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END SEMESTER A$SESSMENT (ESA) B&Jd SEMESTER- DECEMBER zA1H

uE14cy10t- ENGTNEERING CHEMISTRY {-r*q:rff 'd

1" a) For a cell represented by B

cd/cd2"(0. 5M)//Ag"{0.2 M)/Ag

(i) Write the half cell reactions and overall reaction.
{ii} DERIVE Nernst equation for the above ceflreaction.
(iii) Determine Eo"*11 and E."x at 25oC.
(Given: Eoco"ico'= - 0.40v , EoAg+/ee = 0.80v
b) Write one example for eich of these electrodes and the coresponding reaction when it acts as 3
cathode: \

(i) Redox electrode (ii) Gas electrode

c) Calculate solubility product (Kro) of AgClat 25oC from the following data: 4
Eoeg/egcrcr=0.22v , EoAs+/As* [Link],R: 8.314 JKlmaL, F: 96500 C
d) Draw a neat labeled diagram of a glass electrode. 2

2. a) List the various components of a Zinc-Air battery and explain its working with relevant reactions. 5
Why does Zinc-Air battery have high energy density?
E
b) Discuss the construction and working of alkaline H2-O2 fuel cell. Mention one advantage of fuel
cell.
c) Define the foltowing sensor properties and represent on a graph: 6
iinser error (ii) Lineariiy (iiii i-iange
ii)
3. a) Discuss electrochemical theory of corrosion. 5

b) What is the type of corrosiot"l taking place for a ship sailing in the ocean? How is sacrificial anode 4
method used to prevent corrosion of the ship?
c) How is hard chromium plating different from decorative chromium plating (Mention two points)? 4
ln an electroptating process, how many hours are required to deposit 259 of Cr from a solution of
CrCls by a current of 2.75A.(Gmm atomic mass of Cr = 52)
d) Define throwing power of an electroplating bath. Mention three ways by which throwing power 4
can be improved.

4. a) Draw a neatly labeled phase diagram of water indicating the various phases and the temperature 6
and pressure ualues ai tripte point and critical point. Calculate degrees of freedom on the melting
point curve and explain why the melting point curve for water has a negative slope.
simple harmonic motion, the vibrational spectrum shows 6
PY For a KCI molecule undergoing
fundamental frequency at 378 cm''.
(i) Calculate reduced mass of l(Cl.
{ii) Determine force constant of KCl.
(iii) Determine zero point energy for KCI molecule.
(Given: Avagadro's number = 6.023x10?e,Speed of light = 3x108m/s,
Gram molar mass of K=39 and Cl = 35.5, n = 3.14, Planck's constant = 6.627x 10'34Js;
an electronic transition 5
?Y State Franck Condon Principld, Draw the energy level diagram showing
from v" = 0 i
v' = 2, where the upper electronic state(e') is at a slightly larger internuclear
distance than the lower electronic staie(e"). What happens if the higher electronic state is at a
considerably large internuclear distance?
I

t7?O
 Ho* Oo the following ptop*rti*t of polymers depend on their structure:
{i} Strength of Kevlar

Mon*mers used fot

synth*sis{etructure)

Cnnditions required
for synthe*is

ri***ityaverage molecular weight of a

ffi average , weight
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uno
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potymer with the totowirJJitrinyii"il
moiar mass and 40 molecules of 5000 nrolar mass'
ta' in the vircosity rn!$urern:gis.S"SQ
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fn* BOU OT lne $ample t$
the same $i'rlrl'rrtr rrr'-u ppm'
is 320 }Jt/'rr'
The COD Of a WaSte watef Sample iS 700 ppm. The
Account for the difference.
For the ahovc waste watcr sample{CQD=?00Ppm) ,calculate the
volurne of 0"5N FA$ required
acidified K:CraOr using Ferroin
for back titration against S0 mL of waste **]1ii;,1i,pf*
"oniiining
as indicator. The blank titration volurne is 21.2 mL'
mg of .Cafil3 '47"5mg of MgCl2 and ssme
hardness of the sampl* is
bicarb*nate* of catcium and magnesiu* p**,li* ot *.ii"t. If the i*tal
125ppnn, calculate the lempomry hardness.
(Given: Gram atomic mass: Mg = I4,,s = 32, o = 16' ca = 40'.Cl= 35'5)
ic estirnali*n of Nitrate in a water

List any 4 principles of Green Chemistry

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(Established under Karnataka Act No. 16 of 201 3)
RHS
DEC 2016: END SEMESTER ASSESSMENT (EsA) [Link]. I SEMESTEB
UE{ 6CY{ 01. ENGINEERING CHEMISTRY ft-$exrr'N
Time:3 Hrs Answer All Questions Max Marks: 100

1. a) Derive Gibb's phase rule for an equilibrium system consisting of 'C' components distributed 4
between 'P' phases.
b) The water system is a single component system. 6
l. Draw a wetl labeled phase diagram of water system and identify the different areas, lines
and points (triple point and critical point) in the phase diagram of water systern.
ll. Mention the temperature and pressure corresponding to critical point.
lll, Mention the temperature and pressure below which sublimation of water takes place .
lV. What do you understand by metastable equilibrium?
tr Derive an expression for the mornent of inertia of a rigid diatomic molecule. Write an expression
for the change in energy when a diatomic molecule possessing permanent dipole moment
E

undergoes r6tational transitions. The first spectral line in the rotational spectrum of
HBr riolecute appears at 17 .19 cm"l. Calculate the moment of inertia of HBr molecule . ($iven:
gram molar mass of H=l.0, Br=79.9 ,^fi=3.14, h=6.627x10-3aJs, 1 amu=1.66x10-z' Kg,
c=3x10'"cm/s, Avagadro's number=6.023x1 0")
iY State Frank-Condon principle. Draw the energy level diagram and the spectrum showing 5
electronic transitlons when the upper electronic state of a diatomic molecule has the same
equilibrium inter-nuclear dista4ce as the lower electronic state. Explain the spectrum using
FrankOondon principle.

2. a) @insAg/Agcr0r(0-1M)andPUSn"*(0.01M),Sn..(0.1M) 10
:
electrodes. (Given: E-g-e-;sc; 0'222 , E!'a+75,34= 0'15 l', R:8.314 J/I(/mol,
lt
F=965O0C/mol )
i. Write the representation for the above constructed cell.
ii. Write half cell reactions and overall cell reaction.
iii. Derive Nernst equation for the above cell reaction using thermodynamic principles.
iv. Determine EosE1sahd E5s1 at 298 K.
v. Calculate the eouilibrium constant for the above cell reaction.
b) The representation of an electrode concentration cell is given below; 4
Pt/Cl2(s) (0.5 atm) i Cf (0.65 M) / Cl21g1 (p atm ) / Pt
i. Write the reactions taking place at anode and cathode in the above galvanic cell
:
un6 Elt:iu ilcl: 1-.36
1".
ii. Calculate the pressure ?' given Ecen= 0.011 V at 2gB K
c) What are ion selective electrodes ? Derive an expression for electrode potential of an ion 6
selective electrode. Explain how an ion selective electrode is used to determine ionic
concentrations.

