at the top of a ring of mass ‘M’ and radius ‘R’
placed on a rough horizontal surface as shown in the figure. Friction F
is sufficient to prevent slipping. The friction force acting on the ring is
F F
(A) towards right (B) towards right
2 3
2F
(C) towards right (D) Zero
3

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CHEMISTRY – (PART – B)
This part contains 4 Multiple Choice Questions number 5 to 8. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

5. For which of the following species, Bohr's theory is not applicable

+3 +2
(A) Be (B) Li
+2
(C) He (D) H

6. 6.02  1020 molecules of urea are present in 200 mL of its solution. The concentration of urea
solution is
(A) 0.001 M (B) 0.01 M
(C) 0.005 M (D) 0.10 M

7. Which one is most stable conformers of n-butane?

CH3
CH3 CH3
H CH3

(A) (B)
H H H
H
H H H
CH3 CH3
H H H

(C) (D)
H H
H CH3
CH3 H H

8 The correct order in which the C–O bond length in CO, CO32 and CO2 is :
(A) CO32  CO2  CO (B) CO 2  CO32  CO
(C) CO  CO32  CO2 (D) CO  CO2  CO32

MATHEMATICS – (PART – C)
This part contains 4 Multiple Choice Questions number 9 to 12. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

9. If a – b, b – c, c – a are in A.P., then the straight line (a –b)x + ( b – c)y +(c –a) = 0 will pass
through
(A) (1, –2) (B) (2, 1)
(C) (2, 3) (D) (3, 1)

10. The equations of the lines representing the sides of a triangle are 3x – 4y = 0, x + y = 0 and
2x – 3y = 7. The line 3x + 2y = 0 always passes through the
(A) incentre (B) centroid
(C) circumcentre (D) orthocentre

11. The range of values of  for which the line 2y = gx +  is a normal to the circle
x2 + y2 + 2gx + 2gy  2 = 0 for all values of g is
(A) [1, ) (B) [1, )
(C) (0, 1) (D) (–, 1]

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12. The circle drawn with variable chord x + ay – 5 = 0 (a being a parameter) of the parabola
2
y =20x as diameter will always touch the line
(A) x + 5 = 0 (B) y + 5 = 0
(C) x + y + 5 = 0 (D) x – y + 5 = 0

PHYSICS – (PART – D)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 13 to 14

We generally ignore the kinetic energy of the moving coil of a spring but consider a spring of
mass M, equilibrium length L and spring constant k. Consider a spring, as described above, that
has one end fixed and the other end moving with speed v. Assume that the speed of points
along the length of the spring varies linearly with distance L from the fixed end. Assume also that
the mass M of the spring is distributed uniformly along the length of the spring. Assume further
that the force applied by the spring is spring constant times its deformation. In a spring gun, such
a spring of mass 0.243 kg and force constant 3200 N/m is compressed 2.50 cm from its
unstretched length. When the trigger is pulled, the spring pushes horizontally the ball of mass of
0.053 kg.

13. Kinetic energy of the spring

1 1
(A) Mv 2 (B) Mv 2
2 6
1
(C) Mv2
2
(D) Mv
4
14. Ball’s speed when the spring reaches its uncompressed length is
(A) 3.9 m/s (B) 6.1 m/s
(C) 14 m/s (D) 1.62 m/s

Comprehension–2 for Q. No. 15 to 16

The minimum and maximum distances of a satellite from the centre of earth are 2R and 4R,
where R is radius of earth. If mass of earth be M:

15. Minimum and maximum speeds of the satellite are:

GM 3 GM GM 2 GM
(A) , (B) ,
5R 2R 6R 3 R
GM 2GM GM 5 GM
(C) , (D) ,
6R R 3R 2R

16. Angular momentum of the satellite about centre of earth:

1/2 1/2
(A)  2 GMm R 2
(B)  4 GMm R 
2

1/2
1/2 8 

(C) 3 GMm2R  (D) 
 3
GMm2R 


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 DST-2425-SAMPLE PAPER-C-XII-(Paper-2)-PCM

CHEMISTRY – (PART – E)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 17 to 18

Vitamin C ( M = 176) is a compound of C, H and O found in many natural source, especially citrus
fruits. When a 1.0 g sample of vitamin C is placed in a combustion chamber and burned, the
following data are obtained
Mass of CO2 absorber after combustion = 85.35 g
Mass of CO2 absorber before combustion = 83.85 g
Mass of H2O absorber after combustion = 37.96 g
Mass of H2O absorber before combustion = 37.55 g

17. What is the percentage of carbon, by wt. in vitamin C?

(A) 66.67% (B) 40.8%
(C) 20% (D) 60%

18. What is the empirical formula of vitamin C?

(A) CH2O (B) C3H4O3
(C) C6H4O6 (D) CHO

Comprehension–2 for Q. No. 19 to 20

In a vessel, the equilibria: N2  g   3H2  g  2NH3  g and N2  g   2H2  g  N2H4  g are

achieved simultaneously. Initially the vessel contains N2 and H2 in molar ratio of 9: 13. The
equilibrium pressure is 7Po in which due to ammonia, the pressure is Po and due to hydrogen,
pressure is 2Po.

