Class: XI

CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
1. For the reaction P(white) → P(red) ∆H = -18.4 KJ, it follows that;
A. P red cannot be converted into P white D. P white cannot be converted to P red
B. P red is more stable E. both a & b
C. P white is more stable
2. CO + ½ O2 → CO2, heat energy change of this chemical reaction is known as;
A. Heat of formation D. Heat of sublimation
B. Heat of combustion E. Heat of vaporization
C. Heat of reaction
3. For which of the following reaction ∆H = ∆E?
A. PCl3 + Cl2 ⇌ PCl5 D. 2NO + O2 ⇌ 2NO2
B. CO + ½ O2 ⇌ CO2 E. N2 + 3H2 ⇌ 2NH3
C. ½ H2 + ½ I2 ⇌ HI
4. Enthalpy change for the reaction PCl5 ⇌P + Cl2 is 287KJ/mole & for another
reaction PCl3 + Cl2 ⇌ PCl5 is --137KJ/mole. What is ∆H for formation of
PCl3.
A. 150 KJ/mol D. -424 KJ/mol
B. 424 KJ/mol E. -287 KJ/mol
C. -150 KJ/mol
5. Heat of formation for the reaction H2 + Cl2 → 2HCl ∆H = 44 [Link] is:
A. 44 [Link] D. -22 [Link]
B. -44 [Link] E. 88 [Link]
C. 22 [Link]
6. The standard heat of combustion of C is -94.0 [Link]. Hence the heat of
formation of CO2 will be:
A. 94.0 D. -47.0
B. -94.0 E. None of These
C. 47.0
7. Which properties of the following are intensive?
i. Entropy
ii. Enthalpy
iii. Vapour pressure
iv. Density
A. I, II, III D. III, IV
B. I, III, IV E. III, V
C. II, III, V
8. Incorrect statement of the following is:
A. Total energy of system & surrounding remains same
B. Work is a state function.
C. Enthalpy is a state function
D. 1 calorie = 4.18J
E. Concentration is an intensive property
9. If C + O2 → CO2 ∆H = R & CO + ½ O2 → CO2 ∆H = S, then the heat of formation of
CO is:
A. R + S D. SR
B. R – S E. S/R
C. S – R
10. The heat change for the process H2O(l) ⇌H2O(g) is called as;
A. Heat of fusion D. Heat of combustion
B. Heat of reaction E. Heat of vaporization
C. Heat of formation
11. Relation between enthalpy change & change in internal energy at constant
pressure is given by:
A. ∆ = ∆ + ∆ D. ∆ + ∆ = ∆
B. ∆ − ∆ = ∆ E. None of These
C. ∆ = ∆ + ∆
12. If 790J of heat is given off by the system. Piston moves downward doing work
of 470J. Change in internal energy is:
A. 320J
D. -1260J
B. -320J
E. -300J
C. 1260J

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
13. If the heats of combustion of glucose(C6H12O6), carbon and hydrogen are -5000,
- 394 and – 286 KJ/mol respectively. Heat of formation of glucose is?
A. -920KJ/mol D. 800KJ/mol
B. 920KJ/mol E. None of These
C. -800KJ/mol
14. A mixture of two moles of CO & one mole of O2 is ignited in a closed vessel to
convert into CO2. If ∆ is enthalpy change & ∆ is the change in internal energy,
then;
A. ∆ < ∆ D. ∆ = 0 but ∆ ≠ 0
B. ∆ > ∆ E. ∆ ≠ 0 but ∆ = 0
C. ∆ = ∆
15. At constant temperature & pressure which one of the following is correct for
the reaction? CO + ½ O2 → CO2.
A. ∆ < ∆ D. ∆ ≠ 0 but ∆ = 0
B. ∆ > ∆ E. ∆ = 0 but ∆ ≠ 0
C. ∆ = ∆
16. Given that ½ S8 + 6O2→ 4SO3 ∆H = -1600KJ/mol. The enthalpy of formation of
SO3 is;
A. -1590 KJ/mol D. -397.5 KJ/mol
B. 1590 KJ/mol E. 400 KJ/mol
C. -400 KJ/mol
17. 3g of C on combustion produce 90KJ of heat. Heat of combustion of C is?
A. 90KJ D. -360KJ
B. -90KJ E. 180KJ
C. -180KJ
18. The heat of combustion of C2H4, C2H6 & H2 are -1409.5KJ, -1558.3KJ & -285.6KJ
respectively. The heat of hydrogenation of ethene is? C2H4 + H2 ⇌ C2H6
A. 136.8KJ D. -1.368KJ
B. 273.6KJ E. 13.68KJ
C. -136.8KJ
19. If the heats of combustion of C, S & CS2 are -395KJ, -295KJ & -1110KJ
respectively. The heat of formation of CS2 is?
A. 125KJ D. 250KJ
B. 31.25KJ E. 420KJ
C. -125KJ
20. Heat of formation H2O(l) is -285.9 KJ/mol & that for H2O(g) is -242.8 KJ/mol. The
heat of vaporization of water is?
A. 43.1 KJ/mol D. -242.8 KJ/mol
B. -43.1 KJ/mol E. 285.9 KJ/mol
C. 242.8 KJ/mol
21. According to Hess’s Law heat changes in a reaction depends upon:
A. Initial condition of reaction D. Steps of reaction
B. Final condition of reaction E. Both A & B
C. Path of reaction
22. Formation of H2O from H2(g) & O2(g) is an exothermic reaction hence;
A. H2(g) & O2(g) have higher chemical energy than H2O
B. H2(g) & O2(g) have lower chemical energy than H2O
C. H2(g) & O2(g) have higher temperature than H2O
D. H2(g) & O2(g) have lower temperature than H2O
E. None of These
23. The heat changes in a chemical reaction depends upon:
A. Amount of substances
B. Physical state of substances
C. Temperature
D. Conditions of reaction either constant pressure or constant volume
E. All of These
24. Which one is not a state function?
A. Internal energy D. Pressure
B. Temperature E. None of These
C. Volume

