MARKING SCHEME PAPER 2 1 NO a (i) (ii) (iii) (iv) b (i) (ii) c (i) (ii) NO (a) (i) (ii) (iii)

) (b) (i) (ii) (iii) ANSWER Ester Saponification -COONa Ca2+ and Mg2+ B Biological enzymes//fragrances//Whitening agent//drying agent//Stabiliser//Perfume//Builder//Foam control agent (Any other suitable answers) P Aspirin / paracetamol / codeine Q Psychotherapeutic To relieve anxiety/ restlessness / nervous feeling TOTAL ANSWER Argon 2.8.8 1. Period 3 2. It has 3 shell occupied/consist with electrons The sum of / The total number of protons and neutrons in the nucleus of an atom 6 Estimate the age of fossils / artifacts 1. Show all the number of electron of sodium ion and oxide ion correctly 2. show the nucleus and correct ratio of atom Sample answer: 2 MARKS 1 1 1 1 1 1 1 1 1 9 MARKS 1 1 1 1 1 1 1 1 1

+
O

2Na

Na

or 2O

Na

TOTAL 1

NO (a) (b) (c) (i) (ii) (d) (e) (i) (ii) (f)(i)

ANSWER Voltaic cell

Na2SO4 From magnesium plate to copper plate in the external circuit Magnesium electrode : oxidation Copper electrode : reduction Mg + Cu2+ Mg2+ + Cu
Brown colour solution formed 2Br- Br2 + 2e Fe2+ ion is oxidized to Fe3+ ion Bromine acts as oxidizing agent / Bromine receive electron from Fe2+ TOTAL ANSWER Method B Method A CuO + H2SO4 CuSO4 + H2O A white precipitate is formed Deliver the gas produced to a test tube containing lime water, Lime water turns chalky/milky Number of moles of zinc carbonate - 7.5 / 125 = 0.06 mol, Hence Number of moles of zinc sulphate = 0.06 mol Mass = 0.06 x 161 = 7.696 g ( with unit) TOTAL

MARKS 1 1 1 1 1 1 1 1 1 1 10 MARKS 1 1 1+1 1 1 1 1 1 1 10

NO (a) (i) (a)(ii) (a)(iii) (b) (i) (b(ii)

NO 5 (a) (b) (c)(i) (c)(ii) (c)(iii) (d)(i)

ANSWER * draw stopper on the mouth of conical flask Zn + H2SO4 ZnSO4 + H2 Rate = 30/20 cm3s-1 // 1.5 cm3s-1 Rate = 30/32 cm3s-1 // 0.94 cm3s-1 Rate = 30/12 cm3s-1 // 2.5 cm3s-1 1. The rate of reaction in Expt I is higher than Expt II 2. The total surface area of zinc is larger / bigger in Expt I 3. The frequency of collision between zinc atom and hydrogen ion / H+ is higher 4. The frequency of effective collision is higher. 5. The rate of reaction is higher Point 1 1 mark Point 2 1 mark Point 3/ 4/ 5 1 mark

MARKS 1 1 1 1 1 Max 3

(d)(ii)

* draw three curves with different gradient * the total volume of gas release for the curves are the same

TOTAL NO ANSWER 6 (a) CnH2n+1OH (b) (i) Ethanoic acid (ii) 1. Add Magnesium / zinc / marble chips / calcium carbonate into compound P in a test tube, 2. Gas bubbles produced (iii) Sodium hydroxide (c) (i) Esterification (ii) Colourless liquid // sweet fruity smell //less dense than water // does not dissolve in water . ( any 2 ) (iii) O II CH3 C O CH2 CH2 CH3 (d)
Physical properties Colourless / volatile/ miscible with water / good organic solvent Volatile / highly flammable /high heat content Volatile/ miscible with covalent Uses As a solvent in perfumes / cosmetics / toiletries// As a thinner in varnish/ink // As a cleaner for compact disk/ video cassette // As As a fuel As a raw material to make

11 MARKS 1 1 1 1 1 1+1

compound / antiseptic Chemically reactive

pharmaceutical products in antiseptic/ cough syrup/ rubbing alcohols. As a raw material in the manufacture of vinegar/ fibre/ explosive

Any pair - correct TOTAL 7 NO (a) (b) 1. 2. 1. 2. 3. 1. 2. 3. 4. (d)(i) 1. 2.