19. The value of KP for the reaction: N2  g   3H2  g  2NH3  g is

20Po2
(A) 20 Po2 (B)
3
1 3
(C) (D)
20Po2 20Po2

20. The value of KP for the reaction: N2  g   2H2  g  N2H4  g is

20Po2
(A) 20 Po2 (B)
3
1 3
(C) (D)
20Po2 20Po2

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MATHEMATICS – (PART – F)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 21 to 22

2
For the equation  2x  1  2ax  2x  1  x  4a  1  0
2 2 2 2

21. The values of a which above equation has all roots positive
(A)  ,  1 (B)  1, 2 
(C)  2,   (D) None of these

22. The values of a for which above equation has two positive and two negative roots
(A)  ,  4  (B)  5,  
 1 1 
(C)   ,  (D) None of these
 3 3

Comprehension–2 for Q. No. 23 to 24

Consider a pair of perpendicular straight lines ax 2  3xy  2y 2  5x  5y  c  0.

23. The value of a is

(A) 1 (B) 3
(C) 2 (D) – 2

24. The value of c is

(A) – 3 (B) 3
(C) – 1 (D) 1

Section – II
Time: 45 Minutes

PHYSICS – (PART – A)
This part contains 4 Multiple Choice Questions number 25 to 28. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

25. Two identical spherical masses are kept at some distance as shown.
Potential energy when a mass m is taken from surface of one sphere to m
the other
(A) increases continuously (B) decreases continuously
(C) first increases then decreases (D) first decreases then increases

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26. Two particles, one of mass m and the other of mass 2m, are m 2m
projected horizontally towards each other from the same level 10 m/s 5 m/s
above the ground with velocities 10 m/s and 5 m/s, respectively.
They collide in air and stick to each other. The distance of the 60m
combined mass where they fall from point A is A B
(A) 40 m (B) 20 m
(C) 30 m (D) zero

27. A wheel of radius R rolls on the ground with a uniform velocity v. The relative acceleration of
topmost point of the wheel with respect to the bottom most point is
v2 2v 2
(A) (B)
R R
v2 4v 2
(C) (D)
2R R
28. A cubical block of side L rests on a rough horizontal surface P
with coefficient of friction  . A horizontal force F is applied on F
the block as shown. If the co efficient of friction is sufficiently M L
high so that the block does not slide before toppling, the
minimum force F required to topple the block is
(A) Infinitesimal (B) Mg/4
(C) Mg/2 (D) Mg 1  

CHEMISTRY – (PART – B)
This part contains 4 Multiple Choice Questions number 29 to 32. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

29. For the configuration which rule is violated ?

(A) Aufbau principle (B) (n +  ) Rule
(C) Pauli's Rule (D) Hund's Rule

30. The oxidation state of iodine in H2IO6 is :

(A) +7 (B) –1
(C) +5 (D) +1

31. The mass of Mg3N2 produced if 48 g of Mg metal is reacted with 34 g NH3 gas is
Mg + NH3 → Mg3N2 + H2
(A) (200/3) g (B) (100/3) g
(C) (400/3) g (D) (150/3) g

32. P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3 is an example of :-

(A) Inter molecular Redox reaction (B) Intra molecular Redox reaction
(C) Disproportionation Redox reaction (D) None of these

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MATHEMATICS – (PART – C)
This part contains 4 Multiple Choice Questions number 33 to 36. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

33. If A={x|x 2 = 4}and B={x | x2-5x + 6 = 0}, then A  B

(A) {2, 3} (B) {–2, 3}
(C) {2} (D) {–2, 2, 3}

34. A and B are two sets having 3 and 4 elements respectively and having 2 elements in common.
The number of relations which can be defined from A to B is
(A) 25 (B) 210  1
12
(C) 2  1 (D) none of these
2 2
35. For any real , the maximum value of cos (cos) + sin (sin)
(A) is 1 (B) is 1 + sin21
2
(C) is 1+ cos 1 (D) does not exist

36. If  and  are the roots of the equation x 2  x  11  0 , then the value of
3  3  3 2  23  22  11 is equal to
(A) 33 (B) – 33
(C) 22 (D) – 22

PHYSICS – (PART – D)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 37 to 38

In a container of negligible heat capacity, 200 gm ice at 0oC and 100 gm steam at 100oC are
added to 200 gm of water that has temperature 55oC. Assume no heat is lost to the surroundings
and the pressure in the container is constant 1.0 atm.

