ANALYTICAL CHEMISTRY LECTURE | BS MEDICAL BIOLOGY

 
PAA #2 Select one:
3.7 × 10–5 M
Question 1 8.5 × 10–4 M

What would be the mass-balance expression for a 1.9 × 10–4 M

solution that is 0.10 M in H3PO4. 7.6 × 10–6 M

 Select one: Question 4

4
–
4
2– 3–
[H3PO4] + [H2PO ] + [HPO ] + [PO4 ] + 0.10 = 0 
Gravimetric methods of analysis are based on the
[H3PO4] + [H2PO4–] + [HPO42–] + [PO43–] = 0.10  measurement of:
[H3PO4] + [H2PO4–] + [HPO42–] + [PO43–] = 0  Select one:

[H2PO4–] + [HPO42–] + [PO43–] = [H3PO4] Volume

Clear my choice Mass
Solubility
Question 2
Weight
Calculate the molar solubility of SrC 2O4 in a solution
that has a fixed H3O+ concentration of 1.0 × 10-6 M. Question 5

Given: An aqueous solution contains NaNO3 and KBr. The

bromide ion is precipitated as AgBr by addition of
1. Equations for the pertinent equilibria: AgNO3. After an excess of the precipitating reagent has
been added, there is positive charge on the surface of
SrC2O4(s) ⇌ Sr2+ + C2O42–     Ksp = 5.0 × 10-8 the coagulated colloidal particles. What is the source
of the charge and what ions make up the counter-ion
layer?
H2C2O4 + H2O ⇌ H3O+ + HC2O4–     K1 = 5.6 × 10-2

 
HC2O4– + H2O ⇌ H3O+ + C2O42–     K2 = 2.42 × 10-5
Select one:
2. Solubility: The positive charge arises from adsorbed Na+ ions,
and Br– ions make up the counter-ion layer.
S = [Sr2+] = [C2O42–] + [HC2O4–] + [H2C2O4] The positive charge arises from adsorbed Na+ ions,
and NO3– ions make up the counter-ion layer.
3. Since an unknown buffer is maintaining the pH, no
The positive charge arises from adsorbed Ag+ ions,
charge balance equation can be written in this case. 
and NO3– ions make up the counter-ion layer.
Select one: The positive charge arises from adsorbed Ag+ ions,
and Br– ions make up the counter-ion layer.
2.3 × 10-4 M
0.028 M Question 6
7.62 × 10  M-6

Treatment of a 0.2500-g sample of impure potassium

4.3 × 10-3 M chloride with an excess of AgNO 3 resulted in the
formation of 0.2912 g of AgCl. Calculate the
Question 3 percentage of KCl in he sample.

Calculate the molar solubility of BaSO4 in a solution in  Given: MAgCl = 143.32 g/mol; MKCl = 74.55 g/mol.
which [H3O+] is 3.5 M. 
 Select one:
Given:
24.31%
Equations for the pertinent equilibria: 48.52%
60.59%
BaSO4 ⇌ Ba2+ + SO42–      Ksp = 1.1 × 10–10
88.31%
– + 2–
HSO4  + H2O ⇌ H3O  + SO4       K2 = 1.02 × 10 –2

Question 7
ANALYTICAL CHEMISTRY LECTURE | BS MEDICAL BIOLOGY
The mercury (Hg) in a 1.0451-g sample containing Question 11
Hg2Cl2 (among other compounds) was precipitated
with an excess of paraperiodic acid, H5IO6: A mixture of the 8-hydroxyquinoline complexes of Al
and Mg weighed 2.5375 g. When ignited in a furnace
5Hg2+ + 2H5IO6 → Hg5(IO6)2 + 10H+ open to the air, the mixture decomposed, leaving a
residue of Al2O3 and MgO weighing 0.3135 g. Find the
The precipitate was filtered, washed free of weight percent of MgQ 2 in the original mixture, where
precipitating agent, dried, and weighed, and 0.5718 g Q is the abbreviation for the 8-hydroxyquinoline anion.
was recovered. Calculate the percentage of Hg 2Cl2 in
the sample. Given: M(AlQ3) = 459.43 g/mol; M(MgQ2) = 312.61
g/mol; M(Al2O3) = 101.96 g/mol; M(MgO) = 40.304
Given: M(Hg5(IO6)2) = 1448.75 g/mol; M(Hg2Cl2) = g/mol.
472.18 g/mol.
 
