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THERMODYNAMICS (Shortnotes)

Basics Of Thermodynamics

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Aritra Goswami
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31 views4 pages

THERMODYNAMICS (Shortnotes)

Basics Of Thermodynamics

Uploaded by

Aritra Goswami
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
REED OW GE aio ' _ BASIC CONCEPT. % Intensive properties '- Independent of mass | afProp. memains same on its fraction] {xz Temp, press, density. sp. vol", sp heat Lé[Link]) Sp. enthalphy + Extensive properties? depends on mass Exe volM, enexgy, heat cap, enthalphy PY= maT (x [Pv= ORT Pabs. 9ress.(ka) n> [Link] mole = = NO YoIMat canines) perc we masimass of gases Saree oe Recher gas conch (KiTkg-6) > 8.214 Ks} KmalA T= abs. Temp (k) Re mol ut xR (Press = const 1 Cid vo = contt BV=MRT Y= maT e= Cyr Y=(@gyt ; {ty) ! 4 Mid. of Temp measurement *2-sefesence point system; Wee point [i)stesen poi std en [T=a4bP] b> const Po>thermomels ic prop from eg? ($i) (WIce point: T =e sozatbe -O Xs pte at ice point (id steam point !- T= too > Woo = 4 bR —Uii), Single ref. point systern:- ef Point is the Trigele point of water Tip = WK Gremp. at tripple paint (TeaP pier 5 rere zohip ga BEE , Pkp [ \T = 24316 | Pip Fa steam point: we ane mak we mak frteaig got: | s te times of -tvipple point of Hater. * Anis defined as Boi. (erie 4 hibs phase sule oof phase(s,hig,gas) No of component (af ofan) C22 W Fee Wates/ steam 3 44442 3 =2 Sasa dfah (i tee +Wates 5 24 (id Tee + Hateststeam 3 Fz0 WORK INTERACTION _ Sign _cony.:— WWD by the system > We eat (i) WD on the systems ve + closed ¢ open syctem WD in various process !- frocess closed sist: Gedy open sysb (ue (ews, _cinsed sick: § ‘ remiss y ip a Pit. unde = } the curve: a t era BS eenst vol Wo RenTGE:S) Gieonst press. W = PLV-W) Wee | Gi) > Teme. Neen Coe) Wop = Welosed jf =P Piva maT =meh, GupAdiabatic We Pi -Pava. es oe ae Wop =Wielesed W>Palytropie Wy Woon process, ST=C STI, precess Kan pv =e Poly tropic » kos evccsadicbation 20S v= vol" const, Slope fins oles esnst press > * Giyemstvoims 4P | Slope SAqna=0 tha Gid 50th Palytropic, naiabatic grecess’~ slope $8 uF) + Tsothevmal (= 4) > slope = =P * Polytropic (k=n) 3 slope = neg) + Adiabatic (k=¥d > Slope = w EE)! Scanned with CamScanner HEAT INTRACTION . (g- meat] csp, pace) AT Temp dif. ede heat me->Hert oxpacity( $y % vei of [Link] :— ky subst st temp acid & HR _ eeett heat & requi. dA By kg, aT= ou Weak aad 3486 » Re 3 Cerey > because Op include = #6 includes only Tat. energy. [ ds =| Prele=co-c] Adis alfa gy 3] index Sensible} Phase game Latent 3 Temp same Hest temp. aie eat — phase ait A LAW OF TD Valid for = closed system, cyclic, BV. fh ivev: process. NoTE:= Heat § Work Transfer is @ path fn inexact differential £ Boundary phenomena SO= dbs Gu h Ea of 18+ law of To for afprocess} E=0 3 for cychi 1c ef dE= d(ke+pesu) : pea yc eo [SG= du + SW [PNAid for > closed sys. process Aswerl as aide gev give. process Neglect Keg pe GG= dU + Pav| > for closed, Rev. process [Enthatphy tay = ut oy e(se-enthalphy(h)= ures] Flow work, j # for ideal gas;- [a cu }3 valid fox AU types of process meat mepdt —4£ Ex of Heat transter for closed system :— (i) const vol™ Process (ji) const: press. §e=d0+6n" so= du+pay §e=d(used f= at= red ofngpocrd (iw) Adiabatic process (uv) palytropic process Pi int. enexgy aswell as e+ ove Serres ag? > ©) (y= we = Se tiultie xi Any DOTA = Ba Sma wt 2c AD aggua os foeogs ca POT OFM eg SW Scots fg ‘Open system mass f energy Balance. i mm = const ae locity GAG = hae a = ‘ Steady flow > Teratet Hie) + Geexilnat ch 5 Bay ie ¥als Shs kils kis SEO divide by mm coe v o| (r+ sk Mr) = brs B+ B32), ey 1080 unit = KS/eg @ Steady flow enesg eqn(on Ist lau of To foropnag| formula orm] 48) Qw=hon Sa Gneggle SS, Cha PECange — GD Treatated ( 2. ORG Gi) Tuveine 2G @: 2 Wi) cysea Gii) compresses >. G) seal) 920 ene 2 WD asa ty ae "| Mg () Theetting. © ceativacae {he hal WW Wev=0, g20. [Esse] (ou= EP Gwe] Scanned with CamScanner 2" LAW OF TD concept of COPS done (Tn RAC Gasic concept) 13.2nd 19 of tp #E clausiue Thequatity for a cycle. lausius Thequatity := cl § aa. + § 98 5 5 cmposible device $e Entropy : = Measure. of disordemess(exyrandorness aE Entsopy principle :- BORA. device § 48 comer. device (S)yqi =o 5 Rev. device «Bienes fo" | CSuniro ste, — Lerarge Te) (As)unico Stmpossible » # Entropy change of a system for Secsss tn (=, (When heqt is added +o the system} entropy (s)} f= seh Dithen heat is tes fom the stems sy EE ve sue = const (as= ## Entsopy Change of syst fox Int. process ‘— > [as = (58 ln. [As = (EY, + S300 nota prep its dust (Heat addition 5 st quantity Gi) Heat veq9 3 entropy vill inct, deet (ox) const aoe Soges"® depend on Value of S900, TNwe 48 Ti i Th , 5 [trea = Fras} 5, (eRe) oes uate stig 4coanct a\dles- = 1-25 Tsent. comp 2-3-3 const temp: heat adit J,. 3-4 sen}. exon ’¢ 4A) Tsothermal heat sefn, Ar combine 1S g and Jaus of TDi- Serine HT Band Jaws of TD :~ Sa=dusedv4i) gg =tds Ci) From (i) shi) ores appa fox Be (re proces elt-ds = du-vdPb fox Rev ¢ Drv. intews of enthaiphy HFSlope of Various process on dig Osothrermal process @ Rev. Adiabatic process (Gc) cS — dope =o! pe @ wnst voll process: Ww =O) ® Const press (P=ey Tas =dyt pdy [Link] eae ley @ Slope of const vain > Slope of const press. Ht Entsopy of Tdeal gas in texms of - OTemp £0 [es cre) net & fesHfaungy sania] Pad © Temp { press:- Bes=coin(y-elo[ dy a © Vols. press: [ese cin &) sean s 7 Ar Erhvopy change of finite 4 cond af phase chan of ieagrent Teak u [Link] ( have Yap (TE-Ta) | Bbq = hed glTa-Ta)}OSa= Step), eta hotcedua Ue: 9), PSO¥CQ, In e qin @) > SO-Chhig. An (@) “SUMIT KR” Scanned with CamScanner

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