Interatomic and Intermolecular Forces Explained
Interatomic and Intermolecular Forces Explained
Unit
7
Elasticity
Interatomic Forces (i) When two atoms are at very large distance, the potential energy
is negative and becomes more negative as r is decreased.
The forces between the atoms due to electrostatic interaction (ii) When the distance between the two atoms becomes r , the
between the charges of the atoms are called Interatomic forces. These forces potential energy of the system of two atoms becomes minimum (i.e. attains
0
are electrical in nature and these are active if the distance between the two maximum negative value). As the state of minimum potential energy is the
atoms is of the order of atomic size i.e. 10 metre.
–10
(2) When two atoms are brought closer to each other to a distance decreasing. It becomes zero and then attains positive value with further
of the order of 10 m, the distances between their positive nuclei and
–10 decrease in r (as shown in the figure).
negative electron clouds get disturbed, and due to this, attractive Intermolecular Forces
Interatomic force is produced between two atoms.
The forces between the molecules due to electrostatic interaction
(3) This attractive force increases continuously with decrease in r
between the charges of the molecules are called intermolecular forces. These
and becomes maximum for one value of r called critical distance,
forces are also called Vander Waal forces and are quite weak as compared
represented by x (as shown in the
to inter-atomic forces. These forces are also electrical in nature and these
Repulsion
(5) When the distance between forces becomes repulsive in nature and is found to vary inversely as ninth
the two atoms further decreased, the O r power of the distance between them i.e.
Interatomic force becomes repulsive in r0
nature and increases very rapidly with 1 b
Frep or Frep .
decrease in distance between two atoms. r9 r9
(6) The potential energy U is Therefore force between two molecules is given by
related with the Interatomic force F by a b
the following relation. F Fatt Frep 7 9
r r
dU
F The value of constants a and b depend upon the structure and
dr
nature of molecules.
1|Page
Elasticity
(3) Intermolecular forces between two molecules have the same (iv) Both the forces are attractive up to certain distance between
general nature as shown in the figure for Interatomic forces. atoms/molecules and become repulsive when the distance between them
becomes less than that value.
(4) Potential Energy: Potential energy can be approximately
(2) Dissimilarities
A B
expressed by the formula U n m (i) Interatomic force depends upon the distance between the two
r r
atoms, whereas the intermolecular force depends upon the distance between
A the two molecules as well as their relative orientation.
Where the term represents repulsive contribution and term
rn (ii) Interatomic forces are about 50 to100 times stronger than
B intermolecular forces.
represents the attractive contribution. Constants A, B and numbers m
rm (iii) The value of r for two atoms is smaller than the corresponding
0
and n are different for different molecules. value for the molecules. Therefore one molecule is not restricted to attract
only one molecule, but can attract many molecule. It is not so incase of
For majority of solids n = 12 and m = 6. atoms, since the atoms of one molecule cannot bind the atoms of other
molecules.
A B
So potential energy can be expressed as U 6
r 12
r States of Matter
Comparison between Interatomic and
The three states of matter differ from each other due to the
Intermolecular Forces following two factors.
(1) Similarities (1) The different magnitudes of the Interatomic and intermolecular forces.
(i) Both the forces are electrical in origin. (2) The extent of random thermal motion of atoms and molecules of a
(ii) Both the forces are active over short distances. substance (which depends upon temperature).
(iii) General shape of force-distance graph is similar for both the forces.
Note: The fourth state of matter in which the Elastic Property of Matter
medium is in the form of positive and negative ions, is known as plasma. (1) Elasticity: The property of matter by virtue of which a body tends
Plasma occurs in the atmosphere of stars (including the sun) and in to regain its original shape and size after the removal of deforming force is
discharge tubes. called elasticity.
Types of Solids (2) Plasticity: The property of matter by virtue of which it does not
regain its original shape and size after the removal of deforming force is
A solid is that state of matter in which its constituent atoms or called plasticity.
molecules are held strongly at the position of minimum potential energy
and it has a definite shape and volume. The solids can be classified into two (3) Perfectly elastic body: If on the removal of deforming forces the
categories, crystalline and glassy or amorphous solids. body regain its original configuration completely it is said to be perfectly
elastic.
A quartz fibre and phosphor bronze (an alloy of copper containing Force F
4% to 10% tin, 0.05% to 1% phosphorus) is the nearest approach to the Stress
Area A
perfectly elastic body.
(4) Perfectly plastic body: If the body does not have any tendency to Unit: N / m 2 (S.I.) , dyne / cm 2 (C.G.S.)
recover its original configuration, on the removal of deforming force, it is Dimension: [ML 1 T 2 ]
said to be perfectly plastic.
Stress developed in a body depends upon how the external forces
Paraffin wax, wet clay are the nearest approach to the perfectly are applied over it.
plastic body.
