Scribd
Upload
12 views35 pages

Untitled

Uploaded by

Souradeep Hazra
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
12 views35 pages

Untitled

Uploaded by

Souradeep Hazra
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
POLYMERS The word Poly mea los @ ma al n “a mts ( podts ) foly mes fs ote dined as a Charms Caf Substances of q hah mole Wales morys Combincetioan Jer med by Hee embi nati can £ hu ‘ ° . “y! hue bo of Ample molecules, NéCH, = cH) —> [-chy = CH= J, Ctra lene fog ethap lene Puk omgin, \albrch vneeens -\ he Prews by llbich +e mane mers Te Grbined and Hansfermed “inte Polym iS Known os ‘impmademata n[Menomer] —s Poly mer Diffoenu betureen fly mers and Matromole ules + fotg murs we alo Glleol macromolecules cle Jo theth lodge Sige but Grverse is not doug, ma vho- mole Cule or may het Gunton monomer unis, ad ChloroPhglt C Co Hy My Ma) Io a macromele (ux) e but not a felymow Aree thuie ae ho mokomey units Prermb So we Can ConClucle trou all Polymer, abe Hel macromeletules pllvile all macromole Culex may not be folymuns fr Wotwre , ) Scanned with CamScanner @ Homo Polymers and Co- Palmers. Deperebih upon He nubirke of Phe epeating SHradonad Wt, polymers ake Seyided nto Iwo Gy agentes Ww Homofely mrs Gy Copely rads Ww Hom ofelymens |. felymas Idhene Pepeating Sructural nike ake cberived from only one Ygbe 0] tanorach nits ake Called homepely rtrd, fer oq: pelyrs iwi ih obtained by flgmdizatien of. etylers mole tales, the. 9 epeatih Stmctuhal unrt re 7 Ch Cy = i'n clertved Grom ont - ‘phe 4 Tranpms /¢ Cth lene , nhs = ch, Hlymoiaatian | (-¢y — CH —), CP etaytesy J € ely men ) Ethulens (Menem) WD GPely mars |. folymens [hone Depeading, Shruchural tuntls are clunived fren tise or “more tybe of moncmes Urtt$ are Cll eof Gfolymars , fey on nly —Cow > —Nhy Hera rethyl tntctia ming Poly mudtiation Cmaneras ) [FCN to n HQOE ~ (Cit), — Coot ~ Cty y --] eho cece (Nylon c6) Scanned with CamScanner o Classif tation po mers’ oO uw) folymers are Clauss eof Th @ number of alot, , Clare ‘ WH oclion baseol upon GSOTR | Clawi}'Gtien based ube Shractaxe an p , n UW) ctawse freuen bayeo! p : pan Symctienss, WW) Cla fration based ten ‘craheintepetlemreey, w Classifetion ba ded ben Source |. Depenctlig then tre Seurce Irom Intech, thy Ue Obstet Pokymers are broadly deviated Prte +0 Clettes (1) Nestural Polg vn ers Poly mers hihtth ame found fn hatire je th animals, and Plante are Calleel | ~ Stokes, Cellulore, pe tubs, nucluc gals, hatiral 2ebber te. (2) Sgnthenc Polya OAS Te Poly mens Wich are Prtbared fh He laboratory ake Rrown as Aepetatic felymers OY ‘Man Mracle folymers Jo felpethene, Ayretiatic rebbes, Pvc, Wplen-6¢, teFten, otfen ede. @) SemiSpnthetie Jolyrmers!. Poly mens obtain ed raking Some meets J Gabi sn iy Na Peaep folymurs asipey means, We [Known as CemiSyrtnadic felyrers « G- Cellud ose acetate Coe40n) Scanned with CamScanner @ an Classi fi Cation based on Structure | _ onthe bees of Structure, floly mersare clavicled fate Huu tghee : (1) Liner Polymers These ae the oly mers i'n Id hich He Trenomes Unite are Linked to whe anotwh fo Jom fony Linear Cheuns. Tare (Ubeah Chains ohe Clepely fleck ea th spau, The Close facing. petults th bh elise dena'e Shength and high reels g and boiling forrts. q- eon ee RPO, algatasexe ate AN Line chk Polymer (2) Branched Chain Polymer’. Th uch Poly mAs, the manomers untts ade iste Ke fore long “Chalns tasith Some branche! Chains © differant lengths with Source, fs aoaut of Brunch gree poly mus are net Cly Packeol fn spac, Thus , have fous olinsit'es "lon fesileg4y ength as well “os fow rrelding anol oil Porists ey rumor ep etc, L tleen Branch ed Chain, Poly mer Scanned with CamScanner © B) (voss- binkeol Poly mens ' ‘Mm Such, fly mers, the monemds unthe are Like tages fe Jom fate climmsianal nediorke, Thuse abe Chpect ed to "be quite hand, rigvd and fotttte , oy - emedale g i THEE lamaicejormetdelyyole faiymer + I 0 Cress linked Pelg rte UD Cla Glen bas eal OH Syvtreer (Poly rev’ secbion Peymaigavon Taal octuas by tMto Toole |. Ww) Adetitron Paty muri gation 2) Gnolurpatinn Poly morse Depenclng Upon Htrese balo trocles of deyrcthuses , foly mers hove