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Chemical Engineering Process Calculations

This document contains 8 problems related to chemical engineering processes involving heat exchange, separation, and reaction. Problem 1 involves calculating stream flow rates for the removal of benzene from air using zeolites. Problem 2 involves mass balances on multiple components in a reaction/separation process. Problem 3 calculates the condensation of water from humid air during cooling.
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0% found this document useful (0 votes)
31 views5 pages

Chemical Engineering Process Calculations

This document contains 8 problems related to chemical engineering processes involving heat exchange, separation, and reaction. Problem 1 involves calculating stream flow rates for the removal of benzene from air using zeolites. Problem 2 involves mass balances on multiple components in a reaction/separation process. Problem 3 calculates the condensation of water from humid air during cooling.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Tutorial-II

Introduction to Chemical Engineering (CET-201)


Department of Chemical Engineering
National Institute of Technology, Srinagar

Date: 06-11-2021

Note: Submission is not required.

1. The process shown underneath removes benzene from air by adsorption onto the
surfaces of porous solids called zeolites. The adsorption unit shown below has a
countercurrent flow of zeolites, and 1.00 kg zeolite can adsorb 0.10 kg benzene.
Stream 6 purges 2% of the zeolite in stream 5.

Calculate the flow rates of streams 4 and 8.

2. The chemical Q reacts to form Z. Unreacted Q is separated from Z and recycled to


the reactor. The feed contains an impurity, P, which is inert and is purged from the
system via stream 7. The splitter purges 5.0% of stream 5. Note that a mass balance
on Q must account for the Q that reacts to form Z. Likewise a mass balance on Z
must account for the Z formed from Q.
(a) Which stream has the highest flow rate of Q?
(b) Calculate the flow rate of product stream 4, in kg/min.
(c) Calculate the composition of purge stream 7.
(d) Calculate the flow rate and composition of stream 2.

3. Air at 95◦ F can hold a maximum of 3.52 wt% water, defined as 100% humidity at
95◦ F. On a hot humid day the temperature is 95◦ F and the air contains 3.20 wt%
water (90.9% humidity). The air is cooled to 68◦ F. Because air at 68◦ F can hold a
maximum of 1.44 wt% water (100% humidity at 68◦ F), water condenses from the air.
Hot, humid air (95◦ F, 90.9% humidity) flows into a cooler at a rate 154.0 kg/min.
Calculate the flow rates of the two streams leaving the cooler: (1) air at 68◦ F and
100% humidity and (2) the water condensed from the air.

4. Air can be dried by bubbling through sulfuric acid. The absorber below passes air
countercurrent to a sulfuric acid solution. 99.0 wt% sulfuric acid is added to the
recycled sulfuric acid solution to maintain a concentration of 94.0 wt% sulfuric acid
into the absorber.

(a) Calculate the flow rate and composition of the effluent, stream 4.

Page 2
(b) Calculate the flow rate and composition of the recycle, stream 5.

5. The separator shown below produces pure acetone from a mixture of acetone and
toluene.

(a) Derive an equation for the flow rate of stream 2 as a function of x.


(b) Check your equation at x = 0.50. Does your predicted flow rate for stream 2
seem correct?
(c) Check your equation at a different value of x. Choose a value of x that yields an
obvious answer for the flow rate of stream 2.

6. Water is used to cool a stream of cyclohexane (C6 H12 ) in the heat exchanger shown
below. The water is available at 10◦ C and the maximum discharge temperature is
30◦ C. What flow rate of cyclohexane can be accommodated with this unit? Assume
that the pressure in all streams is 1 atm.

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7. A stream of formula X is to be gently warmed to 80◦ C from 30◦ C. Because formula X
is heat-sensitive, the heating source must be exactly 100◦ C. The temperature of the
heating source is maintained by a steam/water mixture at 1 atm.

However, steam is available only at 360◦ C and 1 atm. The process below cools the
hot steam before using it to warm formula X.

(a) Calculate the flow rate of stream 6.


(b) What flow rate of formula X (stream 9) can be accommodated by this design?
(c) What is the flow rate of the water recycle, stream 7?

