40 IN-CHAPTER EXERCISES
SOLUTIONS
Module - 1 / JEE-2022
Chemistry Chapter - 1 Stoichiometry - I
EXERCISE-A
g 24
1. (a) gm-atoms = gm-atoms in 24 gm Mg 1
A 24
62
(b) gm-atoms in 62 gm P4 2
31
196 196
(c) H3PO4 n-factor 3 moles 2 and gm eq 6
98 98/ 3
196
(d) Ca(OH)2 n-factor = 2 moles = 2.65 and gm-eq = n-factor moles = 2 2.65 = 5.30
74
(e) 1 mol Na2CO3 Mo gm = 106 gm
16 1 1
(f) moles of SO2 = No. of Molecules = moles No = 6.02 1023 1.5 1023
64 4 4
(g) Mo H2O 18 gm Mass of 6.02 1023 H2O molecules Mass of 1 H2O molecule = 3 10–23 gm
g CO2
2.(C) No. of CO2 molecules = 1021 = 6.02 1023 g CO2 removed = 73.3 mg
44
mass of CO2 left = 200 – 73.3 = 126.7 mg 0.126 gm
60 60 1 4
3.(A) Volume of 1 mol atoms = cm3 Vol. of 1 atm 23
r 3 1.0 10 23 cm3
10 10 6.02 10 3
4. (i) (B) Let weight of compound = 100 gm
A 50 gm 50 /10 moles 5 2
Simplest Ratio A 2 B
B 50 gm 50 / 20 moles 2.5 1
0.0018
(ii) (A) Let density of H2O 1 gm/ml gm in drop of H2O = 1 0.0018 gm moles 104
18
molecules of H2O = 6.02 1023 10–4 = 6.02 1019
(iii) (B) (a) gm of N2 = 7 2 = 14 (c) 1 moles S 32 gm
3 1023
(b) gm of C = 12 6 (d) 7 gm Ag
6 1023
Chemistry [JEE-2022/Module - 1]
IN-CHAPTER EXERCISES 41
EXERCISE-B
1000 2000
1. (a) Sugar C12H22O11 342 gm moles of sugar (nB) = ; moles of H2O (nA) =
342 18
nB
sugar (B) 0.0256 ; A 1 B 0.974
nA nB
gB 1000
% of sugar (by mass) = 33.3% % of H 2 O(by mass) 66.7%
gA gB 1000 2000
x 750 x / 95
(b) n MgCl2 (B) ; n H 2O (A) kg m MgCl2 1.05 x 74.8gm
95 1000 0.75
49 1
2.(C) g H 2SO 4 49gm n H2SO4 ; V 1Lt gsolution 1000 1.049 1049gm
98 2
g H 2O 1049 49 1000 gm
1/ 2 1 1 1/ 2 1
M H 2SO 4 ; N H 2SO4 2 1 ; m H 2SO4
1 2 2 1 2
3. (a) x% by mass
x g of solute in 100 g solution
(100–x) = mass of solvent
x
M0 1000x
1000 m
100 x (100 x)M 0
x
M0 10xd
1000 M M
d M0
(b) x% volume
xg of solute in 100 mL of solution.
x x
M0 1000x M0 x
1000 m ; 1000 M 10 M
100 M0 (100d x) 100 M0
4. (a) Let the volume of solution = 1L moles of solute = 1 mol
1
m 0.8 g A 1250, g B 1 85 85gm M NaNO 85gm / mole
g A /1000 3
1335
gsolution 1250 85 1335gm dsolution 1.33 g / cm3
1000
29.2 / 58.5
(b) n NaCl 0.5 [Cl ] 0.5M (in 1 lit) [Note : 2.92 gm NaCl in 100 ml. So, 29.2 gm NaCl in 1000 ml]
1
Ba 2 2Cl 2x 0.5 x 0.25M
BaCl2
xM 2xM
n BaCl2 0.25
Let ‘n’ be moles of BaCl2 0.25 n BaCl 2 g BaCl2 n BaCl2 208.5 gm 12.75gm
1/ 4 4
[JEE-2022/Module - 1] Chemistry
42 IN-CHAPTER EXERCISES
10 xd 10 x 1.2
5. (i) M 3 x 39.5%
Mo 158
(ii) Let the volume of solution is 1L g H2 O 1200 474 726 g
3
Na 2S2O3 0.069
726
3
18
3
(iii) m Na 2S2 O3 4.13 m 2 4.13 8.26 and m 4.13 2Na S2O32
Na 2S2 O3
726 /1000 Na S2 O32
6. (i) (A) Moles HCl req = 0.2 2 = 0.4 (n-factor HCl = 1) [Moles = Molarity × Volume of Solution (in L)]
