Chemical Bonding and Hybridization Concepts
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yayINORGANIC CHEMISTRY
EXERCISE # 1
INTRODUCTION
1. The molecule which contain same number of and bonds is
(A) (CN)2 (B) C2H2 (C) HNO2 (D) HCN
2. Correct energy order of hybrid orbital is:
(A) sp < sp2 < sp3 (B) sp < sp3 < sp2 (C) sp3 < sp2 < sp (D) sp2 < sp3 < sp
LEWIS DOT STRUCTURES
3. Which of the following is hypovalent species?
(A) IC (B) SO2 (C) NO2+ (D) NH2+
4. Which one of the following element do not have tendency to form hyper valent compound ?
(A) P (B) N (C) S (D) Se
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5. Which of the following set of species are hypovalent?
(A) NH3, CO2 (B) SO2, CO2 (C) BeH2, BF3 (D) BeCl2, PCl3
6. Which of the following pair of species are isostructural but not isoelectronic ?
(A) N2O and SO2 (B) CO3–2 and NO3–1 (C) NF3 and NH3 (D) O3 and NO2
7. Which of the following xenon compound has the same number of lone pairs as in I3– :–
(A) XeO4 (B) XeF4 (C) XeF2 (D) XeO3
8. Which of the following molecules is adequately represented by a single Lewis structure?
(A) O3 (B) NOC1 (C) SO2 (D) N2O
TYPES OF BOND
9. The molecule which contain both polar and non-polar covalent bond present in its structure?
(A) H2F2 (B) O2F2 (C) O3 (D) All of these
10. Which one of the following species have coordinate bond present in its Lewis structure
(A) SO2 (B) O3 (C) NO2 (D) All of them
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–2
11. [Re2Cl8] molecule has
(A) only bond (B) only bond (C) quadruple bond (D) None of these
12. Which of the following statement is correct regarding covalent bond ?
(A) Filled orbitals of two or more atoms overlap with one another.
(B) Unoccupied orbitals of two or more atoms overlap with one another
(C) Electrons are simultaneously attracted between more than one nucleus.
(D) Electrons are transferred from one atom to another atom.
VBT
13. If x is internuclear axis, bond can be formed by :
(A) d x y d x y
2 2 2 2 (B) dxy + dyz
(C) dyz + dyz (D) dxz + dxy
14. Which of the following leads to non-bonding on z-axis
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(A) px + px (B) Py + Py (C) dxy + dxy (D) dxy + dyz
15. Which of the following statement is false ?
(A) -bond is a result of 4-lobe interaction between two p-orbitals.
(B) -bond is weaker than -bond
(C) -bond & -bond have unequal bond strength
(D) Representative elements do not have tendency to form -bond.
16. Choose the incorrect order of bond strength :-
(A) 3p - 3p < 2p - 3d (B) 3p - 3p < 3d - 3d
(C) 3p - 3d < 2p - 3d (D) 3p - 3d < 3p - 3p
17. Which of the following specie does not contain p - d bond(s) ?
(A) SO2Cl2 (B) N2O (C) H2PO3ϴ (D) SO32–
18. Correct order of bond strength is:
(A) 1s – 1s > 1s – 2s > 2s – 2p (B) 1s – 1s < 1s – 2s < 2s – 2p
(C) Is – 2s > 2s – 2p > 1s – 1s (D) None of the above
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19. If x is internuclear axis, bond can be formed by :
(A) d x y d x y
2 2 2 2 (B) dxy + dyz
(C) dyz + dyz (D) dxz + dxy
20. Choose the CORRECT statement about the structure of SO2.
(A) Two 2p – 3d bond (B) Two 2p – 3d bond
(C) One 2p – 3d & one 2p – 3p bond (D) It is hypovalent
21. The species having no P – P bond but has bond order equal to that of O2 .
(A) C1O3– (B) PO43– (C) SO42– (D) XeO3
22. Which of the following orbital cannot form bond with dxy orbital .
(A) s (B) px (C) d (D) All of these
x2 –y2
23. Which of the following statement is correct ?
(A) s -orbital always forms bond with p orbital
(B) s-orbital is more directional than -orbital
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(C) p-orbital always form 7i-bond
(D) a covalent bond is directional in nature.
24. Which of the following overlapping is correct regarding -bond formation ?
(A) 2px + 2px, when y-axis is inter nuclear axis
(B) 1s + 2px, when x - axis is inter nuclear axis
(C) 2py + 2py, when z-axis is inter nuclear axis
(D) 2py + 2pz, when x-axis is inter nuclear axis
25. Which of the following shows maximum covalency ?
(A) F (B) I (C) S (D) O
26. Which of the following overlapping is not present in XeO3 molecule ?
(A) sp3 + px (B) sp3 + py (C) dxz + px (D) sp3 + s
27. According to VBT, which of the following overlapping results -type covalent bond in O2
molecule formation, when Z-axis is internuclear axis?
(I) 2s – 2s (II) 2px – 2px (III) 1s – 1s (IV) 2py – 2py (V) 2pz – 2pz
(A) I, III (B) III, IV (C) II, IV (D) IV, V
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28. Which of the following would result in the formation of strongest -bond if the molecular axis
is x-axis?
(A) 2px + 2px (B) 2py + 2py (C) 2py + 3dxy (D) 2pz + 4pz
29. In which of the following species p–d bond is present but p-p bond is absent?
(A) SiH4 (B) CS2 (C) SO2 (D) SO2Cl2
HYBRIDISATION
30. The set of planar chemical species in which d-orbital participate in hybridisation.
(A) C1O4– , C1O3 –, C1O2– (B) XeF5, IF4, XeF4
(C) XeF5, XeF6, XeF4 (D) IF7, CF3, SF4
31. Hybridisation of N in NO2 is ?
(A) sp3 (B) sp (C) sp2 (D) N atom is unhybridised
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32. Which one is only V-shaped molecule or ion-
(A) I3– (B) N3– (C) S3 (D) C34–
33. In which of the following molecules hybridisation of central atom is sp3d2.
(A) XeF6 (B) S2F10 (C) SF4 (D) PEt3
34. Which of the following molecule involve d z2 orbital in it‘s hybridisation
(A) XeF4 (B) XeOF4 (C) XeO2F2 (D) All of these
35. Hybridisation of ClFO3, SF4 & SOF4 respectively will be
(A) sp3, sp3d sp3d (B) sp3, sp3 sp3
(C) sp3, sp3d2 sp3d2 (D) All sp3d
36. Electron geometry of the molecule XeF2 & IC12– are respectively ?
(A) square bipyramidal, tetrahedral (B) linear & linear
(C) Trigonal bipyramidal & tetrahedral (D) Both Trigonal bipyramidal
37. Which of the following molecule have all atoms sp2 Hybridised ?
(A) (B)
(C) Benzene (D) None of these
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38. Which of the following statement is CORRECT?
(A) Lattice energy is always highest for compound with highest ionic character
(B) Hydrated radius is inversely proportional to hydration energy
(C) Dissolution of salt in water depends upon lattice energy and hydration energy
(D) None of these
39. Correct statement about a molecule of type AB3L where A = central atom, L = lone pair, B =
bond pair.
(A) It is pyramidal in shape (B) NH3 is one of the example of this case
(C) It has tetrahedral electron geometry (D) All are correct.
40. Phi() bond is present in
(A) Mn2(CO)10 (B) U2 (C) O2 (D) None of these
41. Which of the following compound is planar ?
(A) PH4+ (B) XeF4 (C) XeOF4 (D) SF6
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42. Hybridisation of cationic part of Cl2O6(s) is -
(A) sp2 (B) sp3 (C) sp3d (D) sp3d2
43. Which compound given below has sp3, sp2 and sp orbitals in the ratio of 6 : 3 : 2 ?
(A) CH3 – CH = CH – CH2 – C C – CH3 (B) CH3 – CH = CH – CH2 – C CH
(C) CH3 – CH2 – C C – CH = CH2 (D) CH3 – CH = CH – C CH
44. The molecule/ion in which bond angle is less than 107º.
(A) NF4+ (B) CCl4 (C) ClO4¯ (D) None of these
45. Select pair of compounds in which both have different hybridisation but have same molecular
geometry.
(A)BF3, BrF3 (B) ICl2¯, BeCl2 (C) BCl3, PCl3 (D) PCl3, NCl3
46. Choose the correct option for following statements :
(I) sp3 hybrid orbitals are at 90º to one another
(II) sp3d2 adjacent hybrid orbitals are at 90º to one another
(III) sp2 hybrid orbitals are at 120º to one another
(IV) Bond order of N–O bond in NO3– is 1.33
(A) T F T F (B) T T F F (C) F T T T (D) F T F T
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3 3
47. Which of the following specie has sp d hybridisation ?
(A) XeF5– (B) SO3 (C) SO2 (D) XeF2
48. If x is the no. of hybrid orbital containing 33.3% s-character and y is the number of hybrid
orbital's containing 50% s-character then, find the value of x y for allene.
(A) 2 (B) 3 (C) 6 (D) 3.5
49. All fluorine atoms are in same plane in:
(A) CHF3 (B) ClF3 (C) XeOF4 (D) All of these
50. Select hybridisation which have non planar geometry when all are bond pair, but planar when
there are 2 lone pairs on central atom:
(A) sp3 (B) sp3d (C) sp3d2 (D) All of these
51. Select correct statement for BrF5.
(A) All fluorine atoms are in same plane
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(B) Four fluorine atoms and Br atom is in same plane
(C) Four fluorine atoms are in same plane
(D) It has all F – Br – F bond angles at 90º
52. In which of following cases, the central atom is not perfectly sp3 hybridised?
(A) BF4– (B) SiF4 (C) CHF3 (D) CCl4
53. Which of the following compound has the smallest bond angle (X – A – X) in each series
respectively :
(A) OSF2 OSCl2 OSBr2
(B) SbCl3 SbBr3 SbI3
(C) PI3 AsI3 SbI3
(A) OSF2, SbCl3 and PI3 (B) OSBr2, SbI3 and PI3
(C) OSF2, SbI3 and PI3 (D) OSF2, SbCl3 and SbI3
54. Molecule which does not contain any F – X – F bond angle which is less than 90°:
(X = central atom)
(A) IF7 (B) BrF3 (C) PF5 (D) SF4
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–
55. What is the geometry of the IBr2 ion ?
(A) Linear
(B) Bent shape with bond angle of about 90º
(C) Bent shape with bond angle of about 109º
(D) Bent shape with bond angle of about 120º
56. What is the shape of the ClF3 molecule ?
(A) Trigonal planar (B) Trigonal pyramidal
(C) T-shaped (D) Tetrahedral
57. The H—O—H bond angles in H3O+ are approximately 107º. The orbitals used by oxygen in
these bonds are best described as :
(A) p-orbitals (B) sp-hybrid orbitals
2
(C) sp -hybrid orbital (D) sp3-hybrid orbital
58. The shape of XeF3+ is :
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(A) Trigonal planar (B) Pyramidal (C) Bent T-shape (D) See-saw
59. Which of the following shape are not possible for possible value of ‗n‘ in XeFn molecule?
(A) Linear (B) Square planar
(C) Trigonal planar (D)Capped octahedral
60. Which of the following is the correct set with respect to molecule, hybridization and shape?
(A) BeCl2, sp2, linear (B) BeCl2, sp2 triangular planar
(C) BCl3, sp2, triangular planar (D) BCl3, sp3, tetrahedral
61. The pair of species with similar shape is :
(A) PCl3, NH3 (B) CF4, SF4 (C) PbCl2, CO2 (D) PF5, IF5
62. The hybridization of the central atom in ICl2+ is :
(A) dsp2 (B) sp (C) sp2 (D) sp3
63. The state of hybridization of the central atom is not the same as in the others :
(A) B in BF3 (B) O in H3O+ (C) N in NH3 (D) P in PCl3
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64. Which is the following pairs of species have identical shapes ?