Page 4
8. Calculate the temperature of the stream leaving the mixer below.

Page 5

Common questions

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At 95°F, air can hold 3.52 wt% water at 100% humidity; however, the actual water content is 3.20 wt% (90.9% humidity) at this temperature. When the air is cooled to 68°F, its capacity to hold water at 100% humidity decreases to 1.44 wt% due to the reduction in temperature, causing some water to condense out. The relationship between temperature and humidity capacity is evident since cooler air holds less water vapor, resulting in condensation during cooling as the air becomes supersaturated relative to its cooler state .

When performing a mass balance for recycling unreacted chemical Q, one must account for several key factors: 1) The amount of Q that reacts to form product Z must be calculated to understand how much Q is utilized in the reaction. 2) The presence of inert impurities like P should be considered, as these will be purged from the system, specifically through stream 7. 3) The process must also consider the purge of unreacted Q in the recycle loop to avoid the accumulation of impurities and ensure process stability. This involves determining which streams have the highest concentrations of Q to optimize recycling efficiency .

When designing a heat exchanger to cool cyclohexane with water, key thermodynamic considerations include balancing the heat transfer between hot cyclohexane and cool water, ensuring sufficient heat exchange surface area, and maintaining effective temperature gradients. The water must enter at 10°C and not exceed a discharge temperature of 30°C. The heat capacity of both fluids, calculated using their specific heat, influences how much heat will be absorbed by the water and removed from cyclohexane. This design must ensure adequate cooling without exceeding the operational limits of the materials involved and consider the heat transfer coefficients for both fluids to optimize thermal performance .

To derive the flow rate equation for a separator producing pure acetone, one must establish mole balance equations based on the separation efficiency and the input mixture composition. The equation should account for the total input flow, the acetone purity requirement, and the residual components such as toluene. For instance, if x represents the acetone fraction in the inlet, setting up the balance involves determining acetone and toluene balance separately and then solving for stream 2's flow rate as a function of x. The accuracy can be verified by evaluating the function at known acetone fractions, ensuring consistency with theoretical expectations .

Engineering a gentle warming process for formula X involves precise temperature controls to avoid degradation. The system uses steam at 360°C, cooled by a separate process, to maintain the heating source at 100°C. This controlled approach prevents abrupt temperature increases. The necessity of maintaining a consistent temperature of the heating source arises due to the sensitivity of formula X, which requires warming only to 80°C. Steam cooling serves as a temperature regulator by condensing controlled portions of steam to achieve the desired lower temperature without fluctuating, ensuring the process's integrity and efficiency .

Sulfuric acid's drying capabilities stem from its hygroscopic nature, meaning it can absorb moisture from the air. In the described process, air is passed countercurrent to a sulfuric acid solution, allowing it to draw moisture effectively from the air stream. The system is maintained by adding 99.0 wt% sulfuric acid to keep the solution entering the absorber at 94.0 wt% sulfuric acid concentration. This controlled concentration is critical to ensuring efficient moisture absorption while minimizing sulfuric acid loss .

Zeolites function as porous solids in an adsorption unit by capturing benzene from air due to their porous structure, which allows them to trap and hold benzene molecules. In this system, 1.00 kg of zeolite can adsorb 0.10 kg of benzene. The process is designed with a countercurrent flow of zeolites which enhances the contact and efficiency of benzene capture. However, the purging of 2% of the zeolite in stream 5 (as part of stream 6) suggests a necessary compromise between maintaining process efficiency and preventing zeolite saturation and degradation. The purging may reduce the overall adsorption capacity temporarily but is essential to preserve the efficacy of the zeolites in the long term .

The principles of vapor-liquid equilibrium (VLE) dictate the interaction between steam and the heat-sensitive stream by ensuring energy transfer occurs efficiently across phase boundaries. For stream 6, which involves condensing steam to provide heat, VLE impacts how much steam can be condensed before the heating efficiency diminishes. The flow rate of stream 6 must correspond with the required heat duties, balancing the need to condense sufficient steam to achieve target temperatures without compromising VLE. The design must consider the latent heat transfer capacity of steam and the sensitivity of vapor pressure changes concerning temperature stabilization .

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