bean broadly Clamsi fied fro uso type Ud Aletetr-tian fly mens i The Poly mons formed the poly muri seution of Tan om Gitawhq clowble or Arple bonols ( Cunsaturabe/ Gmpourcty Pins led addition Ply Aeeitiisn Polgrmons howe he Same empiri Gal formula 4 —Hhelr mransmdc, (Hy nO CH= cy — 5 (-n- y-), Prefglehe Pelpb rep dene (Monomer ) Se \ Scanned with CamScanner ) (2) Gonden sation Polymets |. THe Poly yaks lthich are formed by the Gomhination of I Harta ehs With te Clim) notLion of Pemulh qnole tales Such as Wat, (sho! , drogen Chloride ele. ane hexametly lene cliamthne — i lth adipic aud, Thee ake albo (abled Sine ey Oe ferred wa %eull of stepwise yeathons. nH, —CChy), — Ney, 9 le te )¢ —Nblg ask tt 2 : + - > [nn terye-nn eee, -E wn Hooc Cl Dy, —(0oH Nylon 66 Aenic acl Falteo (WV) Clase AGtian bagel on moleluler Forces |. YW) Llastomers Thise care Dubber Lhe Ach Poly mera fn kd ntch Hee Cheu'ng coe ul dog etres frees Go hatesal Sabber, F Poly mes break est inten mole Cetees he Una-5- buna-N ede, The Veteak —bihetrag force Pormit the Pelymirs to be Stretched A fur ‘ Crets inks are Introckuced > beliareen pve Chains, Ihuth help Phe Joly mas te Petract te Its onde fesit'on aftr the Jere Ws Weleaged os fh Viels's tel Dubber, , (2) Fibers! Firbre, belong fe a clans of ae Iulvth ore hres! dike and” Gn be Itven fi We. Mae are Wii: used for tre lng, Clothes, Wess, 4 gangs, de. A Scanned with CamScanner Fibres Possers hugh fensile Strength belause phe Chours fo mes Shen Prd mele (ules fores Auth ar hg ebreg / lap hate honcliing, » Ore Jibrey are Crptallene in ¥ tie ond bate Sharp malig fetnts. q Jao enanplex “4 ig thes irene, seerrphene and ' () Thamoplashes!. There have ake fi'neas Begrom and howe tweak Vancdes Meal! forces athig inthe Veetsous Chouns, Prege forces ahe fmt Oh rmecticete of the Jor ces Prevent fy the Clartemers anol fy the Wiboer. When banded thay mutt and form a J hed Wh sets ty = fede a hand mats con Cooly. Thus they Gn be Gyr fate chifferend haps by cing, Austtable rmoutels, eg | EE papayas. y Thermo setting Plastics! . Phase are normally Semifliy! Substancu yuith low Ymsletulan meses, abhin hected , tly LeCome paral crref in-Pistble lus to -the Cross dint bebwieen the flyer Cheuins, fs a peputh, they tho helene -+iree Amansienal fn na tude 4 Jus fe s Grnman —Hurmosett rans U!U!Uw!_—£€ Scanned with CamScanner ) . ’ ’ é (hod.s of Ply mensch wmetheds ag? natal, octirs by tue foty mosseation me ) NetotHonal Poly meru'sa tian Y 4 en CQ) Goolensatioh fest mnths Salsa d Wy) Aotels Honad Poly men sation’. his tebe of fly mo sertin frvelver hu Ceansve adolit/as » 4 c of Menemes Unis fo the Rowolng Chau, Gre ing a yeactive frteymediate fuck “as a “Jree yack’ Gut Q a , a i ' GrboGHen or a (arbowan Ts, add #0 or Chetty ps foly me sation Pryel¥Ct Cheri > ececkens ct W) free RadliGl mechanism |- Ge mahomeths Ubeol cL thal monosub SH tute alk- -ertss Ge mest Grmmanly used Gtalysts cre bengegd Pereraiote, bydrepensperciadle ot coobypy le Perovaite: ‘Oe, i , Mecharasm ;. The Qeaetion Mmueluer the fiewg Steps, Steph! Chain indlading Step Gn ths a Sb, flercouite tmotrgoes hamelyte fission, ey a en hada! Pradaces fata Scanned with CamScanner 2 ° ' ! Gle— 08 ! a a ul $F O-o= Gy ——> 2 GH 6-0 o Benzoyl Prewile Beha ey fon Yael Gl (fads) J PGi + 2, — Ghe + Ch =cH : TO Gis ch, —Oy Step T- chain haan Propegatin SHep |. qT ne fre Rei ect adely fe ano-ther mrelettes =f rrahomes orm a dodger pu Rete Gul Gis Ch —cH, +0 =>; : a 2 $= CH, > G Hy Cty Ctly Cy Clty Repub ramp Hires nCHy = Chy Ghee (C4 ~ Cy Cy — Cn, siep Chain 40mination Step. Thre are Hoe was of chain Fermingten . Gupti ‘reactlagy spo por Hanalicon Peach on, Chetin transdo, oe eng rmmole of fete net oh of Chain fs Shown ay — CMs-ClH—CHle pC Hy Cy + . ch = Gel Cy Cy dy Chhy CMe hb es Che dy Ore Crary ~ Cy Co Ms Scanned with CamScanner © CH) Gebtvonie Poly merisation |. CarboCtion \ich aro germrected T+ fvelves formation o Fy, Ally, ShUy ede and prete hewrs accls (Le ~We avels Kuch as H, Sey 1 HE Oe bogher the Sta bi hing of (Catbobablan Indetmediate mere Is He each 09 mane mery -leroatele Gane %deb41 cs, poly ran Seti ory Gs Mvol ves the fellocotag step . Stps)- Duration <+ep '. Hy Sey > Wy HS0y = Bhz +e — ut + BF, Con) + — (ty); Cc Cy Zecca) ey, ™~ (CH3); C+ Cy = CCH), —5 Ct ),—C — CH ECO), nly = CC) ( é (Ci) C= [ Ce eC CHG), ], — Cy CCH) g Step IT - Termination |. 