(a) Moles HCl = 0.5 0.5 + 0.1 1.5 = 0.4 (b) Moles HCl = 0.5 1.5 + 0.1 0.5 = 0.8
(c) Moles HCl = 0.5 1 + 0.1 1 = 0.6 (d) Total volume = 2L ; Moles HCl = 0.5 0.75 + 0.1 1.25 = 0.45
(ii) ( B) Let volume of solution = 1L gsolution 1000 1.0585 1058.5 gm
1
g B 1 1 58.5 58.5 gm g A 1058.5 58.5 1000 gm m 1
1000 /1000
(iii) (D) mmoles HCl (from 0.2 mol HCl) 200 ; mmoles BaCl2 100
mmoles Cl 200 mmoles Cl 200 Ba 2 2 Cl ]
[BaCl 2
400 /1000
[Cl ] 0.8M
500 /1000
(iv) (D) Na 2SO 4 .nH 2 O Na 2SO 4 n H 2 O
100 55.9
(100gm) moles (55.9gm) moles
142 18n 18
100n 55.9
1mol Na 2SO4 .nH 2 O n mol H 2 O n = 10
142 18n 18
10xd 10 90 1.8
(v) (C) M H 2SO4 16.5 16.5 V 0.2 1 [M1V1 M 2 V2 ] V 12 ml
Mo 98
(vi) (AB) Molarity and Normality depends on the volume of solution (“T” dependent).
1
(vii) (C) M1 V2 = M2 V2 M 2 0.2 2 10 4 N 2 2 2 10 4 4 10 4 N
1000
B 1000
(viii) (D) Use : m B = 0.051 [MA = 18 gm / mole]
1 B MA
(ix) (D) Use : A Avg. Xi Ai 63.546 x 63 1 x 65 x 0.727
Chemistry [JEE-2022/Module - 1]
IN-CHAPTER EXERCISES 43
EXERCISE-C
1
1. (a) Ag 2 CO3 2Ag(s) CO 2 (g) O2 (g) [Residue = Ag]
2
2.76
0.01 moles of Ag 2 CO3 gm of Ag = (2 × 0.01) 108 = 2.16 gm
276
(b) K 2SO 4 BaCl2
BaSO 4 2 KCl
5 /174 10 1.2 10
M K 2SO4 ; Moles BaSO4 Moles K 2SO4 V V 44.7 ml
1/ 4 87 233 87
(c) Ca(HCO3 ) 2
CaO 2CO 2 H 2 O
1
Moles Ca(HCO3)2 = 2 Moles CO2 = 2 2 = 4 % yield CO2 = 25%
4
(d) NaHCO3 Na HCO3 n-factor = 1 E NaHCO3 84 /1 84
SO2 H2SO3 n -factor = 2 ESO2 64 / 2 32
1
2. (i) (D) H 2 O 2
H2O
2
Initial moles 3 1.5 – Both gets consumed completely (H2 and O2)
Final moles – – 3
(ii) (C) 4I Hg 2
HgI 24
Initial moles 1 1 I– is the limiting reactant
1 1
Final moles – 1 0.25
4 4
(iii) (A) 2H 2 O( ) O 2 (g)
2H 2 O 2 (aq)
3L
3 1 1
Moles O2 = moles H2O2 Moles H2O2 = 0.1 X X 2.5M
24 2 4
10 10 4
(iv) (A) 10 gm X4O6 = moles gm X = X 5.72 X = 32 amu
4X 96 4X 96
(v) (B) 1 mole of Mg3(PO4)2 8 mole of Oxygen atoms.
1 1
1/4 mole of oxygen atoms mole of Mg3(PO4)2
8 4
= 3.125 × 10–2 mole of magnesium phosphate.
Heating
(vi) (A) BaCl 2 . xH 2 O
BaCl2 xH 2 O
(1.763gm) (1.505 gm)
1 mole of BaCl2.xH2O 1 mole of BaCl2
1.763 1.505
mole of BaCl2.xH2O = mole of BaCl2 (given)
209 18x 209
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44 IN-CHAPTER EXERCISES
1.763 1.505
x2
209 18x 209
(vii) (B) Zn I 2
ZnI 2
Let ‘g’ grams of Zn & I2 were taken initially.
g g g g g 189g
moles of Zn moles of I 2 moles of Zn left =
65 2 127 254 65 254 65 254
189 g
65 254
fraction of Zn left = 0.74
g
65
4Ca 5 (PO 4 )3 F 18SiO 2 30C
3P4 2CaF2 18CaSiO3 30CO
(viii) (A) 0.1 moles 0.36 moles 0.9 moles
Initially
Using mole concept :
4 moles of Ca5(PO4)3F 18 moles of SiO2 30 moles of C 3 moles of P4
Here : SiO2 is limiting reagent.
