Melting Point and Thermal Physics Problems
The experiment involves heating a known mass of water until it vaporizes, then using an electrical heater to supply energy. A balance measures the mass change as water vaporizes. The specific latent heat of vaporization (L) is calculated using the formula: L = Q/m, where Q is the energy supplied. Measurements include initial and final mass, time, and energy supplied. Errors may arise from heat loss to the surroundings, inaccuracies in mass measurement, and fluctuations in power supply. Reducing these involves insulation, precise balancing, and a stable electrical input .
Specific heat capacity (c) is defined by the equation c = Q / (mΔT), where Q is energy (Joules, J), m is mass (kilograms, kg), and ΔT is temperature change (Kelvin, K). Therefore, the SI base unit for specific heat capacity is J/(kg·K), which derives from energy per unit mass per temperature change .
Specific latent heat of fusion is the energy required to change a unit mass of a substance from solid to liquid at constant temperature. It is significant as it quantifies the energy needed for phase transitions without temperature change, enabling precise calorimetric calculations and applications in material science, indicating thermal stability during phase changes .
From a temperature vs. time graph, the plateau at the boiling point represents the latent heat of vaporization, while the plateau at the melting point represents the latent heat of fusion. The ratio is determined by comparing time durations for each phase change under constant power input, assuming no heat loss. This ratio reflects the energy required for liquid-gas versus solid-liquid transitions .
When the aluminum block is immersed, thermal energy transfers from the hotter aluminum (80 ºC) to the cooler water (290 K) through conduction. This transfer occurs until thermal equilibrium is reached. The aluminum block loses energy and cools down, while the water absorbs energy and its temperature increases. The final temperatures depend on the masses and specific heat capacities of both substances .
The graph of temperature vs. time for gallium heating shows three sections: Constant temperature at the melting point represents a phase transition where energy is used to overcome molecular forces, increasing potential energy without temperature change. Before and after the transition, during heating of solid and liquid phases respectively, the temperature rises as molecules gain kinetic energy, increasing speed and internal energy .
In solids, molecules are closely packed together, experiencing strong intermolecular forces and limited to vibrational movements within fixed positions, resulting in a definite shape. In liquids, the molecular forces are weaker than in solids, allowing molecules to move past one another while remaining in contact, granting liquids a definite volume but an indefinite shape. Gases have negligibly weak intermolecular forces compared to solid and liquid states, allowing molecules to move freely and occupy the entire volume of a container due to rapid motion and increased separation .
An electrical circuit is set up with a power source connected to an embedded heater within the metal block. As the heater operates, it increases the block's temperature, which is monitored using a thermometer. The specific heat capacity is calculated by measuring the power input, the mass of the block, and the temperature change, then applying the formula: Q = mcΔT, where Q is energy supplied, m is mass, c is specific heat capacity, and ΔT is temperature change .
Calculate the energy required to heat the milk using Q = mcΔT, where m = 0.25 kg, c = 4200 J/kg K, ΔT = 80 ºC - 15 ºC = 65 K; Q = 0.25 kg × 4200 J/kg K × 65 K = 68250 J. The mass of steam (m) is given by m = Q/Lv, where Lv = 2.26 × 10^6 J/kg. Thus, m = 68250 J / 2.26 × 10^6 J/kg = 0.0302 kg .
The thermal energy required is calculated using the formula Q = mcΔT. For the pitch, m = density × volume = 2500 kg/m³ × (1.3 × 10^4 m² × 0.06 m) = 1950,000 kg; c = 1600 J/kg K; ΔT = 0 ºC - (-5.5 ºC) = 5.5 K. Thus, Q = 1950,000 kg × 1600 J/kg K × 5.5 K = 1.716 × 10^10 J .



