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Applications of Super Absorbent Polymers

The document discusses applications of super absorbent polymers (SAPs) including in agriculture to improve soil properties, in concrete to improve strength and curing, and in medicine for drug delivery and wound treatment. SAPs can respond to environmental stimuli for uses like smart hydrogels and controlled drug release. They have potential in many other fields such as cosmetics, waste treatment, and more.

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0% found this document useful (0 votes)
17 views8 pages

Applications of Super Absorbent Polymers

The document discusses applications of super absorbent polymers (SAPs) including in agriculture to improve soil properties, in concrete to improve strength and curing, and in medicine for drug delivery and wound treatment. SAPs can respond to environmental stimuli for uses like smart hydrogels and controlled drug release. They have potential in many other fields such as cosmetics, waste treatment, and more.

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phantanhung5443
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© All Rights Reserved
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Applications of Super absorbent POLYMERS

Article · December 2016

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Applications of the Super Absorbent Polymers
By
Assist. Prof. Dr. Auda Jabbar Braihi
Polymer and Petrochemical Industries Dep. / College of Materials Engineering / University of
.Babylon /Iraq

Due to their outstanding characteristic, super absorbent polymers


(SAPs) have been used in many applications. Figure 1 reflects some of
.these uses

[Figure 1: SAPs applications in various fields [1


Smart Applications .1
Smart hydrogels are sensitive to environmental changes which may be
physical or chemical variations like fluctuations in magnetic field, photo-
irradiation pH, temperature, urea, glucose and solution's ionic strength
(Figure 2). Smart hydrogels used in many applications such as
biosensors, actuators (artificial muscles), self-regulating drug delivery
systems, on–off regulation of enzymatic reactions and purification of
. chemical agents

The pH-response polymer gel is an example of smart hydrogel which


can responds to the environmental pH variations similar to variations
occur within the human body. pH values can change greatly between
injured and infected tissues. For example normal tissue fluid has a pH
≈7.4, but it can be as low as 3.5 in a wound, and increase to 9.0 for an
.[infected wound tissue [2

[Figure 2: Swelling behaviors of intelligent hydrogels [1


Normally, the pH- responsive gel possesses a molecular structure
contains cross-linked network with ionize-able groups within its network.
These groups will ionize in different ionization levels analogs to the pH
.and ionic strength levels
As the network structure changed with the surrounding pH, the H- bond
is converted also, which in turn created changes in mass and volume of
.the gel
Medical Applications .2
SAPs can be used in many medical applications, such as drug delivery
systems (DDSs), wound closure , healing products, removal of body
water during surgery(treatment of edema), and surgical implant devices
[3]. SAPs, also used in the health care field to manufacture an efficient
.heating pads to help patients whom suffer from rheumatism
One example of the control on–off drug release is the sugar responsive
gel which is used for diabetes treatment. In healthy physiological
conditions, cells in the pancreas releases insulin hormone to control blood
glucose level within the range of 70 - 110 mg/dl. In contrast, for patients
whom cannot control blood glucose levels, it is necessary to added
insulin externally. Hypoglycemia and coma may result from the irregular
.doses, thus insulin must be accurately added
Insulin hormone is produced from beta cells in the pancreas to control
glucose levels in the blood. Diabetes disease arises when there is no
.[enough production of this hormone [4
Recently, super-porous hydrogels (SPHs) have been developed with
very fast swelling behavior due to their open porous structure in order to
controlling the delivery of drugs to intestine or stomach, as well as for
.[gastric retention applications [5
Agricultural Applications .3
SAPs inside the soil can absorb water from rainfall or excessive
irrigation, then releasing it slowly upon the root demand through osmotic
pressure difference, resulting in improved growth rate. Furthermore they
can be used for the controlled release of pesticides and agrochemicals
.[[6
SAP hydrogels can influence many properties of soil such as
permeability, aeration,density, structure, erosion resistance, evaporation,
microbial activity and infiltration rates. SAPs also used to increase both
the nutrient retention andthe water-holding capacity for sandy soils
(macro porous medium) in the arid areas [7]. Furthermore, SAPs can
reduces both of the losses of water, irrigation frequency and soil
.[compaction tendency [8
For plants, SAPs can increase color intensity, coverage percentage and
sport turf density, and decreases it's wilting level. SAPs in agriculture can
be used as mixtures with soil, seeds, agricultural chemicals, and
fertilizers(called water-absorbent slow release fertilizer).For forestry
field, SAPs is covered over the roots to protect tree from drying during
transportation
Strengthening of Concrete Application .4
Although mortar and concrete are popular construction materials, but
they sever from some weaknesses such as late hardening, large drying
.shrinkage, low chemical resistance, and low tensile strength
SAPs can act as an internal water source to provide hydration process
:[with the required water according to the following mechanism [9
SAPs absorbs water molecules from the fresh concrete mixture, then - 1
releases it in a later stage if its relative humidity decreases because of the
.hydration process
When SAPs have got their final sizes, they establish stable, water- - 2
filled inclusions, then water will sucked from these inclusions into
smaller capillary holes and consumed by the cement hydration action
.[[10
SAPs can be used to promote internal curing of concrete; thus mitigate
its autogenous shrinkage. This is because internal curing allows curing to
be 'from inside to outside' by the created internal reservoirs; thus provides
water throughout the mix not just penetration for a few millimeters such
.[as in external curing (Figure 3) [11
Also, the created gel can improve both the workability and stability due
.[to provide the concrete mass with cushioning and lubrication effects [12
Effective mortar properties are the consistency and the setting
[Link] of standard paste refers to the water content of the
.paste which will produce the wanted consistency
Setting indicates the change from a fluid state to a rigid state and
mainly caused via the hydrationoftricalcium silicate(C3S) andtricalcium
.aluminate (C3A) and occurs in two stages; initial and final sets
Setting is important in concrete work to keep fresh concrete plastic for
enough time which helps the processes of transporting, casting, and
.[compaction [11