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
25. Which one is correct order?
A. 1Cal > 1J > 1erg D. 1Cal > 1erg > 1J
B. 1J > 1Cal > 1erg E. 1J > 1erg > 1Cal
C. 1erg > 1Cal > 1J
26. Enthalpy changes for certain reactions are as; +286KJ, -300KJ, +780KJ, -890KJ
& 890KJ. Which value for enthalpy change gives product of highest stability?
A. +286KJ D. -890KJ
B. -300KJ E. 890KJ
C. +780KJ
27. Enthalpy for reaction H2O2 → H2O + ½ O2 is 38.5KJ/mole. Enthalpy of formation
of H2O is -94KJ/mole. The enthalpy of formation of H2O2 is:
A. 132.5 KJ/mol D. -55.5 KJ/mol
B. 55.5 KJ/mol E. -85.5 KJ/mol
C. -132.5 KJ/mol
28. Incorrect statement of following is;
A. Enthalpy change for exothermic reaction is –Ve
B. Mostly exothermic reactions are spontaneous
C. In endothermic reaction product is less stable
D. Gibb’s free energy is an extensive property
E. None of These
29. 500J of work is done on a system which gives off 200J of heat. What is ∆ ?
A. -300J D. -700J
B. 300J E. 250J
C. 700J
30. If the enthalpies of formation of NO & NO2 are 80KJ & 120 KJ, then the enthalpy
change for reaction;
2NO + O2⇌2NO2
A. 40 KJ D. -40 KJ
B. 80 KJ E. -80 KJ
C. 200 KJ
31. Enthalpy change of a reaction is independent of:
A. Conditions of a reaction D. No: of steps in the reactions
B. Initial & final concentration E. Temperature
C. Physical state of reactants
32. H2+Cl2⇌2HCl ∆H= 44 [Link]-mol-1. Heat of formation of HCl is
A. -44 D. 22
B. 44 E. None of These
C. -22
33. Heats of combustion of C, H2 & CH4 are -394, -286, -890 KJ/mol respectively.
The heat of formation of CH4 is.
A. -76 D. 76
B. 210 E. -149
C. -210
34. For which of the following reactions ∆E=q?
A. PCl5⇌PCl3 + Cl2 D. 2CO+O2 ⇌ 2CO2
B. 2HI⇌ H2 + I2 E. 2NO2+O2 ⇌ 2NO2
C. 2SO2+O2⇌ 2SO3
35. Which statement of the following is incorrect?
A. All combustion reactions are exothermic.
B. In exothermic reaction reactant is less stable than product
C. Change in enthalpy is a state function
D. Heat of fusion of ice is positive
E. None of These
36. Standard heat of combustion of carbon is -94.0 [Link]-1. Hence the heat of
formation of CO2 will be?
A. -94.0 D. 94.0
B. -47.0 E. 47.0
C. -188.0
37. Which one is incorrect relation?
A. ∆E = q-w D. qv = ∆E

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
B. q = ∆E +P∆ V E. None of These
C. ∆E = ∆H- P∆ V
38. In the combustion of 4g of CH4 2.5 [Link] of heat is liberated. The heat of
combustion of CH4 is:
A. 20 [Link] D. 2.5 [Link]
B. 16 [Link] E. 4 [Link]
C. 10 [Link]
39. The enthalpy of formation of HI is 30.4 KJ/mol. From this information, state
which of the following statement is false.
A. Reaction is endothermic
B. For the reaction H2+I2 ⇌ 2HI ∆H=60.8 K.J
C. HI is more stable than either reactants
D. H2 & I2 are less stable than HI.
E. Both C & D
40. 88 K.J of heat is given off by the surrounding at constant volume. Change in
internal energy would be?
A. -44 KJ D. 88 KJ
B. 44 KJ E. No change in internal energy
C. -88 KJ
41. Which one of the following does not depend upon condition of the system.
A. E D. H
B. P E. None of These
C. V
42. The enthalpy of formation & combustion of CO is -174 & -148 KJ/mole
respectively. The heat of combustion of C is?
A. -322 D. 322
B. -26 E. -200
C. 26
43. Intensive property among following is?
A. Enthalpy D. Gibb’s free energy
B. Entropy E. Temperature
C. Internal energy
44. The enthalpies of formation of N2O & NO are 82 & 90 KJ/mole. The enthalpy of
reaction 2N2O+O2 4NO is:
A. 196 D. -16
B. 148 E. 8
C. 88
45. If ∆H1 is the enthalpy for reaction H2+½O2 H2O(g) & ∆H2 is the
enthalpy for reaction H2+½O2 H2O(l) then,
A. ∆H1 > ∆H2 D. ∆H1 + ∆H2 = 0
B. ∆H1 < ∆H2 E. None of These
C. ∆H1 = ∆H2
46. Which of the following value of ∆H represents that the product is least stable?
A. -231.6 [Link] D. +21.4 [Link]
B. +64.8 [Link] E. +88.0 [Link]
C. -94.0 [Link]
47. The heat of combustion of C is 394 [Link]-. The heat evolved in combustion of
6.02x1023 atoms of carbon is
A. 3940 KJ D. 3.94 KJ
B. 394 KJ E. 0.394 KJ
C. 39.4 KJ
48. According to Hess’s law of constant heat of summation heat change in a
reaction depends upon:
A. Initial condition of reaction D. Both a & b
B. Final condition of reaction E. None of These
C. No: of steps of reaction
49. If the change in enthalpy for reaction 2P +3/2Cl2 → 2PCl3 is -158 KJ/mole &
change in enthalpy for reaction PCl3+Cl2 ⇌ PCl5 is -78 KJ/mole. Then the heat of
formation of PCl5 is:
A. -157 KJ/mole D. 80 KJ/mole