J. a) Answer the following for a Zinc - air battery. 7

i. Draw a neat labeled diagram of Zn - air battery.
ii. Write ihe reaciions taking place during discharge of the battery.
iii. -
Define energy density of a battery and calculate energy density of zinc air battery in
watt hour /kg if 5.69 of Zn is stored in the battery weighing 25.59. Given; voltage of the
given Zinc -air battery is 1"3 V and gram molar mass of zinc is 65.38 .
b) Give examples of batteries which possess the following battery characteristics and Justify your 4
answer; (i) Long shelf life
(ii) high voltage.

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c) Name an electrolyte used in solid oxide H2 - Oz fuel cell . Why is this frr-el cetl operated at a very 5
high temperature ? Calculate the energy efficiency of the fuej cell if E0""1= [Link] V, Enthalpy oi
formation of water = - 285.3 KJ/mol, F=SGSO0 C/mot.
d) Mark the regions in whiih the following energy storage devices appear in the Ragone plot : 4
(i) Fuel cell (ii) Lithium -ion battery and (iii) Supercapacitor.
4. a) Discuss electrochemical theory of corrosion of iron metal undergoing corrosion in an environment 6
containing oxygen. How is the amount of oxygen in a corrosive environment affect the corrosion
process.
b) What is inorganic coating? Explain the-process of phosphating. Give one application of the 4
process.
c) Discuss the importance of complexing agent in electroptating process. Give an example of a 4
complexing agent used in electroplating process.
d) Completg the following table for decorative chromium plating : o
I t. Electroplating bath composition
I
I
2. Anode I

3. Cathode I

| +. Application I

, 5. Two reasons for not using Chromium anodes I

5. a) Give a method of synthesis of plexiglass from acetone. ls plexiglass a thermoplastic or a 5

thermosetting plastic? Justify.
b) What are the structural requirements for a polymer to be conducting? Write the structure of 3
conducting polyaniline.
c) What are polymer composites? Give the synthesis of Carbon fiber from polyacrylonitrile (with 6
reqgtrons). Write one application of carbon fiber reinforced polymers.
d) With the help of a graph, explain how tensile strength varies with average molecular weight of a 6
polymer. Calculate weight average molecular weight and viscosity average motecular
weight of a poiymer sampie lravirrg the follovuing distributicn:
70 molecules of molecular mass 800,
100i molecules of molecular mass 2500 and
130 molecules of molecular mass 3500.
( The Mark - Houwink co-efficient 'a'in the viscosity measurements = 0.G5 )

2 of}
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1-{
UE16CY1O1
(Established urder Karnataka Act No. 16 of 2013)

MAY 2017t END SEMESTEB ASSESSMENT (ESA) [Link] SEMESTER

UE16CY1O1- ENGINEERING CIIEIITISTRY

Tlme:3ILs .dnswer All Questions Max fuIarks: 100

1 a) Drav; a neat labeled phase diagram of Lead-Silver system. What is the significance of 5
eutetic point?
b) In thephase diagram of,.water; 4
Justify the following,
a). Fusion curve has negative siope.
b). Metastable curve Iies above sublimation culve.

YT Give an expression for the allowed energy levels of rigid diatomic molecule Sigid rotor 5
nrodel). Draw tlre egergy level diagram. Show first two lines on th_e energy level
diagram and calculate the frequency of first two lines in terms of B cm'r. In a resulting
spectnrm, what is the spacing between rwo lines?
rf Using harrnonic oscillator model calculate zero point vibrational enelgy of NO 6
molecule given that the folce constant of NO is 1530 N/m.
Draw the vibrational energy level diagram for the above model and calculate the enelgy
of v=l and v:2 level. Evaluate the frequency of spectral lines for the ftansition
corresponding to v:0 to v:l and v'=i io r:2. (Ai1 energies antl fiequencies must be
given in cm-l). Given: Atomic masses of N & O are 14.004 and 15.999 respectively,
it:[Link]: x 10bmol-l ,h= 6.626x 10'3a J s., c:3x 10s m s-l .

a
L. a) A Cluomium electrode in coutact with CrCl: elech'olyte of concentration 0.0026 M is 5
coupled with decinormal calomel electrode.
GiYen: Eoo'*lcr= -0.74V, Eo*grrurrrrri : 0,27 Y,
i). Write cell representatiou.
ii). Write the reaction at anode and cathode.
iii). Calculate E0 c"trand Ecenat 298 K.
a
b) What is electrode concentration cell. Caleulate the potential of the following gaivanic -]
cell at 298 K. Pt/ Oz(0.5 atm)/O2-(0.8 M)/Oz(s atm)/Pt
c) Starurous chloride reduces ferric ions to fersus ions. Show that this reaction is highly 3
0C from standald reduction
soontaneous bv calculatins equilibrium constant at 25
potentials. Civen: Eo."'*rr"'a: [Link] y, E0rno*on'*: C.15 V.
d) Draw a neat labeled diagram of glass electrode, Arrive at an expression for the potential 9

f;f::;t:lli:ll cornbination with saturated caloinet electrode was used to calculate

"
pH of unknown solution. The observed cell potentials are,
i). O.20g4V when in contact with buffer solution of pH=4.
ii). 0.1163 V when in contact with unknown solution.
Calculate the pH of unknown soltttiou. Given: Escr= 0.241 V.

P-i o
 SRN

3. a) What are hydrogen storage alloys? Give an example. 5

Describe the construction and working of nickel metal hydride battery.

6
b) i?xplain following battery characteristics; a) Capacrty b). Energy density.
Cahulate c€lpaoiry (n Ah}and energy density (in wtr/kg) of 2 kg iithium rg-U"tt rV
which contai:rs 2d g anode material. The cell voltage is 4 V. Atomio weight of lithirm is
7. Nurnber of electrons transfenrsd in redox reaction is 1.

c) Cir. tft" and working of H2-O2 fueL cell whish operates by polymer 6
electrolyte. Caleulate'the efficiency of above fuel cell if the standard
membrane"*struction
enthalpy of formatitn of product of the cell reaciion is -286 kJ/mol. The cell voltage is
1.2Y.
d) anode and cathode reaetion taking place during its' J
workins.

4. a) Wry do metals undergo corrosion? Give the meehanism of electrochemical theory of 6

corrosionwhenanironarticleisexposedtosurroundingatmosphere,
b) Explain, how pitting corrosion takes ptace, Why is it considered to be most dangerous 4.
type of conosion?
c) Justify the following, 6..'
i). Aluminum is more corrosion resistant than iron'
ii). Arsenic and antimony salts are used as cathodic cottosio4 inhibitors.
iii). Automobile body is phosphateri before painting. .

d) Some metals show active passive behavisur. How are these protected fi'om conosion by 4
taking advantage of this behaviour?