(A) NO2+ and NO2– (B) PCl5 and BrF5
–
(C) ClO3 and SO3–2 (D) TeCl4 and XeO4
65. The shapes of XeF4, XeF5– and SnCl2 are :
(A) Octahedral, trigonal bipyramidal and bent
(B) Square pyramidal, pentagonal planar and linear
(C) Square planar, pentagonal planar and angular
(D) See-saw, T-shaped and linear
66. Which is not correctly matched ?
(A) XeO3 — Trigonal bipyramidal (B) ClF3 — bent T-shape
(C) XeOF4 — Square pyramidal (D) XeF2—Linear shape
67. The geometry of ammonia molecule can be best described as :
(A) Nitrogen at one vertex of a regular tetrahedron, the other three vertices being occupied by
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three hydrogens
(B) Nitrogen at the centre of the tetrahedron, three of the vertices being occupied by three
hydrogens
(C) Nitrogen at the centre of an equilateral triangle, three corners being occupied by three
hydrogens
(D) Nitrogen at the junction of a T, three open ends being occupied by three hydrogens
BOND LENGTH / BOND ORDER
68. Which of the following bond length is shortest ?
(A) H–F (B) H–O (C) H–N (D) H–Cl
69. CORRECT order of bond length is :-
(A) Si–O, < P–O < S–O < Cl–O (B) Cl–O < S–O < Si–O < P–O
(C) Cl–O < S–O < P–O < Si–O (D) S–O < P–O < Cl–O < Si–O
70. The average charge on each O atom and average bond order of I–O bond in IO65– is :
(A) –1 and 1.67 (B) – 5/6 and 1.67 (C) –5/6 and 1.33 (D) –5/6 and 1.167
71. The correct order of C–N bond length ?
P : CH3CN Q : HNCO R : CH3CONH2
(A) P > Q > R (B) P = Q = R (C) R > Q > P (D) R > P > Q
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BOND ENERGY
72. Which of the following has maximum oxidising character.
(A) F2 (B) Cl2 (C) Br2 (D) I2
73. Which of the following having second highest bond dissociation energy (out of given
molecules).
(A) F2 (B) Cl2 (C) Br2 (D) I2
BOND ANGLE
74. Which is the correct order of the bond angle ?
(A) NH3 < NF3 (B) H2O > Cl2O (C) PH3 < SbH3 (D) H2Te < H2S
75. Which of the following order is/are CORRECT :-
(A) CO32– < CO2 (C–O bond length) (B) NO3– < NO2 (N–O bond length)
(C) O2 < O3 (O–O bond length) (D) C6H6 < C2H4 (C–C bond length)
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76. CORRECT order of bond angle is ?
(A) BCl3 > BF3 (B) CCl4 > BF3 (C) BF3 > BF4– (D) H2O = O(CH3)2
77. Which of the following has smallest bond angle X–A–X is present ? (X is halogen & A is
central atom)
(A) COCl2 (B) COF2 (C) POCl3 (D) POF3
78. Maximum bond angle will be present in which of the following molecule?
(A) CH4 (B) CF4
(C) CI4 (D) All have same bond angle
79. Which one of the following has maximum bond angle ?
(A) CH4 (B) CF4
(C) CCl4 (D) All have same bond angle
80. Number of C-atoms in next homologue of first member of ester family is :
(A) 5 (B) 4 (C) 3 (D) 2
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+ –
81. The bond angles of NH3, NH4 and NH2 are in the order
(A) NH2 NH3 NH4+ (B) NH4+ NH3 NH2
(C) NH3 NH2– NH4+ (D) NH3 NH4 NH2
82. In which of the following pair of species, all bond angles are equal
(A) CO32– , COCl2 (B) PO43– , POCl3
(C) BF4¯ , BH4¯ (D) CH3F , CH4
83. The correct order of bond angle is
(A) H2O > OF2 > SF2 (B) H2O > SF2 > OF2
(C) H2O < OF2 > SF2 (D) H2O > OF2 < SF2
VSEPR THEORY
– –
84. The shape of [ClF4] and [ClF2] ions is respectively
(A) See-saw and linear (B) See-saw and bent
(C) Tetrahedral and linear (D) Square planar and linear.
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85. More correct structure of ClF3 is :
F
F F
Cl
(A) Cl (B) (C) Cl (D) All of the above
F
F F F F F
86. Which of the following molecules/species has the minimum number of lone pairs?
(A) ICl3 (B) BF4– (C) SnCl2 (D) XeF4
87. adjacent angles (90º+72º) in IF7 molecule is
The number of FIF
(A) 10 (B) 15 (C) 20 (D) 14
88. The number of F–I–F angles less than 90º and equal to 90º are respectively in IF7
(A) 5 and 5 (B) 10 and 5 (C) 5 and 10 (D) 10 and 15
89. The number of I – F bonds having the longer and shorter lengths are respectively in IF7
(A) 5 and 2 (B) 2 and 5 (C) 5 and 5 (D) 2 and 2
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90. Find the pair of species having the same shape but different hybridization of the central atom.
(A) SO3, CO32– (B) NO2–, ClO2– (C) BeCl2, HCN (D) XeF2, SnCl2
91. The pair of species with similar shape is?
(A) XeF4 & SF4 (B) PF5 & IF5
(C) XeO2F2 & SeF4 (D) All pairs are iso-structural
92. Which of the following molecule have all the bond angle equal is?
(A) PF5 (B) SF4 (C) NH3 (D) None of these
93. Which of the following is isostructural with XeOF4?
(A) BrF5 (B) PCl3F2 (C) SeF4 (D) XeO2F2
94. Which of the following is planar?
(A) XeO3 (B) BrF5 (C) ClF3 (D) All are planar
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95. The number of species given below having angles equal to 90º are ?
BrF3, IF5, SeF6, ICl4–, PCl5
(A) 3 (B) 4 (C) 5 (D) 2
96. Which of the following molecule contain maximum number of atoms in one plane ?
(A) CCl4 (B) PF5 (C) XeF5– (D) SF6
97. Which of the following specie is non-planar ?
(A) ClF3 (B) H3O+ (C) NO2– (D) ClO2–
98. Molecular shape of XeF3+, SF3+ and CF3+ are :
(A) the same with 2, 1 and 0 lone pairs of electrons, respectively
(B) different with 2, 1 and 0 lone pairs of electrons, respectively
(C) different with 0, 1 and 2 lone pairs of electrons, respectively
(D) the same with 2, 0 and 1 lone pairs of electrons, respectively
99. Which of the following statements is incorrect ?
(A) In H2O, the bond angle is less than OF2
(B) In ClF3, the axial Cl–F bond length is larger than equatorial Cl–F bond length.
(C) In SF4, F–S–F equatorial bond angle is not equal to 120º due to lone pair-bond pair
repulsions.
(D) In ICl4–, bond angles is 90º
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100. According to VSEPR theory, in which species do all the atoms lie in the same plane ?
1. CH3+ 2. CH3–
(A) 1 only (B) 2 only (C) both 1 and 2 (D) neither 1 nor 2
101. In SNF3, the FSF should be :
(A) less than 120º and more than 109º28 (B) less than 109º28
(C) less than 180º and more than 120º (D) Exactly equal to 109º28
102. Give the correct order of initials T or F for following statements. Use T if statement is true and
F if it is false :
(I) The order of repulsion between different pair of electrons is lp – lp > lp – bp > bp – bp
(II) In general, as the number of lone pair of electrons on central atom increases, value of bond
angle from normal bond angle also increases
(III) The number of lone pair on O in H2O is 2 while on N in NH3 is 1
(IV) The structures of xenon fluorides and xenon oxyfluorides could not be explained on the
basis of VSEPR theory
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(A) TTTF (B) TFTF (C) TFTT (D) TFFF
103. The H—C—H bond angle in CH4 is 109.5º, due to lone pair repulsion, the H—O—H angle in
H2O will :
(A) remain the same (B) increase (C) decrease (D) become 180º
104. The compound MX4 is tetrahedral. The number of XMX angles in the compound is :
(A) three (B) four (C) five (D) six
SOLID OR LIQUID STATE HYBRIDISATION
105. The number of non-axial set of 'd' orbital participate in the hybridisation of the anionic part of
PCl5
(A) 1 (B) 2 (C) 3 (D) 0
106. The (Cl–P– Cl) adjacent angle difference in cationic part and anionic part in PCl5(s) is :
(A) 60 (B) 90 (C) 19.5 (D) 10.5
107. Hybridisation of cationic part of Cl2O6(s) is -
(A) sp2 (B) sp3 (C) sp3d (D) sp3d2
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STRUCTURES
108. Ratio of / present in the XeO3 will be
(A) 1 : 4 (B) 1 : 2 (C) 1 : 1 (D) 2 : 1
109. Oxidation state of Cr in CrO5 is -
(A) +10 (B) +8 (C) +6 (D) +5
110. Which of the following compound has peroxy linkage present in its structure ?
(A) K3CrO8 (B) Cl2O6 (C) N2O5 (D) H2S2O7
111. Which of the following species have maximum p-p bonds ?
(A) P4S10 (B) HCO3– (C) S3O9 (D) P4O10
112. Find the correct statement about P4O8 :
(A) molecule does not exist
(B) five P–O–P linkage
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(C) four P=O bonds present in it's structure
(D) Six P–O–P linkage
113. In the structure of H2CSF4, which of the following statement is incorrect ?
(A) Two C – H bonds are in the same plane of axial S – F bonds.
(B) Two C – H bonds are in the same plane of equitorial S – F bonds.
(C) Total Six atoms are in the same plane.
(D) Equitorial S – F bonds are Perpendicular to nodal plane of bond.