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
B. -236 KJ/mole E. -193 KJ/mole
C. -80 KJ/mole
50. Certain amount of heat is absorbed by the system due to which piston moves
upward performing a work of 398J & change in internal energy is 300J. The
heat given to system is:
A. -98J D. -698J
B. 98J E. None of These
C. 698J
51. When heat is given to a system at constant volume:
A. Work is done by the system. D. Both a & c.
B. Work is done by the surrounding. E. No work is done.
C. Work is done on the surrounding.
52. Which pair of the following properties are either intensive or extensive
properties?
A. Concentration, density D. Temperature, volume
B. Viscosity, mass E. Both a & c
C. Melting point, pressure
53. If a gas absorbs 200J of heat & expands by 5x10-4 m3 against a constant
pressure of 2x105 N/m2. Then change in internal energy is:
A. +300J D. +100J
B. -300J E. +500J
C. -100J
54. The enthalpy for the reaction H2O2 H2O+½O2 is 23.5 [Link]/mol and
the enthalpy of formation of H2O2 is -44.8 [Link]/mol. The enthalpy of
formation of H2O is:
A. -91.8 [Link]/mol D. 68.3 [Link]/mol
B. 91.8 [Link]/mol E. -21.3 [Link]/mol
C. -68.3 [Link]/mol
55. In thermo chemical reaction.
A. Change in heat energy takes place only.
B. Change in heat energy takes place along with material changes.
C. Energy is absorbed along with material change.
D. Energy is released along with material change.
E. All of These.
56. Study based on principle of conservation of energy is known as:
A. Thermo chemistry C. Thermodynamics
B. Electro chemistry D. All of these
57. In thermo chemical reactions:
A. Heat energy changes take place
B. Material changes take place
C. Both A & B
D. Energy is given off along with material change.
58. Heat evolved or absorbed during chemical reactions depends upon:
A. The amount of substances
B. Physical states of the substance
C. The temperature
D. Whether reaction occurs at constant pressure or constant volume.
E. All of these
59. In combustion reactions:
A. Reactants are more energetic C. Products are more energetic
B. Reactants are less energetic D. Both B & C
60. Which one is not an intensive property?
A. Composition C. Volume
B. Concentration D. None of these
61. Which one is an intensive property?
A. Internal energy C. Density
B. Free energy D. All of these
62. Which one is not a statement of first law of thermodynamics?
A. Energy can neither be created nor C. In any process energy remains
destroyed. conserved.

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
B. Total energy of a system and D. None of these
surrounding must remain constant.
63. The equation of first law of thermodynamics ∆ = − , shows that the .
A. Work is done by the surrounding. C. Work is done on the system
B. Work is done on the surrounding D. Both A & C
64. Which one does not represent first law of thermodynamics?
A. ∆ = − C. = − ∆
B. = ∆ + D. ∆ = −
65. When amount of heat energy is given to a system at constant volume.
A. Work is done by the system. C. Work is done by on the surrounding.
B. Work is done by the surrounding. D. No work is done
66. If in a reaction, product is more energetic than reactant.
A. Energy is absorbed C. Energy may absorb or evolve
B. Energy is evolved D. No energy change.
67. Heat evolved or absorbed in a chemical reaction at constant pressure is called
as:
A. Enthalpy C. Free energy
B. Entropy D. Change in enthalpy
68. Enthalpy of a system depends upon:
A. Initial state of system C. Both A & B
B. Final state of system D. Independent of state of system.
69. I Cal = ___________ joule?
A. 0.239J C. 8.148 J
B. 4.184 J D. 1.481 J
70. Most of the chemical processes take place at:
A. Constant volume C. Both A & B
B. Constant pressure D. None of these
71. Which one of the following is a state function?
A. Internal energy D. Enthalpy
B. Pressure E. All of these
C. Volume
72. Which of the following relation is incorrect?
A. ∆ = ∆ + ∆ C. ∆ − ∆ = ∆
B. ∆ = ∆ − ∆ D. ∆ + ∆ = ∆
73. Enthalpy of a reaction is independent of:
A. Initial state of the system C. Path of reaction
B. Final state of system D. None of these
74. Energy change accompanied by the formation of one mole of a substance from
its elements is called as:
A. Lattice energy C. Heat of fusion
B. Heat of formation D. Heat of neutralization
75. “Total enthalpy change of a reaction always remain same, regardless of the
manner in which reaction take place” is called as:
A. First law of thermodynamics C. Second law of thermodynamics
B. Hess’s law of heat summation D. Law of conservation of energy
76. If 300 Cals of heat is absorbed by a system at constant volume. Its internal
energy change will be:
A. Equal to heat absorbed C. More than heat absorbed
B. Less than heat absorbed D. None of these
77. Enthalpy of reaction is a:
A. State function C. Path function
B. System function D. Surrounding function
78. Total enthalpy change for the formation of Na2 CO3 from NaOH & CO2 is:
A. −41 KJ/mol C. −100 KJ/mol
B. −59 KJ/mol D. −90 K. J/mol
79. Melting of ice is an example of process:
A. exothermic C. non energetic
B. endothermic D. none of these
80. When 760 J of heat is added to a system and work equivalent to 390 J is done
against surrounding. The change in internal energy is?