{ a) Account foq a). High strength of kevlar fiber. 6

b). Hlgh elecEical conductancCI of conducting polyaniline.
Explain the a6ove with the help of suitable skuctures
b) Give the synthesis of epoxy resin fiom monomers, How is it cured? 5

c) Explain any tluee important principles of green chemistry. J

d) If a polymer samplehas the followirU population, calculate number average and weight 6
avemge and viscosity average moieculal weight of polymer. MarkHowink coefficient
a=0.'7.
i) 10 molecules of molecular weight i,000
ii) 20 rnolecules of molecular weight 2,500
iii) 25 molecules of molecular weight 3,000
iv) 40 molecules of molecular weight 4,000
 s: :i ir [&l Aj{]-t rl-"r-d$.z]fl_ L_j

pf.S Li :r [ve rsl'ilv. [.iea sto, elerrc+

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lJ Ef 8CY'i 0'i - ENGI N [: EFI I I-lG G I-f ElUi I STIRY

Tir:s.-inrl_.______.____::-___]o.u:ryer_,[_qg4l!-;ns_-_________@
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(ii) If thc sauie tnolecule sh.-'rvs anharmonic oscillations, caictilate the wave nuritbr.,,'of
fundi:mental absorption;lnd {irst oveftone if the anharmonicity constant for the molecule
is 0.0l7 and the eguliibriurrr vibratisnalfrequency is 2ti,i9 cm'I.'

1 I (Given: A'v;rgadro's nunber' : 6.A23x1C23.:;-reecl of ligl:t:3x1(ilc'cav's, I amu = 1-66 x10-27kg, I

i '.-:;,:::il iili,lai".r..rass
t

i c.'ir.-, 1,,i ;.:ii: ii:

-.:..L:.-._j--.._..--._,-:-.._-...-,.,,-_.'......-.-'.
-- ij,.l,ti. ., -, 1.l4,1]3:-.tl('s consi:: i*:6.627x10-''lJ:i) i I

; ;il I u"'r* riii, ruo ro, ;;t;, ; ;iJ"""r,p.,,*,it; i;lr J;';; ;'ili.l,-*-" i, =q"iliurir,, *ttii.,"r, i+ i
phase" rule to lvator sysrern at triple pcint ancl calculate the degrees of fieedotn
II|
i iI [Link] . A1:piy the
il .-,.-,^ ' tieedorn at ||

I i liriplepoin'..
I-_-_-.-------.:_-----------l
.- -,'-^. i
I

l---------=-.-., -r---.]
i 2. l n) il i.-rrau
i.-'rau ;i,neatiy tJsing the phase diagram explain I 55
,i,neatiy .labeled pliese diergranr for Pb-Ag system . IJsing |

i I Pattirisotr's process.
iiPatti,rsotr'sprocess i i I
I L--_! --.L-J

|ti lforth::f<rllowingcell: t5
,!

I
i i il;',lifi;i:ffiltij'i;:Ylf;;,f*:j,1.',';:l'f#""
(ir) reac'[iLn
resrcti,.;n
i
i"
I

II [ii]i::#l:[::1Ti:;:]';,],i?
Iii,ltbvuw"li
W-iite thc half cell reactions anci overiiil cerr
ceII I

"''"ra,
i

= 0.0\', : "i{ihrol, Itl

i i r,iiivtn
tt
;Reciuction potential values I Eu
C,1nol)
p,,Ir,rH* ,,ln r"'*, r,e'*,,r,r= '[Link] ,R 8.314
lr I

i -'r:-'Ii F'-
r--'- '-"96500
965110 C iino!) i
'*-.--,-"-'--i- *l i

anoJ';. I6
ri..I a;, ;ri ,t, gi:r^s:i
.,.1,r
e,:c1r'ode as cathode is uo':pled ivitli r ilecir'"or:rnaE 1.'rr r;-r)(:l electrode
.;-:.:;-'
,..:. :^-^;::;^:^-"_:;'^:^,;;^;.,.:::*'-;:,.:., llurcirocl€.
,r.1'.rrlii'3n one acirrantage anci one tjisltlvantage,:f .glasl:
as

i
I
i

t:ii) rlalcul"ate slectrode potential of a tlecitio;nial r:riran:ti elechode at298K '

(ii;),i)etennine pH of tle solution if an ei:rf cf (1. i 1-2,i\./ ls [Link] in the above cell at 29BI(

I .l ' L\.iir'vrr. I-l:alomelelectrOf,s-V,LO i\.vrIi6--\.',J0UJY r I

_j
i 'j; , i,\i'lrt" ,:.e :epresentation of an elr.,,ctro!;rtr., ci.,ncentlaiicn ceil usirig zinc - amalsam
ll -
electrocie.s. i 3l I

.l 'ihlcrrltie,ih,]-Eceli fi298V., ifiihe concentx.]ticns of Zi;rc ici:s:il'e D.5l\ri-, and 0.2M.

' r\.1 ,-. |
^.., I
;
Ir
ll I
li
i

L_ ,. t:.1i4j/I(/r:-rol, F= 96!00 q{g! I _-l

I
t-

SRitl

-.--r ---=T--
lZ
l.' i a) ji Drirrv Ilagone ::,i..it
Dr.,rv a [iagone ,i,,rt,irrdrr:aie
,irrdir:a';e anci rliscuss
riisc'uss ihe rf a supercapacitor
ilre pcsiticn cf superclp;.citcr on tlte Rzrgone plot.
the Rtrgone 4
i'
i

liiora l-,a-atr h;rilei"v: o.

I
tl
I (i) Srlry is tltc etieri:', densiiy very higir'i
i

i
I I . (ii) \!'rite the reactii:irs takinlt place at rinode anC carhode.
i I '(iii) C:alcula,te capacity, ener'[iy densifyfii(g) anrt pov;er ciensity(Wkg) of the hattery if 90g
i of Zinc is used au,j tiie, battary lasts t;' 12000 mins .The [Link] weighs'1209 and gives a

Calculate efficiency of tllis cell if lt, ilr.nnntion111,o; = - 285.5 kJ/rnol , Eo""rr:

(Giveil : I:96500 C/rnol)

Discurrs th',? oonstl'u"tiou c'f an oxyl,.iii' sensor and explain why. it is classified as olectrocie
t__
cottcsirtration cell, Wiry is the voltage diiferent;'or a lear,r and rish mixture?
l+ a) I [Link].s tL;cr/ ol c,.xosion with relevant rcacticns.
electrochemical
- _-_--_:_-__.__
b) | Describe the sacrificiai anr:de ;::ethod. Ilentien one advantage and one'disadvantage of this
I---L-i--- I method.

| "i I
Discuss the f5,pe cl'corrosion laking place in the lollowing cases: /

I
lr i (i) Gaps en thr: su,'face ;:rf a;inned iron sheet.
I i (ii ) ;{r'ass [Link] ni{.poli;"ri ir., ;:.!1is16njp"1l rr;1.-1r,. '.
r.;;:; ;; ;;._' -"-,-
-.
'.l- ,",;;- :*,"-;. ....':.'^::,;;;: _-.; .,::--.;._ or,,,
;",sui-.,,,";;;;s;;i1;li;;;;;,;,j;li]t* ;. ^;;'.:;-:.:^_:;
,,^,- 1;0,;,k,, o"*',"i*
- I
il,:-rr. _.___l I

5.