55 (chy ClCH, Cou), J, CHC Ce) -h , a ig )g¢ [ery eC 1], Cy = C06), Scanned with CamScanner yw Gil) Aponte Poly meni saci - T+ fvelues Jermatian of Involved th thus procs ae Steps - Iwhation /, ‘putatien Strong bese, gd cy inibater, a Crbelation Grbanian, Steps + HANH, —> Rr 4 Su, 6 S i Ch = CHEN + Nt —— HN-CH,CHCN b c , GN CYCHEN EC =CHCN —> Hy N— Cy — CH Oem) — [my — CHEN JC Chen Step D- Trmnation’. © - Hy NCH CHCCN) [cH cHen), — ClCH CN ={3 All, Ch, CHC CN) [-C% CHM] | ~ CH, Cy CN (2) Grelensetiisn oly merisution '- Se peat en: ; ; ae Plymor'satian Mibith occurs Ih g SHepuo'ne is notion of Dome Amally mole tus) e4 ke po, ih ( ty Pete? Ret oe 15 Concerned py tps, Step oly mer sation en. bic ’ as aclbic aul and henar ere - ~clramine Phenol b Prymerseian, = Te Malgele ee: tneltge Sb ahaa Scanned with CamScanner W Nededrol Rubber ’- ar fs prtpared J rom qubber frees, Chem Gully , Gy ofr jure, His a polyenes ° (a Po metal. J, 3 bulacting), fodeae lalsch 1 obtalined (poem dubbo prucdoraed robber ts poly ee 9 pre bey alro tub ats 1'coprthe }™ 9 Ch; ony ! n= C-CH aC s (oly 6 = CH Me) [Soprene, Polpt's oprens Synthe'e Zubbar Canta percha J obtained by Yree dadlns Polgmei Sees n of fsopene has all drans - Con ipicra tian oH, 9 ¢ Nae] an) Y=o me Neng | Ch : ve Ly Neue as - “pel 1coprene CMatural yb$ a) Vadlanizea Rubber‘ Niacbadad frcbh os i's soft and weithy and belomes eytn more So iw het micacther 5 Sis Sensile Adsegte anol 2etstance 4 abrasiny J's alo | drans- Poly "sep deme CG uta preche) ol anol cai fy modntal neo! wt OVW a fow ¢ of Hermp ara putes » 4 1 phese properties Gn se f voved ynahKed: i t z en, lee 2 : a procs (ulled Valcutu’sa Qubbr inh IY, Sulfbac, ea, bridges od (hess Links ta my Chaths cre phtrockeecead . During Yul Gus a Sul, pe ¢ og Scanned with CamScanner Tuse Oss Leks make subbey | the Hick ness “4 Gn be le Teg thay ina Gited Vato ‘n 1839 demove wd ana SH owgen Ons heclchad Subbes Ut the trol Vi choad Punhny we SAup OVER He ote, hut are 1S 1 cue) loc bee pe sige me le Cule Mahle VilGurio ed abbey “Se, S's Clb Mepawite. G)., Pets of Was his Gvered bg Charles Ged yee ( J Sypeteh'e Rubbers o> Some boy tant farms of} Ayrteeli¢ Dubbs are bor emcee! mpm Fy he wef lsotbed below '- Teme double ban brows nef. at ae alt OS. Pry eI eh Abe crntlar te these 5 Ply hectura} Heb b Gn VulGndsed ty tine Hae wy . 2 =CH CH= cH, Gre) ta MrT nC, Scanned with CamScanner @ a) Neoprene ;- Poly yes Jermed by Poly murisatoan ‘ Ayn Heetic. Pbba + d : 4 Chlore pr eet "5 neoprene oF at 7 nCe=d —cH= Ch) — [oy 6a cH Cte, Cidereprenc rrnepr ene G+ 's ured for tne ranufact ring Te belhs , gue and” hones 3) Bung =$ + Tis a Gpely mes of 42 budachene and SHAsrt- Jor 4,3- The o of the name Gune-s ' Ss OB “budads'ens (ail for Socbium Which fs Wed as Hes Poly munis ing aged and Stanels fer Stpere. Dt 1s also Gl Led GB ( Stepene, Butaclene, Rubbery- Sterding mat eal; - 4,3- Butadiene CCH = ch—CH= CH) and Stpune (lg Ug CH = CHy) alow wit. Sbobium , nol, = CH=CH = = Na, Heed fy H=CHy Sa ac, —_—— a 1, 3- butereb'ene Gig es S Ts t Buna- S$ oF SBR, Scanned with CamScanner Molelulas Maw of fegmas. parle Lults have ele — “phead NM, , Mo, Ny Supponing 25 bejore vs cn 1,, Me, Ms et male lafes pave rrolelileh 5 My wespect vel t fo Nit +e Ma + Ng Mg Fon then, I, Ny ere e SNM SN Pobyeu'spersity Trolen \- J4°S the peti, 04 the raw avehage mole (ul ae mar +o the hip 64 avrhage Yrole luda mreess PDI = Ma/Mn for ond Poy ras Por rs Ue 4 uat feo Bhe lbhich rears Hot hey ate munods's pose. Goth, lords, uch fol rere au moht hemeghesus, Gy he Grtraty, eprthatic fols mors Goal, hove PIT >] bthich means thot they ae tay hamegenenus , Gio and Bi'oclerractable Poly mers '- Sythe flyin ade meotlp non = bi ig iis wey difficatt te ala pore off the plymale q* prly monic laste - Paly Cthene bags . Scanned with CamScanner ra Walhith Guy pied ws a vary © of eye ants and the brolegi Gel sores mf vine, Guisel ane Gall bill Preteins , wuclic acids de