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Toluene Safety Data Sheet Summary

This document provides a safety data sheet for toluene commercial grade. It lists toluene as the main component, along with small amounts of benzene and ethyl benzene. Toluene is highly flammable and exposure can cause skin, eye and respiratory irritation. Ingestion may be fatal. Proper precautions and protective equipment should be used when handling toluene. In the event of exposure, flush skin/eyes with water and seek medical attention if symptoms persist.

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0% found this document useful (0 votes)
19 views19 pages

Toluene Safety Data Sheet Summary

This document provides a safety data sheet for toluene commercial grade. It lists toluene as the main component, along with small amounts of benzene and ethyl benzene. Toluene is highly flammable and exposure can cause skin, eye and respiratory irritation. Ingestion may be fatal. Proper precautions and protective equipment should be used when handling toluene. In the event of exposure, flush skin/eyes with water and seek medical attention if symptoms persist.

Uploaded by

jg
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

TOLUENE COMMERCIAL GRADE Gen. Variant: SDS_US_GHS


Version 1.3 Revision Date 11/22/2019 Print Date 12/16/2021 SDS No.: 48

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKI NG

Trade name : TOLUENE COMMERCIAL GRADE


CAS Number: : 108-88-3
Chemical name : Toluene
Synonyms : Methyl benzene, Toluol, Toluene Commercial Grade

Identified uses : Use as intermediate; Use in solvents

Prohibited uses : Pesticides or Pesticide Formulations

Company Address Company Telephone


Equistar Chemicals, LP Customer Service 888 777-0232
LyondellBasell Tower, Suite 300 [Link]@[Link]
1221 McKinney St.
P.O. Box 2583
Houston Texas 77252-2583

Emergency telephone number


CHEMTREC USA 800-424-9300
EQUISTAR 800-245-4532

E-mail address : [Link]@[Link]


Responsible/issuing person

2. HAZARDS IDENTIFICATION

GHS Classification

Flammable liquids Category 2


Skin corrosion/irritation Category 2
Germ cell mutagenicity Category 2
Carcinogenicity Category 1A
Reproductive toxicity Category 2
Effects on or via lactation
Aspiration hazard Category 1
Specific target organ toxicity - single exposure Category 3
Specific target organ toxicity - repeated exposure; Category 1
Inhalation
Central nervous system, Haematopoietic system
Short-term (acute) aquatic hazard Category 2
Long-term (chronic) aquatic hazard Category 3

Label elements

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Hazard symbols :

Signal word : Danger

Hazard Statements : H225 Highly flammable liquid and vapour.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H335 + H336 May cause respiratory irritation, and
drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs through prolonged or
repeated exposure.
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary : Prevention
Statements P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been
read and understood.
P210 Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P271 Use only outdoors or in a well-ventilated area.
P242 Use non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash hands thoroughly after handling.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P263 Avoid contact during pregnancy/ while nursing.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.

Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P370 + P378 In case of fire: Use alcohol-resistant foam,
carbon dioxide or water mist for extinction.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
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P302 + P352 IF ON SKIN: Wash with plenty of soap and


water.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P312 Call a POISON CENTER/doctor if you feel unwell.

Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
P233 Keep container tightly closed.
P405 Store locked up.

Disposal
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards

Hazards Not Otherwise Classified (HNOC)


Static-accumulating flammable liquid can become electrostatically charged even in bonded
and grounded equipment. Sparks may ignite liquid and vapor and may cause flash fire or
explosion

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Components
Chemical name CAS-No. Weight % Component
EC-No. Type
Toluene 108-88-3 95.0 - 99.0 % A

Benzene 71-43-2 <1.5 % C

Ethyl Benzene 100-41-4 <0.3 % C

Key:
(A) Substance
(C) Impurity

4. FIRST AID MEASURES

General advice : Take proper precautions to ensure your own health and safety
before attempting rescue and providing first aid.
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If inhaled : Move to fresh air.


Do not leave the victim unattended.
Keep patient warm and at rest.
Get immediate medical advice/ attention.
If breathing is difficult, give oxygen.
If unconscious, place in recovery position and seek medical
advice.
In the event of unconsciousness, apnea or cardiac arrest (no
pulse), apply cardiopulmonary resuscitation.
No artificial respiration, mouth-to-mouth or mouth to nose. Use
suitable instruments/apparatus.

