Salting Methods for Fish Preservation

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The document discusses various methods for preserving fish and meat through salting, curing, and fermentation. It describes how salt draws water from foods like fish to lower water activity …

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Gret Chen
  • Salting, Curing, and Fermentation
  • Cured Meat Color
  • Other Optional Ingredients in Cured Meats
  • Curing Methods
  • Smoking

SALTING, CURING, AND FERMENTATION

• Curing
- Curing when applied to the preservation of meat or fish means
preserving with salt followed by drying and or smoking. Salt was used for
preserving fish probably as far back as 20, 000 years ago as evidenced by
archeological studies of marine fish bones found in cave dwellings.
• Preservation of Fish by Salting
- Salt is an effective osmotic agent that can draw water from food
materials, such as fish, thus lowering its water activity and affecting
preservation. However, longer product shelf life can only be achieved when the
salt concentration approaches the saturation concentration of over 25% salt.
• The Salting Process
- The salting method applied depends on the size and composition of the
fish. The common methods are dry salting, brine salting, and a combination or
hybrid method.
Dry Salting Brine Salting

Various methods of salting are applied depending on the objective of the salting
process:
1. In products like Tinapa the objective of salting is mainly for flavoring
with preservation being achieved by smoking and chilling on freezing.
2. Immersion in concentrated brine is also called pickling. This is done foe
longer-term preservation and is advantageous for fatty fishes because
oxygen from the atmosphere is restricted by immersion thus retarding
rancidity.
3. Some fish, usually bigger non-fatty fishes, are split, opened out flat, and
salted. The salted split fishes are layered and the brine that forms are
allowed to drain off.
The other method is a modification of the kench curing, where the brine that
forms is allowed to collect and the fish is immersed in the brine.
• Salt and Salt Impurities
- Various places in the Philippines produce solar salt which is prepared by
evaporating seawater from salt beds where seawater collects. As the water
evaporates and saturation concentrations are achieved coarse sodium chloride
crystal form.
Nitrate/nitrite, now used as preservatives and an essential in meat curing were
first discovered as an impurity in salt. Such impurity was in abundance in the
salt deposits of Prague in the Czech Republic. This is the origin of the name
Prague power for nitrate salt.
Salt impurities of solar and minced salt may be as high as 20%. It is necessary
to be cognizant of impurities when using salt in food preservation.
• Spoilage of Salted Fish
- The most significant spoilage microorganisms are halophiles which require
10% salt for growth and exhibit pink discoloration in the fish.
• Meat Curing Ingredients
- The basic curing ingredients are salt, sugar (or another sweetener), and
nitrite.
• Salt
- Salt is the basis for all curing mixtures. Its preservative action is due to its
effect of lowering water activity and inhibiting microbial growth. It is a
flavoring material and also increases the gel strength of sausage mixtures.
• Sugar
- Sugar is added to the curing mixtures to balance the flavor. It is also has a
softening effect on the cured product by preventing the removal of some
moisture on the surface.

• Nitrate and/or nitrite


- Nitrite is an effective curing agent and nitrate is a source of nitrite. Nitrite
functions as follows:
1. stabilize the color of the lean tissue,
2. contribute to the characteristics and flavor of cured meat,
3. inhibit bacteria responsible for spoilage and food poisoning, particularly
Clostridium botulinum
4. retards the development of rancidity.