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
A. 370 J C. -370J
B. 1150 J D. -760J
81. Certain amount of heat is absorbed by the system due to which change in
internal energy is 308 J and 120 J of work is done against surrounding. Amount
of heat energy is.
A. 428 J C. -188 J
B. 120 J D. -428 J
82. For endothermic change.
A. Container becomes cold
B. Enthalpy of product is more than reactants.
C. Change in enthalpy is positive
D. All of these
83. In endothermic process.
A. Container becomes hot C. temperature of system decrease
B. Container becomes cold D. Both B & C
84. Which is incorrect?
A. Heat absorbed by the system is positive
B. Work done on the system is positive
C. Work done by the surrounding is positive
D. None of these
85. Which of the following is always true for an endothermic reaction?
A. Δ = D. ΔS <
B. ΔH < E. ΔS = O
C. Δ >
86. The heat change for the reaction ( ) + ( ) → ( ) is called?
A. heat of reaction D. heat of vapourization
B. heat of formation E. heat of combustion
C. heat of fusion
87. If heats of formation of ( ) and ( ) are respectively − and − . . ,
the heat change taking place in the reaction () ⟶ ( ) is;
A. 11.5 . D. 125.5 .
B. −11.5 . E. 13.5 .
C. −125.5 .
88. Consider the reaction → = + . From the above reaction we can say
that;
A. ozone is more stable than oxygen.
B. formation of ozone is feasible at high temperature
C. oxygen associated readily forming ozone.
D. Ozone is less stable than oxygen.
E. Both B and D
89. Bond energy of a substance:
A. is always positive D. depends upon physical state
B. is always negative E. depends upon conditions of system
C. either positive or negative
90. For which of the following conditions a given process is spontaneous only at
high temperature:
A. ΔH = + ve, ΔS = + ve D. ΔH = - ve, ΔS = + ve
B. ΔH = - ve, ΔS = - ve E. None of these
C. ΔH = + ve, ΔS = - ve
91. The enthalpy change for the process ( ) → ( ) corresponds to enthalpy of;
A. Fusion D. combustion
B. Vapourization E. None of these
C. sublimation
92. Which of the following expression gives fist law of thermodynamics?
A. = ΔE − W D. ΔE = ΔH + PΔV
B. Δ = − E. ΔH + ΔE = PΔV
C. Δ = +
93. The formation of water from hydrogen and oxygen is an exothermic reaction
because:

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Class: XI
CHEMSITRY CHAPTER#11
THERMOCHEMISTRY
A. and have higher temperature than .
B. and have low temperature than .
C. and have high energy than .
D. and have lower energy than .
E. reaction takes place at higher temperature.
94. Entropy decreases in:
A. rusting of iron D. sublimation of dry ice
B. melting of ice E. crystallization of sucrose from solution
C. vapourization of camphor
95. From the properties given below;
I) Concentration II) Enthalpy III) Vapour pressure IV) Entropy
V) Mole fraction VI) Internal energy
Extensive properties are;
A. I, II, IV D. II, IV, VI
B. II, IV, V E. II, IV
C. II, III, IV
96. From the given data;
⟶ + = / + ⟶ =− / . Calculate the
heat of reaction for;
+ ⟶
A. +86 / D. −350 /
B. +304 / E. −86 /
C. −304 /
97. If → + =− / then heat of formation of H I is:
A. −234 D. +488
B. +234 E. +936
C. −468
98. ( )+ ( ) ⟶ ( ) =+ . / . If this reaction is brought about at
constant volume, the heat liberated would be?
A. same C. more
B. less D. none of these
99. Gibb's free energy G, enthalpy H and entropy S are related to one another by;
A. = + D. = −
B. = − E. = =
C. = −
100. For the system ( ) + ( ) ⟶ ( )?
A. Δ = Δ D. Δ =
B. Δ > Δ E. Δ =
C. Δ < Δ
101. Heat and work are;
A. State functions D. Path & state functions respectively
B. Path functions E. None of these
C. State & path functions respectively
102. Heat of formation and combustion of CO is respectively − and − /
respectively. Heat of combustion of carbon is;
A. −392 / D. +196 /
B. +392 / E. −4 /
C. −196 /
103. If heats of combustion of C,H and are − ,− and − /
respectively. Heat of formation of is;
A. +540 D. −740
B. −540 E. −826
C. −1388
104. Which of the following relation is correct?
A. = − D. = +
B. = + − E. = +
C. = +
105. Which of the following equation correctly represents formation of methanol?
A. ( ) + 2 ( ) + 1/2 ( ) ⟶ ( ) D. ( ) + 2 ( ) + 1/2 ( ) ⟶ ( )

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Class: XI
CHEMSITRY CHAPTER#11
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B. ( ) + 4 ( ) + 1/2 ( ) ⟶ ( ) E. ( ) + 2 ( ) + ( ) ⟶ ()
C. 2 ( ) + 4 ( ) + ( ) ⟶ 2 ()
106. Heat of combustion of is . / . of on combustion produce
energy?
A. 18 D. 27
B. 9 E. 36
C. 3
107. For which of the following process & both are positive?
A. melting of ice D. freezing of water
B. crystallization of salt E. none of these
C. condensation of water vapours.
108. Which of the following statement(s) is/are correct?
i. in endothermic reaction product is less energetic.
ii. exothermic reactions are feasible at low temperature.
iii. for exothermic reactions = +ve.
iv. In endothermic reaction container becomes cold.
v. Molar mass is intensive property.
A. I, II, III D. I, III, V
B. II, III, V E. II, IV, V
C. II, III, IV
109. For the given data;

correct statements are;

