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CHAPTER 1:
UNITS OF
MEASUREMENTS
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Chemistry is the study of matter and the changes it
undergoes
Matter is anything that occupies space and has
mass.
A substance is a form of matter that has a definite
composition and distinct properties.
liquid nitrogen gold ingots silicon crystals
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DIMENSIONS
Defined as:
Any physical quantities that can be measured by measuring
devices.
There are 2 types of dimension:
[Link] dimension
o The simplest and the most basic physical quantities
o There are 7 basic dimensions:
- Length
- mass
- time
- temperature
- amount of substances
- luminous intensity
- electrical current
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2. Derived dimensions
o Physical quantities that are obtained by combining basic physical by multiplying / dividing the
basic dimensions.
Derived dimensions Combination of Basic
dimensions
Area Length x length
Volume Length x length x length
Speed Length / time
Force (mass x length) / (time x
time)
Density Mass / (length x length x
length)
Pressure Mass / (time x time)
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International System of Units (SI)
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S.I system of units
Symbol of
Dimension Name of unit Symbol of unit Definition of unit
dimension
Basic SI Units
length L meter m
mass m kilogram Kg
time t second s
temperature T Kelvin, degree celcius K, °C
Amount of n mole mol
substance
Derived SI Units
Energy E Joule J / Nm Kg.m2.s-2
Force F Newton N Kg.m.s-2
Power P watt W /J/s Kg.m2.s-3
Velocity V Meter per second m.s-1
Acceleration a Meter per second m.s-2
squared
Pressure P Newton per meter N.m-2
squared, Pa
Pascal
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Density ƿ Kilogram per cubic Kg.m-3
t
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MASS
Matter - anything that occupies space and has mass.
mass – measure of the quantity of matter
SI unit of mass - kilogram (kg)
1 kg = 1000 g = 1 x 103 g
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VOLUME
Volume – SI unit for volume is cubic meter (m3)
1 cm3 = (1 x 10-2 m)3 = 1 x 10-6 m3
1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3
1 L = 1000 mL = 1000 cm3 = 1 dm3
1 mL = 1 cm3
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DENSITY
Density – SI unit for density is kg/m3
1 g/cm3 = 1 g/mL = 1000 kg/m3
mass d= m
density = OR
V
volume
EXAMPLE:
A piece of platinum metal with a density of 21.5 g/cm3
has a volume of 4.49 cm3. What is its mass?
m
d= V
m = d x V = 21.5 g/cm3 x 4.49 cm3 = 96.5 g
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EX. 1.1
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EX. 1.2
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Temperature
• Measurement of how hot/cold a substance is
relative to another substance.
• Three temperature scales:
oF
9 oF o
i) 0F – degrees Fahrenheit = x C + 32 oF
5 oC
oC
5 oC
ii) 0C – degrees Celcius = (oF – 32oF) x
9 oF
iii) K - Kelvin K = (oC + 273.15oC) x 1 K
1oC
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Example:
Convert 172.9 0F to degrees Celsius.
0C = 5 x (0F – 32)
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0C = 5 x (172.9 – 32) = 78.3
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Scientific Notation
The number of atoms in 12 g of carbon:
602,200,000,000,000,000,000,000
6.022 x 1023
The mass of a single carbon atom in grams:
0.0000000000000000000000199
1.99 x 10-23
N x 10n
N is a number n is a positive or
between 1 and 10 negative integer
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568.762 0.00000772
move decimal left move decimal right
n>0 n<0
568.762 = 5.68762 x 102 0.00000772 = 7.72 x 10-6
Addition or Subtraction
1. Write each quantity with the same exponent n
2. Combine N1 and N2
3. The exponent, n, remains the same
4.31 x 104 + 3.9 x 103 = 4.31 x 104 + 0.39 x 104
= 4.70 x 104
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Multiplication
1. Multiply N1 and N2
2. Add exponents n1 and n2
(4.0 x 10-5) x (7.0 x 103) = ?
= (4.0 x 7.0) x (10-5+3)
= 28 x 10-2
(a x 10m) x (b x 10n) = (axb) x 10m+n
= 2.8 x 10-1
Division
1. Divide N1 and N2
2. Subtract exponents n1 and n2
8.5 x 104 ÷ 5.0 x 109 = ?
= (8.5 ÷ 5.0) x 104-9
(a x 10m) ÷ (b x 10n) = (a ÷ b) x 10m-n
= 1.7 x 10-5
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Significant Figures
- The meaningful digits in a measured or calculated quantity.
RULES:
• Any digit that is not zero is significant
1.234 kg 4 significant figures
• Zeros between nonzero digits are significant
606 m 3 significant figures
• Zeros to the left of the first nonzero digit are not significant
0.08 L 1 significant figure
• If a number is greater than 1, then all zeros to the right of the
decimal point are significant
2.0 mg 2 significant figures
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• If a number is less than 1, then only the zeros that are at
the end and in the middle of the number are significant
0.00420 g 3 significant figures
• Numbers that do not contain decimal points, zeros after
the last nonzero digit may or may not be significant.
400 cm 1or 2 or 3 significant figures
4 x 102 1 significant figures
4.0 x 102 2 significant figures
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How many significant figures are in each of
the following measurements?
24 mL 2 significant figures
3001 g 4 significant figures
0.0320 m3 3 significant figures
6.4 x 104 molecules 2 significant figures
560 kg 2 significant figures
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Significant Figures
Addition or Subtraction
The answer cannot have more digits to the right of the decimal
point than any of the original numbers.
89.332
+1.1 one significant figure after decimal point
90.432 round off to 90.4
3.70 two significant figures after decimal point
-2.9133
0.7867 round off to 0.79
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Significant Figures
Multiplication or Division
The number of significant figures in the result is set by the original
number that has the smallest number of significant figures
4.51 x 3.6666 = 16.536366 = 16.5
3 sig figs round to
3 sig figs
6.8 ÷ 112.04 = 0.0606926 = 0.061
2 sig figs round to
2 sig figs
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Significant Figures
Exact Numbers
Numbers from definitions or numbers of objects are considered
to have an infinite number of significant figures
The average of three measured lengths; 6.64, 6.68 and 6.70?
6.64 + 6.68 + 6.70
= 6.67333 = 6.67 = 7
3
Because 3 is an exact number
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Dimensional Analysis Method of Solving Problems
1. Determine which unit conversion factor(s) are needed
2. Carry units through calculation
3. If all units cancel except for the desired unit(s), then the
problem was solved correctly.
given quantity x conversion factor = desired quantity
desired unit
given unit x = desired unit
given unit
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Dimensional Analysis Method of Solving Problems
How many mL are in 1.63 L?
Conversion Unit 1 L = 1000 mL
1000 mL
1.63 L x = 1630 mL
1L
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The speed of sound in air is about 343 m/s. What is this
speed in miles per hour?
conversion units
meters to miles
seconds to hours
1 mi = 1609 m 1 min = 60 s 1 hour = 60 min
m 1 mi 60 s 60 min mi
343 x x x = 767
s 1609 m 1 min 1 hour hour
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