0% found this document useful (0 votes)
21 views5 pages

Ceramix-R Safety Data Sheet

This safety data sheet provides information on CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING. It lists the product as a water-based e-coating lacquer and identifies key hazardous components including 1-methoxy-2-propanol and butan-1-ol. The document outlines health hazards like skin and eye irritation, lists first aid measures, and provides handling and storage guidelines to mitigate fire and exposure risks.

Uploaded by

Atazha Aguilar
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
21 views5 pages

Ceramix-R Safety Data Sheet

This safety data sheet provides information on CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING. It lists the product as a water-based e-coating lacquer and identifies key hazardous components including 1-methoxy-2-propanol and butan-1-ol. The document outlines health hazards like skin and eye irritation, lists first aid measures, and provides handling and storage guidelines to mitigate fire and exposure risks.

Uploaded by

Atazha Aguilar
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Safety Data Sheet

CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING

Safety Data Sheet dated 14/7/2011, version 2

1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY

Trade name: CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING

Product type and use: Water-based e-coating lacquer


Company:
LEGOR GROUP S.p.A.
Via del Lavoro, 1
36050 Bressanvido (VI)
Italy

Emergency telephone number of the company and/or of an authorised advisory centre:


LEGOR GROUP S.p.A.
tel. +39 0444 467911 fax +39 0444 660677

Centro Antiveleni
Ospedale di Niguarda "Ca Grande"
Piazza Ospedale Maggiore 3
20162 Milano
Telephone: +39 (0) 2/66 10 10 29
Telefax: +39 (0) 2/64 44 27 68
Italiano (French, English)
(24-hour-service)

2. HAZARDS IDENTIFICATION
The product is a liquid that can catch fire at temperatures in excess of 21 °C if exposed to an igniti on
source.
If brought into contact with the skin, the product causes appreciable inflammation, with erythema, scabs,
and oedema.
If brought into contact with the eyes, the product causes serious eye injury, such as opacity of the cornea
or lesions to the iris.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components within the meaning of EEC directive 67/548 and corresponding classification:
30 % 1-methoxy-2-propanol
N.67/548/CEE: 603-064-00-3 CAS: 107-98-2 EC: 203-539-1
R10-67; substance with a Community workplace exposure limit

10 % butan-1-ol
N.67/548/CEE: 603-004-00-6 CAS: 71-36-3 EC: 200-751-6
Xn,Xi; R10-22-37/38-41-67

4. FIRST AID MEASURES


In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the
product must be rinsed immediately with plenty of running water and possibly with soap.

AP032-371/2
Page n. 1 of 5
Safety Data Sheet
CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING
In case of eyes contact:
Wash immediately and thoroughly with running water, keeping eyelids raised, for at least 10
minutes. Following this, protect the eyes with sterile gauze or a clean, dry, handkerchief. OBTAIN A
MEDICAL EXAMINATION.
Do not use eyewash or ointment of any kind (before obtaining an examination or advice from an eye
specialist).
In case of Ingestion:
Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data
sheet.

A suspension of activated charcoal in water, or liquid paraffin may be administered.


In case of Inhalation:
Ventilate the premises. The patient is to be removed immediately from the contaminated premises
and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL
ATTENTION.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:
CO2 or Dry chemical fire extinguisher.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes.
Protective equipment:
Use protection for the respiratory tract.
Cool the containers exposed to the fire with water.

6. ACCIDENTAL RELEASE MEASURES


Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
Eliminate all unguarded flames and possible sources of ignition. Do not smoke.
If the product has escaped into a water course, into the drainage system, or has contaminated the
ground or vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination. The product might, where appropriate,
be absorbed by inert material.
After the product has been recovered, rinse the area and materials involved with water.