In case of skin contact : Take off contaminated clothing and shoes immediately.
In case of contact, immediately flush skin with soap and plenty
of water.
Wash off immediately with plenty of water for at least 15
minutes.
Seek medical attention if ill effect or irritation develops.

In case of eye contact : In case of eye contact, remove contact lens and rinse
immediately with plenty of water, also under the eyelids, for at
least 15 minutes.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
DO NOT induce vomiting. If vomiting does occur, have victim
lean forward to reduce risk of aspiration. Get medical attention
immediately.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.

Notes to physician
Symptoms : Signs of eye, throat, and respiratory tract irritation (cough and
difficulty breathing), CNS depression (fatigue, dizziness,
headache, collapse, coma and death) and possible cardiac
sensitization may occur after exposure to high vapor
concentrations.

Hazards : Causes skin irritation.


Aspiration may cause pulmonary edema and pneumonitis.

Treatment : Treat symptomatically.


Treatment of overexposure should be directed at the control of

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symptoms and the clinical condition of the patient.


Consider activated charcoal and/or gastric lavage.
Gastric lavage is indicated in those patients who require
decontamination. Be sure that an endotracheal tube is in place
prior to lavage; use cuffed tubes in patients over 7 years of age.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : SMALL FIRE: Use dry chemical, CO2, water spray or regular
foam. LARGE FIRE: Use water spray, water fog or regular
foam. Do not use straight streams.

Specific hazards during fire : Flammable vapors may be heavier than air.
fighting Extremely flammable vapors may be generated by material
(flash point < freezing point) below normal ambient
temperatures.
Fine sprays/mists may be combustible at temperatures below
normal flash point.
Vapors may travel long distances along the ground before
reaching a source of ignition and flashing back.
Fight fire from maximum distance or use unmanned hose
holders or monitor nozzles.
Apply water spray/fog for cooling.
Do not use solid water stream - may spread fire.
Move containers from fire area if it can be done without risk.
Blanket with firefighting foam.
Withdraw immediately in case of rising sound from venting
safety devices or discoloration of tank.
Heat may build enough pressure to rupture closed
containers/spreading fire/increasing risk of burns/injuries.
Always stay away from tanks engulfed in fire.
For massive fire, use unmanned hose holders or monitor
nozzles; if this is impossible, withdraw from area and let fire
burn.
This material releases flammable vapors at well below ambient
temperatures and may form flammable mixtures with air.
When mixed with air in certain proportions and exposed to an
ignition source, these vapors can burn in the open or be
explosive in confined spaces. Being heavier than air, these
vapors may travel long distances along the ground before
reaching a point of ignition and flashing back.

Special protective equipment : Wear positive pressure self-contained breathing apparatus


for fire-fighters (SCBA).
Structural firefighter’s protective clothing will only provide
limited protection.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Use personal protective equipment.


Clean-up to be performed only by trained and properly
equipped personnel.
Both local exhaust and good general room ventilation must be
provided not only to control exposure but also to prevent
formation of flammable mixtures.
Beware of vapors accumulating to form explosive
concentrations. Vapors can accumulate in low areas.

Environmental precautions : Do not allow uncontrolled discharge of product into the


environment.

Methods for containment / : Extremely flammable liquid.


Methods for cleaning up Eliminate all sources of ignition. Let evaporate. If possible,
turn leaking container so that gas escapes rather than liquid.
Do not direct water at spill or source. Use water spray curtain
to divert vapor drift. Prevent entry into sewers, basements or
confined areas.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
For larger spillages on water contain with booms or barriers,
use surface acting agents to thicken spilled materials.
Remove trapped material with suction hoses.

Additional advice : See Section 15: Regulatory Information.


Spillages of liquid product will create a fire hazard and form an
explosive atmosphere
Avoid direct contact with released material. Stay upwind.
Keep non-involved personnel away from the area of spillage.
Ensure adequate ventilation, especially in confined areas.

7. Handling and storage

Precautions for safe handling


Advice on safe handling : Smoking, eating and drinking should be prohibited in the
application area.
Use in a well-ventilated area.
Keep away from all sources of ignition.
Use only non-sparking tools.
Take measures to prevent the build up of electrostatic charge.
Carefully vent any internal pressure before removing closure.
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Do not overfill containers which may burst on freezing.