On this basis there are two types of stresses: Normal and Shear or
Practically there is no material which is either perfectly elastic or perfectly tangential stress
plastic and the behaviour of actual bodies lies between the two extremes.
(1) Normal stress: Here the force is applied normal to the surface.
(5) Reason of elasticity: In a solids, atoms and molecules are
arranged in such a way that each molecule is acted upon by the forces due It is again of two types: Longitudinal and Bulk or volume stress
to neighbouring molecules. These forces (i) Longitudinal stress
are known as intermolecular forces.
(a) It occurs only in solids and comes in to picture when one of the
For simplicity, the two molecules in
three dimensions viz. lengths, breadth, height is much greater than other
their equilibrium positions (at inter-
two.
molecular distance r = r ) are shown by
0
connecting them with a spring. (b) Deforming force is applied parallel to the length and causes increase
in length.
In fact, the spring connecting the
two molecules represents the inter- (c) Area taken for calculation of stress is the area of cross section.
molecular force between them. On applying the deforming forces, the
molecules either come closer or go far apart from each other and restoring (d) Longitudinal stress produced due to increase in length of a body
forces are developed. When the deforming force is removed, these restoring under a deforming force is called tensile stress.
forces bring the molecules of the solid to their respective equilibrium
(e) Longitudinal stress produced due to decrease in length of a body
position (r = r ) and hence the body regains its original form.
0
under a deforming force is called compressive stress.
(6) Elastic limit: Elastic bodies show their property of elasticity upto
a certain value of deforming force. If we go on increasing the deforming (ii) Bulk or Volume stress
force then a stage is reached when on removing the force, the body will not (a) It occurs in solids, liquids or gases.
return to its original state. The maximum deforming force upto which a
body retains its property of elasticity is called elastic limit of the material of (b) In case of fluids only bulk stress can be found.
body.
(c) It produces change in volume and density, shape remaining same.
Elastic limit is the property of a body whereas elasticity is the
property of material of the body. (d) Deforming force is applied normal to surface at all points.
(7) Elastic fatigue: The temporary loss of elastic properties because (e) Area for calculation of stress is the complete surface area
of the action of repeated alternating deforming force is called elastic fatigue. perpendicular to the applied forces.
Due to elastic fatigue: (f) It is equal to change in pressure because change in pressure is
(i) Bridges are declared unsafe after a long time of their use. responsible for change in volume.
(ii) Spring balances show wrong readings after they have been used (2) Shear or tangential stress : It comes into picture when successive
for a long time. layers of solid move on each other i.e. when there is a relative displacement
(iii) We are able to break the wire by repeated bending. between various layers of solid.
(8) Elastic after effect: The time delay in which the substance (i) Here deforming force is applied tangential to one of the faces.
regains its original condition after the removal of deforming force is called (ii) Area for calculation is A F
elastic after effect. It is the time for which restoring forces are present after the area of the face on which force
the removal of the deforming force; it is negligible for perfectly elastic is applied.
substance, like quartz, phosphor bronze and large for glass fibre.
(iii) It produces change in
Stress shape, volume remaining the same. Fixed face
3|Page
Elasticity
Strain elongation) we get the curve as shown in figure. From this curve it is clear
that:
The ratio of change in configuration to the original configuration is
called strain. Elastic region
Plastic region
Being the ratio of two like quantities, it has no dimensions and units. Breaking
Strength
Strain are of three types :
B
(1) Linear strain: If the deforming force produces a Elastic limit A
change in length alone, the strain produced in the body is E C
called linear strain or tensile strain. l P
Stress
l
Linear strain in the direction of deforming force is called
longitudinal strain and in a direction perpendicular to F
force is called lateral strain. O Strain
(2) Volumetric strain: If the deforming force
(1) When the strain is small (< 2%) (i.e., in region OP) stress is
produces a change in volume alone the strain
proportional to strain. This is the region where the so called Hooke’s law is
produced in the body is called volumetric strain.
obeyed. The point P is called limit of proportionality and slope of line OP
Change in volume( V ) (V – V)
Volumetric strain gives the Young’s modulus Y of the material of the wire. If is the angle of
Original v olume( V )
OP from strain axis then Y = tan .
(3) Shearing strain: If the (2) If the strain is increased a little bit, i.e., in the region PE, the
deforming force produces a change in the x stress is not proportional to strain. However, the wire still regains its
shape of the body without changing its F original length after the removal of stretching force. This behaviour is
volume, strain produced is called shearing shown up to point E known as elastic limit or yield-point. The region OPE
strain. L represents the elastic behaviour of the material of wire.