RESONANCE
114. Total number of resonating structure possible of the molecule ClO4– is -
(A) 2 (B) 3 (C) 4 (D) 5
115. The formal charges on the three atoms in O3 molecule are :
(A) 0,0,0 (B) 0,0,–1 (C) 0,0, +1 (D) 0, +1, –1
116. Minimum number of resonating structure possible in : -
(A) O3 (B) NO2– (C) N3– (D) COCl2
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INORGANIC CHEMISTRY
117. The compound having shortest S–O bond length ?
(A) SO3F– (B) SO4–2 (C) SOF4 (D) SOCl2
OXY ACID
118. Which of the following acid have highest number of P–H bonds :-
(A) H4P2O8 (B) H4P2O7 (C) H4P2O5 (D) H3PO3
119. Oxidation state of S in H2S2O8 is ?
(A) +5, +5 (B) +6, +5 (C) +5, +6 (D) +6, +6
120. Which of the following oxy acid have sulphur atoms with different oxidation states?
(A) H2S4O6 (B) H2S2O3 (C) H2S2O5 (D) All of these
121. Which of the following compound has different value of basicity from the others ?
(A) H3PO3 (B) H4P2O5 (C) H3BO3 (D) H2SO5
122. Which of the following acid have highest number of P–H bonds :-
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(A) H4P2O8 (B) H4P2O7 (C) H4P2O5 (D) H3PO3
a b
123. Find the value of if; a is the total number of sp3 hybridised atoms, b is total p–pbonds
c
2
and c is the total sp hybridised atoms in the structure of H4P4O12.
(A) 2 (B) 1 (C) 3 (D) 4
DIPOLE MOMENT
124. Which of the following have maximum dipole moment?
Cl
Cl
Cl
(A) (B) Cl
Cl
Cl Cl
Cl Cl Cl
(C) Cl Cl (D)
Cl Cl
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125. Which of the following is most polar in nature ?
NO2 CH3 CH3
(A) (B) (C) (D)
NO2
126. Which of the following molecule has permanent dipole moment:
(A) SO3 (B) SO2 (C) CO2 (D) BF3
127. The correct sequence of polarity of the following molecule :
I. XeF4 II. XeF2 III. XeF5– IV. XeO3
(P stands for polar and NP stands for non-polar)
I II III IV
(A) P NP NP P
(B) NP NP NP P
(C) NP P NP P
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(D) NP P P NP
128. Which of the following is most polar in nature?
(A) CH2Cl2 (B) CHCl3 (C) CH3Cl (D) CH3F
129. Total number of polar species among the following will be ?
(OH)2 , (SCN)2 , CF3 , C3O2 , SeF4
(A) 2 (B) 4 (C) 5 (D) 3
130. Arrange the following in increasing order of their polarity.
(I) Ortho/chloro/Toluene (II) Meta/chloro/Toluene (III) Para/chloro/Toluene
(A) III > II > I (B) II < I > III (C) III > I > II (D) I < II < III
131. Which of the following molecule / species is polar.
(A) O3 (B) NO2+
(C) paradichlorobenzene (D) None of these
132. Which of the following molecule is non polar?
(A) NF3 (B) ClF3 (C) XeO3 (D) SO3
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 15
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HYDROGEN BONDING
133. Which of the following have intramolecular H-bonding ?
(A) Chloral (B) Orthochlorophenol
(C) Paranitrophenol (D) C6H6
134. What is the order of boiling point of the following compounds ?
HF , NH3 , H2O , CH4
(A) CH4 > NH3 > H2O > CH4 (B) HF > H2O > NH3 > CH4
(C) H2O > HF > NH3 > CH4 (D) H2O > NH3 > HF > CH4
135. Which of the following have weakest intermoleculear forces ?
(A) CH3COOH (B) HO OH
(C) NC CN (D) H2O2
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136. Select the INCORRECT statement ?
(A) Cationic part of NH4F can form hydrogen bond with water
(B) Hydrogen bonding is not present in ethene ( H2C = CH2)
(C) Anionic part of NaHCO3 have inter molecular hydrogen bonding
(D) Vapour pressure decreases due to intramolecular H-bonding.
137. The strength of H-bonding order is
(A) H2O > H2O2 > HF (B) H2O2 > H2O > HF
(C) HF > H2O > H2O2 (D) HF = H2O = H2O2
138. Give the correct order of initials T or F for following statements. Use T if statement is true and
F if it is false.
(i) HF boils at a higher temperature than HCl
(ii) HBr boils at lower temperature than HI
(iii) Ka1 of maleic acid is higher than that of fumaric acid
(iv) Ka2 of maleic acid is higher than that of fumaric acid
(A) TFTT (B) TTTF (C) TFTF (D) TTTT
139. Strongest hydrogen bond present in :
(A) O – H ------ S (B) S – H ------ O (C) F – H ------ F (D) F – H ------ O
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140. Which of the following will prefer intramolecular hydrogen bonding :
(A) CCl3CHO.H2O (B) Orthodichlorobenzene
(C) Sulphuric acid (D) Both (A) & (B)
141. Which of the following is correct order for extent of Hydrogen Bonding
(A) H2O2 > H2O > HF > NH3 (B) H2O > HF > NH3 > H2O2
(C) H2O2 > H2O > NH3 > HF (D) H2O2 > NH3 > H2O > HF
MISCELLANEOUS
142. Which is correct about D2O
(A) Its boiling point is higher than that of H2O ()
(B) O – D - - - - O bond is stronger than O – H - - - - O bond.
(C) D2O(s) sinks in H2O ().
(D) all the above are correct.
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143. Which of the following do not exist?
(A) KHF2 (B) CsHCl2 (C) KHCl2 (D) KF
144. Which of the following species is an example of odd electron molecule?
(A) NO2 (B) N2O (C) ClO3 (D) Both (A) and (C)
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 17
INORGANIC CHEMISTRY
EXERCISE # 2
LEWIS DOT STRUCTURES
1. Lewis theory fails to explain which of the following structure(s) ?
(A) SF6 (B) XeF2 (C) XeF4 (D) BeCl2
2. In which of the following molecule/ion the central atom have + 1 formal charge ?
(A) O3 (B) N3– (C) NO3– (D) CO3–2
3. In which of the following molecule all the atoms are present in ground state ?
(A) PH3 (B) CO (C) SF4 (D) HOF
4. In which of the following molecule number of lone pairs & number of covalent bonds are equal ?
(A) SO3 (B) SO2 (C) CO2 (D) H2Se
5. Which of the following statement is incorrect regarding molecule NOCl
(A) It has covalent as well as ionic bond present in its structure.
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(B) It has Cl atom present as a central atom.
(C) It has one lone pair.
(D) It has linear structure.
6. Lewis theory fails to explain which of the following structure(s) ?
(A) SF6 (B) XeF2 (C) XeF4 (D) BeCl2
TYPES OF BOND
7. Type of bonds present in PH4I is/are:
(A) Ionic (B) Covalent (C) Co-ordinate (D) H-bond
8. Which of the following set of elements have tendency to combine with each other by sharing of
valence electron.
(A) Mg & O (B) B & F (C) Na & H (D) P & F
9. Coordinate bond is present in the following molecule(s) :
(A) NO2 (B) N2O4 (C) PCl4+ (D) CO3–2
10. Which of the following set contains covalent as well as ionic species ?
(A) NO, CO, OF2 (B) NH3 BF3 AlF3 (C) CO2, CsCl, NO2 (D) SO3, BCl3, CaO
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 18
INORGANIC CHEMISTRY
VBT
11. Which of the following statement is correct?
(A) Extent of overlapping : 3p – 4s < 3s – 3s
(B) s-orbital can never form -bond
(C) p-orbital can form and as well as bond.
(D) non axial d-orbitals (dxy, dxz, dyz) have more directional nature than the axial d-orbitals
( dz & dx
2 2
y2
)
12. Select the correct statement(s) :
(A) bond is stronger than bond
(B) bond is the result of collateral overlapping between two half filled atomic orbitals.
(C) s –orbital & py –orbital can be never form bond on z–axis.
(D) py & py on z–axis form bond
13. Choose the correct order(s) of strength of overlapping of orbitals :
(A) 2p – 2p > 2p – 3p > 3p – 3p (B) 3d – 3d > 3p – 3d > 3p – 3p
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(C) 2s – 3s > 3p – 3p > 3s – 3p (D) 2s – 2s > 2s – 2p > 2p – 2p
14. Which of the following molecules have P – dbond in their structure ?
(A) SOF4 (B) SO2F2 (C) CO3–2 (D) CO
HYBRIDISATION
15. Which of the following specie(s) contains all bond angles equal?
(A) PCl4+ (B) AsF5 (C) CH2F2 (D) XeF4
16. Which of the following combination of bond pair (b.p) & lone pair (l.p.) gives same shape?
(i) 3b.p. + 1 l.p. (ii) 2 b.p. + 2 l.p. (iii) 3 b.p. + 2 l.p.
(iv) 2.b.p. + 3 l.p. (v) 2 b.p. + 1 l.p. (vi) 2 b.p. + 0 l.p.
(A) (ii) & (v) (B) (vi) & (iv) (C) (iii) & (iv) (D) (i) & (iii)
17. Which of the following molecules has/have linear structure
(A) BeCl2 (B) XeF2 (C) XeO4 (D) SF4
18. Which of the following molecules have H Bonding
(A) H2O (B) NH3 (C) HF (D) CH4
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 19
INORGANIC CHEMISTRY
3
19. Which of the following molecules is/are sp d hybridised
(A) PCl5 (B) PCl6– (C) XeO2F2 (D) IF7
20. Which of the following molecules has/have d x 2
y2
and dz orbitals in hybridisation
2
(A) SF6 (B) XeF4 (C) SF2 (D) NO2+
21. Which of the following molecules has/have capped octahedral geometry
(A) XeF6 (B) IF6– (C) XeOF5– (D) XeF2
22. In which of following, vacant orbital take part in hybridisation :
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(A) BF3 (B) PCl6– (C) BF4– (D) NH3
23. Which of the following is correct match for ABxLy (where B = Bond pair & L = lone pair).
(A) x = 3, y = 2 planar & polar (B) x = 3 , y = 1 polar & non planar
(C) x = 2, y = 3 non planar & non polar (D) x = 4, y = 1, non planar & polar
BONED LENGTH / BOND ORDER
24. Select the INCORRECT Order ?
(A) SO3 < SO3–2 < SO4–2 (S – O bond order)
(B) CO > CO2 > CO3–2 (C – O bond order )
O
(C) CN– < NCN–2 < RCNH2 (C – N bond order)
(D) ClO– > ClO2– > ClO3– > ClO4– (Cl – O bond order)
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 20
INORGANIC CHEMISTRY
BOND ENERGY
25. The correct order of bond dissociation energy will be ?
(A) H–H > Cl – Cl > Br – Br (B) Si – Si > P – P > Cl – Cl
(C) C – C > N – N > O – O (D) F – F > Cl – Cl > Br – Br
VSEPR THEORY
26. There are three elements X, Y and Z which belong to the p-block of periodic table they all form
trifluorides with F2, such that 'XF3 ' is lewis acid but 'YF3' is weak Lewis base (dipole
moment = 0.23D). These two compounds react with each other in presence of F2 to produce
YF4+XF4–. The compound ZF3 is a T-shape interhalogen molecule. Which of the following
is/are correct statements with reference to above information ?
