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CHEM112 Fall Exam Formula Sheet

The document provides a formula sheet that will be provided with the December CHEM112 exam. It contains various physical constants, elemental symbols, and common chemistry formulas. The sheet includes 18 numbered sections with information such as atomic masses, the gas constant R, the Boltzmann constant kb, Avogadro's number NA, fundamental constants like the charge of an electron e, Planck's constant h, and the speed of light c. Common formulas are also listed at the bottom such as the ideal gas law, heat capacity formulas, enthalpy of vaporization, and kinetic energy.

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65 views29 pages

CHEM112 Fall Exam Formula Sheet

The document provides a formula sheet that will be provided with the December CHEM112 exam. It contains various physical constants, elemental symbols, and common chemistry formulas. The sheet includes 18 numbered sections with information such as atomic masses, the gas constant R, the Boltzmann constant kb, Avogadro's number NA, fundamental constants like the charge of an electron e, Planck's constant h, and the speed of light c. Common formulas are also listed at the bottom such as the ideal gas law, heat capacity formulas, enthalpy of vaporization, and kinetic energy.

Uploaded by

neemine329
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

CHEM112 Fall Formula sheet (to be provided with December exam)

Data/Formula Sheet
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

Symbol Value 1A
1
2A 3B 4B 5B 6B 7B 8B 8B 8B 1B 2B 3A 4A 5A 6A 7A 8A
2
1 H He

R 8.31451 J·K–1·mol–1
1.0079 4.0026
3 4 5 6 7 8 9 10

0.08206 L·atm·mol–1·K–1
2 Li Be B C N O F Ne
6.941 9.0122 10.811 12.011 14.007 15.999 18.998 20.180
11 12 13 14 15 16 17 18

kb 1.3807 × 10–23 J·K–1


3 Na Mg Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.065 35.453 39.948
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

NA 6.0221 × 1023 mol–1


4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.098 40.078 44.956 47.867 50.942 51.996 54.938 55.845 58.933 58.693 63.546 65.38 69.723 72.63 74.922 78.96 79.904 83.798
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

F 96485 C·mol–1
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62 88.906 91.224 92.906 95.96 98 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.6 126.90 131.29
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

e 1.6022 × 10–19 C
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.9 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 210 210 222
87 88 89

h 6.6261 × 10–34 J s
7 Fr Ra Ac
223 226 227
58 59 60 61 62 63 64 65 66 67 68 69 70 71

mp 1.6726 × 10–27 kg
6 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 145 150.36 151.96 157.25 158.93 162.5 164.93 167.26 168.93 173.05 174.97
90 91 92 93 94 95 96 97 98 99 100 101 102 103

me 9.1094 × 10–31 kg
7 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.04 231.04 238.03 237.05 244.06 243.06 247.07 247.07 251.08 252.08 257.1 258.1 259.1 262.11

RH 2.179 × 10–18 J 1 atm = 101.325 kPa = 760 mm Hg = 760 torr


or 1.09687 × 107 m–1
STP = 750 mm Hg = 100 kPa = 1 bar
c 2.9979 × 108 m·s–1

ℎ 𝑛𝑛2 𝑎𝑎
1L = 1 dm3 | 0⁰C = 273.15 K | E = hν | c = λν | 𝜆𝜆 = | PV = nRT | d = m/V | �𝑃𝑃 + � (𝑉𝑉 − 𝑛𝑛𝑛𝑛) = 𝑛𝑛𝑛𝑛𝑛𝑛
𝑚𝑚𝑚𝑚 𝑉𝑉 2

V1 V2
∑ BE − ∑ BE χa = na = Pa = Va
1 1
∆H = 𝐸𝐸 = ℎ𝜈𝜈 = 𝑛𝑛𝐻𝐻 � − � x(A) +x(B) + …=1 =
𝑛𝑛12 𝑛𝑛22 T1 T2
broken formed ntot Ptot Vtot

P1V1 = P2V2 | w = –PeΔV = –ΔngasRT | ∆U = q + w | ΔU = qv | ΔH = qp

q Δ𝑈𝑈 Δ𝐻𝐻
q = mCSΔT 𝐶𝐶 = Δ𝑇𝑇 𝐶𝐶𝑉𝑉 = 𝐶𝐶𝑃𝑃 = C P – CV = R pA = xAPA*
Δ𝑇𝑇 Δ𝑇𝑇

P*  ∆H vap  1 1 3RT


ln 2* =−  −  u rms = ∆H o = ∑ ∆H fo (P) − ∑ ∆H fo (R)
P  R M
 1   T2 T1 
KE = ½ mv2 | hν = KE + φ | M = m/n | ΔH = ΔU + PΔV
Past exam “chem112a-2015” selected ANSWERS:

1.A, 2.A, 3.D, 4.B, 5.A, 6.C, 7.D, 8.A, 9.E, 10.C, 11.C, 12.C, 13.C, 14.E, 15.B, 16.B, 17.A,
18.C, 19.C, 20.D, 21.B, 22.C, 23.B, 24.A, 25.C, 26.D, 27.A, 28.A, 29.A, 42.A, 43.B, 45.D

Past exam “chem112a-2018” selected ANSWERS:

1.C, 2.B, 3.D, 4.A, 5.C, 6.D, 7.E, 8.E, 9.C, 10.E, 11.D, 12.E, 13.A, 14.C, 15.A, 16.D, 17.B, 18.E,
19.A, 20.B, 21.B, 22.C, 23.D, 24.A, 25.C, 26.B, 27.A, 28.E, 29.E, 30.A, 31.C, 32.B, 33.A, 35.A,
36.C, 37.C, 38.D, 39.D, 40.B

Common questions

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The entropy change (ΔS) at constant volume can be calculated using the equation ΔS = ΔU/T, where ΔU is the change in internal energy and T is the temperature. This assumes reversible heat exchange at constant volume .

Hess's Law states that the enthalpy change of a reaction can be calculated using bond energies by the equation: ΔH = ΣBE(bonds broken) - ΣBE(bonds formed), where BE represents the bond energy .

The ideal gas law is expressed by the equation PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin .

In gas mixtures, the mole fraction is related to the partial pressure of a component and the total pressure through the relation χa = pa/Ptot. Here, χa is the mole fraction, pa is the partial pressure of component a, and Ptot is the total pressure of the mixture .

According to thermodynamic principles, the addition of pressure increases the boiling point of a liquid. This is described by the Clausius-Clapeyron equation, which states that the change in pressure and temperature is related to the latent heat and the change in specific volume during phase transitions .

The Reduced Planck constant (denoted as h) is significant as it relates energy and frequency through the equation E = hν. It shows that the energy of photons is proportional to their frequency, which is a fundamental concept in quantum mechanics .

The change in internal energy (ΔU) is related to the heat added to the system (q) and the work done on the system (w) by the equation ΔU = q + w. This relationship is a statement of the first law of thermodynamics .

The pressure of a component in a mixture of gases is described by Dalton's Law of Partial Pressures, expressed as pA = xAPA*, where pA is the partial pressure of the component A, xA is the mole fraction of A in the mixture, and PA* is the vapor pressure of the pure component A .

The specific heat capacity plays a crucial role in the calculation of heat transfer in chemical reactions, as it is used in the equation q = mCΔT, where q is the heat transfer, m is the mass, C is the specific heat capacity, and ΔT is the temperature change. It represents the amount of heat required to change a substance's temperature by a certain amount .

The electrostatic constant used in calculations related to electric forces is the permittivity of free space, often denoted as ε0. Its value is not directly provided in the sources but can be derived from the relationship involving the force between charges, which is foundational in physics [in that source context].

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