Gh Hasse fodyrmor de ompe se ok huyselys 7 oan of Liffeunh eng yes Quis mens trad Hay able - Apate Polyetes are the Commun trample 7 clable fe lyme: oy and THs @ Gofalameh « — aad aad (oof —— © Nature has pre be precicceal by ply Aare chadscle rts, J * 7 qhe Leet Ayden “ft Pome Gus oe CH — dH —Chy (oot + CHy—Hy tHe Hy 3 yng wlano‘e Shy dene feulano au: aad oH (y—€ —0- CH ~~ | I oy 7 Gute Seme Gmmor rant Polymers ’- J- folyole frins 2 Twese ake obal ned by the aadelitian foly merisaich CGA amony mele Gules Llhich Contain olouble qu rs Scanned with CamScanner @ nM =H > ON ~ cH )n G 4 Monomer Poly rmer llhore G =H, CHy Gg Hy eC Some Imposter Ply mes ake cuisuured elon 1x Poly ethane ; - Pely muy of eahuyle ne od CHhene. ly Low olinsity Poly Chane CLDP) ois vranurfa led ” heating eHylene 4° 4IZK unedtr a > Oy ube of | Soo ed masp heres ane In presence ofa frac of coy gen: Y FIM, Ise Oct POM etal Cy Cy), That C04 of orgy ‘Relgctiena (High clansrity Paty ebrane (1/00) (CH, = (Hy) 333° 313K Jad n= Me) Rigo Matta (CH chy) Gly a ; ‘ 4 Te olensity clue 40° Clode pring , G4 1's abso rv rurt ancl ynore fouegher and horroles 94 Is red for making yan Coats, fous, fedyG) inslubias, Gt 15 hard and Msictpl Jo heat anol Chemy Gls. CHa = Ne Scanned with CamScanner 6 Sty Rene | @) Pagpstg ene GH Us Terme plstse m > yale Lu Les Fhe manomers Ue Stepan yal e pla enmo pla 4 a fen, joys, vadeo Ge 1S thermo/h stic tesed fer nat ‘d yi fee] Mister I cH My (He Benzoyl fegoructe : | In (gts Styrene GB) folg-vinplchlow de ‘+ Cpve) hl] Ch = Chg Dibeng yf [ | - > J— (4, - CH a Perevele I l a 4 Chilo vo ethene (Vinge Chilo Wels) pyc Gh ts tered for making Yate, Goats, tom, led Gl (nsulation, GF} fs hard and Peslstant fo hat and Chen Gd 4) Poly Propylene ."- Cpp) Dt fs obtatned by fly rudistng Prpulene tn Preence of Batu Gel ty the ' 1 of fol " Clg or dae Seen OF " / 4. h EL P>=belene h Pip pebylene ( PP) Scanned with CamScanner i $) Poly tetra flucroetnene io CTeflen) Clalit nce ( t il Oa = ch) hugh Ff f 6 - cha} h Id [eoreethune : q teflon DH's ChemsGtly (rt and reertont 4e attack. by Gracie engent 94 is Gye} in making oh Stal, qarkebe and qe sola d 4. alc fev hon. Suck Solace “ Cated wensits. 4) Prlpacrmplonitvile '- C PAN) ( Pal ha Seat r" nly = chon) Bly meysatran : 4 ( feronide G klip feo th Polya chalonst ule, AOlons tytle + Poly amides’. [he Poly mins Ialiuich (onder an anu'cle Uiaage in Chen are frnown as fol ya male oi - hon -6,6, 4- Nglon - 66 io G4 1's obtosned by The (ondensation of aclibie au'd cane : . / an hema methylenecdiamine kuith he elimsnab'en of Water Mole Cute ir nHo —¢ ~(CHy)y Sa i Sask 0 M4 —— y + fMyruns satian | —C~(C) y~ CNH Ac Ne nly {Ch ), — iH, ‘Houwisethypencararl na = 5 Scanned with CamScanner © The folyamicies arg febentt Peo] by numbers. 4 hese cee refou fo the Juembes of oben asoms jn chiamins Ano In the clibasie aaids As inthe abave Gat, the (urban alery are 6 fn bith Gre, thotefore fhe reduc 15 cles ubed as upton Cb Properties andl uses Niglen - 66 fs a Unto, Pela mar and has you hugh fensile Strenpth » G} Lhows good Resuiance $0 abrasion Nylon 66 16 usually, fabriGaded tte Abts, G4 1h ed In bristles fey byughes and tn featile, hy) Nylen- 6 Nyton- 6 15 obtained by breaching Ghrelaclar With biater ot 4 , a hgh reesp theta Nott Odvelectreen My sey — Ny oH O Oy a “Gahran A eadangerent Gy Clohenanche Gelohena hoitene hac i My e is 74 Gp¥eledan a (uy ho ie ty WCC ' ome eat” 't Se A Fa “0,2 h Cab rolactem hon ~ 6. Scanned with CamScanner ® % Resine |. “0 Bak elite ) de mn ch , f- Phenol - formelde rreaence of Jreoted pith fer rucetehgele in | eh nated goes (onelenset a” pel mucatron Tt uncle g i a Cons Linked Poly mh hidken flrenef 1 a basic Gtalyst , Jo rn ether a Urea ier oH on oH H Ae ° 6 + \. <0 ny eye He P a oH on n CHyoty Poly merisecticen [ (or On ess Ch Chg -th-1) ho [ oH oH on 6H olf CH, oH pune Toy chy CH. # poly ynens- Co ~shtran CHy Che oe i oH oH oH Scanned with CamScanner we ' ye ts ead for mating Gos, Palgeaph mrt: Baxevte / bahebites alth [ols efor etc: SoH ci eiset on ee fd as bfincling yuue pe “d fam nat eal tnzeocken th 2-) Melamine Formeldehwele fustn | - Chis a Cpely mer Formed