0% found this document useful (0 votes)
131 views1 page

Imidacloprid Formulation Overview

Uploaded by

Nopastu
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
131 views1 page

Imidacloprid Formulation Overview

Uploaded by

Nopastu
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Development Formulation CCG0013

Imidacloprid 450 g/L SC


Suspension concentrate containing imidacloprid, a systemic insecticide. Long term
stability is achieved by the use of polymeric surfactants Atlox™ 4913 and Atlox™ 4894.

Product Function g/L % w/w


Imidacloprid (97%) Insecticide 463.92 39.90
(d=1.54 g/cm3)
Atlox™ 49131 Polymeric dispersant 25.00 2.15
Phase A

Atlox™ 48941 Polymeric wetter/dispersant 25.00 2.15


Antifoam Antifoam 1.00 0.09
Proxel GXL2 Biocide 2.00 0.17
Water Continuous phase 580.75 49.95

Xanthan gum3 Rheology modifier 5.00 0.43


Phase B

Propylene glycol Antifreeze 60.00 5.16

Suppliers: 1. Croda 2. Arch Chemicals 3. CP Kelco

Method
1. Mix Phase A ingredients with low shear, then high shear (10,000 rpm, 1 minute). Colloid mill
(Eiger mini-mill 3500rpm, 15 minutes) to form a small particle dispersion.
2. Pre-mix Phase B ingredients to pre-disperse & pre-wet xanthan gum. Then slowly add Phase B
slurry to Phase A with low then high shear mixing (10,000 rpm, 1 minute) to fully homogenise the
xanthan.

Formulation developed for: Global use (exemptions appy)

Results
Appearance: White pourable suspension

Viscosity Particle size


Stability
(100 rpm, spindle 6) d(0.5), d(0.9)
(CIPAC MT 46.1.3)
cP µm
Initial STABLE 1770 -
28 days 54 °C STABLE 1770 10.4, -

This formulation has been developed by our dedicated Crop Care formulation team to illustrate how
our ingredients can be used. We hope this formulation is useful to you but we’d also love to talk to you
if this formulation does not meet all of your needs - please click here or contact your Croda
representative.
Non-warranty
The information in this publication is believed to be accurate and is given in good faith, but no representation or warranty as to its completeness or accuracy is made. Suggestions for uses or applications
are only opinions. Users are responsible for determining the suitability of these products for their own particular purpose. No representation or warranty, expressed or implied, is made with respect to
information or products including, without limitation, warranties of merchantability, fitness for a particular purpose, non-infringement of any third party patent or other intellectual property rights including,
without limit, copyright, trademark and designs. Any trademarks identified herein are trademarks of the Croda group of companies.
©2019 Croda Group of Companies

Innovation you can build on™


04/19 CCG0013 v2

Common questions

Powered by AI

Potential environmental impacts for the global use of this formulation include the risk of toxicity to non-target species due to imidacloprid, which is a systemic insecticide known for environmental persistence. The use of polymeric surfactants, while aiding stability, may also contribute to bioaccumulation and ecological disruption if not managed correctly. Consideration of local environmental regulations and eco-toxicological assessments is crucial to mitigate adverse effects .

Particle size of imidacloprid directly influences its surface area to volume ratio, affecting its dissolution rate and, subsequently, its bioavailability and efficacy. Smaller particles can lead to more uniform application and faster action, while larger particles may settle more quickly, compromising long-term stability. Therefore, maintaining the specified particle size is critical for ensuring consistent performance and effectiveness of the insecticide .

Employing both low and high shear mixing is important to ensure thorough dispersion and homogenization of ingredients. Low shear mixing helps to avoid creating air bubbles and provides initial combining of components, while high shear mixing breaks down any remaining agglomerates, ensuring a uniform and stable suspension. This dual approach maximizes the effectiveness of each ingredient in the formulation .

Using water as a continuous phase benefits the formulation by serving as a solvent and medium for dispersing the active ingredients and other components. It aids in achieving the desired viscosity and homogeneity, facilitating easier application and uptake of the insecticide by plants. Additionally, water's inert properties minimize negative interactions with other formulation components .

Using proprietary trademarks like Atlox™ implies that the formulation relies on unique, possibly patented components, which can offer competitive advantages such as enhanced performance and stability. However, it also restricts the ability of others to replicate the formulation without proper licensing, protecting the intellectual property of the developers but possibly impacting cost and accessibility .

The addition of propylene glycol as an antifreeze component is beneficial as it lowers the freezing point of the suspension, helping to maintain its liquid state in cold conditions. This prevents crystallization of the active ingredients, ensuring consistent delivery and efficacy of the insecticide across diverse environmental conditions .

Using a biocide like Proxel GXL2 is vital for preventing microbial growth in the formulation, which could otherwise lead to spoilage, separation, and degradation of the active ingredients. It helps in maintaining product integrity, prolonging shelf life, and ensuring that the suspension remains effective and safe for use over extended periods .

Potential challenges with using xanthan gum as a rheology modifier include the possibility of forming lumps if not properly pre-wetted before incorporation, which can lead to an uneven distribution of viscosity. Additionally, its behavior under various shear rates can affect the flow properties of the final suspension, which might require careful control during the homogenization phase .

Atlox™ 4913 and Atlox™ 4894 function as polymeric dispersant and wetter/dispersant, respectively. They are crucial because they help to evenly distribute the imidacloprid particles throughout the suspension, preventing settling and ensuring that the active ingredient remains effective over time. This also supports the long-term stability of the suspension .

The long-term stability of the imidacloprid suspension concentrate is enhanced by using polymeric surfactants Atlox™ 4913 and Atlox™ 4894. These surfactants function as dispersants, reducing particle agglomeration and maintaining a consistent suspension. This ensures the formulation remains stable under varying conditions .

You might also like