It is defined as angle in radians (3) If the wire is stretched beyond the elastic limit E, i.e., between
Fixed face
through which a plane perpendicular to EA, the strain increases much more rapidly and if the stretching force is
the fixed surface of the cubical body gets removed the wire does not come back to its natural length. Some
turned under the effect of tangential force. permanent increase in length takes place.
x (4) If the stress is increased further, by a very small increase in it a
very large increase in strain is produced (region AB) and after reaching
L
point B, the strain increases even if the wire is unloaded and ruptures at C.
In the region BC the wire literally flows. The maximum stress corresponding
Note : When a beam is bent both compression strain as
to B after which the wire begins to flow and breaks is called breaking or
well as an extension strain is produced. ultimate tensile strength. The region EABC represents the plastic behaviour
of the material of wire.
Stress-strain Curve (5) Stress-strain curve for different materials are as follows:
If by gradually increasing the load on a vertically suspended metal
wire, a graph is plotted between stress (or load) and longitudinal strain (or
C
E C E
C
Stress
Stress
Stress
P P
The plastic region between E and C is small for The material of the wire have a good plastic Stress-strain curve is not a straight line within
brittle material and it will break soon after the range and such materials can be easily changed the elastic limit for Elastomers and strain
elastic limit is crossed. into different shapes and can be drawn into produced is much larger than the stress
Example: Glass, cast iron. thin wires applied. Such materials have no plastic range
Example. Mild steel and the breaking point lies very close to elastic
limit. Example rubber
Stress
material of the body and the manner in which the
body is deformed.
(2) It's value depends upon the temperature l
O Strain As by definition, coefficient of linear expansion
of the body. L
(3) It’s value is independent of the l
Thermal strain
dimensions (length, volume etc.) of the body. L
There are three modulii of elasticity namely Young’s modulus (Y), So thermal stress = Y [As Y = stress/strain]
Bulk modulus (K) and modulus of rigidity () corresponding to three types And tensile or compressive force produced in the body = YA
of the strain.
5|Page
Elasticity
L
to F and the elongation in wire is l then energy stored in the wire
2
It is clear that the value of force constant depends upon the dimension 1 (F1 F2 )
(length and area of cross section) and material of a substance. U l
2 2
(vii) Actual length of the wire : If the actual length of the wire is L,
then under the tension T , its length becomes L and under the tension T , its 1
1 1 2
Thermal energy density = Thermal energy per unit volume =
length becomes L . 2 2
T1 Thermal stress strain
L1 L l1 L1 L …(i)
k 1 F l 1 1
= = (Y )( ) = Y 2 ( )2
T 2 A L 2 2
and L 2 L l 2 L 2 L 2 …(ii)
k Breaking of Wire
L1 T2 L 2 T1 When the wire is loaded beyond the elastic limit, then strain increases much
From (i) and (ii) we get L
T2 T1 more rapidly. The maximum stress corresponding to B (see stress-strain
curve) after which the wire begin to flow and breaks, is called breaking
Work Done in Stretching a Wire stress or tensile strength and the force by application of which the wire
In stretching a wire work is done against internal restoring forces. breaks is called the breaking force.
This work is stored in the wire as elastic potential energy or strain energy. (i) Breaking force depends upon the area of
If a force F acts along the length L of the wire of cross-section A and cross-section of the wire i.e., Breaking force A
stretches it by x then
Breaking force = P × A
stress F / A FL YA
Y F x Here P is a constant of proportionality and
strain x/L Ax L A
known as breaking stress.
So the work done for an additional small increase dx in length, F
(ii) Breaking stress is a constant for a given
YA material and it does not depend upon the dimension
dW Fdx x . dx
L (length or thickness) of wire.
Hence the total work done in increasing the length by l, (iii) If a wire of length L is cut into two or more parts, then again
l l l YA 1 YA 2 it's each part can hold the same weight. Since breaking force is independent
W 0 dW 0 Fdx 0 . x dx l of the length of wire.
L 2 L
(iv) If a wire can bear maximum force F, then wire of same material
This work done is stored in the wire.
but double thickness can bear maximum force 4F
1 YAl 2 1 YAl (v) The working stress is always kept lower than that of a breaking
Energy stored in wire U Fl As F L
2 L 2 stress.
Dividing both sides by volume of the wire we get energy stored in breaking stress
So that safety factor = , may have large value.
unit volume of wire. working stress
1 F l 1 1 (vi) Breaking of wire under its own weight.
UV stress strain Y (strain )2
2 A L 2 2 Breaking force = Breaking stress Area of cross section
1 Weight of wire = Mg = ALdg = PA [P =Breaking stress]
(stress)2 [As AL = volume of wire]
2Y [As mass = volume density = ALd]
Total energy stored in wire (U) Energy stored in per unit volume
of wire (U )
Ldg P L P
V dg
1 1 Fl This is the length of wire if it breaks by its own weight.