by He Poly mets Sectroen of ymelarune Cidien (Sa helenecpeue brfamine) and formelditgate 44 fellows N a 2 A fe sd \ =o — A _» % “ MHC Hy Nv Hh O f t — Mtg Prlyresisction | (~ ee =O ae b = Scanned with CamScanner lens, fh Vabnishes and lacyues, %. Mu 2 3B. MW ‘Which of the following isa polymer containing nitrogen? (a) Polyvinyl chloride (b) Bakelite (@) Nylon (d) Terylene Inelastomer, intermolecular forces are (a) strong (b) weak (©) zero (d) None of these [Natural rubber 1s a polymer of (a) butadiene (b) isoprene (¢} 2-methylbutadiene — (d) ews, 3tiene —{NH(CH3 , NHCO(CH3),CO}s~ Is {a) addition polymer —_(b) thermosetting polymer {e) homopolymer (4) copolymer Which of the following is an example of thermosetting polymer? {a) Polythene (b)PVC_(c) Neoprene(d) Bakelite ‘A condensation polymer among the following ts (a) dacton (b) PVC) polystyrene (d) teflon Which ofthe following is not polyamide? a) Nylon (b) Gilyptal structure (6) Protein (a) Nylon-66, Ebonite is () natural rubber (b) synthetic rubber (©) highly vulcanized rubber (d)_polypropene Which of the following is not an example of addition 99. polymer? {a) Polystyrene (b) Nylon f) AC (d) Polypropylene Dacron is obtained by the condensation polymerisation of (a) Dimeths| terephthalate and ethylene glycol 2 (b) Terephthalic acid and formaldehyde {e) Phenol and phthalic acid (a) Phenol and formaldehyde Which ofthe following isa polyamide? (a) Bakelite (b) Terylene (©) Nylon-66 (d) ‘Teflon PVCis (a) thermoplastic polymer_(b) compound polymer {c) thermosetting polymer (d) simple polymer The synthetic polymer which resembles natural rubber is {a) neoprene (b) chloroprene fe) slyptal (a) nylon ‘The condensation of hexamethylenediamine with sebacoyl chloride at 525 K gives (@) nylon620 (b) nylon601 (©) nylon6,10 (2) none of these Which ofthe following is nota biopolymer ? (a) Proteins (b) Rubber (©) Cellulose (@) RNA Which isnot an example of copolymer ? (a) SAN (b) ABS (@) Saran (4) FNC For natural polymers PDI is generally a @o bt te) 1 (@) 1000 ‘Which is used as medicine” (a) NC (b) Terslene (c) Glyptal(d)_Urotropine Ntlon 66 sa polyamide obtained by the reaction of {@), COOHCH,), COOH + NH.C,[Link]-¢p) {b) COOHKCH.), COOH NIE (CH), Ni (©) COOH (CHf,), COOH+ NEL (CHL), NI {4 COOHC,H, CooleAp) + Nii Ci EXERCISE - 1 (QS MCLs ernny 20, Which ofthe following isnot correctly matched” 2. I th (b) Neoprene [—CHl, —C=CH— CH, f wo wrom fueaciamed cna “The monomer(s) used to prepare polyvinyl polythene is (a) vinyl chlonde and ethene () ethene (6) ssoprene (@) 1, 3-butadiene cu Monomer of| —C—CH,—] is cu, . (a) 2-methylpropene ——(b) styrene (c) propylene (d) ethene ‘Acrilan i hard, horny'and a high melting material Which fof the following represents its structure ? © [* a = | ( a | ay ©) —cy—c— \ o (c= | toocsns) ‘Match Listl (Monomer) with List If (Polymer) and select the correct answer using the codes given below the lists List List It 1 Hexamethylenediamine A. Bakelite ML Phenol B Dacron ML Phuhalicacid € Glyptal IV. Terephthalic acid D Melamine E Nylon Scanned with CamScanner 25, 26. nD. 31. 32. Codes (@) FEMA MERIC (b) LEILA ILC IV-B, (©) FDIECMLAIV-B (4) ED,ILC LA,IV-B ‘The monomer of the polymer; Hy cH, vw, -C- CH < is cn cH, cH, 2 (@) Hc=c (b) CH CHECHCH, cH (© CHCH=CH, Orlon i a polymer of (@) styrene (b) tetraforoethylene (6) vinyl chloride (©) acrylonitrile PN. is formed by polymerisation of (a) (CH),C=CCH,), (a) ethene (b) I-chlocopropene (©) propene (@) I-chloroethene Caprolactam polymerises to give (a) terylene (b) teflon (¢) glyptal (d) nylon-6 ‘The process involving heating of rubber with sulphur is called (@) galvanisation (b) vulcanization (©) bessemerisaion (@) sulphonation Which of the following is used in paints? (a) Terylene (b) Nylon (©) Glyptal (@) Chloroprene Which of the following polymers do not involve cross linkages? (a) Melmae (b) Bakelite (©) Polythene (@) Vuleanised rubber ‘Number average molecular mass, 37, and weight average molecular mass (M7,,) of synthetic polymersare related as (@) My = (My)? (b) Wn= My © Mv>Mn Select the correct statement {@) Vinyon is a copolymer of vinyl chloride and vinyl acetate (b) Saran i chloride (©) Butyl ruber is a copolymer of isobutylene and isoprene (@) All of the above are correct “The polymer used in the manufacture of lacquers is (@) bokelte () glyptal (@) PVC (d) PHBV Low density polythene is prepared by (@) Freeradical polymerisation (©) cationic polymerisation (6) anionic polymerisation (@) Zieglet-Natta polymerisation @ MyCi)> (ii) () (i> (i>, ©) G, i i cH, ° cucu, 0 (CHEMISTRY Nylon isan example of p03] (a) Polysaccharide (b) Polyamide (©). Polythene (@) Polyester Which ane of the following is an example ofa thermosetting polymer? Poi] (@) €C1= C =CH-CHs>, a tb) €CH:=CH, “ 4 HO ° | Ii I (©) N(CH) -N-C ~(CH3)4 = C9, OH ou cH, CH, @ Which ofthe following organic compounds polymerizes to {orm the polyester Dacron? Pony (a) Propylene and para HO—{(C,H,)—OH (b)_Benzoiec acid and ethanol (©) Terephthalic acid and ethylene glycol (a) Benzoic acid and para HO-{C,H,)-OH Biodegradable polymer which can be produced from glycine ‘and aminocaproic acid is Poms] (a) PHBV (b) Buna-N fe) Nylon 6,6 (a) Nylon 2-nvion6 Scanned with CamScanner 1 (© Nylon is a polymer of adipic acid and hexamethylenediamine thus it contains — nitrogen Polyvinyl chloride is polymer of vinyl chloride. It does not contain nitrogen Bakelite isa resin of formaldehyde and phenol. It does ‘ot contain nitrogen. ‘Teryleneisa polymer of ethylene glycol and terephthalic ‘acid. It does not contain nitrogen. It salso called dacron, Elastomers are the polymers having very weak intermolecular forces of attraction between the polymeric ‘chains. The weak forces permit the polymer to be 2 a +o vcr be! feu-ome-cu 1, « @ neennompund sa smentneananine diamine and adipic acid. It is actually Nylon-66, Bakelite isa thermosetting polymer. On heating it becomes hard and infusible thus eannot be remoulded. Polymers which form from condensation polymerisation are called condensation polymers dacron is a condensation polymer of terepthalic acid and ethylene elyco! Glyptal is nota polyamide sw 6 @ 2 t Apobyamide has amidelinkage N= ; i a Hooou t I i -N~(Cliz)y=N. (CHg)4-C~ 1 oO Nilonts honite is a hard highly vulcanized rubber, containing 20-25%, sulphur ‘Nylon isa condensation polymer ‘The polymer of ethylene glycol and tere-phthalie acid is known as terylene or dacron (HO CHa CH ~O11) + yee ol (2) “Terephihalie acid 8 © ow) 10 @ Hints & Solutions Lo 2 @ B@ 4 © 15 16 18 @) 1) a @ ‘Terylene or Dacron It isa condensation polymer. [Note Now a days dimethyl terepthalate is used instead ofterephthalic acid. Thisis due tothe fact that terephthalic ‘cid és non-volatile and very slightly soluble in most of the solvents. Dimethyl terepthalate on the other hand, can be purified by distillation very easily], Thus, option (aiscorrect Nylon is a general name forall synthetic fibres forming, polyamides PVC isan example of thermoplastic polymer. ‘The synthetic polymer neoprene (polychloroprene) is prepared by polymerisation of chloroprene. CH; = C~CH = CH, —22 senses I cect al I Loa a citopee Thisisinfrioetonatral ruber but sore resistant 1 aerial oxidation and oer solvents t t i M,N (CHy~)gNHy +C1~C~ (CHa ~C-Cl Meumctne dine” Seal re f 2s tin =(cHty), (NHC (Ct — Wee Since proteins, cellulose and RNA contra various cries of plants and animals they ate called biopolymers, 17. 6) Urotropine is used as antibiotic for urinary tract infection, nHHOOC(CH,), COOH + nl¥yN(CH3)gNH ‘lipid Herametniene ‘damn ° ° 05K ut i 2585 |-C— (CHC NACH, NH Ip Paine Nba 6 ‘Terylene is prepared by condensing terephthalic acid and ethylene glyco! nllooc: Tevet ci ° ° > ¢ LO) C04, Terylene COOH + nHlOCH,CH,OH exten seo! CH,-0 Scanned with CamScanner 2 2 Be SR 3L S eS Ree 8 4 @ roc (0) Monomer of — € —chts + polymers i dH 2-methylpropene (©) Acrilan isa polyacrylonirle (PAN). © (2) Addition of monomers fellows isoprene rule cH, chy 5 CH, ®C—CH,-C—CH, wane du, dy, (@) Orlon isa wade name of polyacrylonitile (8) PVC. (Polyvinyl chloride) is formed by polymerisation of vinyl chloride, CHj=CHCl, whose IUPAC name is |-chloroethene @ Bb) () Polythene isa linear polymer We (©) PD 30.10) For synthetic polymer, PDI> 1 ° Mw> Mn o © @ ‘Glyptal is used in preparation of lacquers. Ethene on free