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What is meant by Fuel(Biomass) Characterization?
Fuel characterization concerns with the “analysis” and “energy
content of fuel” (also known as calorific value). Fuel analysis
comprises of “proximate” and “ultimate”.
Analysis of biomass:
There are two methods of analysis:
(1) Proximate analysis
(2) Ultimate analysis.
The proximate analysis determines only the fixed carbon,
volatile matter, moisture and ash percentages and the ultimate
analysis determines all biomass elemental components
(C,H,O,N,S).
(1)Proximate Analysis
Measurement of Moisture
Determination of moisture is carried out by placing a sample of
powdered raw biomass in an uncovered crucible and it is placed in
the oven kept at 105+2 °c along with the lid. Then the sample is
cooled to room temperature and weighed again. The loss in weight
represents moisture.
Measurement of Volatile Matter
Fresh sample of biomass is weighed, placed in a geyered crucible,
5. fot 6 AF Minuteo
and heated in a furnace at 900 +10 C,,The sample is cooled and
weighed. Loss of weight represents moisture and volatile matter.
The remainder is coke (fixed carbon and ash).
Measurement of Carbon and Ash
The cover from the crucible used in the last test is removed and the
crucible is heated over the burner until all the carbon is burned. The
residue is weighed, which is the incombustible ash (Ash is made of
inorganic materials, mostly calcium, potassium and magnesium
etc). The difference in weight from the previous weighing is the fixed
carbon. In actual practice Fixed Carbon or FC derived by
subtracting from 100 the value of moisture, volatile matter and ash.
FC(%d.b.) = 100-VM(%d.b.)-Ash(%d.b.)-M.C. (%d.b.)(2)UItimate Analysis:
The ultimate analysis indicates the
constituents such as Carbon, Hydrogen, Oxygen, Nitrogen, Sulphur
ash element etc,
various elemental chemical
Calorific value of biomass: ///// Shir @
Calorific value is defined as the amount of energy released from the
complete combustion of a unit mass or volume of a combustible
material. It is measured in kJ/kg, MJ/kg, kcal/kg or keallm’ ete.
Two calorific values are generally defined; these are the higher
heating value (HHV) and the lower heating value (LHV)
The High heating value (HHV) or high calorific value (HCV) or gross
calorific value (GCV):
High calorific value may be defined as, the total amount of heat
products when one unit of the fuel has been burnt completely and
the products combustion have been cooled, so that the water of
combustion is entirely condensed and that the heat contained in the
water vapour is recovered
The low heating value (LHV) or low calorific value (LCV) or net
calorific value (NCV):
Low calorific value may be defined as, the net heat produced when
unit mass or volume of fuel is completely burnt and products are
allowed to escape and that the heat in the water vapours is not
recovered.
Net or lower C.V. = Gross C.V. - Latent heat of water formed