Thaw frozen containers only at room temperature.
Containers must be properly grounded before beginning
transfer.
All equipment must conform to applicable electrical code.
Handle used containers with care - residue is
flammable/poisonous.
Isolate, vent, drain, wash and purge systems or equipment
before maintenance or repair.
Check atmosphere for explosiveness and oxygen deficiencies.
If any residual product may be present, total encapsulating
impervious protective suits, gloves, and boots should be worn.
Observe precautions pertaining to confined space entry.
Provide grounding/equipment conforming to electrical codes.
Bonding and grounding measures may not be enough if
nonconductive flammable liquids are involved. Refer to NFPA
77 for relevant consensus guidance.

Fire-fighting class : OSHA/NFPA Class IB Flammable Liquid.

Conditions for safe storage, including any incompatibilities


Requirements for storage : Store in tightly closed/properly vented containers away from
areas and containers heat/sparks/open flame and strong oxidizing agents.
Store closed drums with bung in up position.
Avoid breathing vapors in top of shipping container; may
contain a known human carcinogen.
Bonding and grounding measures may not be enough if
nonconductive flammable liquids are involved. Refer to NFPA
77 for relevant consensus guidance.

Specific end use(s)


: See Section 1.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Ingredients with workplace control parameters

Occupational Exposure Limits

Components CAS-No. Type Limit Value Basis Additional


Revision Date Information
Toluene 108-88-3 TWA 20 ppm US (ACGIH)
2012

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Toluene 108-88-3 IDLH 500 ppm NIOSH


September 2007

Toluene 108-88-3 Peak 500 ppm 98/24/EC


June 23, 2006

Remarks: 10 minutes

Toluene 108-88-3 CEILING 300 ppm US (OSHA)


June 23, 2006

Toluene 108-88-3 TWA 200 ppm US (OSHA)


June 23, 2006

Benzene 71-43-2 STEL 2.5 ppm US (ACGIH)


2012

Benzene 71-43-2 TWA 0.5 ppm US (ACGIH)


2012

Benzene 71-43-2 IDLH 500 ppm NIOSH


September 2007

Benzene 71-43-2 Peak 50 ppm 98/24/EC


June 23, 2006

Remarks: 10 minutes

Benzene 71-43-2 CEILING 25 ppm US (OSHA)


June 23, 2006

Benzene 71-43-2 STEL 5 ppm US (OSHA)


June 23, 2006

See 29 CFR 1910.1028

Benzene 71-43-2 TWA 10 ppm US (OSHA)


June 23, 2006

Benzene 71-43-2 TWA 1 ppm US (OSHA)


June 23, 2006

Ethyl Benzene 100-41-4 TWA 20 ppm US (ACGIH)


2012

Ethyl Benzene 100-41-4 IDLH 800 ppm NIOSH


September 2007

Remarks: 10% LEL

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Ethyl Benzene 100-41-4 TWA 100 ppm US (OSHA)


435 mg/m3 June 23, 2006

Consult local authorities for acceptable exposure limits.

Biological Exposure Indices

Components CAS-No. Control Biological Sampling Concentration Basis


parameters specimen time
Toluene 108-88-3 Toluene blood prior to last 0.02 mg/l ACGIH_BEI
shift of S
workweek
Toluene 108-88-3 Toluene urine end of shift 0.03 mg/l ACGIH_BEI
S
Toluene 108-88-3 o-Cresol with urine end of shift 0.3 mg/g ACGIH_BEI
hydrolysis creatinine S
Remarks: background.
Benzene 71-43-2 S- urine end of shift 25 µg/g ACGIH_BEI
Phenylmerca creatinine S
pturic acid
Remarks: background.
Benzene 71-43-2 t,t-Muconic urine end of shift 500 µg/g ACGIH_BEI
acid creatinine S
background.
Ethyl Benzene 100-41-4 Sum of urine end of shift 0.15 g/g ACGIH_BEI
mandelic creatinine S
acid and
phenylglyoxyl
ic acid
Remarks: nonspecific.

Exposure controls
Engineering measures
Both local exhaust and good general room ventilation must be provided not only to control
exposure but also to prevent formation of flammable mixtures.
Special attention should be given to low areas/pits where flammable vapors can accumulate.