F
Z F
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F
(A) All the Z–F bond lengths are equal in ZF3 molecules
(B) In the structure the angle 180º
(C) The Y and X both are sp3 hybridised in YF4+ XF4–
(D) The elements X, Y, Z can be B, N and Cl respectively
27. In which of the following species all bond lengths are not identical ?
(A) ClF6 (B) SeF4 (C) SO4–2 (D) IF3
28. Which of the following molecule(s) is/are planar
(A) BF3 (B) H2O (C) ICl2– (D) ClF3
STRUCTURES
29. Which of the following statements is/are true for P4O6 molecule -
(A) It contains six P-O bonds and three P-P-bonds
(B) It contains six P-O-P linkage and 16 lone pairs
(C) It has all atoms sp3–hybridised
(D) It has planar structure
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 21
INORGANIC CHEMISTRY
30. Select the CORRECT statement about C3N3(N3)3 (cyanuric triazide) :
(A) Total number of sp2 hybridized atom in the molecule is 12
(B) Total number of bond present in molecule is 15
(C) Total number of bond present in molecule is 9
(D) Total number of lone pair present in molecule is 12
31. Find the correct statement about croconate ion C5O5–2
(A) It is cyclic compound
(B) It is in particular aromatic and symmetric as the double bond and the negative charge
become delocalized over the five CO units
(C) C5O5–2 has four bonds
(D) C5O5–2 has three bonds in rings.
OXY ACID
32. Select the INCORRECT statement(s) about the structure of H2S2O3.
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(A) Two 2p– 3dbonds present in the structure.
(B) Hybridization of each 'S' atom is sp3
(C) Oxidation states of 'S' are + 6 & –2
(D) Total number of lone pair present in molecule is 8.
33. Which of the following oxy acid have per-oxy linkage :-
(A) H2S2O8 (B) H3PO5 (C) HNO3 (D) H2S2O3
DIPOLE MOMENT
34. Which of the following statement (s) is/are true about lone pair moments ?
(A) sp > sp2 > sp3 : Order of lone pair moment
(B) The unshared pairs residing in pure s or p orbitals do not contribute to the resultant
molecular polarity
(C) The unshared pair residing in hybrid orbitals contributes to the resultant molecular polarity
(D) The lone pair moments acts in the opposite directions in which it is projected.
35. Correct Statement among following ?
(A) Dipole moment order BF3 = CCl4 = PCl5 = SF6
(B) dipole moment of CHCl3 > CHF3
(C) μexperimental is less than μtheoritical for CO molecule
(D) If a AX4 type molecule has μ = 0 then it can have either tetrahedral or octahedral electron
geometry (A = central atom, X = side atom)
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 22
INORGANIC CHEMISTRY
HYDROGEN BONDING
36. Choose the INCORRECT order(s) of boiling point .
(A) NH3 > SbH3 > AsH3 > PH3 (B) H2O > TeH2 > SeH2 > SH2
(C) HF > HI > HBr > HCl (D) CH4 > SnH4 > GeH4 > SiH4
37. Which of the following statement(s) is/are not correct ?
(A) Density of water increases from 0ºC to 4ºC then further increases on increasing the
temperature
(B) Solid boric acid has 2-D sheet like structure due to intermolecular hydrogen bonding
(C) Urea has high boiling point due to intramolecular hydrogen bonding.
(D) HCl2– ion exists with Cs+.
38. Hydrogen bonding is responsible for ?
(A) Lower volatility of HF than that of HCl.
(B) More viscosity of glycerol than glycol.
(C) Stability of chloral hydrate
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(D) High boiling point of SbH3 than that of NH3
39. Which of the following contain H-Bonding ?
(A) K2HPO4 (B) K2HPO3
(C) Chloral hydrate (D) O-nitro phenol
MISCELLANEOUS
40. Choose the CORRECT statement about given molecule : -
F H
C1 = C2 = C3 = C4 = C5
F H
F
If C1 lies in xz plane then
F
(A) Nodal plane of -bond between C1 – C2 lies in xz plane.
(B) Nodal plane of -bond between C3 – C4 lies in xz plane.
H
(C) C5 part lies in yz plane
H
(D) Maximum number of atom in plane is 7
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 23
INORGANIC CHEMISTRY
EXERCISE # 3
INTEGER
1. Find total number of orbitals in which electron density is observed along any of the axis
(x, y or z).
px, py, pz, dxy, dxz, dyz, d z ,d x 2 2
y2
2. Total number of molecules which follow octet rule among the given molecules are:
AlBr3 , BeCl2 , MgF2 , SF4 , NO2 , NO, CO, LiF, SO2Cl2 , XeF2 , PH3,
3. The number of set of orbitals given below forming -bonds are ?
Orbitals Inter Nuclear Axis
(1) px + py – x
(2) pz + pz – y
(3) dxy + dxy – z
(4) dyz + dyz – z
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(5) dyz + pz – z
(6) dxz + pz – x
(7) d x 2
y2
+ py – x
4. Number of orbitals which can form bond with px orbital on y -axis :
dz2 , dxy, px, pz, s, d x 2 y2 , dxz
5. Atomicity of O,S,P and He are p, q, r & s respectively : Calculate the value of p + q + r + s ?
[Write your answer as sum of digits till you get the single digit answer]
6. How many sets of given orbitals can from bond ?
(z - axis is internuclear axis)
px + py , py + py , pz + px , pz + pz , d x 2
y2
+ dz pz + dxy , pz + dxz , pz + dyz, dxz + dyz, dyz +
2
dyz, dxy + dxy , dxy + d x 2
y2
.
7. Find the number of molecules having sp3d hybridisation
I3–, SF4, BeCl2, XeF4,
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 24
INORGANIC CHEMISTRY
8. Find out the number of species which have at least one atom is sp3d hybridised among the
following :-
O3 , O2F2 , I3– , I(CN)2– , PF3Cl2 , XeF6 , IOF5 , XeF5+
9. The number of planes of symmetry in SbF5 is -
10. Find the number of p–d bonds present in P4S10
11. Total number of angle(s) in SeCl4 which are less than 90º
12. Number of molecules having all bond angles equal are ?
CH2F2, BHF2, NF3, XeF5–
13. Total number of identical bond angle in CF2Cl2 is -
14. How many of the following are planar molecules/ions
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XeO2F2 , IF5 , XeO4 , BrF3 , I(CN)2–
15. Total number of molecules which contain any F– X̂ –F bond angle which is less than 90º ?
(X = Central atom)
IF7 , BrF3 , PF5 , SF4 , XeOF4 , SF6
16. How many planes are present in PCl3F2 molecule which contains maximum number of atoms ?
17. Number of non-polar molecule among the following is x and number of planar molecule is y.
calculate the value of x + y.
BF3 , CO2 , SO2 , PCl5 , ClF3 , NH3 , CH4
18. Number of atomic orbitals involve in hybridisation of anion part of Cl2O6 (s) is -
19. In tetrathionic acid number of p – p bonds is :
20. In the structure of P4S10 molecule, total number of sp3 Hybridised atoms = x, total number of
p – d bonds = y, total number of bridging sulphar = z, calculate the value of x + y + z.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 25
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21. Total number of species among the following in which X–O–X linkage is present [X=P, S]
H2S2O6, H2SO5 , H2S2O7 , H2S2O8 , P4O10 , S4O62– , S2O62– , P4O6
22. The number of water molecules(s) directly bonded to the metal centre in CuSO4 5H2O. is –
23. Observe the following statements about the structure of molecule F3SSF
(a) Total number of lone, pairs present in molecule is x
(b) Number of S –S bond present is y
Calculate the value of ' x + y' ?
[Write your answer as sum of digits till you get the single digit answer]
24. The sum of oxidation states of all P atoms in the following compound of phosphorus is-
P4, PH3, H3PO2, P2O5
25. How many of the following contains peroxy linkage in their structures :
S2O6–2, S2O8–2, SO5–2, CrO3
26. Find the number of lone pair in N3S3Cl3.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.
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27. Find the correct statements about [NPCl2]3 (phosphazene).
(i) Resonance structure can be drawn analogous to those for benzene indicating aromaticity in
the rings.
(ii) The dxz orbital of the phosphorous atom overlaps with the pz orbitals of nitrogen atoms
adjacent to it (if x is inter nucleuar axis).
(iii) PNCl2 monomer is analogous to RCN.
(iv) / ratio is 3 in [NPCl2]3.
28. In tetrathionic acid number of p – p bonds is :
29. In (HF)4 the number of H bonds is ………
30. Total number of molecules which can have intermolecular hydrogen bonding ?
CH3Cl , C2H2, C2H5OH , HCl , H3PO4 , SiH4 , metafluorophenol, orthochlorophenol.
31. Find the number of H bond form by one boric acid in solid state
32. Find the number of hexogonal rings in C60 fullerene.
Fill your answer as sum of digits till you get the single digit answer.
33. Number of following species which are planar & polar ?
XeF4 , H2O2 , H2O , C2H4, ClF3 , SO2 , XeO3
34. Find the number of chemical species(s) which are planar and nonpolar in the following :-
NO2–, O2F2 , XeF5+ , HCN , XeF5– , B3N3H6
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 26
INORGANIC CHEMISTRY
EXERCISE # 4
Paragraph for question no. 1 to 2
According to Lewis Longmuir concept atoms combine to complete their respective octet.
1. The species following the octet rule is
(A) ICl3 (B) SbCl3 (C) BeCl2 (D) AlCl3
2. From the species given below which one is hypervalent ?
(A) AlF3 (B) SF4 (C) OCl2 (D) NF3
Paragraph for question nos. 3 to 4
The formation of BH3 CH4 & NH3 like compounds cannot be explained by V.B.T. For example
the all equal bond lengths of CH4 molecule & also the bond angles (109º28‘) cannot be
explained. Hence a new phenomenon is introduced to explain the above observation, which is
known as hybridisation. Hybridisation can be defined as the mixing of pure atomic orbitals of
comparable energy.
3. Select the correct statement ?
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(A) Hybridisation takes place in all covalent as well as ionic compounds.
(B) Intermixing of different shells takes place in hybridisation
(C) Hybrid orbitals are more directional than the pure atomic orbitals.
(D) If % p character increases in hybrid orbital, it becomes bulkier & shorter.
4. Which of the following orbital may involve in hybridisation in PCl5 ?
(A) dxz (B) dyz (C) d z2 (D) d
x2 –y2
Paragraph for question no. 5 to 6
Valence Bond Theory explains the formation of covalent bond such as two filled atomic
orbitals having e– with opposite spin combine axially or collaterally to from and bond
respectively.
