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Problem set # 12 ‘Chemistry 200
Thermodynamics
Name:
1, Automobile airbags solid azide, NaNs, that reacts to produce nitrogen
2NaNa(s) — 2Na(s) + 3No(g)
Calculate the value of work, w, for the following system if 39.1 g of NaNs reacts completely at
1.20 atm and 24°C.
W=- RSV
V met wan
B94 Mans x coed = 0.6 02 mel Van,
0+ 602 mel Nang x —S eve
Deel wow
PVEMRT my 120 tmx Vy, = 0-903mel x 082 SERE y 297K
= Vvzigl
= 0-903 med Mr
. 3235
ee 2-1 a HUG atm Lb x ONE? 5.918855 2-2190
We ~%, AV = -)2eate x (18-04) = nana 3 y
2. 25.1 g sample of methanol, CH3OH, was combusted in the presence of excess oxygen in a
‘bomb calorimeter conaining 3600 g of water. The temperature of the water increased from 25°C
to 65°C. The heat capacity of the calorimeter was 2657 J/°C. The specific heat of water is 4.184
Wg°C. Calculate the intemal energy change (AU) for the reaction in kI/mol.
Heat gainesl by Water = MxCpxAT= B6ooyx 4.184 x (652-252) 2 C0245
3
se
= boo Ky
Heat gaineh by calenimeter = Cx OT = 265Fy x (656-252) = 062807 enous
Total heat evelved = books + Noks eFloky
25.14 CHyon x peseicew = 0.784 aos ao
Hees, = tees 906 Mt Aue = woe HS, oa
3. Calculate the molar heat capacity of copper given that 204.75 J of energy raises the
temperature of 15g of copper from 25° t0 60°C.
VS 5 cor ye NSH = 0.24 mel Cu
BE RCH
Fan KAT a> 204.755 =
124 mol x Cp x (60 b= 25e)
= a
ee as
Dr. Behrang Madani Chem 200 We 4. A piston confines 0.36 mol Na(g) in 2.3L at 25°C. Two experiments are performed. (a) The
gas is allowed to expand through an additional 2.3L against a constant pressure of 0.960 atm.
(b) The gas allowed to expand reversibly and isothermally to the same final volume. Which
process does more work? fe
4013235
A) We - Pe AV =-O:960atm x (MGL~ 2-3 LIE ~E Patel x Goa = Lr0F
Sy 298Kx Ln (HE
bY we-na4ddn Vie a5 w= 0-36 mol x 8314 a
ay we - 685 = -820T
The veversidle proccess cloer move werk than Constant
Pre ssure
5, Calculate the heat that must be supplied to a 600.g ice at -10.0°C to raise its temperature to
the boiling point of water, 100.0°C (the molar heat capacity of liquid water is 75 J.K"'mol"
the molar heat capacity of ice is 37.6 J.K'' mol, and enthalpy of fusion of ice is 6.0 [Link]".
‘The melting point of ice is 0.00°C.
1
6004 Ho x
Wre = 33.3 mal Hio (ice)
BSt0
x\o0 =\28005
\
G@) Best sol. ¢ eme cy x AT © 35.3 mol x 97-6 5
ee
oe &OKT . yooos _ 5
@) Fusion : 33.3 me\ tho x Tan ige * “Ege = Reoonle S
@ Hest Wail ten eg AT =33.3meln ¥5 Toy * lioo'e 0°) = 2:50 x8 J
H
total = Mest ad+ By y+ Heat CSolict) = 2.50 (e854 2 oextfSe125005 BAS KIS T
6. Calculate the heat that must be supplied to a 18.0g of liquid mercury (Hg) at 26°C to raise
its temperature to 390°C. (the molar heat capacity of liquid mercury is 28.0 J.K"|mol the
molar heat capacity of vapor mercury is 81 J.K"!.mot", and enthalpy of vaporization of liquid
mercury is 59.1 [Link]'. The boiling point of bromine is 356°C.
Amt HS x 0.0897 mel H
too. Hy O° 5
@ Heat lig ¢ GenxCea x OT
1805 Hy x
£0089 Fmely 23-0 x (3860 -260) = 8305
e
Z) Vap, & cc BIFmal Nyx ZAK , Weed . [Link]
® ver, a Shy * Tey 3
CD) Wrest Yap 2 4 enn Cyn AT 2d $20.06 9Fmolx BS y (3902-3560) 2 LAFF
mobi
Hy cea Meat (lig.) + SH + Mene(vap) = 8305 + [Link]' Se UF = 63807
De. Behrang Madani Chem200 vc 7. For the following reaction: CHa(g) + 202(g}> CO2(g) + 2H20(g)
1f 650 kJ of heat energy is released per mole of methane (CHa):
8) What is the enthalpy of this reaction if 342 g of methane reacts?
Amel CHy - 650 KS
Amel Sxl KT | QHs —blewie ky
16 § chy A mmel CY,
Buds CMY x
‘b) Find the enthalpy of reaction when sufficient methane is bumed to produce 0.56 mole
of water vapor?
Amel Cty — — 650 KS
x = (oly AW = So KS
Del yo 1 mel CHy
0-56 mel Ho x
8. Calculate AH? for the reaction:
Naz0(s) + SOs(g) > NaxSO«(g)
given the following information:
AH®
(1) Na(s) + H:0(0) > NaOH(s) + 1/2 Fh(g) “146 kd
(2) Na2SO.(s) + H20()) > 2NaOH(s) + SOs(g) +418 kd
(3) 2Na.O(s) + 2Ha(g) ~> 4Na(s) + 2H2O() +259 KT
step 1: we clivide veaction(3> by 2:
asks
@ ~a206s) «Wy > ewalsd © HeM) — OH SRBES Le IB0 KT
Step 2: Reverse veaction(@) : e
2 4S
@ rnaowls) + Sos(s) > Marsoqcsr# Hre0) ABE a a Po
Q Ane 4 BonKts = 288
Ae —AWazols) + trl) + Waotl(s) + Sony) —> rWals) 4 NagS04(5} # ZHLOC1)
Step 3% to cancel UnWantesl VACH, He, Va, and Heo, muleiply readin 1
Bee vals) ZrO Cl) > LvaoW(s) + Hs) As 2x L-WGp— 292 Wy
49 = e =292KS 2 - $80
STER4 2 Combine CAD => Ans 28845 Sgr $805
Dr. Betrang Madani 9. Calculate the standard heat of formation, AH, for FeS2(s) given the following
information:
2FeS2(s) + 5O2(g) >2FeO(s) + 4S02(g)
AHP nxn = -1370 kJ
AH? for SOx(g) = -297 ki/mol OH/ foro, = 0-0 KAZ)
AH? for FeO(s) = -268 kJ/mol
AW = EN Aue” (predects) — Endy,” (reactants)
f
AW on = [CR mel) (iy Fe) 4 (amet) e (engso,)}- [C0 (ony FeS2) +
(Smet) (ony? on) |
H\BFoks = [Com)x (- 2 63Ky) + Camel) * cuir )]- [camry x (AME Fe)
+ (Seayx(o-o¥sy,) |
(BFo Kye HIRE KT - ( 2moleDHy Fese)
B54 IT = Lele AW Fesy
=> AL Fes, = +1FF by
Dr. Bebrang Madani ‘Chem 200 ve