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Specific Heat Capacity of Kerosene

1) The experiment determined the specific heat capacities of water and an unknown liquid (kerosene oil) by measuring temperature changes over time when heating each liquid. 2) Calculations showed the specific heat capacity of water was 4.19 J/g°C as expected, and the specific heat capacity of the unknown liquid (kerosene) was determined to be 2.84 J/g°C, with an 18.33% error from the theoretical value. 3) The experiment demonstrated how the heat capacities of different liquids can vary and the importance of determining heat capacities in applications like industrial heating processes.

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0% found this document useful (0 votes)
294 views6 pages

Specific Heat Capacity of Kerosene

1) The experiment determined the specific heat capacities of water and an unknown liquid (kerosene oil) by measuring temperature changes over time when heating each liquid. 2) Calculations showed the specific heat capacity of water was 4.19 J/g°C as expected, and the specific heat capacity of the unknown liquid (kerosene) was determined to be 2.84 J/g°C, with an 18.33% error from the theoretical value. 3) The experiment demonstrated how the heat capacities of different liquids can vary and the importance of determining heat capacities in applications like industrial heating processes.

Uploaded by

Safin Rafin Haq
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Lab Report

Experiment Number: H1
Experiment Name: Heating different liquids
and heat capacity of unknown liquid

COURSE TITLE: University Physics – I Lab


COURSE ID: PHY101L
SECTION: 15
SUBMITTED TO: Dr. Md. Mahbub Alam
Department of Physical Science, Independent
University, Bangladesh
SUBMITTED BY:
Shovik Sarker
Student Id: 2325652
Serial No: 25
Experiment No: H1

Experiment Name: Heating different liquids and heat capacity of


unknown liquid.

Assignment: To investigate temperature rise in different liquids


and determine the unknown specific heat
capacity of a given liquid

Theory: Heat capacity or thermal capacity is a measurable physical


quantity equal to the ratio of the heat added to the heat added to (or
removed) an object to the resulting temperature change. When
expressing of same phi someone as an intensive property, the heat
capacity is divided by the amount to substance, mass or volume, thus
the quantity is independent of the size or extent of the sample. heat
absorbed by the object,

Q = mw c w ∆θ

= mo c o ( θf −θi )

c o can be obtained from the equation where,

cw = Specific heat capacity of water

co = Specific heat capacity oil

mw = Mass of the water

mo = Mass of the oil

θi = initial temperature
θf = Final Temperature

∆θ = difference in temperature

Known Specific Heat Capacity


Water 4.19 j/gmk
Oil (Theoretical value) 2.40 j/gmk

Apparatus: (i) Beaker


(ii) Thermometer
(iii) Water, Kerosene Oil
(iv) Stop watch
(v) Sprit lamp
(vi) Wire Gauze
Observation & Measurements:

Table: Measurements of temperature in various liquids with time.


100 ml of water 100 ml of oil (Kerosene)
Time Temperature Rise in Rise in Rise in Rise in Rise in
t θ(℃) Temperature Temperature Temperature Temperature Temperature
(mm) (℃) in 5 min (℃) in 5 min
∆ θ (℃) ∆ θ (℃)

0 27.8 0 27 0
0.5 29.3 1.5 28.8 1.8
1.0 36.7 3.3 34.6 5.8
1.5 36.7 4.1 41.9 7.9
2.0 39.5 2.8 50.0 8.1
2.5 43.2 3.7 33.3 57.31 7.1 62.3
3.0 47.2 4 64.6 7.5
3.5 50.8 3.6 70.8 6.2
4.0 54.8 4 76.7 5.9
4.5 57.9 3.1 82.9 6.2
5.0 61.6 3.7 89.3 6.4
Time Water Kerosene
0 27.8 27
0.5 29.3 28.8
1 32.6 34.6
1.5 36.7 41.9
2 39.5 50
2.5 43.2 57.31
3 47.2 64.6
3.5 50.8 70.8
4 54.8 76.7
4.5 57.9 82.9
5 61.6 89.3

Calculation: In the experiment water & oil have given some amount
of heat in a fixed period of time
c mw c w ∆ θ w c w =4.19 j/ gmk
0=
m0 ∆ θ
mw = v x fw

= 100 X 1

= 100 g
m o = v x po

= 100 X0.8

= 80 g
100× 4.19 ×33.8
∴ co = 80.623

= 2.84 j/8-oc

For water: Temperature ( θfinal−θinitial ) c=33.8 ℃ mean rise in temperature


unit time = ( θfinal−θinitial
5 ) ℃ min
❑ =6.73 ℃/min

For water: Temperature ( θfinal−θinitial ) c=62.3 ℃ mean rise in temperature


unit time = ( θfinal−θinitial
5 ) ℃ /min=12.64 ℃ /min
Theoretical Value exp . Value
Error = ×100 %
Known Value

2.48−2.40
= ×100 %
2.40

= 18.33%

Result:
j
The specific heat capacity of kerosene is 2.84 gm ℃ and the parentage
of error is 18.33%

Discussion : The aim of this experiment was to investigate the heat


capacity of different liquids and determine the heat capacity of an
unknown liquid. To measure the temperature change of different liquids
after wating them to specific temperature. The specific heat capacity of a
substance of heat energy required to heat or cool a substance by a
certain temperature.

