Sr.

Reagent Rxn Type Functions

No.
1. PCl3, PBr3, PI3 NSR Alcohols into Alkyl halides
2. SoCl2, PCl5 NSR Alcohols into Alkyl chlorides
&
Carboxylic acids into Acid Chlorides
3. (Lucas reagent HCl/ZnCl2,) HBr, NSR Alcohols into alkyl halides
HI
4. Cl2/Fe or FeCl3 ESR Cl group substituting on Benzene
5. NaNO2 /HCl 0-50C A_B Diazotisation (Diazonium Cholride
formation from aniline)
6. CuCl,CuBr,CuCN,KI,H2O,H3PO2 D-S/hydrolysis Diazonium Cholride into
ChloroBenzene,BromoBenzene,
Benzonitrile, IodoBenzene Phenol,
Benzene respectively
7. HBF4 or NaBF4 D-S/hydrolysis Diazonium Chloride into Fluoro
Benzene
8. AgF or Hg2F2 or SbF3 or CoF2 NSR Alkyl halides into alkyl fluorides
9. Na / dry ether FRSR Alkyl halides into alkanes
10. NaOH 623/443/368K NSR Chloro benzene to phenol
11. Br2 /FeBr3 ESR Bromination of Benzene
12. Cl2 /FeCl3 ESR Chlorination of Benzene
13. CH3Cl /AlCl3 ESR alkylation of benzene and its derivatives
14. CH-CO-Cl /AlCl3 ESR Acylation on benzene
15. H2SO4 /HNO3 ESR Nitration of benzene
16. (CHCO)2O /AlCl3 ESR O – Acylation of Phenol
17. H2SO4 ESR Sulphonation on Benzene
18. H2O/ H2SO4 EAR alkenes into alcohols
19. Aq KOH NSR Alkyl halide into alcohol
20. BH3 /H2O2 /OH- EAR Alkenes into alcohols (Anti Markonikov
product)
21. NaBH4/ LiAlH4(LAH) RED. Aldehydes, ketones, acids into alcohols,
Nito & Cynides , Isocyanides into
amines
22. H2/ Ni or H2/Pd RED reduction of aldehydes, ketones and
cyanides
23. RMgX/H3O+ D-S/hydrolysis Aldehydes, ketones into alcohols
24. O2/H+ OXI Cumene to phenol
25. Na A-B Alcohol or phenol into Sodium
alkoxide/ Phenoxide
26. (CHCO)2O/ CH-CO-Cl ESR O acylation on phenol or N acylation on
Aniline or amine
27. Conc.H2SO4/443K ER Conversion of primary alcohols into
Alkenes
28. Conc.H2SO4/410K NSR Conversion of alcohols into Ethers
29. 85% H3PO4 / 440K ER Secondary alcohol into alkene
30. 20% H3PO4/358K ER Tertiary alcohol into alkene
31. Alcoholic KOH ER Alkyl halide into alkene
32. CrO3/KMnO4 or K2Cr2O7 OXI oxidation of alcohols into acids
in acidic medium
33. Cu /573k OXI dehydrogenation of alcohols gives 10
alcohols into aldehydes and 20
alcohols into ketones & 30 alcohos
into alkenes
34. Dil. HNO3 ESR Mono nitration of Phenol
35. Conc.HNO3 ESR tri nitration of phenol
36. Br2 /H2O ESR tri bromination of phenol
37. Br2 /Cs2 ESR mono bromination of phenol
38. NaOH /CO2 ESR Phenol to salicilic acid
39. CHCl3 /NaOH ESR Phenol to salcilaldehyde
40. Zn dust RED Phenol to Benzene
41. Na2Cr2O7 /H2SO4 or air OXI Phenol to Benzo quinone
42. Zn/Cr2O3 200to 300 atm OXI CO & H into methanol
573 – 673K
43. Invertase ENZYETIC Sucrose into Glucose or Fructose
44. Zymase ENZYMETIC Glucose or Fructose into ethanol
45. HI NSR Ether into alcohol & alkyl halide
46. PCC OXI alcohol to aldehyde
47. Pd /BaSO4,H2 RED acid chloride into aldehyde
48. SnCl2/HCl/H3O+ RED Cyanides into aldehydes
49. AlH(i-Bu)2/H2O RED Cyanides into aldehydes