5. Which of the following orbital cannot form bond with dxy orbital .
(A) s (B) px (C) d (D) All of these
x2 –y2
6. Which of the following statement is correct ?
(A) s -orbital always forms bond with p orbital
(B) s-orbital is more directional than p-orbital
(C) p-orbital always form -bond
(D) a covalent bond is directional in nature.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 27
INORGANIC CHEMISTRY
Paragraph for question no. 7 to 9
IF7 is a molecule in which I atom is in the maximum oxidation state, and the hybridization for I
atom is sp3d3.
7. adjacent angles (90º+72º) in IF7 molecule is
The number of FIF
(A) 10 (B) 15 (C) 20 (D) 14
8. angles less than 90º and equal to 90º are respectively
The number of FIF
(A) 5 and 5 (B) 10 and 5 (C) 5 and 10 (D) 10 and 15
9. The number of I – F bonds having the longest and shortest lengths are respectively
(A) 5 and 2 (B) 2 and 5 (C) 5 and 5 (D) 2 and 2
Paragraph for question no. 10 to 11
hydridisation helps to determine the shape of a molecule but shape of a molecule is mainly
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define by VSEPR theory According to this theory l.p-l.p > l.p – b.p > b.p – b.p
10. In which of the following pairs hybridisation of the central atom is not same?
(A) ClF3, ClF3O, (B) ClF3O, ClF3O2
–
+
(C) [ClF2O] [ClF4O] (D) [ClF4O]– [XeOF4]
11. More correct structure of ClF3 is :
F
F
Cl
(A) Cl (B) F
F F F
F
(C) Cl (D) All of the above
F F
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 28
INORGANIC CHEMISTRY
Paragraph for question no. 12 to 13
Valence shell electron pair repulsion theory (VSEPR) can be used to predict the approximate
shape of a molecule. Electrons in bonds and in lone pairs can be thought of as ―charge cloud‖
that repel one another and stay as far apart possible, thus causing molecules to assume specific
shapes.
The repulsive interactions of electron pairs decrease in the order :
Lone pair-lone pair > Lone pair - bond pair > Bond pair-bond pair.
These repulsions result in deviations from idealized shapes and alteration in bond angles in
molecules.
12. Molecular shape of XeF3+, SF3+ and CF3+ are :
(A) the same with 2, 1 and 0 lone pairs of electrons, respectively
(B) different with 2, 1 and 0 lone pairs of electrons, respectively
(C) different with 0, 1 and 2 lone pairs of electrons, respectively
(D) the same with 2, 0 and 1 lone pairs of electrons, respectively
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13. Which of the following statements is incorrect ?
(A) In H2O, the bond angle is less than OF2
(B) In ClF3, the axial Cl–F bond length is larger than equatorial Cl–F bond length.
(C) In SF4, F–S–F equatorial bond angle is not equal to 120º due to lone pair-bond pair
repulsions.
(D) In ICl4–, bond angles is 90º
Paragraph for Question 14 to 15
According to the VSEPR theory of molecular geometry in chemistry, which is based on the
general principle of maximizing the distances between points, a square antiprism is the favored
geometry when eight pairs of electrons surround a central atom. Square antiprism, in which the
eight atoms occupy the eight vertices of the antiprism, and the eight triangle edges of the
antiprism correspond to single covalent bonds.
14. Which of the following molecules have square anti prismatic structure
(A) XeF8–2 (B) PaF8–3 (C) S8 (D) XeF6
15. In molecule nitrosonium octa fluro xenate (VI) central atom Xe has
(A) fsp3d (B) d4sp3 (C) sp3d3 (D) no hybridisation
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 29
INORGANIC CHEMISTRY
Paragraph for question no. 16 to 17
Various oxy acids of non metals are found in nature. Some derivatives of oxy acids can also be derived
from the parent oxy acid.
Derivatives of oxy acid can be derived by removing H2O molecule from the parent oxy acids such as :
2 moles of oxy acid — H2O = pyro acid.
1 mole of oxy acid — H2O = meta acid.
16. Parent oxy acid of H4P2O5 acid is ?
(A) phosphorous acid (B) ortho phosphoric acid
(C) pyro phosphorous acid (D) hypophosphorous acid
17. Which of the following is not a hypo acid ?
(A) H2N2O2 (B) HOCl (C) H2S2O7 (D) H4P2O6
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Paragraph for Question 18 to 19
Various derivatives of oxy acids can be derived from the parent oxy acids for example pyro acids and
meta acids can be derived from various parent oxy acid by removing a water molecule, from two moles
of oxy acid (for pyro acid) and from one mole of oxy acid (for meta acid) respectively.
18. For which of the following oxy acid meta acid is not possible :
(A) H2S2O8 (B) H2S2O6 (C) H3PO4 (D) H2SO3
19. For A is any parent acid observe the following reaction :
H2O
A B
Which of the following statement is INCORRECT ?
(A) If A is H3PO4 then there are four P–O–P linkage present in the cyclic trimer of B.
(B) If A is H2SO4 then there are 6 shorter S–O bond lengths are present in cyclic trimer of B.
(C) If A is HNO3 then meta form of A does not exist.
(D) If A is HNO2 then on removing one mole of water from A will give a mixed anhydride.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 30
INORGANIC CHEMISTRY
Paragraph for Question 20 to 21
Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge
separation q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to
10–18 esu cm.
Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a
molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds
alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the
geometry of a molecule. Dipole moment values can be used to distinguish between cis-and trans-
isomers, orhto-, meta-and para-forms of a substance, etc.
20. Arrange the following in increasing order of their polarity.
(I) Ortho chloro Toluene (II) Meta chloro Toluene (III) Para chloro Toluene
(A) III > II > I (B) II < I > III (C) III > I > II (D) I < II < III
21. Correct Statement among following ?
(A) Dipole moment order BF3 = CCl4 = PCl5 = SF6
(B) dipole moment of CHCl3 > CHF3
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(C) μexperimental is less than μtheoritical for CO molecule
(D) If a AX4 type molecule has μ = 0 then it can have either tetrahedral or octahedral electron
geometry (A = central atom, X = side atom)
Paragraph for Question 22 to 24
The attractive force that binds hydrogen atom of one molecule with electronegative atom of the
other molecule of the same or different substance is known as hydrogen bond.
22. Which of the following chemical species having inter molecular hydrogen bonding.
(A) Ortho boric acid (B) Ortho nitrophenol
(C) Ortho hydroxybenzaldehyde (D) Ortho chlorophenol
23. Which of the following boiling point order is INCORRECT.
(A) H3BO3 > B(OMe)3 (B) C2H5OH > CH3OCH3
(C) HF > HCl (D) NH3 > SbH3
24. Which of the following molecule will form Hydrogen-bond with water ?
(A) Chloral hydrate (B) C6H5OH (C) NH3 (D) C2H5OH
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 31
INORGANIC CHEMISTRY
Paragraph for question no. 25 to 26
A hydrogen bond is an electrostatic attraction between two polar groups that occurs when a
hydrogen atom covalently bound to a highly electronegative atom.
25. Correct order of boiling point is -
(A) H2O > NH3 > HF (B) HF > NH3 > H2O
(C) HF > H2O > NH3 (D) H2O > HF > NH3
26. In which of the following compound H-bond is not present ?
(A) KH2PO3 (B) K2HPO3 (C) KH2PO4 (D) K2HPO4
Paragraph for question no. 27 to 28
In an oxy acid the acidic hydrogen is connected to the oxygen atom covalently. And generally
the oxygen is covalently bonded to a non-metal. And in Hydra acid Hydrogen is covalently
bonded to a more electronegative atom (Eg.: halogen) except oxygen.
27. Which of the following has higher boiling point
(A) HF (B) HI (C) HCl (D) HBr
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28. Which of the following compound(s) doesn't have hydrogen bond
(A) K3PO4 (B) K2HPO4 (C) KH2PO4 (D) H3PO4
Paragraph for question no. 29 to 30
Hydrogen bonding originates from the dipole-dipole interaction between H-atom and any of the
other atom like F, O, N and in some cases with Cl atom. There are two types of H-bonding like
intermolecular and intramolecular H-bonding.
29. Which of the following molecule consist of intramolecular H-bonding.
(A) HF (B) Ice (C) Boric acid (D) Chloral hydrate
30. Which of following statement is incorrect
(A) Boiling point of H2O2 is greater than that of H2O
(B) Ortho-nitrophenol has less boiling point than para-nitrophenol.
(C) In ice each ‗O‘ atom is tetrahedrally bonded by four H-atoms which are all equidistant.
CH2–OH
CH2–OH
(D) (Ethylene glycol) is less viscous than CH2–OH (Glycerol)
CH2–OH
CH2–OH
31. Which of the following is correct order for extent of Hydrogen Bonding
(A) NH3 > H2O2 > H2O > HF (B) H2O > HF > NH3 > H2O2
(C) H2O2 > H2O > HF (D) H2O2 > NH3 > H2O > HF
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 32
INORGANIC CHEMISTRY
EXERCISE # 5
MATRIX MATCH
1. Column–I Column–II
(Sum of lone pair + Bond pair + bond)
(A) N3– (P) 11
–
(B) NO3 (Q) 10
–
(C) I3 (R) 7
(D) CO (S) 13
2. Column–I Column–II
(A) XeO3 (P) Pyramidal geometry
(B) XeO2F4 (Q) Non–planar molecule
(C) XeO2F2 (R) d orbital is involved in hybridization
z2
of central atom
3. Column–I Column–II
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–
(A) NH2 (P) Square pyramidal
(B) XeOF2 (Q) V–shaped
(C) ICI4– (R) T–shaped
2–
(D) [SbF5] (S) Square planner
4. Match the compounds with their properties.
Column–I Column–II
(A) BCl3 (P) All atoms are central atom.
(B) SiF4 (Q) It has only –bond.
(C) SiC (R) It is non–planar.