Conclusion: In conclusion, this experiment has shown that the heat


capacity of different liquids can vary greatly. Water ha the highest heat
capacity among the liquids we tested, while the unknown liquid had the
lowest. Such as in the design of heating and boiling systems for
industrial processes, and in the study of thermodynamics

Precaution:

i. The temperature should be taken after some the of heating.


ii. The temperature value should be set carefully based on the
stop watch time.
iii. Calculations should be done with care.
iv. Be careful of fire, because it is really dangerous.

Common questions

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Several precautions are crucial: (i) ensure accurate temperature readings by allowing sufficient time for heating to stabilize and using a reliable thermometer; (ii) synchronize temperature measurements with stopwatch timing to correlate time with temperature changes accurately; (iii) carefully perform calculations to avoid arithmetic mistakes; (iv) handle the apparatus carefully to avoid exposure to dangerous elements like open flames. These measures help reduce errors associated with experimental conditions and data collection inaccuracies.

The observed specific heat capacity of kerosene was 2.84 J/g°C. This result is compared to the theoretical value of 2.40 J/g°C. The experimental value exceeds the theoretical value, with an error percentage of 18.33% calculated as (observed - theoretical) / theoretical × 100%. This discrepancy indicates deviations potentially arising from experimental errors such as heat losses or measurement imprecision.

The specific heat capacity of an unknown liquid can be determined by utilizing the relationship between heat energy, mass, specific heat, and temperature change: Q = m * c * Δθ, where Q is the heat added, m is the mass, c is the specific heat capacity, and Δθ is the temperature change. By measuring the temperature change (Δθ) for a known mass (mo) of the unknown liquid as it is heated, and comparing it with the measurements of a liquid with known specific heat capacity (such as water), one can rearrange the formula to solve for the unknown specific heat (co), using the known heat absorbed by the liquid (Q = mw * cw * Δθ for water). This calculation requires accurate temperature and mass measurements to minimize errors.

The mass of a liquid affects its heat capacity measurement because the total heat required to change the temperature of the liquid depends directly on its mass, as denoted in the formula Q = m * c * Δθ. In the experiment, mass is accounted for by using a fixed volume (100 ml) for both water and oil. Due to the difference in densities, this results in different masses for the two liquids (100 g for water and 80 g for oil in this experiment), which is incorporated into calculating the heat applied. Accurate mass measurements are crucial for precisely determining specific heat capacities.

Precise measurement of temperature rise is crucial because the accuracy of determining heat capacity directly depends on the change in temperature (Δθ) observed during the experiment. Small errors in temperature measurement can significantly skew the calculation of specific heat, as it is used in the formula Q = m * c * Δθ. Inaccuracies in temperature recording can lead to large errors when calculating the specific heat capacity, especially since the experiment involves precise multiplication and division operations with measured quantities.

Heat capacities are critically significant in the design of industrial heating and boiling systems because they determine the amount of heat required to achieve desired temperature changes in different substances. Materials with higher heat capacities, such as water, are used as coolants in systems where temperature regulation is necessary. Conversely, substances with lower heat capacities might be preferred for quicker heating applications. Understanding these properties ensures energy efficiency and process optimization, which is essential for industrial system design and operation.

Water is often used as a reference liquid in heat capacity experiments due to its well-known and relatively high specific heat capacity (4.19 J/g°C), which provides a reliable standard for comparing with other substances. Its heat capacity is also constant over a wide range of temperatures, and it is chemically stable and non-toxic, making it a safe and convenient benchmark in experimental settings.

Based on the experiment, water has a significantly higher specific heat capacity of 4.19 J/g°C compared to kerosene's observed specific heat capacity of 2.84 J/g°C. This means that water requires more heat energy per gram to increase its temperature by one degree Celsius compared to kerosene. This higher heat capacity of water affects its heating and cooling properties in practical applications, making it slower to change temperature than liquids with lower heat capacities, such as kerosene.

The error percentage in experimental heat capacity values can significantly affect the conclusions as it indicates the deviation from expected theoretical values. A high error percentage, like the 18.33% observed for kerosene, can call into question the accuracy of the experimental setup and the reliability of the results. Such discrepancies might be attributed to experimental errors such as heat loss to the environment or measurement inaccuracies. Addressing these errors is crucial for ensuring that the conclusions drawn are accurate and reflective of true material properties. High error margins can also impede practical applications, as they reduce confidence in using these values for industrial or scientific purposes.

Calculation errors in determining specific heat capacity can stem from inaccurate temperature measurements, incorrect mass measurements, and misapplication of formulae (Q = m * c * Δθ). Mitigating these errors involves calibrating thermometers, accurately weighing samples, properly aligning the timing with temperature readings, and ensuring correct formula usage. Additionally, data should be repeated with multiple trials, and averaging results can help minimize random errors and provide a more reliable measurement.

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