[Figure 3: Internal curing vs. external curing [11


Initial set considers as the time elapsed since the moment of mixing
water with the cement to the moment of penetration of no deeper than 4-6
mm from the bottom. The minimum initial set time is45 minutes
.according to the ASTM C 150-09
The final setting is usually calculated from the moment of mixing
water with the cement. There are no limits appearing in the European or
.[ASTM standards for the final setting time [12
Other Applications .5
SAPs can be used also in many applications such as, fire retarders,
dewatering of adulterated fuel, artificial snow [13], athletic garment,
ornamental (colored) products, sanitary towels, building internal
decoration[14], modifying weather condition, as dehydrating agent to
solidify waste in the sludge treatment ,absorb alcohol as well as the heavy
metal ions likeCo2+ andCr3+,extract urea from urine in artificial kidneys
(urea absorbing material), to improve the moisturizing effects of different
.[cosmetic products and cleaning radioactivity from porous structures [14
References

A. J. B. Sansuri, " Synthesis and Swelling Behavior of Bentonite - 1


Based Superabsorbent Polymer Composites", Malaysia Pahang
.University, Bachelor of Chemical Engineering,2010
Joyce Y. Wong, and Joseph [Link], " Biomaterials" , Taylor & -2
.Francis Group, LLC, 2007
A. Sannino, A. Esposito, A. De Rosa, [Link] , L. Ambrosio, and -3
L. Nicolais, "Biomedical application of a superabsorbent hydrogel for
body waterelimination in the treatment of edemas", J Biomed Mater Res,
.Vol. 67A, pp: 1016-1024, 2003
S. Simões, A. Figueiras, and F. Veiga, "Modular Hydrogels for Drug -4
Delivery", Journal of Biomaterials and Nanobiotechnology, Vol. 3,
.pp:185-199 , 2012
J. Chen, H. Park, and K. Park, "Synthesis of superporous hydrogels: - 5
hydrogels with fast swelling and superabsorbent properties", J Biomed
.MaterRes, Vol. 44, pp: 53-62, 1999
L. O. Ekebafe, D. E. Ogbeifun, and F. E. Okieimen, "Polymer - 6
Applications in Agriculture", Biokemistri ,Vol. 23, No. 2, pp: 81 – 89,
.2011
L. Wu, and M. Liu, "Preparation and properties of chitosan- coated - 7
NPK compound fertilizer with controlled-release and water-
.retention",CarbohydrPolym, Vol. 72, pp: 240-247, 2008
B. Zhou, " Production and Uses of Water- Absorbent Long Effect - 8
Compound Fertilizer" ,Journal of the Chemical Fertilizer Industry, Vol.
.30, pp:55-56, 2013
S. Monnig ," Water Saturated Superabsorbent Polymers Used in High -9
.Strength Concrete",Otto-Graf-Journal, Vol.16, 2005
V. Hareendran, V. Poornima, and [Link], "Experimental - 10
Investigation Aspects of Internal Curing Concrete Using Superabsorbent
Polymer", International Journal of Advanced Structures and Geotechnical
.Engineering, Vol.03, No.02, 2014
M. Daoud, and M. Al-Nasra, "The Use of Super Absorbent Polymer -11
as a Sealing Agent in Plain Concrete", American Journal of Engineering
.Research, Volume 03, Issue 03, pp132-137, 2014
M. Neville and J. J. Brooks," Concrete Technology", Second edition, -12
.2010

L. Davies , J. Novais, and S. Martins-Dias, "Detoxification of olive - 13


mill wastewater using superabsorbent polymers",Centre of Biological and
.Chemical Engineering, Instituto Superior Técnico, Portugal, 2009
PHOSCLEAR," Superabsorbent Polymers and Waste Solidification", - 14
.M² Polymer Technologies, Inc.847-836-1393, 2013

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Super absorbent polymers (SAPs) improve mortar and concrete characteristics by providing an internal water source during the hydration process, reducing shrinkage and cracking. SAPs create water-filled inclusions that release moisture as needed, which aids in mitigating autogenous shrinkage. Furthermore, they enhance chemical resistance by ensuring better consistency and setting characteristics, which can reduce permeability and, thus, susceptibility to chemical attack. SAPs also enhance workability and stability by providing the concrete with cushioning and lubrication effects, further improving its durability and structural integrity .

