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S.3 Chemistry Titration Exam Paper

The document provides instructions for an end of term chemistry exam involving finding the concentration of an unknown sodium hydroxide solution through acid-base titration. Students are given hydrochloric acid and told to titrate sodium hydroxide and record their results to calculate the concentration of the sodium hydroxide solution.

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0% found this document useful (0 votes)
10 views2 pages

S.3 Chemistry Titration Exam Paper

The document provides instructions for an end of term chemistry exam involving finding the concentration of an unknown sodium hydroxide solution through acid-base titration. Students are given hydrochloric acid and told to titrate sodium hydroxide and record their results to calculate the concentration of the sodium hydroxide solution.

Uploaded by

akram kats
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

END OF TERM 1 EXAMINATIONS 2018

S.3 CHEMISTRY PAPER 3

TIME: 1HOUR

INSTRUCTIONS

Attempt ALL questions in the spaces provided on this piece of paper. Keep your work tidy

You are provided with the following solutions;

BA1 which is a 0.1M hydrochloric acid

BA2 which is sodium hydroxide of unknown concentration

You are required to find the concentration of sodium hydroxide solution

Sodium hydroxide reacts with hydrochloric acid according to the equation below

NaOH(aq) + HCl(aq) NaCl(aq) + H2O(l)

PROCEDURE

Fill the burette with BA1. Pipette 20 or 25cm3 of BA2 into a clean conical flask and add 2-3 drops
of phenolphthalein indicator. Titrate with BA1 till the solution just turns colourless. Record the
volume of BA1 used in the table below. Repeat the procedure to get consistent values and record
all your results in the table below.

RESULTS

Volume of pipette used =………………………………cm3

Experimental number 1 2 3

Final burette readings (cm3)

Initial burette reading (cm3)

Volume of BA1 used (cm3)


Titre values used to find the average volume of BA1

............................................................................................................................................................
............................................................................................................................................................

Average volume of BA1

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Questions

a) Calculate the number of moles of;


(i) hydrochloric acid that react
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
(ii) Sodium hydroxide that react
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
b) Find the concentration of sodium hydroxide in;
i. Moles per litre (molarity)
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
ii. Grams per litre (Na=23, O=16, H=1)
....................................................................................................................................
....................................................................................................................................
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...................................................................................................................................

END

Common questions

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To calculate the moles of hydrochloric acid used, multiply the volume of BA1 used in the titration (in liters) by its concentration (0.1M). For example, if 25 cm³ (0.025 L) of BA1 is used, the moles of HCl would be 0.1 mol/L * 0.025 L = 0.0025 mol .

Consistent titre values are crucial for ensuring the reliability and accuracy of the titration results. They indicate that the procedure has been performed uniformly, which allows for a reliable calculation of the average volume necessary for neutralization. This consistency reduces random errors and increases confidence in the calculated concentration of the unknown solution .

Accurate recording of initial and final burette readings is essential in a titration experiment as it directly affects the calculation of the volume of titrant used. Any errors in these readings lead to incorrect determination of the titre volume, leading to significant errors in the concentration calculations and overall results .

First, calculate the moles of hydrochloric acid: 0.1 mol/L * 0.030 L = 0.003 mol. This is the same number of moles for NaOH due to the 1:1 reaction ratio. To find the concentration in grams per liter (g/L), calculate the mass of NaOH in 0.003 mol: (23+16+1) g/mol * 0.003 mol = 0.12 g. Assuming the volume of NaOH solution used is 20 cm³ (0.02 L), its concentration in g/L is 0.12 g / 0.02 L = 6 g/L .

Using different pipette volumes for BA2 affects the final concentration calculation as it alters the ratio of reacted solutions. If a larger or smaller volume than intended is used, it changes the basis for calculating moles of NaOH since the volume directly impacts the moles via the concentration relation. It is crucial to maintain consistent pipette volumes or adjust calculations accordingly to ensure accuracy in determining the concentration of sodium hydroxide .

The titration method finds the concentration of sodium hydroxide by reacting it with a known concentration of hydrochloric acid (BA1). By measuring the volume of BA1 needed to neutralize a known volume of BA2 (NaOH solution), the number of moles of NaOH can be deduced. Given the 1:1 mole ratio from the reaction equation, the concentration of NaOH in moles per liter can be calculated using the formula: \( \text{Molarity of NaOH} = \frac{\text{moles of HCl}}{\text{volume of NaOH in liters}} \).

The stoichiometric relationship between NaOH and HCl in the titration procedure is a 1:1 molar ratio as indicated by the balanced chemical equation: NaOH(aq) + HCl(aq) -> NaCl(aq) + H2O(l). This means one mole of sodium hydroxide reacts with one mole of hydrochloric acid .

Dilution of BA2 solution affects titration results by reducing its concentration, meaning a larger volume of BA1 would be required to reach the endpoint. The decrease in concentration due to dilution would lead to overestimation in calculating the concentration if this factor is not accounted for. Calculations must be adjusted to reflect the actual concentration in the undiluted solution .

Phenolphthalein is used as an acid-base indicator in the titration process. It is colorless in acidic solutions and turns pink in basic solutions. The endpoint of the titration is reached when the solution changes from pink to colorless, indicating that all the sodium hydroxide has reacted with the hydrochloric acid .

Experimental errors in titration can include misreading volumes due to the meniscus, inconsistencies in endpoint detection due to subjective color change perception, and contamination of reagents. These can be minimized by ensuring proper calibration of equipment, using a white background for clear meniscus reading, consistently practicing endpoint detection, and thoroughly cleaning all apparatus before use .

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