; i (iii) I.-r 'lar is stronger ihan steel on ari equili wr,light bas,is.
I ;rt i A
l) 1 A nnlr',,,,."
polf ilrri cr.*,.1o
sample hast.^" fl--
fhe f^Il^,.;...^
following Jia+-il.. -i -,.,.
distrib.,t+n:
I i.5 nrolecules rvith nrolgcular r',,oight 3500, ils inulecules with molecular weight 4000 arrd 20
nr','lecules rvith moler:ular weiglil [Link] value of Mark-Howink cr:efficienr is 0.60. Calculate
I
i i ,tt uumbcr average and viscosity everage [Link].
i r:) Wliie the steps involved in synthesis of ttre followirrg :
|
I (ii) (i) or-'nCucting polyaniline froin polyr,niline.
| P\{[44 from acetone.
| (i) State f:wn prhrciples of Grcei'i tll.":iristry .
.:{iggf.,gl"l,1lii,l::l'0lr* I".?1i:li?lgti4:ii
-Q Yl{r: :'lf
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(Established under famataka
PES ect tO of ZOt:) UE18CY101
UNIVERSiTY

END SEMESTER ASSESSMENT (ESA) B TECH. II

SEMESTER MAY 204_
UE18CY1O1 . ENGINEERING CIIEMISTRY
Time: 3 hours Answer AII euestions Max marks: L00
that rhe. spacing of the lines in the pure ,otut
,9,::l
tz'ou+ cm ', calculate themoment of inerJia and bond lengttrof the molecule.
(Given: Atomie masses of AI : 26.9g15 amu
and H = r.00g amu, Avagadro,s number =
6.023 x
i013,
snee$of light:3 x r0'';,,/r,-; =;.il, pranck,s consrant [Link] :
x l0-3a Js,
1 amu = 1.66 x 10'27 kg)

State Franck-Condon principle. With the help of

eleetronic transitions and oorresponding specffa
;
for the following cases.
i) Transitions takes plaee from vr, = 0 to v, = 2.
ii) Transitions takes place from v" :0 to beyond the dissociation energy of the molecule.
i) why real molecules do not obey simple harmonic oscillator moder?
ii) The force constant of a HF is 970 N/m. Calculate reduced mass
and the spacing
i between
two consecutive levels. (use simple harmonic oscilrator
moder).
(Given: Atomie masses^of FI = 1.00g and F:
1{.99, Avagadro,s number :6.a23 x 1023,
Speed of light:3 x 1010 cm/s, I amu = 1.66x
to''i tg,planck's constant =, [Link] iror;jr,
tc= 3.14) -
i) Define component with respect to the phase *r".
components fbr the following closed system @r*,
:':
,"d
NHaCI 61 NH:rgl + HC\g1
ii) Write the phase rule applicable for Pb-Ag system. Calculate the number
freedom at eutectic point.
of degrees of

i) labetedphase diagram of water rv

?:y i T"t
and ternperature and pressure values at tripre point
and critic; point.
ii) Mention the phases that are in equilibrium with eaeh
other on meta stable curve.
iii) Explain why melting point curye has a negative slope.
For the following cell:
Ag/Ag2CrOa tcroo2-10.25M) tt Fe3*10.2 Mtr, Fe2*10.e
Mypt
i) Write the half cell reaetjons.
ii) Calculato Eoc*rr and Ecrrr at29g K
(Given: EoAglegrcro otcr.,4z' =o.44GV, EoFrr*,F.r* : 0,77 V, R : g,314 J^(/mol,
F =96500 C/mol)
i) Draw a neat labeled
diagram of glass du
the cell
1?,ytit: electroderepresentation for a galvanie cell formed with glass electrode as cathode and
calomel as anode.
iii) When a buffer of pH = 7.00 is used an EMF of 0.729 V is recorded
in the above cell at
'298 K' When the solution of unknown pH is used, an EMF of 0.524 V is recorded.
gglclate the pH of the solution. (Given jisce :
: A.24i2y)

Pagel of 2
 d) Calculate the EMF of the following cell
Hg-zn(c 1)l zn2* Q'25 M/ar-Hg(c z) at z9g K if the concentrations of zinc amalgam are;
Cr = 0.2 g per 100 g of mercury and Cz:0.1 g per 100 g of rnercury.
(Given '. Eo zn2*t2,.: -0.76 V, R = 8.314 J/I(/mol, F = 96500 C/niol)
t a) i) Draw a neat labeled diagram of Hz - Oz fuel cell which uses solid oxide as an electlolyte 1
and wlite the reactions taking place at anode and cathode.
ii) Why the above fuel cell is operated at high temperature?
iii) Calculate the efficiency of the above fuel cell if the cell voltage is i.16 V, Enthalpy of
formation of water is -285.3 kJ/mol and F :96500 C/mol.

) Draw Ragone plot and specify the position of supereapaoitors, batteries and fuel cells.
b) a
3
i) Using the Ragone plot discuss the position of fuel cell.
c) i) What are reserve batteries? Write the reactions taking place at anode and cathode in 6
magnesium water activated batteries.
ii) Calculate capacity, power density (W/kg) and energy density (Whr/kg) of a battery if 2.2 g
of Lithium is stored in the battery and battery lasts for 120 mins. The battery weighs 110 g
and gives steady voltage of 3.3 V. (Given : F:96500 C/mol, atomic mass of Li is 7 )

d) Wliat are supercapaeitor:s? Why porous materials are used as electrode rnaterials in i
+
supercapacitors? Mention any ore advantage and disadvantage of supercapacitors.

tl a) ) What is galvanization? Desuibe the different steps involved in galvanization process. 5

i) Why galvanized artieles are not used to store food items?
b) What is anodic protection? Mention any one advantage of this method. Draw potential current 4
curve used to exptrain u"1iys-passive transitions of metals.

c) What is stress comosion? Describe the caustic embrittlement with relevant reactrons. 5

d) Explain the effects of following faotors on eorrosion of,metal 6

i) Nature of the corrosion product ii) Ratio of anodic to cathodic area iii) Temperature
5 a) Caiculate weight average and viscosity average rnolecular weight of a polymer which 4
contains 15 molecules with molecular weight 4500, 20 molecules with molecular weight 5000
and 30 molecules with 7000 molecular weight. The value of Mark-Houwink coefficient is
0.52.

b) Give the synthesis of epoxy resin from bisphenol-A. How is epoxy rtsin cured? 5

c) Compiete the table for Kevlar 5

Type of polymerization
Advantage
Disadvantage
d) i) Give any two principles of Green chemistry 6
ii) Explain the different steps involved in the sol-gel synthesis of nanomaterials.
{< {.{e {. * * :$

Page 2 of 2
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(Eatablished under Karnataka Act Ns. 16 4i2013)

rrum $SWE$Tf;R &$$E$SliltEr'lT {C$&} [Link]. I SEME$TEft.- See XSsB

UET 8CY{ OT. EruGIruTEruNG CHEffi ISTft.Y
Time: 3 Hrs Answer All &uestions Max Marks: 100

1 e) For a rigid rotor diatomic mclec*le: 5

r' {ii *erive thr exprcssion for moment *f Inertia.