7. HANDLING AND STORAGE


Handling precautions:
Avoid contact and inhalation of the vapours. See, too, paragraph 8 below.
Do not eat or drink while working.
Do not smoke while working.
Incompatible materials:
None in particular.
Storage conditions:
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight.
AP032-371/2
Page n. 2 of 5
Safety Data Sheet
CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING
Instructions as regards storage premises:
Cool and adequately ventilated.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection:
Not needed for normal use.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Eye protection:
Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1).
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Exposure limit(s) (ACGIH):
1-methoxy-2-propanol
VLE 8h: 375 mg/m3 - 100 ppm VLE short: 568 mg/m3 - 150 ppm TLV TWA: 100 ppm - 368,59
mg/m3 TLV STEL: 150 ppm - 552,88 mg/m3
butan-1-ol
TLV TWA: 20 ppm - 60,63 mg/m3 TLV STEL: (C 5 ppm) - (C152 mg/m3) skin

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance and colour: Liquid
Odour: Typical
pH: n.a.
Melting point: N.A.
Boiling point: >100°C
Flash point: 35 ° C
Solid/gas flammability: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
Vapour pressure: N.A.
Relative density: N.A.
Partition c. (n-octanol/H2O): N.A.
Vapour density: N.A.

10. STABILITY AND REACTIVITY


Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
Avoid contact with combustible materials. The product could catch fire.
Hazardous decomposition products:
It may generate flammable gases on contact with elementary metals (alkalis and alkaline earth),
nitrides, and powerful reducing agents.
It may catch fire on contact with oxidising mineral acids, elementary metals (alkalis and alkaline
earth), nitrides, organic peroxides and hydroperoxides, oxidising agents, and reducing agents.

AP032-371/2
Page n. 3 of 5
Safety Data Sheet
CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING

11. TOXICOLOGICAL INFORMATION


There is no toxicological data available on the mixture. Consider the individual concentration of each
component to assess toxicological effects resulting from exposure to the mixture.
Toxicological information on main components of the mixture:
No toxicological information is available on the substances. However, refer to Section 3.

12. ECOLOGICAL INFORMATION


Adopt good working practices, so that the product is not released into the environment.

13. DISPOSAL CONSIDERATIONS


Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In
so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION


ADR-UN number: 1866, Shipping name: RESIN SOLUTION
ADR-Class: 3
ADR-Shipping Name: UN1866, RESIN SOLUTION
ADR-Label: 3
ADR-Packing Group: III
Rail (RID): 3
IATA-Un number: UN1866
IATA-Class: 3
IATA-Technical name: UN1866, RESIN SOLUTION
IATA-Passenger Aircraft: 60 L
IATA-Cargo Aircraft: 220 L
IATA-Label: 3
IATA-Packing group: III
IMDG-Un number: UN1866
IMDG-Class: 3
IMDG-Technical name: UN1866, RESIN SOLUTION
IMDG-Packing group: III
IMDG-Label: 3
IMDG-EMS: F-E, S-E

15. REGULATORY INFORMATION


Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and
subsequent amendments. Council Directive 1999/45/EC (Classification, packaging and labelling of
dangerous preparations) and subsequent amendments. Commission Directive 98/24/EC (Protection of the
health and safety of workers from the risk related to chemical agent). Commission Directive 2000/39/EC
(Occupational exposure limit values). Regulation (EC) No 1907/2006 (REACH).Regulation (EC) No
1272/2008 (CLP) (Annex VI). Regulation (EC) No 790/2009 (Annex IV, Annex V).
Symbols:
F Highly flammable
Xn Harmful
R Phrases:
R10 Flammable.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
S Phrases:
AP032-371/2
Page n. 4 of 5
Safety Data Sheet
CERAMIX-R CONCENTRATED RESIN FOR INDUSTRIAL E-COATING
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39 Wear eye/face protection.

Where applicable, refer to the following regulatory provisions :


Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).

16. OTHER INFORMATION


Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand
Reinold
ACGIH - Threshold Limit Values - 2004 edition
The information contained herein is based on our state of knowledge at the above-specified date. It refers
solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the
specific use intended.
This MSDS cancels and replaces any preceding release.

