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SDS Cristal400 Renew

This safety data sheet provides information on Eastman Cristal 400-50 Renew Copolyester pellets. It lists the product name and manufacturer details, describes the product as a combustible solid polymer, and provides guidance on handling, storage, exposure controls, firefighting and accidental release. Hazards are identified as potential dust explosion if small particles are generated.

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0% found this document useful (0 votes)
16 views10 pages

SDS Cristal400 Renew

This safety data sheet provides information on Eastman Cristal 400-50 Renew Copolyester pellets. It lists the product name and manufacturer details, describes the product as a combustible solid polymer, and provides guidance on handling, storage, exposure controls, firefighting and accidental release. Hazards are identified as potential dust explosion if small particles are generated.

Uploaded by

sri
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

SECTION 1. IDENTIFICATION

Product name
: Eastman Cristal(TM) 400-50 Renew Copolyester

Product code : 400-50, 50220847, 50220842, 50220846, 50220845,


50220844

Manufacturer or supplier's details


Company name of supplier
: Eastman Chemical Company

Address : 200 South Wilcox Drive


Kingsport TN 37660-5280
Telephone : (423) 229-2000

Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

Recommended use of the chemical and restrictions on use


Recommended use
: Polymer

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200


Combustible dust

GHS label elements


Signal Word : Warning

Hazard Statements : If small particles are generated during further processing,


handling or by other means, may form combustible dust
concentrations in air.

Precautionary Statements :
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Components

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SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

Chemical name CAS-No. Concentration (% w/w)


copolyester proprietary 100

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.


Treat symptomatically.
If symptoms persist, call a physician.

In case of skin contact : Wash off with soap and water.


If symptoms persist, call a physician.
Cool skin rapidly with cold water after contact with molten
material.
Do not peel solidified product off the skin.
Burns must be treated by a physician.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : Seek medical advice.

Most important symptoms : The molten product can cause serious burns.
and effects, both acute and
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray


Dry chemical
Carbon dioxide (CO2)

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

Specific hazards during fire : Avoid generating dust; fine dust dispersed in air in sufficient
fighting concentrations, and in the presence of an ignition source is a
potential dust explosion hazard.

Further information : Minimize dust generation and accumulation.

Special protective equipment : Wear an approved positive pressure self-contained breathing


for fire-fighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

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SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

: Wear appropriate personal protective equipment.


Local authorities should be advised if significant spillages
cannot be contained.

Environmental precautions : Avoid release to the environment.

Methods and materials for : Sweep up and shovel into suitable containers for disposal.
containment and cleaning up

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Minimize dust generation and accumulation.


fire and explosion

Advice on safe handling : Wash thoroughly after handling.


Use only in area provided with appropriate exhaust ventilation.
Minimize dust generation and accumulation.

Conditions for safe storage : Keep tightly closed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Contains no substances with occupational exposure limit values.
Engineering measures : Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne
levels to an acceptable level.

Personal protective equipment


Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Wear respiratory protection when its use is identified for
certain contributing scenario.

Hand protection

Remarks : Wear suitable gloves. When handling hot material, use heat
resistant gloves.

Eye protection : Safety glasses


Wear a face shield when working with molten material.

3 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

Skin and body protection : Wear suitable protective clothing.

Protective measures : Ensure that eye flushing systems and safety showers are
located close to the working place.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
: pellets

Color : colorless

Odor : odorless

Odor Threshold : not determined

pH : not determined

Softening point : 176 °F / 80 °C

Flash point : not applicable, combustible solid

Evaporation rate : not determined

Upper explosion limit / Upper : not determined


flammability limit

Lower explosion limit / Lower : not determined


flammability limit

Vapor pressure : not determined

Relative vapor density : not determined

Relative density : >1


(estimated)

Solubility(ies)
Water solubility : negligible

Partition coefficient: n- : No data available


octanol/water

Autoignition temperature : not determined

4 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

Decomposition temperature : Thermal stability not tested. Low stability hazard expected at
normal operating temperatures.

Viscosity
Viscosity, dynamic
: not determined

Viscosity, kinematic : not determined

Explosive properties : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : None reasonably foreseeable.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Stable


tions

Conditions to avoid : Minimize dust generation and accumulation.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Carbon monoxide


products Carbon dioxide (CO2)

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity
: Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Skin corrosion/irritation
Not classified based on available information.
Product:
Remarks : No data available

5 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

Serious eye damage/eye irritation


Not classified based on available information.
Product:
Remarks : No data available

Respiratory or skin sensitization


Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Remarks : No data available

Germ cell mutagenicity


Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Product:
Remarks : This information is not available.

IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Not classified based on available information.
Product:
Effects on fertility
: Remarks: No data available

STOT-single exposure
Not classified based on available information.
Product:
Remarks : No data available

STOT-repeated exposure
Not classified based on available information.
Product:
Remarks : No data available

6 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

Repeated dose toxicity

Product:
Remarks : No data available

Aspiration toxicity
Not classified based on available information.
Product:
No aspiration toxicity classification

Information on likely routes of exposure


Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: The molten product can cause serious burns.

Eye contact : Remarks: The molten product can cause serious burns.

Ingestion : Remarks: None known.

Further information
Product:
Remarks : None known.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

7 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

SECTION 14. TRANSPORT INFORMATION

International Regulations
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity


This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity


This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: Combustible dust

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

California Prop. 65
WARNING: This product can expose you to chemicals including acetaldehyde, which is/are known to
the State of California to cause cancer. For more information go to [Link].
The ingredients of this product are reported in the following inventories:
TCSI
: On the inventory, or in compliance with the inventory

TSCA : All substances listed as active on the TSCA inventory

AICS : On the inventory, or in compliance with the inventory

DSL : All components of this product are on the Canadian DSL

ENCS : On the inventory, or in compliance with the inventory

8 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Further information
NFPA 704: HMIS® IV:
Flammability
HEALTH / 1
1 FLAMMABILITY
Instability

1
Health

1 0
PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating


scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
Special hazard cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemical s
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-

9 / 10
SAFETY DATA SHEET

Eastman Cristal(TM) 400-50 Renew


Copolyester

Version Revision Date: SDS Number: Date of last issue: -


1.0 03/13/2020 150000116089 Date of first issue: 03/13/2020
PRD SDSUS / Z8 / 0001

tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -
United Nations Recommendations on th e Trans port of Dangerous Goods; vP vB - Very Persistent
and Very Bioaccumulative

Revision Date : 03/13/2020

The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

US / Z8

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