1+1 10

(c)

ANSWER MARKS Helium atom achieve stable duplet electron arrangement. 1 Do not donate, receive or share electron. 1 Size of the atom becomes bigger. 1 Force of attraction between nucleus and electron valence become weaker. 1 Atom become easier to donate electron 1 Chlorine atom has electron arrangement 2.8.7. 1 Unstable atom. 1 Need one more electron. achieve stable octet electron 1 arrangement Two chlorine atoms share one pair of electrons to form single 1 covalent bond. Write chemical formula of reactant and product correctly. 1 Balance chemical equation. 1 1

(ii)

Answer : 2Mg + O2 2MgO 1. Calculate the number of mole of magnesium. Answer : 18/24 // 0.75

2. Calculate the mass of magnesium oxide. (iii) 1. 2. 3. 4. 5. 6. 7. Answer : 0.75 X 40 // 30 g Electron arrangement of magnesium atom is 2.8.2 Magnesium atoms donate 2 electrons to achieve stable octet electron arrangement. Form magnesium ion. Electron arrangement of oxygen atom is 2.6 Oxygen atoms receive 2 electrons to achieve stable octet electron arrangement. Form oxide ion. Between magnesium ion and oxygen ion there are electrostatic force to form ionic compound. TOTAL

1 1 1 1 1 1 1 1 20

NO (a)

ANSWER - Nitrogen gas and hydrogen gas are heated together - At temperature of 450 0C and pressure of 200 atm - With iron catalyst - Chemical equation N2 + 3 H2 2NH3 Highly resistance to heat -Inert to chemicals -Transparent except to ultra violet light -Undergoes small expansion and contraction even with great temperature changes. -A good heat insulator -Inert to chemical -Hard and strong Polymer is a long- chained molecules, which is consists of repeating units of monomers

MARKS 1 1 1 1

(b) (i)

(ii)

6 2 2

(c) (i) (ii)

Monomer (iii)

PVC 2

non-biodegradable - disposal into soil can retard the development of root and also hinder the flow of water - hinder the flow of water into the underground streams that cause of flood {Any one explaination} released toxic gases - when they are burnt, they released toxic gases such as hydrogen cyanide, hydrogen chloride and carbon monoxide. Cause deseases . - released carbon dioxide that cause green house effect {Any one explaination} Stable and resistant to oxidation - become breeding ground for mosquitoes - suffocate some of the aquatic animal {Any one explaination} TOTAL

2 20

NO

ANSWER 5

MARKS

(a)

zinc // magnesium // Aluminium // iron Blue solution turns colourless, Brown solid deposited, Zn + CuSO4 Cu + ZnSO4 O/N 0 +2 0 +2 1. the oxidation number of zinc increase from 0 to +2 2. zinc oxidized to zinc ion 3. the oxidation number of copper(II) ion decreases from +2 to 0 4. Copper(II) ion reduced to copper //Zinc replaced by any metal above copper, reject Na/K /Ca Energy Zn + CuSO4 H = - 210 kJ Cu + ZnSO4

1 1 1 1 1 1 1 1

1+1

( b) Apparatus set-up

Correct labell and functional diagram. 1+1

Procedure: 6

1. Put one spatula of solid potassium manganate(VII) in a boiling tube, 2. Then put some glass wool into the boiling tube, 3. Clamp the boiling tube horizontally. 4. Place one spatula of magnesium powder on a piece of asbestos paper and put into the boiling tube, 5. Heat magnesium powder strongly then 6. Heat solid potassium manganate(VII) 7. Repeat the experiment using copper powder, iron fillings, lead powder and zinc powder 8. [Table of observation ] Eg
Reaction Magnesium + oxygen // formulae Copper + oxygen // formulae Observation Burns brightly Glow dimly

1 1 1 1 1 1 1 [1+1] (max 8 )

TOTAL NO 10 (a) ANSWER [able to calculate the percentages of carbon in pentane and pentene correctly] 1. % carbon in hexane = 83.72% 2. % carbon in hexene = 85.71% 3. Percentage of in hexene is higher 4. More soot formed [able to describe an experiment to determine the heat of combustion of named alcohol correctly]

20 MARKS 1 1 1 1

(b)

1. [named] alcohol, water 2. Diagram using suitable apparatus copper [metal]can, spirit lamp, pipe-clay triangle, thermometer 3. [100-300] cm3 of water is measured using measuring cylinder and poured into a copper can 4. The copper can is placed on a tripod stand 5. The initial temperature of the water is measured and recorded 6. About 50 cm3 of [named ] alcohol is poured into a spirit lamp and the mass of the lamp and its contents is recorded 7. The lamp is put under the copper can and the wick of the lamp is lighted immediately 8. The water is stirred throughout the experiment 9. When the temperature of water increases [20 30oC], the flame is put off and the highest temperature reached by the water is recorded. 10. The mass of the lamp and its contents is weighed immediately and recorded (c ) [able to suggest palm oil as the better fats compare to butter] [able to state the advantages of palm oil to our health correctly] 1. Palm oil 2. Highest amount of natural antioxidants such as vitamin E and vitamin A that prevent cancer/ aging/ arteriosclerosis/ Alzheimers disease 3. Does not contain cholesterol that reduce the risk of heart attack/ / boost the immune system // fight cancer 4. Contains beneficial fat such as omega 6 fatty acid that reduce cardiovascular risk factors 5. Has a healthy mixture of saturated and unsaturated fats that are easy to digest and absorb, so that can supply energy needed without causing a rise in LDL or insulin levels in the blood 6. The ability to withstand heat and resist oxidation that makes palm oil an ideal ingredient in frying oil blends TOTAL

1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 20