Personal protective equipment


Respiratory protection : When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.

Hand protection : Use chemical resistant gloves appropriate to conditions of


use.

Eye and face protection : Eye protection such as chemical splash goggles and/or face
shield must be worn when possibility exists for eye contact
due to splashing or spraying liquid, airborne particles, or
vapor.

Skin and body protection : Protective clothing including gloves, apron, sleeves, boots,
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and full head/face protection should be worn.


The equipment must be cleaned thoroughly after each use.

Hygiene measures : Selection of appropriate personal protective equipment should


be based on an evaluation of the performance characteristics
of the protective equipment relative to the task(s) to be
performed, conditions present, duration of use, and the
hazards and/or potential hazards that may be encountered
during use.
Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
The [Link] of Federal Regulations (CFR), 29 CFR
1910.1028, gives detailed information on Benzene health
hazards and symptoms of over-exposure. It also addresses
the requirements and responsibilities for providing, wearing,
and maintaining protective equipment as well as procedures
for medical monitoring of Benzene exposures.
Use good personal hygiene practices.
Wash hands before eating, drinking, smoking, or using toilet
facilities.
Take off contaminated clothing and wash before reuse.
Shower after work using plenty of soap and water.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : Colorless.

Odor : Sweet aromatic

Odor Threshold : 2.5 - 8 ppm


AIHA reports the odor threshold at 1.6 ppm for toluene., Patty's
toxicology reports the odor threshold at 2.5 to 8.0 ppm, for
toluene.

Flash point : 4.4 °C


Method: closed cup

Lower explosion limit : 1.3 vol%

Upper explosion limit : 8 vol%

Flammability (solid, gas) : Not applicable

Oxidizing properties : No Data Available.

Autoignition temperature : 480 °C

Decomposition temperature : not determined

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Melting point/freezing point : -95 °C

Boiling point/boiling range : 111 °C

Vapor pressure : 38 hPa


at 25 °C

Density : 0.866 g/cm3


at 20 °C
(Water = 1)

Water solubility : 519 - 587 g/l


25 °C

Partition coefficient: n- : log Pow: 2.65


octanol/water
Viscosity, dynamic : 0.560 mPa.s
at 25 °C

Viscosity, kinematic : 0.64 mm2/s


at 25 °C

Relative vapor density : 3.1


(Air = 1.0)

Explosive properties : Not considered explosive

Other Information : No additional information available.

10. STABILITY AND REACTIVITY

Reactivity : Will not occur.

Chemical stability : Stable under recommended storage conditions.

Conditions to avoid : Avoid contact with strong oxidizers, excessive heat, sparks or
open flame.

Materials to avoid : Does not react with water or common materials.

Hazardous decomposition : Excessive heating and/or incomplete combustion may


products produce carbon monoxide, carbon dioxide and other harmful
substances.

Thermal decomposition : Carbon oxides (CO, CO2)

11. TOXICOLOGICAL INFORMATION

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Product Summary : The below given information is based on the assessment of


the product including impurities.

Acute toxicity

Acute oral toxicity : Based on acute toxicity values, not classified.

: > 5,000 mg/kg


Species: Rat

Acute inhalation toxicity : Based on acute toxicity values, not classified.

: LC50 (Inhl): > 20 mg/l


Species: Rat

Acute dermal toxicity : Based on acute toxicity values, not classified.

: LD50 Dermal: > 5,000 mg/kg


Species: Rabbit

Skin corrosion/irritation : Classified


Causes skin irritation.

Serious eye damage/eye : Not classified


irritation May cause slight transient eye irritation.

Respiratory or skin : Skin sensitization


sensitization Not classified
No adverse effect observed.

: Respiratory sensitization
Not classified
No study available.

Chronic toxicity

Component Name NTP IARC OSHA


known as a human
Benzene 1 Present
carcinogen
Ethyl Benzene 2B Present

Carcinogenicity : Classified
May cause cancer.

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Germ cell mutagenicity : Classified


Suspected of causing genetic defects.

Reproductive toxicity
Effects on fertility / : Classified
Effects on or via lactation May cause harm to breast-fed children.

Effects on Development : Classified


Suspected of damaging the unborn child.

Target Organ Systemic : Target Organs: Respiratory system, Nervous system


Toxicant - Single exposure Classified

: May cause respiratory irritation., May cause drowsiness or


dizziness.