50. DIBAL-H/H2O RED Esters into aldehydes
51. CrO2Cl2/H2O OXI Toluene to aldehyde
52. CrO3 /(CH3CO)2O OXI Toluene into Benzaldehyde
53. Cl2/hv FRSR Chlorination on alkyl group of Benzene
or
alkane
54. CO, HCl anhydrous AlCl3 ESR Benzene to Benzaldehyde
55. (CH3)2Cd RED acid chloride into ketones
56. RMgX/H3O+ D-S/hydrolysis Cyanides into ketones
57. HCN NAR Carbonyl compound into cyanohydrin
58. NaHSO3 NAR addition to aldehyde and ketone
59. H2NOH NAR carbonyl compound into oxime
60. H2N-NH2 NAR carbonyl compound into hydrazone
61. H2N-NH-Ph NAR carbonyl compound into Phenyl
hydrazone
62. 2,4DNP NAR carbonyl compound into 2,4 dinitro
phynyl hydrazone
63. H2N-NH-CO-CH3 NAR carbonyl compound into semi carbazide
64. ROH/HCl NAR Aldehydes & ketones into hemiacetal
and
acetal
65. HO-CH2-CH2-OH/HCl NAR Aldehyde or ketone into ethelene glycol
66. Zn-Hg/HCl RED carbonyl compound into alkane
67. H2N-NH2 /KOH RED carbonyl compound into alkane
68. KMnO4/OH-/ K2Cr2O7 OXI Ketones into mixture of carboxylic
/H2SO4 or HNO3 acids prolonged oxidation
69. (Ag(NH3)2)NO3+NaOH OXI Tollen’s test
70. Cu(OH)2 OXI Fehiling’s test
71. NaOH+I2 Iodoform
72. NaOH or Ba(OH)2 NAR aldal condensation
73. Conc KOH or NaOH NAR Cannizaro’s reaction
74. KMnO4 /KOH OXI Toluene/alkyl Benzene into Benzoic
Acid
75. H2O/H+ hydrolysis Cyanides into carboxylic acids,
amidesinto carboxylic acids, esters
into carboxylic acis and alcohols,
acid chlorides or anhydrides into
carboxylic acids
76. NaOH D-S/hydrolysis Saponificaiton of ester, acid into salt of
acid
77. Na2CO3 or NaHCO3 Carboxylic acid test
78. P4O10 or P2O5 OXI Dehydration of acids into anhydride,
amides into nitriles
79. ROH/conc H2SO4 A-B Caroxylic acids into esters
80. PCl3, SoCl2, PCl5 NSR-ER Carboxylic acids into acid chlorides
81. NH3 heating NSR-ER Carboxylic acids into amides
82. NaOH/CaO ER/thermal Decarboxylation (acids into alkanes)
83. LiAlH4 RED Carboxylic acids into alcohols,
amidesinto amines
84. Cl2 /red.P4 FRSR HVZ reaction
85. Sn /HCl or Fe /HCl, H2/Pd RED Reduction of nitro compounds into
amines
86. NH3 NSR Alkyl halides into amines
87. H2/ Ni or H2/Pd LiAlH4 RED Amides into cyanindes
88. KOH/R-X NSR Phthalamide into amine
89. NaOH /Br2 DEGRADATION Hoffman bromamide, amide into amine
with one ‘C’ less
90. KOH,CHCl3 ER Amines into Carbyl amines
91. NaNO2/HCl NSR 10 aliphatic amines into alcohols
92. NaNO2/HCl 0 – 50C A-B Aniline into diazonium chloride
93. C6H5SO2Cl Test Distinguishing 10,20 & 30 amines
94. Br2/H2O ESR Aneline into tri bromo aniline
95. Br2/ CH-CO-Cl ESR Aniline into Bromo Aniline
/(CHCO)2O
96. HNO3/ CH-CO-Cl ESR Nitro aniline
/(CHCO)2O
97. H2SO4 ESR Sulphonation on aniline
98. CuCl,CuBr,CuCN,KI,H2O,H3PO2 SALT Diazonium Cholride into Chlor
or CH3-CH2-OH Benzene,
Bromo Benzene, Benzo nitrile, Iodo
Benzene , Phenol,Benzene respectively
99. Mg FR-Mech Alkyl halide to Grignard reagent
100. AgCN NSR Alkyl Halide to alkyl Isocyanides