radical polymerisation gives low density polythene. @ (b) PMMA and polycarbonate is used in bullet proof glass (@) Acrylonitrile isthe monomer used in the preparation of crlon. (b) Giyptl isan alkyd resin obtained from polyydrc alechols and polybasic organic acids or theit anhydrides. They are used for surface coatings (a) Alsoknownas PMMA. Itisa transparent, excellent light ‘transmitter and its optical clarity is better than glass soit {i used in the preparation of lenses for eyes. @ (a) SARAN, a polymer of vinyl chloride (CH,=CHCI) and vinylidene chloride, is used for making synthetic hie wigs 48. (¢) Polystyrene is manufactured by polymerization of styrene inpresence af benzoyl peroxide. CH=CH, maa "HCI T 4. (d) Cellulose acetate has been used in the manufacture of non inflammable photographic films. 45. (@) Nylon tyre cord is made from high tenacity continuous filament yarn by twisting and plying 46 (A) The unbreakable plastic household crockery is made from copolymer of formaldehyde (HCHO) and melamine HN J NA_NH, ‘oon x or HLCOO, _Petuensaton "2 Melamine ohmer Sormalderde Nu, Melaise 47 (@)_Polyhydroxybutyrate-co-B-hydroxyvalerate or PHBV isa biodegradable polymer and thus itcan be used as biomaterials in orthopaedic devices and in controlled drug release CH, -CHCH,COOH+CH,CH, Il gut-cHscoon on on [ : i —> -0-CH-CH, -C-0. ' L oR ly (ney) RACH. CH 48. (d)_ Copolymer of adipic acid (6C) and hexamethylene diamine (6C). ‘8 HOOC(CH,),COOH +nH1y N(CH, )g NU > ‘Alpi Henman 8 ° #C=(CHy)4 = C-NH=(CH)g - NHB, Nsen6 It has high tenacity and elasticity. It is resistant to abrasion and not affected by sea water. It is used for reinforcement of rubber tyres, manufacture of parachute, safety belts, carpets and fabries 2 ©) welt AM ene ZK MA 2a," Ra coy Nowe No (snipe All statements except (b) are correct Scanned with CamScanner aD 50. (a) Neoprene isa polymer ofchloroprene (2-chloro~ 1,3 ~ butadiene) 51a) Pabeters re condensaton polymers fa tsi fndadl eg Tanfene Hocn,ciioHnnooc-Z-coont> 5 4, Stel Prt Te a ao anes f sooncn-oL-Cy-by, a 20) $2 (4) Nepteneisan ation ply spree a r nCH, =CH-C =CH, —Ozetresses — f et ) Leu, -€ «cc Newent 53. (Noon (polyamies are fies SA. (@) Phenol and formaldehyde undergo condensation pohmeanin indo ifr Soins a Be ‘eat i a L0H ae }s cH 25 | cHon @ &) stm 1 8o 7 HOH ao 4 reeeteee, ao Guo ou ou bo a «o se ‘Terylene is made from glycol and Terephthalic acid ay (repaid) The synthetic polymer neoprene is prepared by polymerisation of chloroprene aCH; ~C-CH=CH, +CH,-C-CH=CH, | I a a 4 O,or peroxide (-City-C=CH-Cis~ CH ~C=CH-CH-), 4 4 Plychloroprene of Neoprene ‘This inferior to natural rubber but is more resistant to aerial oxidation and to other solvents Teflon is non-inflammable and resistant to heat so i is ‘used in coating, particularly in non-stcking frying pans SF is used in the vuleanisation of rubber. Sulphur heated with polymer to introduce cross-linking and thus, {form wugh polymer ‘Vuleanization is a process in which natural rubber is treated with sulphur and certain organic compounds which accelerate the reaction between the rubber and sulphur ‘Thusabout 5% is used for making tyre rubber, 20-25% ‘for making ebonite and 30% S for making battery ease rubber Peclon is Nylon-6. Itis prepared fom a single monomer ‘having a potential amino groupat one end and a potential «carbonyl group at other end Biodegradable polymer is Nylon-2- Nylon-6 which is copolymer of glycine (HN — CH, COOH) and amino capric acid HN-(CH),~ COOH) 1nHN—CH, ~COOH + nll;N-(CH,),-COOH Glycine | Amino caproie acid ° ° I I 4HIN—CH,—C-HN~(CH,),- Cy nylon 6 Buna —N isa copolymer of butadiene (CHj=CH-CH-CH,) and acrylonitrile (CH, =CHCN) Scanned with CamScanner 327 67. (b) Nylon6, 6has amide linkage capable of forming hydrogen bonding, {68 (d) Nylon and cellulose, both have intermolecular hydrogen bonding, polyvinyl chloride has dipole-dipole ‘interactions, while natural rubber has van der Waal fares “which are weakest. ow 7. (A) Polynydroxybutyrate-co-f-hydroxyvalerate or PHBV is 1a biodegradable polymer and thus st can be used as ‘biomaterials. in orthopaedic devices and in controlled drug release CH; ~CHCH,COOH+CH;CH - CH-CH,COOH It Il on on i — to-cu-cry-ho LR In censyy Ms, Cally Polystyrene is manufactured by polymerization of styrene Inpresence of benzoyl peroxide &: oS HCI T Bakelite i a eros inked polymer Acrloniie the monomer sed inthe preparation of 7H. (b) Giyptal is used in preparation of lacquers. Be) NEN L(@) Glycine and amino caproic acid are the monomers used for the preparation of nylon-2-nylon-6 2 (@) Polymerisation starts either by condensation or addition reactions between monomers 3. (b) Nylonisa polyamide polymer 4 (b) Nylon6, 6 has amide linkage capable of farming hydrogen ne ou ne Bw wins eta) Sein yay 5 (9 Woh) Me fcr Here X ispoltetrafturoethylene So, none ofthese ie option (ds comet choice 6 (©) PCTFEand PTFE both havesame carbon backtone 4C1FC-CFst, CTF (nec fron) 4RC-Ch}, FIFE (pb tranr yk) (CHEMISTRY 7. (@) Nylon-6 can be manufactured from 0 O NH,OH Cr" = I wie [n,8cem),-co0r| & (SBR (syrene-hutadien) isa synthetic rubber 2 ©) 10. (b) The condensation polymerisation of hexamethylene diamine and adipic acid is done in solution form by interface technique, In this liquid nylon polymer is ‘tained HN ~(CH;), -NH,+ ++nH00C ~(CH;), ~ COOH, {-HN~(CH,), ~ NHCO-(CH,),-CO-], 11, (@) Polymethyl methacrylate ishard thy rigid. tis used fer optical lenses. 12 (@) Generally high boiling esters or haloalkanes act as plasticizer, 13. (&) In addition homopolymers such as teflon, empirical fowmla resembles wth mencmer 14. (@) ABS is acrylonitrile-butadine-styrene rubber which is ‘obtained by copolymerisation of acrylonitrile, butadiene and syrene CH; = CH+CH; =CH I I cn cH=cHy senfentre ‘ebuadene + CH = CHCHs —> Feil; -Ci-CH,CH=CHCH ~CH = CH Low « [ABS rubber Scanned with CamScanner EBD_7327 Polymers 15. (e) Nylon fibres are made up of polyamides. Dacron and orton are made up of polyester, Rayon isartifcial silk made up of polysaccharides. 16. (d) Polyacetylene, due to presence of double bonds, is a condueting polymer. (ch, =cH) 17 (a) Orlonispolymerof acrylonitrile fy) nett, = gH 4 CH= ey os cn 18 (a) Dacron isa polyester and isthe condensation polymer of ethylene glycol and terephthalic aid Its crease resistant v@ 20. (€) Nolon 6, 6 isa fibre with hydrogen bonds thus have strongest intermolecular forces. Buna-S is a elastomer ‘whereas polythene is thermoplastic. the intermolecular forces of attraction in thermoplastics is intermediate between elastomer and fibres. Therefore forces in ¢lastomersare weakest Neoprene is a polymer of ehloroprene, Hence, correct representation is a acl, = CH— ¢ =cH, eri, hep 21 @) f \ [omg HCH; ‘| a Neoprene 2 (b) Vuleanisation isa process of treating natural rubber with sulphur or some compounds of sulphur under heat so as to modify its properties. This cross-linking give ‘mechanical strength to the rubber Bakelite can be heated only once. (@) The time of vulcanisation is reduced by adding accelerators and activators. 25. (b) Due to the presence of strong C-F bonds, teflon has high thermal stability and chemical inertness. aS) 1. (@)_ Glycogen isa polymer of glucose found in live, brain ‘and muscles of animals. 2 (@)_cis:polyisoprene isa synthetic polymer 3 (b) The commercial name of polyacrylonitile is orlon (ccritan), 28 N “en Perondecaaa (CHa — Ce 4. (© PHBVisan example ofbiodergradable polymer. 5 6) HOoe coon nHOCH,—CHOH+ ” os ated © Za OCOCH,, + $68, i ok ocr —er000. Terk ordacron 6d) Lowdensity polythene has lightly branched structure. ; an (@) ncu.=c Moonen CHS oH heey (cH C— CH Om cH Gy, Polymer 4 ° & @) SSB tN —(CH),—Cl, capt Mons SNE Cs cl 9 (b) CH =C-CH= CH, (chloroprene) isthe monomer cof neoprene 10 (b) Nylon isa symthetic polyamide polymer. I. (A) Thermosetting polymers undergo chemical changes ‘when heated and set to hard mass when cooled e.g = omer Kroon B Scanned with CamScanner ne ° t DAA a C xu [Link],CH,OH+n HOOC —_Y—COOH-A > 14 (a) —= Nylows ‘oye wyel Teepatatie aed 15. (a) Natural rubber is found to be a polymer of cis-isoprene ° 9 i its cis-poyisoprene ¢0cH,c-0-C-ZY~ C4, H,C=C—CH= cH, —ehestton ne by, cerbicee tis resistant tomineral and organic acids tis use for ph oe blending with woo! to provide beter erase, in safety ne

You might also like