i. for conversion ⟶ is − .
ii. Conversion ⟶ is endothermic.
iii. Heat change for ⟶ is − .
iv. Heat change for ⟶ is − .
A. I, II D. I, II, IV
B. I, III E. II, IV
C. II, III, IV
110. ( )+ ⟶ =− . . and ( )+ ⟶ = − . . What is
the value for the reaction ( ) ⟶ ( ) ?
A. −0.45 C. +188.55
B. +0.45 D. −188.55
111. Heat of neutralization of & is almost equal to?
A. 13.7 . / D. 27 .
B. 21.3 . /
E. None of these
C. 9.8 . /
112. A system does 500 of work on the surrounding when 300 of heat are
absorbed by the system. for the system is;
A. −200 D. +800
B. +200 E. −700
C. −800
113. Amount of heat absorbed or released when one mole of compound is formed
from its elements at 0℃ & 1 atm is called as;
A. heat of reaction D. standard heat of formation
B. standard heat of reaction E. heat of combustion
C. heat of formation
114. For spontaneity of a process should be?
A. < O D. either b or c
B. O E. unpredictable
C. = O
115. Mode of hybridization possessed by N & S in HNO3& H2SO4 is respectively;
A. sp2, sp2 C. sp2, sp3
B. sp3, sp3 D. sp3, sp2
116. Most stable oxidation state of Fe (Z = 26) is;
A. +2 C. +4

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B. +3 D. +6
117. Copper sulphate dissolved in excess of aqueous ammonia to form deep-blue
solution of complex compound with coordination number:
A. 2 C. 6
B. 4 D. 3
118. Value of co-efficients a, b, c & d for the balanced chemical equation for reaction
of KMnO4 with H2C2O4 is: a +b ⎯ c +d
A. 2, 5, 2, 5 C. 1, 5, 1, 5
B. 2, 5, 2, 10 D. 1, 5, 2, 5
119. Thermal decomposition of AgNO3 yield;
A. AgNO2, O2 C. Ag, NO2, O2
B. Ag2O, NO2 D. Ag2O, NO2, O2
120. Iron ore, magnetite (Fe3O4) contains:
A. Fe+2& Fe+3 in ratio 1 : 2 C. All three iron are in +2 state
B. Fe+2& Fe+3 in ratio 2 : 1 D. All three iron are in +3 state
121. Number of donor sites in dimethyl glyoximato, ethylenediamine& EDTA are
respectively;
A. 2, 2, 6 C. 2, 2, 4
B. 2, 3, 4 D. 1, 2, 6
122. Hydrated ore of iron is:
A. Magnetite C. Haematite
B. Limonite D. Chromite
+1
123. Ag ion is isoletectronic with:
A. Cu+ C. Cd+2
+2
B. Zn D. Pd+2
124. Acidified potassium dichromate (K2Cr2O7) is treated with potassium iodide.
Potassium dichromate undergoes a gain of:
A. 3 Electrons C. 9 Electrons
B. 6 Electrons D. 12 Electrons
125. Number of moles of K2Cr2O7 reduced by one mole of H2S in acidic medium is:
A. 3 C.
B. 2
D.
126. Number of unpaired electrons in ground state of Nickel atom is (Ni = 28):
A. 2 C. 5
B. 3 D. 7
127. Zinc do not show variablevalency because:
A. It is soft
B. Has incomplete d-sub-shell
C. Possess only two electrons in valence shell
D. It is not a transition metal
128. Which group contains coloured ions?
I. Cu+2 II. Ti+2 III. Fe+2 IV. V+5
A. I, III C. I, II, III
B. III, IV D. II, IV
129. Which one of the following is the correct configuration of Fe+3 (Z = 26)?
A. [Ar]4s2, 3d6 C. [Ar]3d5
2 3
B. [Ar]4s , 3d D. [Ar]4s1, 3d4
130. In photography sodium thiosulphate Na2S2O3.5H2O is used as:
A. Reducing agent C. Complexing agent
B. Oxidizing agent D. Both A & C
131. In the dichromate ion :
A. 4 Cr-O bonds are equivalent C. All Cr-O bonds are equivalent
B. 6 Cr-O bonds are equivalent D. All Cr-O bonds are non-equivalent
132. The co-ordination number of cobalt in [Co(en)2Br2]Cl2 is:
A. 4 C. 8
B. 6 D. 2
133. Which of the following complex has same oxidation state of central metal atom
in cationic &anionic part?
A. [Pt(NH3)4] [PtCl4] C. [Pt(NH3)4Cl2] [PtCl4]

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B. [Pt(NH3)4] [PtCl6] D. All Of These
134. Which of the following complex will give white ppt with silver nitrate solution?
A. [Cr(NH3)5Cl]SO4 C. [Cr(NH3)3Cl3]
B. [Cr(NH3)5SO4]Cl D. [Cr(NH3)5SO4]
135. Dimethylglyoximate is a ligand;
A. Neutral bidentate C. Divalent bidentate
B. Univalent bidentate D. Divalent, monodentate
136. Galvanized iron contains a coat of:
A. Tin C. Chromium
B. Zinc D. Nickel
137. Chromium posses same oxidation state in pair of compounds:
A. K2Cr2O7, K2CrO4 C. CrO3, CrO2Cl2
B. CrO3, K2Cr2O7 D. All of These
138. In the exothermic reaction, the enthalpy of reaction is always:
A. Zero C. Negative
B. Positive D. None of These
139. Which relation is incorrect?
A. ∆ = − C. ∆ = − ∆
B. = ∆ + ∆ D. ∆ = ∆ − ∆
140. Which set of the following contain intensive properties only:
A. Enthalpy, Pressure, Temperature C. Vapour Pressure, Molarity, molar Mass
B. Entropy, Volume, Density D. Mass, Volume, Surface Tension
141. Enthalpy change of a reaction does not depend upon;
A. State of reactants & products
B. Nature of reactants & products
C. Different intermediate reaction
D. Initial & final enthalpy change of reaction
142. For the reaction ( ) + ( ) ⟶ ( )
:
A. ∆ = ∆ C. ∆ < ∆
B. ∆ > ∆ D. None of These
143. A system absorbs 50KJ heat & does 20KJ of work. What is the net change in
internal energy of system?
A. Increases by 30KJ C. Increases by 70KJ
B. Decreases by 30KJ D. Decreases by 70KJ
144. Correct relation for enthalpy is:
A. = + C. = −
B. = − D. = +
145. Which one is correct about exothermic reaction?
A. ∆ = + C. Spontaneous at low T
B. ∆ = + D. Spontaneous at high T
146. Which one is endothermic reaction?
A. C + O2⟶ CO2 C. CS2⟶ C + 2S
B. 2HI ⟶ H2 + I2 D. None of These
147. Correct decreasing order of energy unit is:
A. > > C. > >
B. > > D. > >
148. For which set of values of ∆ &∆ process is spontaneous at all temperatures?
A. ∆ = − , ∆ = + C. ∆ = + , ∆ = +
B. ∆ = + , ∆ = − D. ∆ = − , ∆ = −
149. Correct option for Gibb’s-Helmholtz equation is:
A. ∆ = ∆ + ∆ C. ∆ = ∆ − ∆
B. ∆ = ∆ − ∆ D. ∆ = − ∆
150. For the reaction ( )
+ ( )
⟶ ( ) ∆ = − . . What is the enthalpy of
decomposition of HCl?
A. +44Kcal C. –22Kcal
B. –44Kcal D. +22Kcal
151. Change in enthalpy is:
A. Intensive property & state function C. Extensive property & state function
B. Intensive property & path function D. Extensive property & path function