37. What is the final temperature of the system?

o o
(A) 48 C (B) 72 C
o o
(C) 94 C (D) 100 C

38. At the final temperature, mass of the total water present in the system, is
(A) 472.6 gm (B) 483.3 gm
(C) 493.6 gm (D) 500 gm

Comprehension–2 for Q. No. 39 to 40

As shown, the same gas is filled at the temperature To in two containers (1 and 2) both at
pressure Po occupying a total volume Vo. The smaller container of volume V1 is maintained at the
same temperature but the gas in bigger containers is heated at temperature 2T0 .

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 DST-2425-SAMPLE PAPER-C-XII-(Paper-2)-PCM

39. Find the pressure of the gas:

P0 V0 4 P0 V0
(A) (B)
V1  V0 3  V1  V0 
2 P0 V0 P0 V0
(C) (D)
 V1  V0  2  V1  V0 

40. Find the ratio of number of moles in the two containers, when smaller container is maintained at
temperature To and other is heated at 2T0 :
2 V0 V0
(A) (B)
 V0  V1   V0  V1 
V1 2V1
(C) (D)
 V0  V1   V0  V1 

CHEMISTRY – (PART – E)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 41 to 42

Double salts are addition compounds which lose their identity in aqueous solution whereas
complexes which are also addition compounds do not lose their identity in aqueous solution. The
coordination compounds show isomerism and find applications in photography, qualitative
analysis, metallurgy, water purification and in the treatment of various diseases.

41. Which of the following statements is incorrect ?

(A) Alum is a double salt.
(B) EDTA salt of calcium is used in the treatment of lead poisoning.
4
(C) Effective atomic number of the metals in complexes Ni  CO 4  and Fe  CN6  is same.
(D) Chloridotris (triphenylphosphine) rhodium(I) is effective heterogeneous catalyst for
hydrogenation of alkenes.

42. Which of the following statements is true for the complex, Co  NH3 4 Br2  NO2 ?
(A) It shows ionisation, linkage and geometrical isomerism.
(B) It does not show optical isomerism because its cis and trans forms each have at least one
plane of symmetry.
(C) Its ionisation isomers cannot be differentiated by silver nitrate solution.
(D) both (A) and (B)

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Comprehension–2 for Q. No. 43 to 44

Co2   aq.  SCN  aq.  Complex  X  .

NH4 OH
Ni2   aq.  Dimethlg yoxime   Complex  Y  .

The coordination number of cobalt and nickel in complexes X and Y are four.

43. The IUPAC names of the complexes (X) and (Y) are respectively :
(A) tetrathiocyanato-S-cobalt(II) and bis(dimethylglyoximate) nickel (II).
(B) tetrathiocyanato-S-cobaltate (II) and bis (dimethylglyoximato) nickel (II).
(C) tetrathiocyanato-S-cobaltate (II) and bis (dimethylglyoximato) nickelate (II).
(D) tetrathiocyanato-S-cobaltate(III) and bis (dimethylglyoximato) nickel (II).

44. The geometry of complexes (X) and (Y) are respectively :

(A) tetrahedral and square planar (B) both tetrahedral
(C) square planar and tetrahedral (D) both square planar

MATHEMATICS – (PART – F)
This part contains TWO (02) comprehensions. Based on each comprehension, there are TWO (02)
questions of Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

Comprehension–1 for Q. No. 45 to 46

To the circle x 2  y 2  4, two tangents are drawn from P  4,0  , which touch the circle at T1 and
T2. A rhombus PT1P' T2 is completed.

45. The circumcenter of triangle PT1T2 is at

(A)  2,0  (B) (2, 0)
(C)  3 / 2,0  (D) None of these

46. The ratio of the area of triangle PT1P’ to that of triangle P'T1T2 is
(A) 2 : 1 (B) 1 : 2
(C) 3 : 2 (D) None of these

Comprehension–2 for Q. No. 47 to 48

1 1
If sin   sin   and cos+cos=
4 3

47. The value of sin      is

24 13
(A) (B)
25 25
12
(C) (D) None of these
13

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48. The value of cos      is

12 7
(A) (B)
25 25
12
(C) (D) None of these
13

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ANSWER KEY
1. B 2. B 3. A 4. D
5. C 6. C 7. C 8. D
9. A 10. D 11. B 12. A
13. B 14. B 15. B 16. D
17. B 18. B 19. C 20. D
21. D 22. C 23. C 24. A
25. C 26. A 27. B 28. C
29. C 30. A 31. A 32. C
33. D 34. D 35. B 36. D
37. D 38. B 39. C 40. D
41. D 42. C 43. B 44. A
45. A 46. D 47. A 48. B

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