• Cured Meat Color


The active agent in curing is nitrate oxide (NO) and generated as follows:
  NaNO3 --------> NaNO2 ----------> HONO  --------> NO
Note that the sodium nitrate (NaNO3) is first reduced to Sodium nitrite
(NaNO2), then to nitric oxide before it can be useful in the curing reaction.
1. Sodium nitrate is reduced to sodium nitrite by microorganisms present in
meats.
2. Sodium nitrite is reduced to nitrous acid in the presence of an acidic
environment (e. g by fermentation)
3. Nitrous acid forms nitric oxide. Nitric oxide reacts with myoglobin (meat
pigments) to form a red color.
Cured Meat Color Formation
The maximum levels of nitrate and nitrite allowed in cured meat products are
strictly regulated. In a pickle cure at a 10% pump level, the concentration of
nitrite should not exceed 2.27 g per liter, while for direct addition or dry cure
the maximum level is 1.63 g per kilo of meat.
• Nitrosamines
- There has been concern over potential health risks from nitrosamines in
cured meat products. Nitrosamines are compounds that can form when nitrites
combine with amines, a natural component resulting from the breakdown of
proteins.
• Saltire/Potassium
- Nitrate has been disallowed by BFAD to be used in any cured meat
products. The rationale for the prohibition is that it is very easy to overuse.
Instead, curing salts such as Prague Powder which contain more ordinary salt
than nitrite is recommended.
Other Optional Ingredients in Cured Meats
• Phosphate
- Phosphate has wide applications in the meat processing industry.
Phosphate is added to increase water-binding capacity and consequently the
yield of the finished product. Their water retention property is due to 2 actions,
the raising of the pH and the unfolding of the muscle proteins to accommodate
more water binding sites.
• Sodium Ascorbic and Erythorbate
- These reductants react with nitrite to give nitric oxide, thus fastening the
development of the pink-red color in cured sausages. Only sodium ascorbate
and erythorbate (isoascorbate) are used in practice since ascorbate and
isoascobate acids react directly with the nitrite.
• Potassium Sorbate
- Potassium sorbate is an antimicrobial agent, particularly effective in
inhibiting mold growth.
• Monosodium Glutamate
- Monosodium glutamate is used to enhance the flavor of meat products and
although its effect on cured meat flavor is not widely recognized
• Hydrolyzed Vegetable protein
- Hydrolyzed vegetable protein is added to many cured meat products and
sausages both emulsion and non-emulsion types to increase protein content and
yield.
• Carrageenan
- Carrageenan is a naturally-occurring carbohydrate extracted from red
seaweed. There are three basic types of carrageenan: kappa carrageenan, iota
carrageenan, and lambda carrageenan.
• Sodium and Potassium Lactate
- These additives are used to extend shelf life: enhance intrinsic product
safety by controlling food-borne pathogenic bacteria such as E. coli, C.
botulinum, L. monocytogenes, and protect meat flavor.
• Spices
- Spices include a wide assemblage of true spices, herbs the vegetable
bulbs. The term “ true spices” usually refers to genuine natural spices that
include dried rhizomes, flowers, or their parts of fruits or seeds of different
plants, principally grown in tropical and subtropical regions, containing
aromatic and pungent substances and used for seasoning meat products.
Meat Curing Methods
Curing is carried out at refrigeration temperatures (2.2 degrees C/36 degrees
F to 4 degrees C/40 degrees F). At colder temperatures, the meat will not cure
properly. Warmer temperatures encourage the growth of spoilage in the
container.
• Dry Curing
- Dry curing involves applying the cure mix directly on the meat. Once the
blend of curing salt, cure aids and seasonings (optional) is prepared according to
a recipe, it is rubbed on and into the meat at the correct usage rate.
• Brine Curing
- Brine curing is also popular for curing meat. This method is also called a
sweet pickle cure. Brine curing involves mixing the curing salt with water to
make a sweet pickle solution. The meat is cured with this brine by injecting the
brine using a meat pump or by soaking them for a specific time.
• Combination cure
- This method combines the dry rub cure with the injection of brine solution.
A combination cure is used for curing hams. This methods shorten the curing
time required and reduce the chance of spoilage because the curing process
takes place inside and outside of the ham.
• Sausage Cure Method
- The method for making cured sausage is different from the curing
methods described above. Curing salt and spices are mixed with ground meat.
• Smoking
- Three traditionally recognized reasons for smoking meat; for preservatives,
appearance, and flavor. Smoked meat is less likely to spoil than unsmoked
meat. Smoking improves the flavor and appearance, aids to reducing mold
growth, as well as retards rancid flavors.

JESSECA U. FRANCISCO BTVTED FSM-2

Common questions

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In meat curing, sugar is primarily used to balance the flavor by offsetting the salty taste from the curing agents . It also contributes to a softening effect on cured products by preventing excessive moisture removal from their surface, thus enhancing texture . The presence of sugar not only enhances flavor but also ensures that the cured meat retains a desirable mouthfeel and prevents it from becoming too dry or unpalatable .

Spoilage in salted fish is primarily due to halophilic microorganisms, which thrive in high-salt environments, such as those requiring at least 10% salt for growth . These organisms cause pink discoloration and spoilage of the fish . Counteracting strategies include ensuring a sufficiently high salt concentration, often above 25%, to inhibit even salt-tolerant bacteria, and proper handling of fish to reduce contamination . Adequate storage conditions, such as low-temperature environments, further help mitigate spoilage risks by reducing microbial activity .