(ii) Drarv th* energy level diagrain fbr a rigid rotor diatomis male*ule upto J =5.
{iii} Calculate the ererry required(in cm"tl for the molecule to movs fr*trl J = 3 to J :4 level
if B: 10.93 cm'l
h) State Frannk {nndon principle . For the f*lkwing electronic kansititns, drarar tlrri spectrunr and 5
/ state the eonditisn when such a spectri:rn would be observed :
(i) Electronic transition from v" * 0 fo v'* 3
(iiJ Electronie transition from v" = 0 to v'= {i
c) For a HBr molecul*: s

/ (i) Catrcutate the reduced mass and force constant in N/m , rvhen it sh*ws harmonis
oscillatioits, if the vibrational spectrum of the molecule shcrvs a singh intense line
at 3549 cn"r-r.
(ii) If the same motecule shows anharmonic oscillations, calculate the rvave number *f
fnndamental absorption and first overtote if the anharmcni*ity constant ftr tiie ni*lecule
is 0,01? and the equilibrium vibrational frequency is 3649 cm"'.

(Given; Avagadroos number = 6.023 x 1S3:.$peed of light = 3 x I0l0 cm/s, I amu : I .66 * IO'??kg,
Grarn molar mass of H=] .$ and Br: d$.0, :r: 3.l4,Flancr's constant * ti.6??x i 0-ir,ls)
d) Derive Phase ruie for a system of C c*mporrerrts in F phases which are in equiiibrium with each 4
other " Apply the phase rule to water systenl at triplr point and calculate the degrees of freedom ef
triple point.

L a) Draw a ne*tly labeled phase diagram f*r Pb-Ag system . Using flie phasc diagram explain x,

Pattinson's proa*ss.
b) For tlr* foliowing eell: 0
ilt, H2{puu : 2.5 arml#(O. 5 M/1Fe3*(0. 02M), re2*10.S M;/Pt
{i} Name the type of electrode being used at cathode.
iii) \Yrite the half cell reactions and overall cell reaction.
(iiiiCalculate Eocerr and E**s at 398K.

{Oiven :Reduetion potential values : Eo p,,rir1H':0,0V, Eo Fr'*.Fe'*/Fr* *.77V, R: 8.314 J/K*riol,

F= 96500 C /rnol)
c) A glass eleclrode as cathode is coupled,lvith a decixarmal ralomel electrode as anode" 6
(i) Mention one advantage ard one disadvantage of glass eleotrode.
I
(ii) Calculare electrsde potential of a decinormal pak:mel electrode at 298K
.

(iii)}eterminc [Link]?4Yisrceordedintheabove sellat398K.

{Given: Eocaromcl*jeetrode: 0.2810V, Eoc = 0.5863Y }

d) Write cell repr*sentation of *n electrolyte c*ficentrat;or cell using ziuc - amalgam electrcdes"
t
Cal*ulate the E.*1 at 298K, if the concentraticns of Zir:c ions are 0.5hl and 0'2M.

{Civen :Redurti*n potential values I Eo zo'*rzn= - $.?6Y, R * 8.314 J/i(inotr, F= 96500 C/n:ol)

FT*
 3 a) ilr*w n Ragone plot ,indicate and dis*xss the position r:f a sup*rcapacifu on the Rag*ne plot. ,1

b) For a Zn-air hatt€ry: t;.

(i) iVhy is tlie eneri:;, densiry very high?
{ii) lVrit* the reacti*::s taking place at anode anc} cathode.
'{iii) Calculate capacity, exergy density(Jlkg) and [Link] dnnsiry{U//kg) of the battery if ?0g
of Zinc is useei and the baffery lasts firr 12000 [Link] battery weighs 120g and gives a
steady voltage of 1.4V.

{Civen : F: 96500 C/mol, Grarn mol;ir mass *f Zn = 65 )

c) Draw a neat labeled diagrarn af IIa-O: fuel celi [Link] uses poiymer as [Link] and *rite tlie D
ieacticne t*iring pla*e et an*de a;lC"cethi;de.
Calculate efficiency of this cell if A }-lii.no1;ou111,6; = - 285.5 kJirnal , Eoc.g = L191/ . I
i

(Given I F:96500 C/mol)

d) Discuss the construction of an oxygen s*rsor and explxin lvhy it is classified *s electrode 4
cor*entratian eell, why is the vnltage different for a lean a*d rielr mixture?
4. a) Discuss electroclremical theory of corrosion rvitli releyant reactions. 5"
ir) Describe the sacrificial anode meihcd" Mentic:r one advartage ard one disadvantage of this 5
method.
c) Siseuss the type af cnrrosion takir:g piace in the follorving cases: 6
(i) Gaps or the surf*ce of a tinned ir*n *heet.
(ii) Brass article exposed to ammoniacal vapours.
d) Explaiii h*rv kydrogcn overv*ltage affects cornsion How ctr:es As203 rvork &s a corrosiori 4
inhibitor"

a) Justifu:
Is 6
{i) 5-10% isoprene is aclded whi}e synthesizing trufyl rubber.
{ii} Epoxy resin is a condensatiot po}ymer.
Liii)Kevlar is stronger than steel on an equal rveiglrt basis.
b) A palyrxer sample has the fnllowing distribution: 4
15 molecules with molecular rveight 35*A,25 malecules with molecular rveight 4s0$ ancl 20
rnolecules with nolecular weight 250S. The value of hdark-Howink cortTicient is 0.6S" Caleutrate
its number eyetage and visco*ify ayerxge motrecular rveight.
*)j Write the steps invclved in synthesis of the following 6
(i) conducting polyaniline from polynnilire.
_l
I
(ii) PMMA fiom acetone.
d){ {i} State tx,c principles of Sreen Chernistry . 4
{ii} What are zero-dimension and one-dimensir:n uauoparticles?
 SRN {) ils L U GL l: ( ( I 1"

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PES lrstaotisrre
PES Universitv. Bangalore
G of 2013) UE2ocY1ol