SAPs purify chemical agents by selectively absorbing impurities, including heavy metals and other contaminants, from solutions. Their high capacity and selective absorbency make them valuable for refining processes, waste treatment, and decontaminating polluted water. They can be applied in industries such as mining, wastewater treatment, and chemical manufacturing to enhance purity levels and recover useful by-products. Additionally, they can improve the efficiency of manufacturing processes by capturing and recycling solvents and reagents, reducing waste and increasing sustainability .

Super absorbent polymers (SAPs) facilitate the internal curing of concrete by first absorbing water molecules from the fresh concrete mixture. These SAPs then release the stored water when the relative humidity within the concrete decreases due to the hydration process. The water is released into smaller capillary holes within the concrete matrix, essentially acting as internal water reservoirs. This process helps mitigate autogenous shrinkage by ensuring a consistent supply of water 'from inside to outside,' which contrasts with standard external curing methods that only infiltrate a limited depth .

pH-responsive hydrogels within super absorbent polymers possess molecular structures with cross-linked networks containing ionizable groups. These groups ionize differently under varying pH and ionic strength conditions, altering the gel's swelling behavior. This adaptability allows these smart hydrogels to respond to the large pH changes observed in human tissues, such as from 7.4 in healthy tissue to lower as 3.5 in wounds or 9.0 in infected tissues. In medical contexts, this property enables the development of responsive drug delivery systems, such as wound treatments that adjust to the environment's pH levels, ensuring effective localized therapy .

SAPs enhance horticultural applications by improving color intensity and coverage through efficient water and nutrient management. By retaining water and nutrients near the root zone, they ensure a consistent supply, which supports robust plant health and growth. This sustained growth leads to enhanced pigment production and overall vitality, improving the visual quality of ornamental plants. Additionally, SAPs mitigate stress conditions such as drought, which can negatively affect pigmentation and coverage, leading to fuller, more vibrant, and denser plant coverage .

Super absorbent polymers (SAPs) improve agricultural soil properties by absorbing water during rainfall or irrigation and then releasing it as needed by plant roots through osmotic pressure differences. SAPs enhance soil permeability, aeration, and microbial activity while reducing erosion and evaporation. They also increase water and nutrient retention in sandy soils, leading to less frequent irrigation and reduced soil compaction. These improvements support consistent plant hydration and nutrient availability, increasing plant growth rates, improving color intensity, enhancing coverage, and contributing to higher crop yields .

Supplementing slow-release fertilizers with super absorbent polymers (SAPs) benefits agriculture by enhancing soil moisture retention and gradually releasing nutrients, reducing the frequency of irrigation and fertilization. They mitigate nutrient leaching, improve plant nutrient uptake efficiency, and support continuous plant growth. However, there are risks such as potential chemical interactions between the SAPs and fertilizers which may alter SAP functionality. Moreover, over-reliance on SAPs could delay the development of more sustainable agricultural practices. Environmental concerns, such as polymer degradation and subsequent microplastic pollution, also pose risks .

SAPs play a crucial role in designing therapeutic hydrogels for diabetes management by integrating sugar-responsive systems that respond to blood glucose levels. The hydrogels release insulin or other medications in response to elevated glucose levels, mimicking the natural release of insulin by the pancreas. This smart release mechanism reduces the risk of hypoglycemia from conventional insulin dosing by aligning medication release with actual physiological needs. Although promising, challenges remain in ensuring these responsive systems maintain stability and performance under varying physiological conditions, including patient variability and storage requirements .

Super absorbent polymers (SAPs) are used in environmental management to solidify waste, especially in sludge treatment, by absorbing and retaining large volumes of liquid. This capability turns liquid waste into semi-solid form, facilitating easier handling, transportation, and disposal. Additionally, SAPs help prevent the leaching of toxins and heavy metals into the environment. However, a limitation of SAPs in waste solidification includes potential environmental harm if they degrade improperly, especially if they release absorbed pollutants during decomposition. It's also crucial that SAPs are compatible with various waste types to avoid reactions that could compromise their effectiveness .

Super-porous hydrogels (SPHs) are designed for rapid swelling due to their open porous structure, making them highly effective in drug delivery systems for gastrointestinal applications. The swift swelling behavior allows SPHs to occupy more space and release drugs in the stomach or intestines, where they can be absorbed more efficiently. This rapid expansion also contributes to gastric retention, enabling sustained release and absorption of drugs. The porous structure enhances the hydrogels’ capacity to absorb liquid and expand, optimizing the delivery and bioavailability of drugs intended for gastrointestinal uptake .

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