Target Organ Systemic : Exposure routes: Inhalation, Ingestion


Toxicant - Repeated Target Organs: Central nervous system, Haematopoietic
exposure system

: Classified, Causes damage to organs through prolonged or


repeated exposure.

Aspiration hazard : Classified


May be fatal if swallowed and enters airways.

12. Ecological information

Ecotoxicology Assessment
Short-term (acute) aquatic : Classified, Toxic to aquatic life.
hazard
Long-term (chronic) : Classified, Harmful to aquatic life with long lasting effects.
aquatic hazard
Toxicity to fish : Toxic to fish (acute exposure).

: LC50: 5.5 mg/l


Exposure time: 96 HOURS
Species: Oncorhynchus kisutch (coho salmon)

Toxicity to daphnia and : Toxic to freshwater invertebrates (acute exposure)

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other aquatic invertebrates


: EC50: 3.78 mg/l
Exposure time: 48 HOURS
Species: Ceriodaphnia dubia (water flea)
(immobilization)

Toxicity to algae : Toxic to algae.

: NOEC: 10 mg/l
Exposure time: 96 HOURS
Species: Pseudokirchneriella subcapitata (green algae)
(growth rate)

Toxicity to bacteria : EC50: 84 mg/l


Exposure time: 24 HOURS
Toxic to sewage treatment plant microorganisms

Toxicity to fish (Chronic : Low chronic toxicity to fish.


toxicity)
NOEC: 1.4 mg/l
Exposure time: 40 d
Species: Oncorhynchus kisutch (coho salmon)

Toxicity to daphnia and : Harmful to aquatic invertebrates (chronic exposure)


other aquatic invertebrates
(Chronic toxicity)
0.74 mg/l
Exposure time: 7 d
Species: Ceriodaphnia dubia
(reproduction)

Persistence and degradability

Biodegradability : Rapidly degradable.

: Biodegradation: 80 %
(After 20 days in a ready biodegradability test)

Stability in water
benzene : Not expected to hydrolyze readily.

Stability in soil
toluene : Low potential for soil adsorption expected

benzene : Low potential for soil adsorption expected

Bioaccumulative potential
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Bioaccumulation : This material is not expected to bioaccumulate.

: Bioconcentration factor (BCF): 90

Mobility in soil

Distribution among environmental compartments


ethylbenzene : The atmosphere is the main environmental compartment for
releases of ethylbenzene (half-life approx. 1 day). In water,
volatilization to air and biodegradation will result in substantial
losses, with an estimated half-life of approx. 0.1 - 13 days.

Other adverse effects

Environmental fate and : No additional information available.


pathways
Other information

Additional ecological : No additional information available.


information

13. Disposal considerations

Waste treatment methods


Product : Contaminated product/soil/water may be U.S. Resource
Conservation and Recovery Act (RCRA)/U.S. Occupational
Safety and Health Administration (OSHA) hazardous waste
due to potentially low flash point.
Comply with federal, state, or local regulations for disposal.
Use registered transporters.

14. TRANSPORT INFORMATION

CFR_ROAD
UN number : 1294
Description of the goods : TOLUENE
Class : 3
Packing group : II
Labels : 3

Marine pollutant : no

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CFR_RAIL
UN number : 1294
Description of the goods : TOLUENE
Class : 3
Packing group : II
Labels : 3

Marine pollutant : no

BLG (MARPOL Annex II)


Description of the goods : TOLUENE
Pollution category : Y
Ship type : 3

15. REGULATORY INFORMATION

TSCA 12b

No substances are subject to TSCA 12(b) export notification requirements.

Significant New Use Rules (SNUR)

No substances are subject to a Significant New Use Rule.

SARA 302/304

The following substance(s) is/are regulated under SARA 302/304:

Component CASRN TPQ RQ

Toluene 108-88-3 1000 lbs


Benzene 71-43-2 10 lbs
Ethyl Benzene 100-41-4 1000 lbs

SARA 311/312

Based upon available information, this material is classified as the following health and/or physical
hazards according to Section 311 & 312:

Flammable (gases, aerosols, liquids, or solids)


Skin corrosion or irritation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (single or repeated
exposure)

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Aspiration hazard

SARA 313

This product contains the following chemicals subject to the reporting requirements of SARA Title III,
Section 313 and 40 CFR 372:

Component CASRN Reporting Threshold

Toluene 108-88-3 1.0%


Benzene 71-43-2 0.1%
Ethyl Benzene 100-41-4 0.1%

State Reporting

This material contains the following chemical substance which is regulated under California
Proposition 65. However, it is the responsibility of the California business owner to develop his or her
own regulatory compliance plan. Contact Product Safety for further information at
[Link]@[Link].