5. List–I List–II
(Oxy Acid) (Basicity)
(P) H3BO3 (1) Tetrabasic
(Q) H3PO3 (2) Tribasic
(R) H4SiO4 (3) Dibasic
(S) H3PO4 (4) Monobasic
Code:
P Q R S P Q R S
(A) 1 2 3 4 (B) 4 3 2 1
(C) 4 3 1 2 (D) 1 2 4 3
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 33
INORGANIC CHEMISTRY
6. List-I List-II
(P) HF (1) 2-D sheet like structure
(Q) H3BO3 (2) inter molecular H-bonding
(R) H3PO4 (3) Zig-zag chain like
(S) chloral hydrate (4) 5 membered chelate ring found in structure
Code:
P Q R S P Q R S
(A) 1 2 3 4 (B) 3 1 2 4
(C) 4 3 2 1 (D) 1 3 2 4
7. Match the following list :–
List-I (Molecules) List-II (Molecular properties)
(P) SF4 (1) Planar and polar
(Q) H2O (2) Non–planar and polar
(R) SF6 (3) Planar and non–polar
(S) CO2 (4) Non–planar and non–polar
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Code:
P Q R S P Q R S
(A) 1 2 3 4 (B) 2 1 4 3
(C) 2 3 4 1 (D) 3 2 1 4
8. Column–I Column–II
(A) H2S2O6 (P) Basicity = 3
(B) H2S2O3 (Q) X–X single bond is present
(where x is a central atom)
(C) B3N3H6 (R) Aromatic nature present in its structure
(D) Trimeta phosphoric acid (S) Weakest p–d bond present in structure
among the given molecules
9. Column–I Column–II
(Pair of species) (Identical property in pairs of species)
(A) PCI3F2, PCI2F3 (P) Hybridisation of central atom
(B) BF3 and BCI3 (Q) Shape of molecule / ion
(C) CO2 and NO2+ (R) net (dipole moment)
(D) C6H6 and B3N3H6 (S) Total number of electrons
(T) All bond length are equal within molecule
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 34
INORGANIC CHEMISTRY
EXERCISE – 6 # JEE–MAIN
1. Which of the following statements is true ? [AIEEE-2002]
(1) HF is less polar than HBr
(2) Water does not contain any ions
(3) Chemical bond formation takes place when forces of attraction overcome the forces of
repulsion
(4) In covalent bond, transfer of electrons takes place
2. Which one of the following pairs of molecules will have permanent dipole moments for both
members [AIEEE-2003]
(1) NO2 and CO2 (2) NO2 and O3
(3) SiF4 and CO2 (4) SiF4 and NO2
3. The pair of species having identical shapes for molecules of both species is [AIEEE-2003]
(1) XeF2, CO2 (2) BF3, PCl3 (3) PF5, IF5 (4) CF4, SF4
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4. The correct order of bond angles (smallest first) in H2S, NH3, BF3 and SiH4 is : [AIEEE–2004]
(1) H2S < NH3 < SiH4 < BF3 (2) NH3 < H2S < SiH4 < BF3
(3) H2S < SiH4 < NH3 < BF3 (4) H2S < NH3 < BF3 < SiH4
5. Lattice energy of an ionic compound depends upon [AIEEE-2005]
(1) charge on the ion only (2) size of the ion only
(3) packing of the ion only (4) charge and size of the ion
6. Of the following sets which one does not contain isoelectronic species ? [AIEEE-2005]
(1) PO4 , SO42–, ClO4–
3– –
(2) CN , N2, C2 2–
(3) SO32–, CO32–, NO3– (4) BO33–, CO32–, NO3–
7. In which of the following molecules/ions are all the bonds not equal? [AIEEE-2006]
(1) XeF4 (2) BF4– (3) SF4 (4) SiF4
8. Which of the following hydrogen bonds is the strongest [AIEEE-2007]
(1) F–H.....F (2) O–H.....O (3) O–H.....F (4) O–H.....N
9. The hybridisation of orbitals of N atom in NO3–, NO2+ and NH4+ are respectively:-
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 35
INORGANIC CHEMISTRY
[AIEEE-2011]
3 2 2 3 2 3
(1) sp, sp , sp (2) sp , sp , sp (3) sp, sp , sp (4) sp , sp, sp3
2
10. The structure of IF7 is :- [AIEEE-2011]
(1) octahedral (2) pentagonal bipyramid
(3) square pyramid (4) trigonal bipyramid
11. Which of the following has maximum number of lone pairs associated with Xe [AIEEE-2011]
(1) XeO3 (2) XeF4 (3) XeF6 (4) XeF2
12. The molecule having smallest bond angle is :- [AIEEE-2012]
(1) PCl3 (2) NCl3 (3) AsCl3 (4) SbCl3
13. In which of the following pairs the two species are not isostructural ? [AIEEE-2012]
3–
(1) AlF6 and SF6 (2) CO3 and 2–
NO3– +
(3) PCl4 and SiCl4 +
(4) PF5 and BrF5
14. The number of S–S bonds in SO3, S2O32–, S2O62– and S2O82– respectively are :-
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[JEE-MAINS-2012]
(1) 1, 0, 1, 0 (2) 0, 1, 1, 0 (3) 1, 0, 0, 1 (4) 0, 1, 0, 1 (On line)
15. Among the following species which two have trigonal bipyramidal shape ?
[JEE-MAINS-2012]
–
(I) NI3 (II) I3 (III) SO3 2–
(IV) NO3– (On line)
(1) II and III (2) III and IV (3) I and IV (4) I and III
16. Which of the following has the square planar structure :- [JEE-MAINS-2012]
(1) NH4 +
(2) CCl4 (3) XeF4 (4) BF4– (On line)
17. The compound of Xenon with zero dipole moment is :- [JEE-MAINS-2012]
(1) XeO3 (2) XeO2 (3) XeF4 (4) XeOF4 (On line)
18. Among the following the molecule with the lowest dipole moment is :- [JEE-MAINS-2012]
(1) CHCl3 (2) CH2Cl2 (3) CCl4 (4) CH3Cl (On line)
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 36
INORGANIC CHEMISTRY
19. The formation of molecular complex BF3 – NH3 results in a change in hybridisation of boron :–
[JEE-MAINS-2012]
3 3 2 2
(1) from sp to sp d (2) from sp to dsp (On line)
(3) from sp3 to sp2 (4) from sp2 to sp3
20. Trigonal bipyramidal geometry is shown by: [JEE-MAINS-2013]
(1) XeO3F2 (2) XeOF2 (3) XeO3 (4) FXeOSO2F (On line)
21. Which one of the following molecules is polar? [JEE-MAINS-2013]
(1) CF4 (2) SbF5 (3) IF5 (4) XeF4 (On line)
22. Oxidation state of sulphur in anions SO32– S2O42– and S2O62– increases in the orders :
[JEE-MAINS-2013]
(1) S2O62–< S2O42– < SO32– 2– 2–
(2) SO3 < S2O4 < S2O6 2–
(On line)
(3) S2O42– < SO32– < S2O62– (4) S2O42– < S2O62– < SO32–
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23. XeO4 molecule is tetrahedral having : [JEE-MAINS-2013]
(1) Two pp-dp bonds (2) Four pp-dp bonds (On line)
(3) One pp-dp bond (4) Three pp-dp bonds
24. Bond distance in HF is 9.17 × 10–11 m. Dipole moment of HF is 6.104 × 10–30 Cm. The percent
ionic character in HF will be : (electron charge = 1.60 × 10–19 C) [JEE-MAINS-2013]
(1) 61.0% (2) 38.0% (3) 35.5% (4) 41.5% (On line)
25. The shape of IF6– is : [JEE-MAINS-2013]
(1) distorted octahedron (2) Pyramidal (On line)
(3) Octahedral (4) Square antiprism
26. Which has trigonal bipyramidal shape ? [JEE-MAINS-2013]
(1) XeOF4 (2) XeO3 (3) XeO3F2 (4) XeOF2 (On line)
27. The catenation tendency of C, Si and Ge is in the order Ge < Si < C. The bond energies
(in kJ mol–1) of C — C, Si —Si and Ge—Ge bonds are respectively :
[JEE-MAINS-2013 (On line)]
(1) 348, 260, 297 (2) 348, 297, 260 (3) 297, 348, 260 (4) 260, 297, 348
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 37
INORGANIC CHEMISTRY
28. In which of the following sets, all the given species are isostructural ?
[JEE-MAINS-2013 (On line)]
(1) BF3, NF3, PF3, AlF3 (2) PCl3, AlCl3, BCl3, SbCl3
(3) BF4¯, CCl4, NH4+, PCl4+ (4) CO2, NO2, ClO2, SiO2
29. For which of the following molecule significant μ 0 [JEE-M-2014]
Cl CN OH SH
(1) (2) (3) (4)
Cl CN OH SH
(1) Only (3) (2) (3) and (4) (3) Only (1) (4) (1) and (2)
30. Among the following oxoacids, the correct decreasing order of acid strength is :-
[JEE-M-2014]
(1) HClO4 > HClO3 > HClO2 > HOCl
(2) HClO2 > HClO4 > HClO3 > HOCl
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(3) HOCl > HClO2 > HClO3 > HClO4
(4) HClO4 > HOCl > HClO2 > HClO3
31. The number and type of bonds in C22– ion in CaC2 are:
[AIEEE-2005, AIEEE-2011, JEE-MAINS-2014 (On line)]
(1) Two bonds and one – bond
(2) Two bonds and two – bonds
(3) One bond and two – bonds
(4) One bond and one – bond
32. For the compounds [JEE-MAINS-2014]
CH3Cl, CH3Br, CH3I and CH3F, (On line)
the correct order of increasing C-halogen bond length is :
(1) CH3F < CH3Br < CH3Cl < CH3I
(2) CH3F < CH3Cl < CH3Br < CH3I
(3) CH3Cl < CH3Br < CH3F < CH3I
(4) CH3F < CH3I < CH3Br < CH3Cl
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 38
INORGANIC CHEMISTRY
33. Shapes of certain interhalogen compounds are stated below. Which one of them is not correctly
stated? [JEE-MAINS-2014]
(1) IF7 : Pentagonal bipyramid (2) BrF5 : Trigonal bipyramid (On line)
(3) ICl3 : Planar dimeric (4) BrF3 : Planar T-shaped
34. Which of the following molecules has two sigma() and two pi() bonds :-
[JEE-MAINS-2014]
(1) HCN (2) C2H2Cl2 (3) N2F2 (4) C2H4 (On line)
35. The species in which the N atom is in a state of sp hybridization is
[JEE-MAINS(offline)-2016]
–
(1) NO2 (2) NO2 +
(3) NO2 (4) NO3–
36. The pair in which phosphorous atoms have a formal oxidation state of + 3 is :-
(1) Pyrophosphorous and pyrophosphoric acids [JEE-MAINS(offline)-2016]
(2) Orthophosphorous and pyrophosphorous acids
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(3) Pyrophosphorous and hypophosphoric acids
(4) Orthophosphorous and hypophosphoric acids
37. The group of molecules having identical shape is : [JEE-MAINS(online)-2016]
(1) SF4, XeF4, CCl4 (2) ClF3, XeOF2, XeF3+
(3) PCl5, IF5, XeO2F2 (4) BF3, PCl3, XeO3
38. Assertion : Among the carbon allotropes, diamond is an insulator, whereas, graphite is a good
conductor of electricity. [JEE-MAINS(online)-2016]
Reason : Hybridization of carbon in diamond and graphite are sp3 and sp2, respectively.
(1) Assertion is incorrect statement, but the reason is correct.
(2) Both assertion and reason are correct, and the reason is the correct explanation for the
assertion.
(3) Both assertion and reason are incorrect.
(4) Both assertion and reson are correct, but the reason is not the correct explanation for the
assertion.
