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Nuclear Chemistry Practice Problems Key

This document provides a key to solving nuclear chemistry problems. It gives the answers to sample problems involving nuclear reactions and radioactive decay. Example problems include writing nuclear equations, identifying original isotopes from decay processes, and calculating amounts of radioactive material remaining after specific numbers of half-lives. The key provides step-by-step workings to find quantities of isotopes that decay over time based on their given half-lives.
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0% found this document useful (0 votes)
70 views1 page

Nuclear Chemistry Practice Problems Key

This document provides a key to solving nuclear chemistry problems. It gives the answers to sample problems involving nuclear reactions and radioactive decay. Example problems include writing nuclear equations, identifying original isotopes from decay processes, and calculating amounts of radioactive material remaining after specific numbers of half-lives. The key provides step-by-step workings to find quantities of isotopes that decay over time based on their given half-lives.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

NUCLEAR CHEMISTRY PROBLEMS KEY

1. Complete the following nuclear reactions:


A. 221
87 Fr  217
85 At + 4
2 He B. 213
83 Bi  213
84 Po + 0
1 e

C. 37
18 Ar + 0
1 e  37
17 Cl D. 131
53 I  4 01 n + 127
53 I

2. Write equations for the following nuclear reactions:


A) Radon-222 decays by alpha emission.
222
86 Rn  218
84 Po + 4
2 He
B) The carbon-14 isotope undergoes beta decay.
14
6 C  14
7 N + 0
1 e
3. A radioisotope decays to give an alpha particle and Rn-222. What was the original
isotope?
a) Po-218 b) Th-224 c) Pb-220 d) Ra-226 e) none of these

4. Plutonium-239 has a half life of 2.41x104 yr. If you have a 10.00 mg sample how much
will remain after 4 half-lives have passed?
4
10.00 mg   = 0.625 mg
1
2

5. If you ingest a sample containing Iodine-131, how much time is required for a 75.0 mg
sample to decay to 12.5 mg? The half-life for I-131 is 8.05 days.
0.693
k t1/2 = 0.693 k= = 0.0861 d-1 A0 = 75.0 mg At = 12.5 mg
8.05 d
 At  12.5
ln   = - kt
  ln = -(0.0861 d-1) t  ln 0.167 = -(0.0861 d-1) t
 A0  75.0
1.79
-1.79 = -(0.0861 d-1) t  t= = 20.8 days
 .0861d 1

6. The half-life of 98Au is 2.7 days. If you begin with 5.6 mg of this gold isotope, what mass
remains after 9.5 days?
0.693
k t1/2 = 0.693 k= = 0.26 d-1
2.7 day
 At  Au t
ln   = - kt
  ln = - (0.26 d-1)(9.5 day)
 A0  5.6 mg
Au t
ln = -2.47
5.6 mg
At
Take anti ln both sides: = e-2.47 = 0.0846
5.6 mg

At = = 0.08465.6 mg = 0.47 mg

Nuclear Chemistry Problems Key

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Understanding alpha emission in Radon-222 decay is significant as it reveals the emission of a helium nucleus (4 2 He), reducing the mass number by 4 and the atomic number by 2, which transforms Radon-222 (222 86 Rn) into Polonium-218 (218 84 Po). This understanding aids in predicting the type of radiation emitted and the characteristics of the remaining nucleus .

The original isotope was Radium-226. Decay involving alpha emission and generating Radon-222 as a product suggests the loss of a helium nucleus, which identifies the original isotope as Radium-226 (226 88 Ra), since Ra-226 decays to Rn-222 by releasing an alpha particle (4 2 He).

Artificial transmutation involves altering an atom's structure via bombardment with particles like neutrons, resulting in new isotopes or elements. This changes atomic numbers and nuclear compositions, potentially leading to the creation of elements not found naturally. Such processes expand our understanding of nuclear reactions and the ability to produce significant technological materials .

To calculate the remaining mass of gold isotope 98Au after 9.5 days, determine the decay constant using the half-life formula k = 0.693/t1/2, resulting in k = 0.26 d^-1. The remaining mass is calculated using ln(A0/At) = kt, then solving At = A0 * e^(-kt), where A0 is the initial mass (5.6 mg) and At is the final mass. After calculation, 0.47 mg remains .

Half-life is the period it takes for half of a radioactive sample to decay. Knowing the half-life allows calculation of the remaining mass over multiple half-lives through successive halving. For instance, Plutonium-239, with a half-life of 2.41x10^4 years, would reduce from 10.00 mg to 0.625 mg after four half-lives due to the multiplicative effect of halving at each half-life stage .

The time required for Iodine-131 to decay from 75.0 mg to 12.5 mg is 20.8 days. The decay process follows first-order kinetics, using the formula ln(A0/At) = kt, where k is the decay constant (0.0861 d^-1), A0 is the initial amount (75.0 mg), At is the remaining amount (12.5 mg). Solving gives t = 20.8 days .

The decay of Ar-37 through electron capture implies a structural change where an inner orbital electron is captured by the nucleus, converting a proton into a neutron and resulting in Chlorine-37. This process decreases the atomic number by one but retains the same mass number, illustrating how nuclei adjust to reach a stable energy state .

Nuclear stability in radioactive decay pertains to a nucleus's ability to remain in its current state. Isotopes like Plutonium-239 are unstable due to their neutron-to-proton ratio, prompting decay processes such as alpha or beta emission to attain stability. Evaluating these transformations assists in predicting isotopes' behavior and decay products .

Bismuth-213 undergoes beta decay to form Polonium-213. During this process, a beta particle, which is an electron (0 -1 e), is emitted, resulting in the transformation of a neutron into a proton. This increases the atomic number by one unit, changing Bismuth-213 (213 83 Bi) into Polonium-213 (213 84 Po).

Knowledge of Iodine-131 decay is crucial in medical practices for thyroid treatment, as its beta particles help target and destroy thyroid tissues, providing a therapeutic effect for hyperthyroidism or cancer. Understanding the half-life (8.05 days) allows precise treatment dosing, maximizing efficacy while minimizing radiation exposure .

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