Fl
2 2 volume
Bulk Modulus
1 1 When a solid or fluid (liquid or gas) is subjected to a uniform
stress strain volume stress strain
2 2 pressure all over the surface, such that the shape remains the same, then
there is a change in volume.
1 1
Y (strain )2 volume Y (strain ) 2 Then the ratio of normal stress to the volumetric strain within the
2 2
elastic limits is called as Bulk modulus. This is denoted by K.
1 1
(stress) 2 volume (stress ) 2 K
Normal stress
2Y 2Y volumetric strain
F/A pV (V – V)
K
V / V V
where p = increase in pressure; V = original volume; V = change in Fractional Change in the Radius of Sphere
volume
A solid sphere of radius R made of a material of bulk modulus K is
The negative sign shows that with increase in pressure p, the surrounded by a liquid in a cylindrical container.
volume decreases by V i.e. if p is positive, V is negative. The reciprocal of
A massless piston of area A floats on the surface of the liquid.
bulk modulus is called compressibility.
4 m
1 V Volume of the spherical body V R 3
C = compressibility = 3
K pV
S.I. unit of compressibility is Nm and C.G.S. unit is dyne cm .
–1 2 –1 2
V R
3
Gases have two bulk moduli, namely isothermal elasticity E and V R
adiabatic elasticity E .
R 1 V
(1) Isothermal elasticity (E) : Elasticity possess by a gas in …(i)
isothermal condition is defined as isothermal elasticity. R 3 V
For isothermal process, PV = constant (Boyle’s law)
P
Differentiating both sides Bulk modulus K V
V
PdV + VdP = 0 PdV = – VdP
dP stress V P mg
P E E = P …..(ii)
(dV / V ) strain V K AK
P 1
or 1 [1 CP] As K C
K
7|Page
Elasticity
O Strain O Strain
If we have two tyres of rubber having different hysteresis loop then (4) For a given material there can be different moduli of elasticity
rubber B should be used for making the car tyres. It is because of the depending on the type of stress applied and resulting strain.
reason that area under the curve i.e. work done in case of rubber B is lesser
and hence the car tyre will not get excessively heated and rubber A should (5) The moduli of elasticity has same dimensional formula and units as
be used to absorb vibration of the machinery because of the large area of that of stress since strain is dimensionless. Dimensional formula is
the curve, a large amount of vibrational energy can be dissipated.
[ ML 1 T 2 ] while units dyne/cm or Newton/m .
2 2
Factors Affecting Elasticity (6) Greater the value of moduli of elasticity more elastic is the
(1) Hammering and rolling : Crystal grains break up into smaller material. But as Y (1/l), K (1/V) and (1/) for a constant stress, so
units by hammering and rolling. This results in increase in the elasticity of smaller change in shape or size for a given stress corresponds to greater
material. elasticity.
(2) Annealing: The metals are annealed by heating and then cooling
(7) The moduli of elasticity Y and exist only for solids as liquids
them slowly. Annealing results in decrease in the elasticity of material.
and gases cannot be deformed along one dimension only and also cannot
(3) Temperature: Intermolecular forces decreases with rise in sustain shear strain. However K exist for all states of matter viz. solid, liquid
temperature. Hence the elasticity decreases with rise in temperature but the or gas.
elasticity of invar steel (alloy) does not change with change of temperature.
(8) Gases being most compressible are least elastic while solids are
(4) Impurities: Due to impurities in a material, elasticity can most i.e. the bulk modulus of gas is very low while that for liquids and
increase or decrease. The type of effect depends upon the nature of solids is very high. K > K > K
solid liquid gas
(1) The body which requires greater deforming force to produce a Diamond and carborundum are nearest approach to rigid bodies.
certain change in dimension is more elastic. (10) In a suspension bridge there is a stretch in the ropes by the
load of the bridge. Due to which length of rope changes. Hence Young’s
Example : Ivory and steel balls are more elastic than rubber.
modulus of elasticity is involved.
(2) When equal deforming force is applied on different bodies then (11) In an automobile tyre as the air is compressed, volume of the air
the body which shows less deformation is more elastic. in tyre changes, hence the bulk modulus of elasticity is involved.
Example : (i) For same load, more elongation is produced in rubber (12) In transmitting power, an automobile shaft is sheared as it
wire than in steel wire hence steel is more elastic than rubber. rotates, so shearing strain is set up, hence modulus of rigidity is involved.
(ii) Water is more elastic than air as volume change in water is less (13) The shape of rubber heels changes under stress, so modulus of
for same applied pressure. rigidity is involved.
(iii) Four identical balls of different materials are dropped from the
same height then after collision, balls rises upto different heights.
The order of their height can be given by h > h > h > h because
ivory steel rubber clay
9|Page
Elasticity