Juty 2021: lN SEMESTER ASSESSMENT (lSA) [Link]. ll SEMESTER

Test 2
UE2OCY1 01 - Engineering Ghemistry

Time:2 Hrs. Answer A11 Questions Max Marks: 70

I a) i) which of the following molecules show rotational spectra? Give reason. 6

CO2, HCl, HF, Nz (2+4)
ii) The force constant of NO molecule is 1595 N/m. Calculate the reduced mass and the
spacing between the consecutive levels using simple harmonic oscillator model.
(c:3 x 1010cm/s, I amu: 1.66 x 7A27kg,atomic masses of N and O are 14.004 and
15.9994 amu respectively)
b) Account for the following :
i) Real molecules do not obey simple harmonic oscillator model. 4
ii)Nanomaterials possess specific properties significantly different lrom bulk
materials.(Any two points)

2. a) For a cell represented by Fe/Fe2*(0.16 My/ (0.73 M) Ag*lAg 6

i) Write the half cell reactions taking place at anode and cathode
ii) Calculate Eo".lt and E..11 at298 K.
iii) Comment on the spontaneity of the reaction.
[Given : Eo F"2*/F" : -0.44 V, EoAe*iae:0.80 V, R: 8.314 JlVmol, F : 96500 C/moll
b) Draw a neat labelled diagram of Pb-Ag system indicating temperature and composition 4
corresponding to eutectic point. Calculate the degrees of freedom at eutectic point.

3. a) i) With a neat labelled diagram explain the construction and working of solid oxide fuel 6
cell.
ii) Why solid oxide fuel cell is operated at hieh temperarure?
b) Why electricity storage density of lithium batteries is high? Explain the discharging 4
process of lithium ion battery with the relevant reactions.

4. a) i) "Differential aeration corrosion is an electrochemical phenomenon". Explain the 6

formation of oxygen concentration cell with relevant reactions taking place at anode and (4+2)
cathode.
ii) How does the ratio of the anodic and cathodic area formed on the metal surface affect
the rate of corrosion?
b) Explain impressed current method and mention any one disadvantage of this method. 4

5. c) With the labelled diagram explain chemical converstion coatings used to protect 6
aluminium from corrosion by anodized coatings and give any one of it's application.
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d) Sive an example for the following : 4

Anodic inhibitor
Cathodic inhibitor
Sacrificial anode
Metal with active passive transition

6. a) Draw the structures and give an explanation for the following: 4

i) Polyethylene is more mystalline than polyvinyl acetate.
ii) Natural rubber undergoes oxidative degradation: _
b) Give the synthosis of Kevlar from paraphenylene diamine and justify why Kevlar is five 6
times stronger than the steel on equal amount basis. Mention any one application of Kevlar
reinforced oolvmer composites.

7. c) i) What are biodegradable polymers? Mention the different steps involved in 4

biodegradation process.
ii) Draw the structure of conducting polyaniline. Mention any one application of it.
d) Calculate the number average molecular weight, weight average molecular weight and 6
viscosity average molecular weight of a polymer which contains 10 molecules with
molecuiar weig[t 4 x 103, 20 molicules witir molecular weight 5 x 103 and 30 molecules
with molecular weisht 6 x 103. The value of Mark-Houwink coefficient is 0.70.

****{<** * *d. {. **

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PES Universitv. Banqalore
PES (Estabtished under xarnataraTffil6 of
2013) UE20CY101

Julv 2021: lN SEMESTER ASSESSMENT (rsA) [Link].

il SEMESTER
uE2ocyl or - E,ff;t"3ring chemistry
Time:2 Hrs.

i) which of the following molecules show rotationul

,p..t*iEir.."*o..
co2, HCl, HF, N2
ii) The force constant of No molecule is 1595 N/m.
calculate the reduced mass and the
spacing between the consecutive levels using
simple harmonic oscillator model.
(t-:-3 x 1010cm/s, 1 amu: r.66 1027ig,atomic -urr.,
x A.004 and
y2j4 amu respectively) "i*;;;;";
Account for the followin
i) Real molecules do not obey simple harmonic
osciilator moder.
ii)Nanomaterials posse* rp"tifi. properties
,ig"irounit diiferent from bulk
materials.(Any two ooints)

For a cell represented by Fe/Fe2*(0.16@

i) write the half cellreactions taking prace at anode
and cathode
ii) Calculate Eo"e1 and E.r11 at 29g K.
iii) Comment on the spontaneity of the reaction.
A J/K/mol,F : 96500 C/moll
neat labelled diagram of pU-ag systern indicating
temperature and composition
ndin to eutectic point. Calculate the
of freedom at eutectic point.
i) With a neat labeilediiagram explain the construction and working of solid oxide fuel
cell.
O!{!V solid oxide fuel cell is at high temperature?
Why electricity storage density of titfrium-Uatteries
is high? Explain the discharging
of lithium ion ba with the relevant reactions.

i),'Differentialaerationcorrosioni'u,[Link]@
formation of oxygen concentration cell with
relevant reactions taking place at anode and
cathode.
ii) How does the ratio of the anodic and cathod ic arcaformed on the metal surface affect
the rate of corrosion?
Explainimpressedcurrentmethodandmentionanyoneai,uoffi

With the lub"ll"d

aIu m in iu m ri" ; ;;;, ;.; ; ; ;H i;,J; #",ff 1, ;Hf 'jff J"" :'i ?,fJ t rot ect
"ffi: "J:,
 Give an sx G fo. the follo !1g,
Anodic inhibitor
Cathodic inhibitor
Sacrificial anode
ffial*ith active Paqglve hansition
r the following:
tn".tructures and give an explanatl
U
p"rvtirtvlene is more Jrvstally.t tl*t"-111:]f*""'
iil [Link] rubber u!4ereoes %ldative
ine affistifY wff fevlar is
five
,hX#;f; i u, i, il;;;,ppl ilat ion of Kevl ar
ffi fr-YJ:[f I il,fl}ff;;; Mention

puf,r*rp [Link]-o"tht different steps involved in

i) What are biodegrul*Uf"
biodegradation Process' of it'
iline. Mention any one application
iil Draw the structurei!99!9991!
u'"tug' molecular' weight and
iffi., *ii"r,
;.x3;3;;*ll":,l;lm:il,?ilfil,"itr^u';*l-'"ii::t::'^t:t"iir::i"Tf0
;;*4";
r0 morecuris with
molecules
morecular weight 4 x 103, 20 molecule'
rffil:?:Jil:l)"
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pEs (Established under Karnataka Act 16 of 2013) UE2OCYlO1

AUGUST 2O2I - END SEMESTER ASSESSMENT (ESA) B TECH. II SEMESTER

UE2OCY1OI . ENGINEERII{G CHEMISTRY
Time: 3 hours Answer AII Questions Max marks: 100
The internuclear distance (bond. len
Calculate the reduced mass, moment of inertia and energy (in cm-l) of'this molecule
in
the first excited rotational energy level (J : I).
(Given : The atomic masses of r2c : 1.99 x 10-26 kg and t,o :
?..ea x 10'26 kg, Speed of
tight: 3 x 10r0 cmrs,n:3.r4, planck's constant Je .iie*
ror; irl
State Bom-Oppenheimer approxim
molecule which shows rotational, vibrational and eleitronic eneigy levels.