39. Aqueous solution of which salt will not contain ions with the electronic configuration
1s22s22p63s23p6 ? [JEE-MAINS(online)-2016]
(1) NaCl (2) CaI2 (3) KBr (4) NaF
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 39
INORGANIC CHEMISTRY
40. In the following reactions, ZnO is respectively acting as a/an: [JEE-MAINS(offline)-2017]
(a) ZnO + Na2O Na2ZnO2 (b) ZnO + CO2 ZnCO3
(1) base and base (2) acid and acid (3) acid and base (4) base and acid
41. sp3d2 hybridization is not displayed by : [JEE-MAINS(online)-2017]
(1) SF6 (2) BrF5 (3) PF5 (4) [CrF6]3–
42. The number of S = O and S–OH bonds present in peroxodisulphuric acid and pyrosulphuric
acid respectively are :
(1) (2 and 4) and (2 and 4) (2) (4 and 2) and (4 and 2)
(3) (4 and 2) and (2 and 4) (4) (2 and 2) and (2 and 2)
43. The group having triangular planar structure is : [JEE-MAINS(online)-2017]
2– 2– –
(1) BF3, NF3, CO3 (2) CO3 , NO3 , SO3
2–
(3) NH3, SO3, CO3 (4) NCl3, BCl3, SO3
44. The number of P–OH bonds and the oxidation state of phosphorus atom in pyrophosphoric acid
(H4P2O7) respectively are : [JEE-MAINS(online)-2017]
(1) five and four (2) four and five (3) five and five (4) four and four
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45. The correct sequence of decreasing number of -bonds in the structure of H2SO3, H2SO4 and
H2S2O7 is : [JEE-MAINS(online)-2017]
(1) H2S2O7 > H2SO3 > H2SO4 (2) H2S2O7 > H2SO4 > H2SO3
(3) H2SO4 > H2S2O7 > H2SO3 (4) H2SO3 > H2SO4 > H2S2O7
46. The decreasing order of bond angles in BF3, NH3, PF3 and I3– is :- [JEE-MAINS-2018]
(1) I3– > BF3 > NH3 > PF3 (2) BF3 > NH3 > PF3 > I3–
(3) I3– >NH3 > PF3 > BF3 (4) BF3 > I3– > PF3 > NH3
(I) (II)
47. H N N N
In hydrogen azide (above) the bond orders of bonds (I) and (II) are :- [JEE-MAINS-2018]
(I) (II) (I) (II)
(1) >2 <2 (2) <2 <2
(3) <2 >2 (4) >2 >2
48. Identify the pair in which the geometry of the species is T-shape and square-pyramidal,
respectively :- [JEE-MAINS-2018]
– – –
(1) IO3 and IO2F2 (2) XeOF2 and XeOF4 (3) ICl2 and ICl5 (4) ClF3 and IO4–
49. The type of hybridisation and number of lone pair(s) of electrons of Xe in XeOF4 respectively,
are: [JEE-MAINS-2019]
(1) sp3d and 2 (2) sp3d2 and 2 (3) sp3d and 1 (4) sp3d2 and 1
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 40
INORGANIC CHEMISTRY
EXERCISE – 7 # JEE–ADVANCED
Integer Type
1. The number of water molecule(s) directly bonded to the metal centre in CuSO4.5H2O is
[JEE 2009]
2. Based on VSEPR theory, the number of 90 degree F–Br–F angles in BrF5 is [JEE 2010]
3. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is.
[JEE 2011]
4. The total number of lone-pairs of electrons in melamine is [JEE Adv. 2013]
One or more than one correct
5. The linear structure is assumed by : [IIT1991]
(A) SnCl4 (B) NCO¯ (C) CS2 (D) NO 2
6. Which of the following has zero dipole moment? [IIT1993]
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(A) CIF (B) PCl3 (C) SiF4 (D) CFCl3
7. Among the following molecules, which one is planar? [IIT1994]
(A) BCl3 (B) SO2Cl2 (C) NH3 (D) NF3
8. Which of the following species is / are non-linear? [IIT1995]
(A) H2S (B) NH3 (C) CO2 (D) SO2
9. Which contains both polar and non-polar bonds? [IIT1997]
(A) CH4 (B) HCN (C) H2O2 (D) NH4Cl
10. Which of the following compounds has sp2 hybridisation? [IIT1997]
(A) CO2 (B) SO2 (C) N2O (D) CO
11. Which one of the following molecules is planar? [IIT1996]
(A) NF3 (B) NCl3 (C) BF3 (D) PH3
12. The number and type of bonds between two carbon atoms in CaC2 are: [IIT1996]
(A) 1 and 1 (B) 1 and 2 (C) 1 and 1.5 (D) 1
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 41
INORGANIC CHEMISTRY
– +
13. Among the species NF3 , NO3 , BF3 , H3O and HN3 , identify the isostructural species :
[IIT1996]
– + –
(A) (NF3 , NO3 ) and (BF3 , H3O ) (B) (NF3 , HN3) and (NO3 , BF3)
+ –
(C) (NF3 , H3O ) and (NO3 , BF3) (D) (NF3 , H3O+) and (HN3 , BF3)
14. Among the following the one that is polar and has the central atom with sp2 hybridisation is :
[IIT1997]
(A) H2CO3 (B) SiF4 (C) BF3 (D) HClO2
15. The geometry & the type of hybrid orbitals present about the central atom in BF3 is :
[JEE98]
2
(A) linear, sp (B) trigonal planar, sp
3
(C) tetrahedral sp (D) pyramidal, sp3
16. Which one of the following statement (s) is (are) correct? [JEE1998]
5 1
(A) The electronic configuration of Cr is [Ar] 3d 4s . (Atomic No. of Cr = 24)
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(B) The magnetic quantum number may have a negative value
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type.
( Atomic No. of Ag = 47)
(D) The oxidation state of nitrogen in HN3 is –3.
17. Element X is strongly electronegative and element Y is strongly electropositive. Both are
univalent. The compound formed would be : [JEE1998]
(A) X Y (B) Y+X– (C) X+ Y– (D) Y X
18. The correct order of increasing C - O bond length of, CO, CO32–, CO2 is :- [JEE '99]
(A) CO32– < CO2 < CO (B) CO2 < CO32– < CO
(C) CO < CO32– < CO2 (D) CO < CO2 < CO32–
19. The geometry of H2S and its dipole moment are [JEE '99]
(A) angular & non zero (B) angular & zero
(C) linear & non zero (D) linear & zero
20. In compounds type ECl3, where E = B, P, As or Bi, the angles Cl–E–Cl for different E are in
the order [JEE '99]
(A) B > P = As = Bi (B) B > P > As > Bi
(C) B < P = As = Bi (D) B < P < As < Bi
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 42
INORGANIC CHEMISTRY
21. The most likely representation of resonance structure of p–nitrophenoxide is :
– O – O –
O O O O O O
N+ N N+ N
(1) (2) (3) (4)
O– O O– O–
22. Amongst H2O, H2S , H2Se and H2Te, the one with the highest boiling point is [JEE 2000]
(A) H2O because of hydrogen bonding
(B) H2Te because of higher molecular weight
(C) H2S because of hydrogen bonding
(D) H2Se because of lower molecular weight
23. The hybridization of atomic orbitals of nitrogen in NO2 , NO3 and NH4 are [JEE 2000]
2 3 2 2 3
(A) sp , sp and sp respectively (B) sp, sp and sp respectively
(C) sp2, sp and sp3 respectively (D) sp2, sp3 and sp respectively
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24. The correct order of hybridization of the central atom in the following species NH3, PtCI42 ,
PCl5 and BCl3 is [JEE 2001]
(A) dsp2, sp3d, sp2 and sp3 3 2
(B) sp , dsp , sp d, sp 3 2
(C) dsp2, sp2, sp3, sp3d (D) dsp2, sp3, sp2, sp3d
25. Specify hybridization of N and B atoms in a 1 : 1 complex of BF3 and NH3 [JEE 2002]
(A) N : tetrahedral, sp3 ; B : tetrahedral, sp3 (B) N : pyramidal, sp3; B : pyramidal, sp3
(C) N : pyramidal, sp3 ; B : planar, sp2 (D) N : pyramidal, sp3; B : tetrahedral, sp3
26. The nodal plane in the -bond of ethene is located in [JEE 2002]
(A) the molecular plane
(B) a plane parallel to the molecular plane
(C) a plane perpendicular to the molecular plane which bisects, the carbon-carbon s bond at
right angle
(D) a plane perpendicular to the molecular plane which contains, the carbon-carbon bond.
27. Which of the following are isoelectronic and isostructural ? NO3 , CO32 , CIO3 , SO3
[JEE 2003]
2 2 2
(A) NO , CO 3 3
(B) SO3, NO 3
(C) CIO , CO3 3
(D) CO ,SO33
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 43
INORGANIC CHEMISTRY
28. Which species has the maximum number of lone pair of electrons on the central atom ?
[JEE 2005]
(A) CIO 3
(B) XeF4 (C) SF4 (D) I 3
29. The percentage of p-character in the orbitals forming P–P bonds in P4 is [JEE 2007]
(A) 25 (B) 33 (C) 50 (D) 75
30. The structure of XeO3 is [JEE 2007]
(A) linear (B) planar (C) pyramidal (D) T-shaped
31. Statement-1 : p-Hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid.
because
Statement-2 : o-Hydroxybenzoic acid has intramolecular hydrogen bonding. [JEE 2007]
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
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Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
32. Statement-1 : In water, orthoboric acid behaves as a weak monobasic [Link]
Statement-2 : In water, orthoboric acid acts as a proton donor. [JEE 2007]
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
33. The nitrogen oxide(s) that contain(s) N–N bond(s) is/are [JEE 2009]
(A) N2O (B) N2O3 (C) N2O4 (D) N2O5
34. The species having pyramidal shape is/are : [JEE 2010]
––
(A) SO3 (B) BrF3 (C) SiO3 (D) OSF2
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 44
INORGANIC CHEMISTRY
35. Which ordering of compounds is according to the decreasing order of the oxidation state of
nitrogen-
(A) HNO3, NO, NH4Cl, N2 (B) HNO3, NO, N2, NH4Cl [JEE 2012]
(C) HNO3, NH4Cl, NO, N2 (D) NO, HNO3, NH4Cl, N2
36. The shape of XeO2F2 molecule is : [JEE 2012]
(A) Trigonal bipyramidal (B) Square planar
(C) tetrahedral (D) see-saw
37. The compound(s) with TWO lone pairs of electrons on the central atom is(are) [JEE 2016]
(A) BrF5 (B) ClF3 (C) XeF4 (D) SF4
38. The crystalline form of borax has [JEE 2016]
(A) Tetranuclear [B4O5(OH)4]2– unit
(B) All boron atoms in the same plane
(C) Equal number of sp2 and sp3 hybridized boron atoms
(D) One terminal hydroxide per boron atom
39. The sum of the number of lone pairs of electrons on each central atom in the following species
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is [TeBr6]2–, [BrF2]+, SNF3, and [XeF3]– [JEE 2017]
(A) Atomic numbers: 7, F = 9, S = 16, Br = 35, Te = 52, Xe = 54)
40. The order of the oxidation state of the phosphorus atom in H3PO2, H3PO4, H3PO3, and H4P2O6
is:- [JEE 2017]
(A) H3PO4 > H3PO2 > H3PO3 > H4P2O6 (B) H3PO2 > H3PO3 > H4P2O6 > H3PO4
(C) H3PO3 > H3PO2 > H3PO4 > H4P2O6 (D) H3PO4 > H4P2O6 > H3PO3 > H3PO2
41. The option (s) with only amphoteric oxides is(are) : [JEE 2017]
(A) Cr2O3, BeO, SnO, SnO2 (B) ZnO, Al2O3, PbO, PbO2
(C) NO, B2O3, PbO, SnO2 (D) Cr2O3, CrO, SnO, PbO
42. The total number of compounds having at least one bridging oxo group among the molecules
given below is ____.
