3. 4. INDEX Topics Introduction e Internal Resistance Practical Analysis e Objective * Apparatus ¢ Theory © Circuit Diagram © Procedure © Result & inferences © Precautions * Sources of error Flowchart Conclusion BibliographyINTRODUCTION There is a great need of batteries in our daily use electronic appliances and the use is increasing every day. Thus , the batteries need to be made more powerful so that their potential can be increased greatly . Thus , this project report is based on practical analy: Sor the factors affecting the internal resistance of a cell. When the internal resistance of the cell is decreased we can increase the potential difference across it, and hence make it more reliable.INTERNAL RESISTANCE Internal resistance is defined as the resistance offered by the electrolyte of the cell to the flow of ions. © Its S.J. unit is Ohm (Q) gotent = For a cell of emf. (E) and internal resistance (r), connected to an external stance (R) such that (1) is the current flowing through the circuit, E=Vtlr Internal Resistance r= E-VPRACTICAL ANALYSIS OBJECTIVE To study the various factors on which the internal resistance of a cell depends. APPARATUS A potentiometer, a battery (or battery eliminator), two one way keys, a rheostat, a galvanometer, a resistance box, an ammeter, a cell (Leclanche cell), a jockey, a setsquare, connecting wires and sand paper. THEORY The internal resistance of a cell is the resistance offered by its electrolyte to the flow of ions . The internal resistance of a cell © is directly proportional to the distance between the electrodes. A LJis inversely proportional to facing surface area of the electrodes in electrolyte. decreases with increase in temperature of electrolyte. is inversely proportional to concentration of electrolyte. The internal resistance of a cell is given by: (E-V)/I CIRCUIT DIAGRAM i Ks | Power Supply Leclanche cell + ShuntPROCEDURE [Link] the ends of the connecting wires with sand paper and make tight connections according to the circuit diagram. 2. Tighten the plugs of the resistance box. 3. Check the e.m.f. of the battery and of the cell and make sure that e.m.f. of the battery is more than that of the cell, otherwise null or balance point will not be obtained. To study variation of internal resistance with distance of separation 4. Keep both the electrodes at a distance of 16 cm. 5. Take maximum current from the battery, making rheostat resistance small. 6. Without inserting a plug in key K2, adjust the rheostat so that a null point is obtained on the last wire of the potentiometer. 7. Determine the position of the null point accurately using a set square and measure the balancing length (li) between the null point and the end P. 8. Next introduce plugs in both keys K; and K>. At the same time, take out a small resistance (1 — 5 W) from A LJthe shunt resistance box connected in parallel with the cell. 9. Slide the jockey along a potentiometer wire and obtain the null point. 10. Measure the balancing length (12) from end P. Record these observations. 11. Now keep the electrodes 12 cm apart. 12. Then remove the plugs of keys K; and K2. Wait for some time and repeat steps 7 to 10. 13. Next, keep the electrodes 9 cm apart to obtain another set of observations, To study variation of internal resistance with area of electrodes 14. Keeping all other factors constant, increase the area of electrodes in the electrolyte by dipping them into the electrolyte at different depths for each observation. 15. Obtain three such observations by repeating steps 7 to 10. Record your readings. To study variation of internal resistance with concentration of electrolyte A LJ16. concentration of electrolyte by adding Keeping all other factors constant, decrease the Jor different observations. 17. 7 to 10. Record your readings. illed water Obtain three such observations by repeating step OBSERVATIONS ‘Sno. Ammeter Position of null point(em) ‘Shunt Internal Reading Resistance | Resistance (A) WithR Without R Ra r(Q) ay dy) 1 03 6605 | 35.5 1 0.94 2 | 03 660.5 77.2 177 3. | 03 660.5 108.3, 3 2.51 Table for effect of separation between electrodes ‘Sno. | Separation Balancing Balancing | Internal vid between point point | Resistance electrodes Liem) xfem) r(Q) d (cm) i 12 3266 276.9 | 0.456 0.38 2. 25 320.7 [095 0.38 3. | 3.7 660.5, 1.406 0.38Table for effect of temperature [ Sno. | Temperature | Iifem) L¢em) | Resistance | Internal Tr Teo RQ) Resistance | (QK) ny [2 12 3266 | 2769 0.456 038 | 301.44 2 25 320.7 219.1 0.95 0.38 | 291.96 3. 37 660.5 350.9 1.406 0.38 | 283.87 RESULT & INFERENCES © The Electromotive Force of the cell is constant and is equal to E = 0.98 Volt. © The internal resistance of a cell is directly proportional to the separation between the electrodes. © The internal resistance of a cell is proportional to the area of the electrodes dipped in electrolyte. inversely © The internal resistance of a cell is proportional to the temperature of electrolytes. inversely © The internal resistance of a cell is inversely proportional to the concentration of the electrolyte.YY } 1. The connections should be neat , clean and tight. 2. The plugs should be introduced in the keys only when the observations are to be taken. 3. The positive polls of the battery E and cells E; and E> should , all be connected to the terminal at the PRECAUTIONS zero of the wires. 4. The jockey key should not be rubbed along the wire. It should touch the wire gently. 5. The ammeter reading should remain constant for a particular set of observation. If necessary , adjust the rheostat for this purpose. SOURCES OF ERROR 1. The auxiliary battery may not be fully charged. 2. The potentiometer wire may not be of uniform cross section and material density throughout its length. bM resis lances may noi e zero. [Link] te 1y not bFLOWCHART CONCLUSION Factors Affecting Internal Resistance of a Cell Distance between Electrodes Directly Proportional Area of Electrodes Inversely Proportional “Temperature * of Electrolytes Inversely Proportional Conc. of Electrolyte Inversely ProportionalBIBLIOGRAPHY ° [Link] ¢ [Link] ° by my self e our respected teacker