Substance CASRN Type of Toxicity


Carcinogen Developmental Repro-Male Repro-
Female
Toluene 108-88-3 X
Benzene 71-43-2 X X X
Ethyl Benzene 100-41-4 X

This product contains the following chemicals regulated by New Jersey's Worker and Community
Right to Know Act:

108-88-3 Toluene
71-43-2 Benzene
100-41-4 Ethyl Benzene

This product contains the following chemicals regulated by Massachusetts' Right to Know Law:

108-88-3 Toluene
71-43-2 Benzene

This product contains the following chemicals regulated by Pennsylvania's Right to Know Act:

108-88-3 Toluene
71-43-2 Benzene
100-41-4 Ethyl Benzene

Other international regulations

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SAFETY DATA SHEET

TOLUENE COMMERCIAL GRADE Gen. Variant: SDS_US_GHS


Version 1.3 Revision Date 11/22/2019 Print Date 12/16/2021 SDS No.: 48

Global Inventory Status


The ingredients of this product are compliant with the following chemical inventory requirements or
exemptions.
*Additional Explanatory Status Statements follow the table, as necessary.

Country/Region Inventory Status Description


Australia AICS Compliant
Canada DSL Compliant
China IECSC Compliant
Europe REACH See REACH Compliance Statement
Japan ENCS Compliant
Korea KECI Compliant
New Zealand NZIoC Compliant
Philippines PICCS Compliant
United States of America TSCA Compliant
Taiwan TCSCA Compliant

REACh status
If the product has been purchased from any company of the LyondellBasell group of companies
registered in the European Union, we confirm that the chemical substance in this product has been
registered under REACh, in accordance with the deadlines set forth in REACh. (Regulation (EU) No.
1907/2006)

Contact [Link]@[Link] for additional global inventory information.

16. OTHER INFORMATION

Material safety datasheet sections which have been updated:

Revised Section(s): 15 16

HMIS Classification : Health Hazard: 4


Chronic Health Hazard: * 4* 3 0
Flammability: 3
Physical hazards: 0

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SAFETY DATA SHEET

TOLUENE COMMERCIAL GRADE Gen. Variant: SDS_US_GHS


Version 1.3 Revision Date 11/22/2019 Print Date 12/16/2021 SDS No.: 48

NFPA Classification : Health Hazard: 2


Fire Hazard: 3
Instability: 0 3
2 0

Further information

HMIS rating scale (0 = minimal hazard; 4 = severe hazard)


NFPA rating scale (0 = minimal hazard; 4 = severe hazard)

Disclaimer
Information in this document is accurate to the best of our knowledge at the date of publication.
The document is designed to provide users general information for safe handling, use,
processing, storage, transportation, disposal and release and does not c onstitute any warranty
or quality specification, either express or implied, including any warranty of merchantability or
fitness for any particular purpose. Users shall determine whether the product is suitable for
their use and can be used safely and legally.

In addition to any prohibitions of use specifically noted in this document, LyondellBasell may
further prohibit or restrict the sale of its products into certain applications. For further
information, please contact a LyondellBasell representative or visit the LyondellBasell website
at: [Link]
The Trade Name referenced in section 1 is a trademark owned or used by the LyondellBasell
family of companies.

Numerical Data Presentation


The presentation of numerical dat a, such as that used for physical and chemical properties and
toxicological values, is expressed using a comma (,) to separate digits into groups of three and
a period (.) as the decimal marker. For example, 1,234.56 mg/kg = 1 234,56 mg/kg.

Language Translations
The information presented in this document has been translated from English by a vendor
LyondellBasell believes to be reliable. LyondellBasell and its vendor have made a good -faith
effort to verify the accuracy of the translation, but assume no liability or other responsibility for
any errors that may have occurred. Please refer to our web site ([Link]) for
the original document written in English.

End of Material Safety Data Sheet

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