Salt impurities can significantly affect fish preservation by influencing the efficacy of the curing process. Impurities like nitrate/nitrite, originally found as impurities in salt deposits, serve as essential preservatives in meat curing . However, in fish preservation, impurities can interfere with the salting process, potentially leading to a reduced effectiveness of microbial inhibition and spoilage prevention . Proper management involves selecting purer forms of salt or accounting for impurity levels in the salting calculation to ensure effective preservation without adverse effects on flavor or safety .

Phosphates in meat processing primarily enhance water-binding capacity and increase meat yield by raising pH levels and unfolding muscle proteins to create more water binding sites . This not only ensures a juicier, more tender product but also extends shelf life by maintaining moisture content, reducing drying and shrinkage during cooking . Their role is crucial in processing various meat products to maintain quality and consumer appeal by ensuring an appealing texture and appearance in the finished product .

Smoking in meat preservation serves three primary functions: it acts as a preservative, enhances appearance, and improves flavor . The smoke contains compounds that have antimicrobial properties, reducing the likelihood of spoilage and extending the shelf life of smoked meats . Additionally, smoking imparts a unique flavor and a distinctive color to the meat, making it more appealing to consumers . This process also helps reduce mold growth and retards the development of rancid flavors, further extending the meat's freshness and consumer appeal .

Primary methods of salting fish include dry salting, brine salting, and hybrid methods. Dry salting involves directly applying salt to the fish, which is effective for flavoring as seen in products like Tinapa, where preservation is achieved through smoking and freezing . Brine salting, or pickling, involves immersing fish in a concentrated salt solution, which is particularly beneficial for preserving fatty fish by restricting atmospheric oxygen and slowing rancidity . Hybrid methods combine aspects of both dry salting and brine methods to adapt to the size and type of fish . Each method is tailored to achieve a balance between flavor and preservation while considering factors like fish size and fat content.

Nitrite plays several roles in meat curing, enhancing both preservation and quality. It stabilizes the color of lean tissue by reacting with myoglobin to produce a desirable red color . Nitrite imparts flavor characteristics distinctive to cured meats and significantly inhibits growth of bacteria, including Clostridium botulinum, thereby preventing spoilage and food poisoning . Additionally, nitrite delays rancidity development, ensuring both safety and flavor longevity in cured meats .

Fermentation contributes to cured meat color through the reduction of sodium nitrate to nitric oxide, which then reacts with meat pigments like myoglobin to form a stable red color . The process starts with microorganisms in meat reducing sodium nitrate (NaNO3) to sodium nitrite (NaNO2), which is then further reduced to nitrous acid under acidic conditions typical of fermentation . Nitrous acid forms nitric oxide, facilitating the color formation by its interaction with myoglobin . This chemical cascade depends on an acidic environment and microbial activity inherent to fermentation, ensuring consistent color development in cured meats .

The primary health concern associated with nitrosamines in cured meats stems from their potential carcinogenic properties . Nitrosamines are compounds that can form when nitrites react with amines, which are naturally present in proteins . To address these concerns, the levels of nitrates and nitrites in cured meat are strictly regulated to minimize the risk of nitrosamine formation . Furthermore, alternative curing methods or agents that reduce the need for high concentrations of nitrite help mitigate these health risks .

Potassium lactate is used to extend the shelf life of meat products by enhancing their safety and quality. It works by controlling food-borne pathogenic bacteria, including E. coli, C. botulinum, and L. monocytogenes, which are significant contributors to spoilage and foodborne illnesses . By inhibiting these pathogens, potassium lactate ensures that meat products remain safe to consume over extended periods, thus enhancing the product's marketability and reducing waste . Additionally, it helps in maintaining the flavor integrity of preserved meats, offering both consumer safety and taste retention .

SALTING, CURING, AND FERMENTATION
•
Curing
         - Curing when applied to the preservation of meat or fish means 
preservi
The other method is a modification of the kench curing, where the brine that 
forms is allowed to collect and the fish is imm
1. stabilize the color of the lean tissue,
2. contribute to the characteristics and flavor of cured meat,
3. inhibit bacteria
Other Optional Ingredients in Cured Meats
•
Phosphate 
       - Phosphate has wide applications in the meat processing indust
•
Sodium and Potassium Lactate
       - These additives are used to extend shelf life: enhance intrinsic product 
safety by c
•
Smoking 
      - Three traditionally recognized reasons for smoking meat; for preservatives,
appearance, and flavor. Smoked

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