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Zimsec Chemistry Data Booklet
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Zimsec Chemistry Data Booklet
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ZIMBABWE SCHOOL EXAMINATIONS COUNCIL (ZIMSEC) DATA BOOKLET FOR CHEMISTRY (9189) (Advanced level) For use in all papers for the above syllabus, except practical examinations. June 2006‘TABLES OF CHEMICAL DATA. important values, constants and standards: rmojar gas constant the Faraday constant the Avogadro constant the Planck constant speed of light ina vacuum rest mass of proton, 'H rest mass of neutron, fn rest mass of election, "e electronic charge molar volume of gas Ro =8315K"'mol! F =9.65x10'C mol” L 26.0210" mol" ho =6.63x10%Js. © =3.00x10°ms” m, =1.67x10"kg mm, 2167x107" kg mm, =9.11x10 "kg e V, =22.4dm’mo!” at [Link]. =24 dm’ mol” under room conditions (where [Link]. is expressed as 101 kPa, approximately, and 273 K (0°C)) ionic product of water specific heat capacity of water K,=1.00%10 “ mot*de® {at 298 K [25°C)) = 4.18 kskg 'K" (=4.18 JG" K")tontsation energies (1st, 2nd, 3rd and 4th) of selected elements, In kJ mort ZrozoegezgT z zg AL Ba‘42e7 <——= Ba Br+26 == 2B Ca"420 == Ca CL+2e = 20r 2HOCI+2H'+ 28° <= Ch+2H,O Co*+26 === Co Co +8 === Co” [Co(NH),J° +22" <> Co + 6NH, cr s2e° = Cr crsge = Cr CM +e oS Cr C107 + 14H" +60" <== 2Cr"+7H,0 Cure == Cu cu"+2e === Cu cue” <= Cur {Cu(NH,) "+22" <== Cu+4NH, F420 —= oF Fe"+2e <= Fe Fe" +36" » Fe Fo" +e” Fe" IFe(On) +e” <= [Fe(cn Fe(OH), +e Fe(OH), + OH 2H'+2e° =H, ete — 2 Kre —= K ui ev 40.80 “1.66 -2.90 +107 2.87 41.38 +164 ~0.28 182 -0.43 91 “0.74 om 41.33 +052 10.34 4015 ~005 +287 0.44 0.04 40.77 40.36 ~0.56 0.00 4054 -2.92 -3.04Electrode reaction Eon Mg" +2e === Mg 2.38 un 426° <== Mn a8 Mn 4e Mn +549 MnO, + 4H"4267 <== Mni*4-2H,0 41.23 MnO, +e === Mnf 40.56 MnO, +2H,0+3e <> MnO, + 40H" +0.58 MnO; +8H'+5e === Mal" +4H,0 41.52 NO}+2H'+6 <= NO,+H,0 +081 NO3+SH's 26° => HNO, +H, 40.94 NO,+ 10H" +86 =" NH{+3H,O +087 Nase == Na “271 Ne +2e <= Ni 0.25 INIINH),/" 420° s—* Ni 6NH, -05t H,O,+2H"+2e° =< 2H,0 WIT O, +4 ede == 2H,0 41.23 0,42H,0 +407 === 40H" 40.40 0,+2H'+2e" —= HO, +088 2H,O +267 <— = H,+ 20H” 083 Pot+2e <= Pb 0.13 Pos 28 == Pb 41.69 PbO, + 4H" 207 <= Poh 4 2H 1.47 SOP +4H'+28 === $0, +2H,0 40.17 8,0, +2e <== 2807 +2.01 SOF +26 <== 28,05 +0.09 Sn"42@ === Sn 0.14 Sn42e == sn” 40.18 Voage oss a2 Wee me ve 028 VO"+2H +e VFO 40.34 VOl+2H' +e === VO™"+HO +1.00 VO, 44H +e" = VO" 4 2H. 41.00 an 6267 2n ~0.76 Allionie states refer to aqueous ions but other state symbols have been omitted. 4afb) E¥ in decreasing order of oxidisi. {see also the extended alphabetical list on the previous pages) Electrode reaction Fe2e == OF $,0; +28" —= 2807 H,0,42H'+2e" <= 2H,0 MnO; + 8H’ + 5e7 Mni* + 44,0 — PDO, +4H'+2e” == Pb 2H. Chez ach Cr,OF + 14H'+ 68 === 2C1"47H,0 Br +267 eS 2B NO} + 2H + NO, + HO Age” === Ag Fe"se <== Fe 1+28 == or 0,+2H,0+4e = 40H" Cu" 422 —= Cu Sn"+2e <—= sn* SO} +4H' 426° <= $0,+2H,0 SOF +20 = = 25,08 2H 227 tH, PU'42e = Pb Sn" +26 Fe +267 dn +20" Ma" « 26° Ca +26 Kee = K 4287 42.01 +77 +152 +147 41.36 41.33 107 4081 +080 40.77 4984 +0.40 40.94 40.15 40.47 +0.09 0.00 0.43 014 ~0.44 ~0.76 2.38 ~2.87 2.92Bond energies (a) Diatomic molecules Bond Energy /kJ mot HH 436 Dp 442 NeN 994 o=0 496 FF 158 clot 244 BrBr 193 MH 151 HF 562 HOI 431 HOB 366 Ho 299 (0) Polyatomic molecules Bond Energy kmot* cc 350 cmc 610 c= 840 G:C (benzene) 520 CoH 410 c~cr 340 CBr 280 cat 240 CoN 305 can 610 © 90 co 360 c=0 740 N-H 390 NN 160 Nun 410 on 460 o-0 150 si-ot 359 SHH 320 Sito 44g i 202 250 347 264Atomic and janie redil (a) Petiod 3 {co} (d) fe) metalic single covalent van der Waals Group Group iv single covalent metallic Group Vil single covalent First row transition elements single covalent atomic/ run z-@e7" F992 BeepEy RoQvrwREF vEQ
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