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152. The statement “The change in enthalpy of a chemical reaction is same whether
the reaction takesplace in single step or several steps” is:
A. First law of thermodynamics C. Gibb’s law
B. Hess’s law D. Le-Chatelier’s law
153. For which reaction ∆ < ∆ ?
A. ( )
+ ⟶ ( )
C. ( )
⟶ ( )
B. ( )
+ ( )
⟶ ( ) D. ( )
⟶ ( )
+ ( )

154. For the reaction + ⟶ ∆ = − , ∆ is called as:

A. Heat of formation C. Heat of reaction
B. Heat of dissociation D. None of These
155. Amount of heat absorbed or released in a chemical reaction is called as:
A. Change in enthalpy C. Change in Gibb’s free energy
B. Change in entropy D. Change in internal energy
156. In an endothermic reaction:
A. Reactant is less stable C. Container becomes hot
B. Product is more energetic D. Feasibility is favoured at low T
157. Total number of bonding pairs ( & )& lone pairs in CO2 molecule is:
A. 4, 4 C. 2, 2
B. 2, 4 D. 2, 6
158. Hybrid state of C & N in CH3-NO2 is respectively:
A. sp3, sp3 C. sp3, sp2
B. sp2, sp3 D. sp2, sp2
159. Which statement is correct?
A. SO2 is symmetrical while SO3 is unsymmetrical
B. SO3 is symmetrical while SO2 is unsymmetrical
C. SO2& SO3 both are symmetrical
D. SO2& SO3 both are unsymmetrical
160. What is common between the following molecules , , ?
A. All have linear shape C. All have trigonal pyramidal shape
B. All have trigonal planar shape D. All have tetrahedral shape
161. S.I unit of dipole moment is:
A. C-m C. Debye
B. esu-cm D. Both B & C
162. Hydrogen bond is a type of:
A. Dipole-dipole force C. Vander Waal’s force
B. Dispersion force D. None of These
163. Mode of hybridization, shape & bond angle in NH3 is:
A. sp3, tetrahedral, 109.280 C. sp3, pyramidal, 1070
B. sp3, tetrahedral, 1070 D. sp2, pyramidal, 1070
164. Dipole moment is maximum for:
A. NH3 C. HCl
B. H2O D. HF
165. For N2 molecule which order of energy is correct?
A. 2 > 2 C. 2 > 2
B. 2 < 2 D. 2 > 2
166. Which pairs of the following is diamagnetic?
A. , C. ,
B. , D. ,
167. Least bond order is present in:
A. C.
B. D.
168. + → ∆ =− [Link]
+ → ∆ = − [Link]
Find out the heat of formation of SO2
A. (y-2x) C. (x+y)
B. (2x+y) D. 2x/y
169. The enthalpy of neutralization of a weak acid by a strong base is:
A. -57.32 KJ C. Less than -57.32 KJ