So : moles of P4 formed = 3 0.36 0.06
18
(ix) (A) 3
Al Cl 2 AlCl3
2
1 mole of Al 1 mole of AlCl3
6.67
moles of AlCl3 produced = 0.05 moles of Al reacted = 0.05
133.5
0.54
Total moles of Al taken = 0.05 = 0.07
27
3
(x) (A) KClO3 KCl O2
2
1 mole (given) 1 mole 3 / 2 moles
3
2Al O 2 Al2 O3
2
2 moles 3 / 2 moles 1 mole
EXERCISE-D
3 3
1. (a) SHCl 3g / L N HCl Meq HCl 2.5
36.5/1 36.5/1
4000 10 3
Meq Al(OH)3 x Meq HCl [x = No. of tablets] x ~ 14
78 / 3
10xd 10 1.85 1.025
(b) N Ca(OH) 2 0.51
E 74 / 2
Meq Ca(OH)2 = Meq HCl 0.51 25 = (0.1 1) VHCl VHCl = 127.5 ml
(c) Meq NaOH = 0.1 40 = 4 = Meq H3PO4 (in 25 ml)
Chemistry [JEE-2022/Module - 1]
IN-CHAPTER EXERCISES 45
250 g 1.32
Meq H3PO4 = 4 40 1000 g H3PO4 1.32 d g / cm3
25 98/ 3 1
1 5
(d) Meq NaOH = 25 = Meq oxalic acid in 16.68 ml.
15 3
5 250 1.575
Meq oxalic acid in 250 ml = 1000
3 16.68 M o / 2
Mo = 126 = 18n + 90 n=2 H2C2O4.2H2O
1 0.84
(e) Meq H2SO4 = 40 20 = Meq carbonate = 1000 E 42
2 E
2.24 100
(f) Moles NH3 = 0.1 Meq NH3 ( NH 4OH) Meq H 2SO4 (M H2SO 4 2)
22.4 1000
MH2SO4 0.5M
2. Meq acids = Meq HCl + Meq H2SO4 = (1 2) × 500 + (2 2) 100 = 1400
Meq base = (1000 1) = 1000 Meq acidleft = 1400 – 400 (in 600 ml)
30 143
Meq acidleft in 30 ml = 400 20 Meq Na 2 CO3 .xH 2O 20
600 E( M o / 2)
Thus, Mo = 286 = 106 + 8x x = 10
250ml 25ml N 1
NaCl Na 2 CO3 50 ml, HCl 50 5 meq HCl
3.
4gm
10 10
Thus, Meq Na2CO3 in 25 ml = 5 [As HCl doesn’t react with NaCl]
g
Meq Na2CO3 in 250 ml = 50 = 1000 g Na 2CO3 2.65gm
106 / 2
2.65
% Na 2CO3 100 66.25% and % NaCl 33.75%
4
Meq HCl 0.1 100 10
4. (i) (D) In 30 ml Meq HCl left = 10 – 6 = 4 = Meq KOH = 0.25 VKOH VKOH = 16 ml
Meq NaOH 0.2 30 6
Meq H 2SO 4 (2 0.2) 100 40 20
(ii) (B) Meq H2SO4 left = 40 – 20 = 20 [H ] 0.1N
Meq NaOH (1 0.2) 100 20 100 100
(iii) (C) Meq HCl = (1 x) 20 = 20x
Meq NaHCO3 + Meq Na2CO3 = (0.1 1) 10 + (0.2 2) 5 = 3 20x = 3 x = 0.15 M
[JEE-2022/Module - 1] Chemistry
46 IN-CHAPTER EXERCISES
MISCELLANEOUS EXERCISE
2.
3.
4.(B)
5.(B)
Chemistry Mathematics
[JEE-2022/Module - 1]
IN-CHAPTER EXERCISES 47
6.(A)
7.(D)
8.(A)
9.(D)
10.(B)
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48 IN-CHAPTER EXERCISES
Chemistry Mathematics
[JEE-2022/Module - 1]
IN-CHAPTER EXERCISES 49
21.(A)
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