For a diatomic molecul" underg

i) Write the selection rule.
ii) Draw the energy level diagram showing vibrational energy levels and the
corresponding spectrum.
iii) What is zero point energy ? Calculate the zero point energy of KCl molecule if
v - 378 cm-T.
i) What are [Link] ?
ii) Explain how spatiai confinement affects the electrical conductivity of nanomaterials.

What are the number of phases

system ?
NHaCI (s) + N
i) Draw a neat labeled Aiug
Give the temperature and pressure values coresponding io triple point
and critical

ii) With the,help of Clausius Ciapeyron equation explain why melting point cure has a
negative slope.
Forthe following cell :Hg/Hgr@ /Au, write the half cell
reactions, calculate Eocell and Ecell atZgg K.
(Given : Eosce : 0.28 I Y &, EoAu3*/A, : 1.498 V)
i) Justify : "Glass electrode is an ion selective electrode.,' Derive ur.^p..rrio.,
electrode potential of a glass electrode. Give any one application of glass
f*
electrode.
ii) Determine pH of the solution if an emf o f 0 .1g7 0 V is recorded in the galvanic cell
at298 K. (Given I Eocutomerelecrrode:0.281 V, Eo6 :0.7496y.)
What are reserve batteries ? Gi
shelf life. Give any one application of a reserve batterv.
For a zinc - air batterv :
i) Draw a neat labeled diagram
ii) Write the reactions taking place at anode and cathode
ii) Why zinc-air battery has hieh enersy densitv ?
Calculate the energy density t
contains 7 kg anode material and discharges current foig hours.
(Given ; Pb --------> Pbz* + 2e , voltage avaiiable from the battery
is 1.95 V and
atomic mass of lead is 207 .2 )

Page 1 of 2
 .7
d) i) Name the components of H2-O2 alkaline fuel cell. Calculate the efficienCt;Tf*-i
if AH1o.*u1;on (H2o) : -285.5 kJ/mol and Eo..11 : l.2l Y . ".11
(5 +2)
ii) Draw Ragone plot indicating the position of fuel cells, batteries and supercapacitors.

4 a) Explain electrochemical theory of corrosion with relevant reactions taking place at 6

anode and cathode.
b) Discuss caustic embrittlement in boilers. 4
c) What is tinning ? Explain the different steps involved in the tinning process3ive an 6
a4vantage and disadvantage of the tinning process.
d) Account for the following : 4
i) Hydrazine is used as a corrosion inhibitor
ii) ocean going ship is protected from corrosion using masnesium bars.
5 a) i) Mention any two factors affecting tensile strength of a polymer. 4
ii) Based on structure explain the thermal behaviour of thermoplastic and thermosetting
pqlymers.
b) Give the synthesis of butyl rubber mentioning the required conditions. 5
Why is 5 - i0 % isoprene used in the synthesis of butyl rubber ?
c) Complete the followi table for OLEDs 6
Anode material used
Cathode material used
Emissive layer used
Conductive layer used
Advantage
Application
d) Calculate polydispersity index of polymer which contains 30 molecules with )
molecular weight 9000, 60 molecules with molecular weight 10000 and 80 molecules
with 25000 molecular weight.

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The rotational constant

" ICI molecule.
inertia and bond length of
(Given: Atomic masses of I: 126.9
atnuand cl: 34.96gg amu, Avagadro,s number:
f"r?I :i:'j
Js, i*.-1x :l-I,,qh,.:
amu :1.66
3 x r 0r0 cmts, N: 3.14,prur.r.i, constant : 6.627 x l0-3a
10-27kg)
State Franck-Condon
vibrational-electronic transiiion and corresponding
spectrumlf transition takes place
from l"' = 0 to tJ :2.
For a diatomr" *or..rr"
i) Write the selection rule
ii) Draw energy lever diagram showing fundamental absorption,
overtones.
iii) Define zero point ene
i) How are nanom
each of them.
ii) Explain why melting point of nanoparticles is different
materials.
from that of the bulk
Derive Gibb's rule using thermodynamic pri
For a Pb-Ag system :
(i)Why is reduced phase rule used?
(ii)Draw a neat labeled phase diagram
iii)Give rhe tion values at eutectic
For a cell represented by Fe/Fe2+ ([Link]}vl)llCl
(0.35 N4)rct (1 utn ypt
i) Name the types of electrodes used in the above
cell.
ii) write the half cell reactions taking place at anode
and cathode
iii) Calculate Eo"eu anr1 E".u at 29g K.
[Given:Eor.u*rp. , Eop,zcrz,cr-:1.36 V, R: g.3laJiIVmol, F:96500 C/mol]

"?:::::-:":i:1"' "'
ofa glass electrode.
advantage
Define shelf life o, u bu,,.
erve battery(with reactions).
Why do Lithium bun"
hour k!',;_of a Lithium b;,*y which stores 2 08 g of
;T:i:i:,r-:l:1ig.:,*TlrJ,(amp
Uthium. Total weight of the bittery isiz.,A g.
(Given : F: 96500 C/mol, gram aiomic mass of Li is
7
i) Draw a neat labeled Oa
fuel cell and write the reactions taking place at anode
and cathode.
ii) Explain why the above fuel cell is-operated between
60 oc and g0 "c ?
of the H^:__'o: alkarm" ru.i..ir iitr,. ceu vottage is r.2zy,
:ll:?:::lT:^,-l^:..fT,"ncy
enthalpy of formation of water is -2g5.3 kJ/mol and F:96500
c/mol.
What are supercapacito.,
the capacitance of a
supercapacitor?

Page 1 of 2

t:r.
 4 a) Discuss the various steps involved in galvanisation. Mention one advantage and one 6
disadvantage of galvani zation .
b) Explain the improssed cathodic current method for corrosion protection. What is Hz 5
embrittlement?
c) oWith a suitable example explain differential aeration corrosion . Write the reactions 5
takine place at anode and cathode.
d) Discuss the effect of the following on extent of corrosion: 4
i) Anodic and Cathodic polarisation
j!) Temperature
5 a) Calculate the [Link] average molecular weight and weight average molecular weight 4
of a polymer which contains 10 molecules with molecular weight 3800, 20 molecules
with molecular weight 4900 and 30 molecules with molecular weight 6300 molecular
weight.
b) Write the reaction for synthesis of Kevlar. Why is Kevlar stronger than steel on an 6
quql weight basis(give two reasons)? Give any one application of Kevlar.
c) Define conducting polymers. Draw the struoture of any one conducting polymer and 6
write the two structural features of a conducting polymer. Mention any two ways by
urhich doping is done to get a conductins polymer.
d) What are biodegradable polymers? Give two examples. Explain the two steps invol"ed 4
in biodegradation of polymers.
S*r<{€ ***