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B. +57.32 kJ D. More than -57.32 KJ
170. The heat combustion of CH4(g), C(graphite), H2(g) are -20 [Link], -40 [Link], -10
[Link] respectively. The heat of formation of methane is:
A. -40 [Link] C. +40 [Link]
B. -80.0 [Link] D. +80 [Link]
171. Compounds with high heat of formation are less stable because:
A. It is difficult to synthesize them
B. Energy rich state lead to instability
C. High temperature is required to synthesize them
D. Molecules of such compounds are distorted
172. When 0.5 g of sulphur is burnt to SO2 4.5 KJ of heat is liberated. What is the
enthalpy of formation of sulphur dioxide?
A. -144 KJ C. +288 KJ
B. +144 KJ D. -288 KJ
173. The heat of formation of Fe2O3(s) is -824.2 KJ mol-1. ∆H for the reaction 2Fe2O3(s)
→4Fe(s)+3O2(g) is:
A. -412.1 KJ C. -1648.4 KJ
B. -3296.8 KJ D. +1648.4 KJ
174. Heat exchanged in a chemical reaction at constant temperature and constant
pressure is called:
A. Internal energy C. Entropy
B. Enthalpy D. Free energy
175. For the process: G.
Dry ice → CO2(g)
A. ∆H is positive and ∆S is negative C. Both ∆H and ∆S are negative
B. Both ∆H and ∆S are positive D. ∆H is negative whereas ∆S is positive
176. Which of the following reaction defines ∆ °?
A. C(diamond)+O2(g) → CO2(g) C. N2(g)+3H2(g) → 2NH3(g)
B. H2(g) + F2(g) → HF(g) D. CO(g)+ O2(g) → CO2(g)
177. Heat of neutralization of strong acid against strong base is constant and is
equal to:
A. 13.7 [Link] C. 57 KJ
4
B. 5.7 x 10 J D. All of above
178. The neutralization of a strong acid by a strong base librates an amount of
energy per mole of H+:
A. Depends upon which acid and base are involved
B. Depends upon the temperature at which the reaction takes place
C. Depends upon which catalyst is used
D. Is always the same
179. Equal volumes of methanoic acid and sodium hydroxide are mixed. If x is the
heat of formation of water, then heat evolved on neutalizaiton is:
A. More than x C. Less than x
B. Equal to x D. Twice x
180. In thermodynamic process, 200 joules of heat is given to a gas and 100 joules
of work is also done on it. The change in internal energy of the gas is:
A. 100 J C. 300 J
B. -100 J D. -300 J
181. Heat is not being exchanged in a body. If its internal energy is increased, then:
A. It temperature will increase C. Its temperature will remain constant
B. Its temperature will decrease D. None of these
182. A system is provided with 200 cal of heat and the work done by the system on
the surrounding is 400 J. Then its internal energy.
A. Increase by 400 J C. Decrease by 400 J
B. Increase by 200 J D. Decrease by 200 J
183. In a thermodynamic process, pressure of a fixed mass of a gas is changed in
such a manner that the gas molecules give out 20J of heat and 10J of work is
done on the gas. If the initial internal energy of the gas was 40J, then the final
internal energy will be:
A. 30 J C. 20 J
B. 60J D. 40 J

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184. If a system undergoes contraction of volume then the work done will be:
A. Zero C. Negligible
B. Negative D. Positive
185. A gas is compressed at a constant pressure of 50N/m2 from a volume of 10 m3
to volume of 4 m3. Energy of 100 joule is thus added to gas by heating. Its
internal energy is:
A. 450 C. 400
B. 350 D. 410
186. If temperature is increased by 1 K at constant volume then work done on the
gas is:
A. Positive C. Zero
B. Negative D. Data inadequate
187. Consider the following two statements and choose the correct answer:
(I) If heat is added to a system, its temperature must always increase.
(II) If work is done by a system in thermodynamic process, its volume must
increase.
A. I C. Both A & B
B. II D. None of these
188. If Q, E and W denote respectively the heat added, change in internal energy and
the work done in a closed cyclic process then which of these will follow:
A. =0 C. =0
B. ∆ = 0 D. None of these
189. Enthalpy change for the reaction:
4H(g) → 2H2(g) is -869.6 KJ
The dissociation energy of H-H bond is:
A. -434.8 KJ C. -869.6 KJ
B. +434.8 KJ D. +217.4 KJ
190. The internal energy change when a system goes from state A to B is
40KJ/mole. If the system goes from A to B by a reversible path and returns to
state A by an irreversible path what would be the net change in internal
energy?
A. >40 KJ C. <40 KJ
B. Zero D. 40 KJ
191. An isolated system is that system in which:
A. There is no exchange of energy with surroundings
B. There is exchange of mass and energy with the surroundings
C. There is no exchange of mass or energy with the surroundings
D. There is exchange of mass with the surroundings
192. The enthalpy change of a reaction does not depend on:
A. The state of reactants and products C. Different intermediate reactions
B. Nature of reactants and products D. Initial and final enthalpy of a reaction
193. The intensive property among these quantities is:
A. Mass C. Volume
B. Enthalpy D. Mass/volume
194. The relationship between enthalpy change and internal energy change is:
A. ∆ = ∆ + ∆ C. ∆ = ∆ − ∆
B. ∆ = (∆ + ∆ ) D. ∆ = ∆ − ∆
195. If a reaction involves only solids and liquids which of the following is true?
A. ∆ < ∆ C. ∆ > ∆
B. ∆ = ∆ D. ∆ = ∆ + RT ∆n
196. C(diamond) → C(graphite) ∆ = −ve. This shows that.
A. Graphite is more stable C. Both are equally stable
B. Graphite has more energy than diamond D. Stability cannot be predicted
197. The enthalpy of vapourisation of water from the following two equations is:
( )+ ( ) → ( ) ∆ =−

( ) + ( ) → ( ) ∆ =− .
A. 6.02 KJ C. 40.5 KJ
B. 62.3 KJ D. -40.5 KJ
198. For the reaction C+O2 → CO2:

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A. ∆ >∆ C. ∆ > ∆
B. ∆ =∆ D. None of these
∆
199. In the process Cl(g)+e- ⎯ Cl-(g). ∆ is:
A. Positive C. Negative
B. Zero D. Unpredictable
200. The heat required to raise the temperature of a body by 1K is called:
A. Heat capacity C. Molar heat capacity
B. Specific heat capacity D. None of these
201. Entropy is a measure of:
A. Disorder C. Efficiency
B. Internal energy D. Useful work done by the system
202. For which of the following reactions, ∆H is greater than ∆ ?
A. N2(g)+3H2(g) →2NH3(g) C. PCl5(g)→PCl3(g)+Cl2(g)
B. CH4(g)+2O2(g) →CO2(g)+2H2O(l) D. HCl(aq)+NaOH(aq) → NaCl(aq)+ H2O(aq)
203. Which of the following condition does not describe standard heat of formation
of CH4?
A. Isotope of carbon used is diamond C. Pressure of gas = 1 atm
0
B. T=25 C D. None of these
204. Heats of combustion of graphite, methane (CH4), ethane (C2H6) & glucose
(C6H12O6) is -394, -890, -1560 & -2800 KJ/mol respectively. Which one has
maximum calorific value?
A. Graphite C. Ethane
B. Methane D. Glucose
205. Amount of heat released when one mole of H2 gas undergoes combustion is:
A. -286 KJ/mol C. -572 KJ/mol
B. 286 KJ/mol D. 572 KJ/mol
206. Born-Haber cycle is based on:
A. First law of thermodynamics C. Zeroth law of thermodynamics
B. Second law of thermodynamics D. Hess’s law of constant heat
207. Energy of sublimation for sodium metal, energy of ionization of sodium gaseous
atom is 108 & 496 KJ/mole. Enthalpy of atomization of Cl2 & electron affinity
for chlorine is 121 & -349 KJ/mol what heat of formation of solid NaCl if lattice
energy of NaCl is -787 KJ/mol?
A. 411 KJ/mol C. 1198 KJ/mol
B. -411 KJ/mol D. -1198 KJ/mol
208. Bond energy of H2 molecule from free hydrogen atoms is -436 KJ/mol.
Enthalpy of atomization of hydrogen is:
A. -436 KJ/mol C. -218 KJ/mol
B. 436 KJ/mol D. 218 KJ/mol
209. Enthalpy of formation of which of the following is zero?
A. O B. O2 C. O3 D. O4
210. Incorrect statement about exothermic reaction is:
A. Product is more stable C. It is feasible at low temperature
B. Container becomes cold D. All of these
211. Which of the following is correct relation?
A. ∆Hvap = ∆Hsub + ∆Hfus C. ∆Hfus = ∆Hsub + ∆Hvap
B. ∆Hsub = ∆Hfus + ∆Hvap D. None of these
212. Unit for specific heat capacity is:
A. B. C. D.
213. Which of the following reaction is endothermic?
A. H2+I2+53.8 KJ → 2HI C. N2+O2 → 2NO -180.5 KJ
B. C+O2 → CO2+293.5 KJ D. Both A & C
214. Which one is not a state function?
A. Internal energy C. Number of moles
B. Enthalpy D. Heat
215. Heat for the given reaction H2(g) → 2H(g) is called as:
A. Enthalpy of decomposition C. Enthalpy of reaction
B. Enthalpy of Atomization D. Enthalpy of dissociation
216. Enthalpy of combustion of CH4 is -800 KJ/mole. Heat produced due to

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combustion of 2g of CH4 completely is:
A. 1600 KJ B. 400 KJ C. 200 KJ D. 100 KJ
217. Calculate the heat evolved when a Cu cane weighing 100g is cooled from 250C
to 750C at constant pressure. Specific heat capacity of Cu is 0.387 J/g-K?
A. 2902.5 KJ B. 1935 KJ C. 0.774 KJ D. 1.935 KJ
218. Which equation of the following gives a reaction for formation of aluminum
oxide?
A. 4Al + 3O2 → 2Al2O3 C. 2Al + 3/2O2 → Al2O3
B. Al2 + 3/2O2 → Al2O3 D. 2Al + 3O → Al2O3
219. A gas expands from 1 litre to 1500 cm3 against an external pressure of 5 atm.
Work done by the gas is:
A. 0.1 L/atm B. 2.5 L-atm C. 10 atm/L D. 0.5 L-atm
220. Born- Haber cycle is used to determine:
A. Heat of combustion of a compound C. Heat of transition of an allotrope
B. Heat of formation of a compound D. Lattice energy of binary ionic salts
221. Science of measuring heat of a chemical reaction by measuring the temperature
change is called as:
A. Thermodynamics C. Calorimetry
B. Thermochemistry D. Photochemistry
222. Energy can be exchanged between system & surrounding in the form of:
A. Heat C. Both A & B
B. Work D. None of these
223. Specific heat of water is 4.2 J/g-K. Amount of heat required to raise
temperature of 1Kg of water by 10C is:
A. 4200 J B. 0.0042 J C. 4.2 KJ D. Both A & C
224. Which of the following quantum numbers represents an orbital of 3d sub-shell?
A. = 1, = 0, = 0 C. = 2, = 1, = 1
B. = 2, = 0, = 0 D. = 3, = 2, = 0
225. ( )→ ( ); ∆ = + .
Given that,
( )→ ( ); ∆ = + .
The value of ∆ ( ) of ice is:
-1
A. 49.75 kJ mol C. 37.65 kJ mol-1
-1
B. 43.7 kJ mol D. -43.67 kJ mol-1
226. Given that, ( )+ → ( ); ∆ = − KJ, the enthalpy of combustion of
sulphur is:
A. -1590 kJ mol-1 C. -3180 kJ mol-1
-1
B. +1590 kJ mol D. -795 kJ mol-1
+
227. The energy librated per mole of H ion by neutralisation of strong acid and
strong base:
A. Depends on which acid and base are involved
B. Depends on the temperature at which reaction occurs
C. Depends upon which catalyst is used
D. Is always constant
228. Heat liberated by burning 2.0 g of carbon in excess of oxygen is kJ. The value
of ∆ of carbon is:
A. B. 6 1 C. − 1 D. −6 1
229. Which of the following equation represents the standard heat of formation?
A. C(diamond) + 2H2(g) → CH4(g) C. C(diamond) + 4H(g) → CH4(g)
B. C(graphite) + 2H2(g) → CH4(g) D. C(graphite) + 4H (g) → CH4(g)
230. Standard molar enthalpy of formation of CO2 is equal to:
A. Zero
B. Standard molar enthalpy of combustion of carbon (graphite)
C. Standard molar enthalpy of combustion of gaseous carbon
D. Sum of molar enthalpies of formation of CO and O2
231. The heat of the reaction does not depends upon:
A. Temperature of the reaction C. Amount of reactants
B. Physical states of reactants and D. Path of the reaction
products

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