Select one: Select one:

44.58% 32.30%
28.27% 70.05%

82.13% 54.48%
68.55% 23.45%

Question 8 Question 12

Calculate the specific surface area of a theoretical Describe the preparation of 1.00 L of 0.150 M
colloid consisting of 10,000 cubes, each of which has KMnO4 (𝑀A = 158.03 g/mol) from the solid reagent.
an edge size of 0.1 cm and a mass of 3 g.  Select one:
Dissolve 23.70 g KMnO4 in water and dilute to 1.00
Select one: L total volume.
2.0 cm2/g Dissolve 47.40 g KMnO4 in water and dilute to 1.00
0.334 cm /g2 L total volume.

200 cm2/g Dissolve 19.50 g KMnO4 in water and dilute to 1.00

L total volume.
30 cm2/g
Dissolve 63.60 g KMnO4 in water and dilute to 1.00
L total volume.
Question 9

Question 13
Coprecipitation of SrSO4 and BaSO4 typically results in:

A 100.0-mL sample of spring water was treated to

Select one:
convert any iron present to Fe2+. Addition of 25.00-mL
Surface adsorption of 0.002517 M K2Cr2O7 resulted in the reaction:
Mixed-crystal formation
6Fe2+ + Cr2O72- + 14H+ → 6Fe3+ + 2Cr3+ + 7H2O
Occlusion
Mechanical entrapment The excess K2Cr2O7 was back-titrated with 8.53 mL of
0.00949 M Fe2+ solution. Calculate the concentration of
Question 10 iron in the sample in parts per million.

Dimethylglyoxime is an organic precipitating agent  

that specifically precipitates the following metal ion Select one:
from solution: 165.6 ppm
324.8 ppm
Select one:
82.6 ppm
Mg2+
498.3 ppm
Ba2+
Ni2+ Question 14
Fe3+
ANALYTICAL CHEMISTRY LECTURE | BS MEDICAL BIOLOGY
What variables can cause the pH range of an indicator and 60.00 mL of 0.1000 M NaOH at standard room
to shift? temperature.

Select one:  
Select one:
Temperature.
pH 4.15 (40 mL NaOH), pH 9.27 (60 mL NaOH)
Ionic strength.
pH 5.36 (40 mL NaOH), pH 11.96 (60 mL NaOH)
The presence of colloidal particles.
pH 4.76 (40 mL NaOH), pH 10.00 (60 mL NaOH)
All of them.
pH 3.12 (40 mL NaOH), pH 8.87 (60 mL NaOH)
Question 15
Question 19
Which solute would provide the sharper end point in a
titration with 0.10 M NaOH? Calculate the pH of a solution that is 0.0400 M in
NaH2PO4.
 
Select one: Given:
0.10 M Nitrous acid (Ka = 7.1 × 10 ) -4

H3PO4 + H2O ⇌ H3O+ + H2PO4–       Ka1 = 7.11 × 10–3

-1
0.10 M Iodic acid (Ka = 1.7 × 10 )
0.10 M Hypochlorous acid (Ka = 3.0 × 10-8) H2PO4- + H2O ⇌ H3O+ + HPO42-       Ka2 = 6.32 × 10–8

0.10 M Pyruvic acid (Ka = 3.2 × 10-3)

 
Select one:
Question 16
pH 2.40
Calculate the pH of the 50 mL titrated solution of pH 3.58
0.0500 M HCl after addition of 20.00 mL and 26.00 mL
of 0.1000 M NaOH at standard room temperature. pH 4.71
pH 5.95
 
Select one: Question 20
pH 4.65 (20 mL NaOH), pH 9.34 (26 mL NaOH)
What is the value of the relative amount of acetic acid
pH 3.47 (20 mL NaOH), pH 8.18 (26 mL NaOH) (α0) at the half-titration point when titrating 50.00 ml
pH 2.15 (20 mL NaOH), pH 11.12 (26 mL NaOH) of 0.1000 M acetic acid with 0.1000 M NaOH at
standard room temperature?
pH 1.25 (20 mL NaOH), pH 10.06 (26 mL NaOH)
 Select one:
Question 17
0.2
Calculate the pH of a solution that is 0.0400 M in 0.5
H3PO4 (phosphoric acid).
1.0
Given: 2.0

H3PO4 + H2O ⇌ H3O+ + H2PO4–       Ka1 = 7.11 × 10–3

 
Select one:
pH 1.86
pH 2.90
pH 3.45
pH 4.24

Question 18

Calculate the pH of the 50 mL titrated solution of

0.1000 M acetic acid (HOAc) after addition of 40.00 mL