Page2 of 2

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PES UNIVERSITY. BANGALORE \J
(Established Under Karnataka Act 16 of 2013)uE2{cYr4{A \J$
END SEMESTER ASSESSMENT [Link] t SEMESTER, March, 2022 !a
UE21 CY1 41A - Engineering Chemistry
Time: 3 Hrs
Ir a).
Answer All Questions Max Marks:100 N
tflc
For a rigid rotor model of a rotating heteronucleardiatomic molecule:
i)
Derive an expression for the moment of inertia of the molecule.p4
ii) Draw the energy levei diagram from J:0 to J:6. Lrr\ ,
. q$
iii) Calculate the energy required (in cm-1) for the molecule to move from J = 4 to J = 5
if
level 8:13.84
"m-1
:6.627x10-'oJr).
lciven: Speed of light:3x1010cm/s, n:3.14, Planck's
C^) ( e SI
b)"
constant
State Beer-Lambert's law. /T-)
{"r
\J$'
For the following electronic transitions, draw the%nergy level diagram , spectrum and state
the condition for a such a transition to occur:
i) : :
Electronic transition from u" 0 to v' aQW))'/
Sklfwrv^r- $s
8S
ii) Electronic transition from u": 0 to D' :2[,2fuD - {ry 5
Y
a,,
-.J
J.,
c)o For HCI molecule: *>
-9
i) Calculate the reduced mass and force constant (in N/m) if the vibrational spectrum of
the molecule shows a single intense line at 3100 cm-lassuming it to be a harmonic
ss
\<
t
el
Q) --
={
S,

oscillationmodel.
J-( > [Link] fi^'T
t 5fO ,+t Xt/rrrt.
ii) If ttre same molecule were to undergo anharmonic oftillafions, calculate the wave ss
R
-.ti
T3
number of fundamental absorption and first overtone given the anharmonicity constant of
the molecule is 0.0174 and the equilibrium vibrational frequency is 3100 cm-1. ( sV
Y+
Avagadro's number : 6.A23x1023, speed of light : 3x1010cm/s, lamu:I .66x10'27kg gram
molar mass of H :1.0 and Cl = 35.5, n:3.l4,Planck's constant : 6.627x10-34Js) 4 t, o=
24
6
t-.1 L
bn 7
lf. How does the size of the particle being in nanoscale influence the follovnipg propertie-se-zlo fs: 3.4
,/1 RP (i)
Surface N) Oi>Electrical conductivity\rN)
rtN
2. a). rr the Pb-Ag system --
4 (-r.
3ss
\$
sl
(i) Draw a neat and labelled phase diagram. 21n J
(ii) Calculate degrees of freedom along the depression in melting point curves [Link] atQ*t N
s
F,

the eutectic point. wiuux^6-D O ( Un"aro^t ) zq

(ii,
(i)
Give the difference between eulrylieand eutectoid in two component Fe-C system. 5
til\\
b) Draw aneatand labelled diagram of a one component water system(g-*t ) \\
(ii) Using Clausius Clapeyron equation account for the negative slopd of the- melting
point curve in the phase diagram of one component water system. lW )-- 4
s{-
(i) Derive Nernst equation for a single electrode potential using thermodynamic principleg[ w \
,c) (ii) For the given cell: Fe/Fe '* [Link]* [Link], Write the overall cell reaction, \
: -A.44Y, E0ae+tAs:0.7996V)
calculate E0""rr-and E 4t 250c.(GivenE0p"7p*2
I
6
".u
What isasymmetric electrode potential'with reference to a glasselectrode?
The emf of a cell set up by combining glass electrode and.a saturated calomel elebtrode at
d) 298K was found to be 0.1069V when a buffer of pH value 4 was used. With a solution of _s,
unknown pH at the same temperature, tle cell offered an emf of [Link] the cell repre-
'sentation.
s
S
Calculate the pH qf the solution.(Given ESCE: 0.2412V) 5 d)
Fill the following table for M water activated battery s
\l
Anode t(\h ,4r,r ^ , -
=a
a)' Cathode tdl-(. ('l^-g-d-4bbt- JLu-,.k L trw ravduth,J {Yn,,trL UY
hru* sJ
Anodic reaction ,lt'M 6

qh --) /v2nl1$f o-
4dffiffi^nf ffi,W {,,t*'tL-
 Cathodic reaction
ffi
-:WTT{ L-----: ?ag-Ki 1

b). Draw a neat and labelled diagram of a directp$l(

direct!$rOH-Oz polvmeyffife membrane
fuelcell, Write its anodic and cathodic reaction()@
any fwo
Stnfe anv
Statp advantages of firel
two advantases fuel cells over battbries
battbries?
Caliulate the [Link] of fuel cell, if the voltage is 1.32V.
^4.
w-SJ @
(Given:Hl+|l2OlHzo-_>AHiofwater:.285.6KJF:96500ClM 7

c)' @indicatethepositionofthefo11owingenergystorage/conversion J
device in the Ragone plot - capacitors, Super capacitors, batteries and fuel cell.
d)' Why arelithium ion pffiilssafer than lithium batteries? calculate thd energy density (in
Wh/kg) and power &fu-i#(in Wkg) of 15 kg of lead acid battery which contains 3kg of
anodsmaterial and discharges constant current for 8 hours. The voltage of the battery is 2'1
V. (Given: [Link] of lead 207, nwqber olelectrons releasgd iq the redoxgeaction is 2,
r,:.sosooc) (L--0')4q1,tor 4) CGW yo (o,?+4*h\ eb-- 4

What is corrosio>?a-Draw a neat andi6;beled diagram of the $lvanic cell f,brmed of(the
4. a) surface of metd(#lh is differentially apaatqd. Write alt the possible cathodic reactions as
per electrochemical theory of corrosion. Q9 6

b)' @torsinfluencetherateofcorrosioni)pHii)Natureofcorrosion 6
oroduct iii) The ratio of anodic to cathodic area
1gnni1gnarticleisextrlosed to acid medium in the absence of oxygen, account for the
following,
c). i) Iron becomes britile. Q-\
ii) Conosion control in the above condition can be achieved by the addition of
antimony oxide. bi{rwdt U knl"ltorY1l @\ 4

Give reasons:
d)'
(i) lron bolts in copper vessels are undesir aAd U\
(ii) Steel tank should be maintained at its qassivating potential during anodic
corrosion protection technique. n)- ffit"^.t
?4 u"*sl-!W
Lrfin

@eihangeintensilestrengthwithincreasingmo1eculatweiffi&l
5.
a)"
polymer. {wn lrwl
Justify: i'r-
(i) Polyacetylene (PA) conducts electricity but polyethylene does not.
(iil Kevlar fiber is much stronger than steel. 6

Calculate the number average molecular weight, weight average molecular weight and
polydispersity indqx of a polyrner which contains 10 molecules with molecular weight
b)-
r, *$fl;i% weiehliSrlpro morecures with morecurar weight
i?33 T!!p 5

c)r

{*Lr*t
(iil Butvl Rubber 6

d). State any two principles of Green Chernistry and give relevant examples.
3

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