AP032-371/2
Page n. 5 of 5

Common questions

Powered by AI

Emergency preparedness is critical in facilities using CERAMIX-R due to its flammable nature and potential health hazards. Spill management requires immediate containment using earth or sand, notifying authorities in case of environmental exposure, and using protective clothing during recovery processes . Evacuation protocols should ensure safe distance from affected areas, adequate ventilation, and access to medical care if exposure occurs . This underscores the need for comprehensive emergency plans and regular training exercises to minimize risk and ensure a rapid response.

CERAMIX-R should be stored away from unguarded flames, sparks, and direct sunlight in a cool and adequately ventilated area . The product is stable under normal conditions but can become hazardous if it reacts with combustible materials, oxidizing mineral acids, elementary metals like alkalis and nitrides, organic peroxides, and reducing agents . It may generate flammable gases and potentially catch fire in these conditions .

CERAMIX-R is incompatible with several materials that can lead to hazardous situations. It may catch fire or produce flammable gases in contact with combustible materials, oxidizing acids, elementary metals, and organic peroxides . Improper handling, such as exposure to heat or ignition sources, can exacerbate these hazards . Ensuring proper storage away from inciting conditions and incompatible substances is crucial for safety .

The main chemical components of CERAMIX-R are 1-methoxy-2-propanol and butan-1-ol, which pose occupational exposure risks due to their health effects. 1-methoxy-2-propanol has an occupational exposure limit with a VLE of 375 mg/m³ over 8 hours and a short-term exposure limit of 568 mg/m³ . Butan-1-ol has a much lower threshold, with a TLV TWA of 20 ppm, highlighting its volatility and risk . These standards necessitate controlling air quality and personal protection measures to prevent overexposure.

CERAMIX-R poses fire risks, as it can catch fire at temperatures above 21°C if exposed to ignition . Suitable firefighting measures include using CO2 or dry chemical extinguishers . It is crucial to avoid inhaling fumes from combustion, and protective respiratory equipment should be used . Containers exposed to fire should be cooled with water to prevent progression .

The safety data for CERAMIX-R does not provide specific toxicological information on the mixture, but references should be made to individual component concentrations . Good workplace practices are emphasized to prevent environmental release . Eco-friendly handling includes recovering material for reuse, adhering to local disposal regulations, and avoiding environmental contamination . These precautions imply a need for thorough risk assessments and management strategies to prevent potential health or environmental impacts .

Environmental precautions for CERAMIX-R involve limiting leakages with earth or sand and avoiding ignition sources . If the product escapes into water courses or contaminates soil, the competent authorities must be notified . Spill response includes wearing protective gear, stopping the product from entering the drainage system, and recovering the material for reuse or disposal . After collection, the area should be rinsed with water .

Regulations applicable to CERAMIX-R include the Council Directive 67/548/EEC for classification, packaging, and labeling of dangerous substances, Directive 1999/45/EC for dangerous preparations, and Regulation (EC) No 1907/2006 (REACH). Additional directives include Commission Directives 98/24/EC on worker protection from chemical risks, and Regulation (EC) No 1272/2008 (CLP) for hazardous substance labeling .

The primary health hazards of CERAMIX-R concentrated resin include significant skin irritation, such as erythema, scabs, and oedema, and serious eye injury, including opacity of the cornea or iris lesions . In case of skin contact, remove contaminated clothing and rinse the affected area with plenty of water and soap . For eye contact, wash eyes immediately with running water for at least 10 minutes and seek medical examination without using any eyewash solutions unless advised by a specialist . For ingestion, induce vomiting and seek immediate medical attention, potentially administering activated charcoal suspension or liquid paraffin . Inhalation requires moving the person to a well-ventilated area and obtaining medical attention if they feel unwell .

Handling CERAMIX-R requires personal protective equipment including a mask, protective gloves (P.V.C., neoprene, or rubber), and close-fitting safety goggles or face visors conforming to BS 2092 GRADE 1 to prevent skin and eye contact . Comprehensive clothing for skin protection is also needed, using materials like cotton, rubber, PVC, or viton . Adequate ventilation of the storage and handling areas is recommended, although normal use does not require respiratory protection .

You might also like