N2O3, N2O5, P4O6, P4O7, H4P2O5, H5P3O10, H2S2O3, H2S2O5 [JEE 2018]
43. Each of the following options contains a set of four molecules. Identify the option(s) where all
four molecules possess permanent dipole moment at room temperature. [JEE 2019]
(1) NO2, NH3, POCl3, CH3Cl (2) BeCl2, CO2, BCI3, CHCI3
(3) SO2, C6H5Cl, H2Se, BrF5 (4) BF3, O3, SF6, XeF6
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 45
INORGANIC CHEMISTRY
ANSWER KEY
DO YOURSELF – 1
Question 1 2 3 4 5
Answer D B D A C
DO YOURSELF – 2
Question 2 3 4 5
Answer C B C A
DO YOURSELF – 3
Question 1 2 3 4 5
Answer A D D A D
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DO YOURSELF – 4
Question 1 2 3 4 5
Answer D A A C C
DO YOURSELF – 5
Question 1 2 3 4 5
Answer D C B C B
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 46
INORGANIC CHEMISTRY
EXERCISE # 1
1. D 2. A 3. D 4. B 5. C 6. C 7. C
8. B 9. B 10. D 11. C 12. C 13. C 14. D
15. A 16. D 17. B 18. A 19. C 20. C 21. D
22. D 23. D 24. B 25. B 26. D 27. C 28. B
29. D 30. B 31. C 32. C 33. B 34. D 35. D
36. D 37. D 38. C 39. D 40. B 41. B 42. A
43. A 44. D 45. B 46. C 47. A 48. B 49. D
50. D 51. C 52. C 53. D 54. C 55. A 56. C
57. D 58. C 59. C 60. C 61. A 62. D 63. A
64. C 65. C 66. A 67. B 68. A 69. C 70. D
71. C 72. A 73. C 74. D 75. C 76. C 77. D
78. D 79. D 80. C 81. B 82. C 83. A 84. D
85. B 86. C 87. B 88. C 89. A 90. B 91. C
92. C 93. A 94. C 95. A 96. C 97. B 98. B
99. A 100. A 101. B 102. B 103. C 104. D 105. D
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106. C 107. A 108. C 109. C 110. A 111. B 112. D
113. B 114. C 115. D 116. D 117. C 118. C 119. D
120. D 121. C 122. C 123. C 124. A 125. D 126. B
127. B 128. C 129. B 130. D 131. A 132. D 133. B
134. C 135. C 136. D 137. C 138. B 139. C 140. D
141. C 142. D 143. C 144. D
EXERCISE # 2
1. A,B,C,D 2. A,B,C 3. A,B,D 4. A,C,D
5. A,B,C,D 6. A,B,C,D 7. A,B,C 8. B,D
9. A,B,C 10. B,C,D 11. A,B 12. A,B,C
13. A,B,C 14. A,B 15. A,D 16. A,B
17. A,B 18. A,B,C 19. A,C 20. A,B
21. A,B,C 22. B,C 23. A,B,D 24. A,C,D
25. A,C 26. B,C,D 27. B,D 28. A,B,C,D
29. B,C 30. A,B,C,D 31. A,B,C 32. A,B
33. A,B 34. A,B,C 35. A,B,C,D 36. A,D
37. A,C 38. A,B,C 39. A,C,D 40. A,B,C
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 47
INORGANIC CHEMISTRY
EXERCISE # 3
1. 5 2. 4 3. 3 4. 2 5. 15 6. 2 7. 2
8. 3 9. 4 10. 4 11. 4 12. 2 13. 4 14. 2
15. 4 16. 4 17. 8 18. 4 19. 0 20. 20 21. 3
22. 4 23. 16 24. 8 25. 2 26. 15 27. 3 28. 0
29. 3 30. 4 31. 6 32. 2 33. 3 34. 2
EXERCISE # 4
1. B 2. B 3. C 4. C 5. D 6. D 7. B
8. C 9. A 10. C 11. B 12. B 13. A 14. A,B,C
15. B 16. A 17. C 18. A,B,D 19. A,D 20. D 21. A,B,C,D
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22. A 23. D 24. B,C,D 25. D 26. B 27. A 28. A
29. D 30. C 31. C
EXERCISE # 5
1. (A) (Q) ; (B) (S) ; (C) (P) ; (D) (R)
2. (A) (PQ) ; (B) (QR) ; (C) (QR)
3. (A) (Q) ; (B) (R) ; (C) (S) ; (D) (P)
4. (A) (Q) ; (B) (Q,R) ; (C) (P,Q,R)
5. C
6. B
7. B
8. (A) (Q) ; (B) (S) ; (C) (R) ; (D) (P)
9. [(A) P,Q ; (B) P,Q,R,T ; (C) P,Q,R,S,T ; (D) P,Q,R,S]
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 48
INORGANIC CHEMISTRY
EXERCISE - 6 # JEE-MAIN
Que. 1 2 3 4 5 6 7 8 9 10
Ans. 3 2 1 1 4 3 3 1 4 2
Que. 11 12 13 14 15 16 17 18 19 20
Ans. 4 4 4 2 BONUS 3 3 3 4 1
Que. 21 22 23 24 25 26 27 28 29 30
Ans. 3 3 2 4 1 3 2 3 2 1
Que. 31 32 33 34 35 36 37 38 39 40
Ans. 3 2 2 1 2 2 2 4 4 3
Que. 41 42 43 44 45 46 47 48 49
Ans. 3 2 2 2 2 1 3 2 4
EXERCISE - 7 # JEE-ADVANCED
Que. 1 2 3 4 5 6 7 8 9 10
Ans. 4 0 5 6 B,C,D C A A,B,D C B
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Que. 11 12 13 14 15 16 17 18 19 20
Ans. C B C A B A,B,C B D A B
Que. 21 22 23 24 25 26 27 28 29 30
Ans. A A B B A A A D D C
Que. 31 32 33 34 35 36 37 38 39 40
A,B,C
Ans. D C D B D B,C A,C,D 6 D
or A,C
Que. 41 42 43
Ans. AB 5,6 1,3
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 49
INORGANIC CHEMISTRY
ANSWER OF HYDROGEN BONDING
1.
H
O
H B
O O
H H
O O
H B H H
O O
O
H B H H B
O O O O
H H
2. Inter molecular H-Bonding in case of para nitro phenol is strong enough to increase boiling
point which is not favoured in o-nitro phenol.
3. Maleic acid anion gets stabilize due to intra molecular H-bonding which is not possible in
anion of Fumaric acid. So H+ releasing tendency is more in case of maleic acid.
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O O
H C OH C OH
–H+ H
C C H-bonding
H-bonding H
C (Ion-dipole)
C OH (dipole)-dipole C O
H H C
O O
Maleic acid
O
O
H C OH
H C O
C
C No H-bonding
C –H+
HO C H C
HOOC H
O
Fumaric acid
4. Due to strong H-Bonding in H–F
F F
H H H
F
5. Due to H-Bonding in NH3.
6. Density of ice is higher than that of water due to cage like structure of ice volume of ice
increases and density decreases.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 50
INORGANIC CHEMISTRY
7. On heating ice in temperature range 0–4ºC H-bonds of ice break down, which decreases
volume, hence density of H2O increases. On heating ice after 4ºC thermal vibrations of H2O
molecules increases which increases effective volume of ice, so density of ice again decreases.
8. H-I bond is weak as compare to H-F so it can be dissociated easily and can give H+ easily.
9. The organic matter in wood participate in H-bonding with water molecules in ice-cream.
10. K+[F–H….F] But KHBr2 & KHI2 can't form H-Bond.
H-bonding
11. In o-Nitrophenol intra molecular H-bond is present which it's solubility in water.
O–H H–Bonding
O
N
O
Ortho Nitro-phenol
12. In o-hydroxy benzeldehyde intramolecular H-bond is present which is less stronger than
intermolecular H-bond in p-hydroxy benzeldehyde.
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13. Extent of H-bonding in glycerol is more as compare to ethanol so it is more viscous.
14. Due to H-bonding in H2O
15. Due to H-bonding in acetic acid it forms dimer so overall molecular weight is just double of
original
O H O
H 3C C C CH3
O H O
Dimer of CH3 COOH
16. Due to bigger size of 'CI' atom it's interaction is not enough to evolve the amount of energy
which lies in the range of H-bong.
n
(AcOH)n
on vapour
(AcOH)2
17. liquid 2
Not completely converted
But in (H2O)n
on vapour
n (H2O)
liquid
Here all H2O molecule gets vaporised. So change is more
18. As extent of H-bond is more in H2O as compare to HF, heat of vaporisation of water is higher
than HF.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, 70732-22177, Ph. 0744-2423333 [Link] 51
Common questions
Powered by AICCl4 is non-polar because its tetrahedral geometry allows the polar C-Cl bonds to be symmetrically arranged, canceling out the dipole moments .
CO32-, NO3-, and SO3 have similar trigonal planar structures, making them isostructural .
Diamond is an insulator because its carbon atoms are sp3 hybridized, leading to a strong 3D covalent structure that doesn’t allow free electron movement. In graphite, carbon atoms are sp2 hybridized, creating layers with delocalized electrons enable electron flow, making it a good conductor .
PF5 does not exhibit sp3d2 hybridization; it shows sp3d, forming a trigonal bipyramidal structure. SF6, BrF5, and [CrF6]3- show sp3d2 hybridization .
VSEPR theory suggests that the shape of a molecule is defined primarily by the repulsion between electron pairs, while hybridization can help determine the basic geometry of the molecule . However, the actual shape might deviate due to lone pair repulsion, with VSEPR describing these deviations .
The structure of IF6- is a distorted octahedron due to electron pair repulsions causing deviations from perfect octahedral angles .
The bond angle in water is less than in methane due to lone pair-bond pair repulsions in water, which causes a decrease from 109.5° in methane (tetrahedral) to 104.5° in water .
BF3 is planar due to its trigonal planar shape according to VSEPR theory .
The presence of lone pairs in XeF4 causes it to adopt a square planar structure. The lone pairs occupy positions in the axial plane, reducing repulsion in the equatorial plane and resulting in a planar geometry .
IF5 has bond angles equal to 90 degrees. SeF6 and ICl4- also have angles of 90 degrees, but BrF3 does not .
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