Toluene Safety Data Sheet Summary
Toluene Safety Data Sheet Summary
2. HAZARDS IDENTIFICATION
GHS Classification
Label elements
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Hazard symbols :
Precautionary : Prevention
Statements P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been
read and understood.
P210 Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P271 Use only outdoors or in a well-ventilated area.
P242 Use non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash hands thoroughly after handling.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P263 Avoid contact during pregnancy/ while nursing.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P370 + P378 In case of fire: Use alcohol-resistant foam,
carbon dioxide or water mist for extinction.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
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Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
P233 Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Components
Chemical name CAS-No. Weight % Component
EC-No. Type
Toluene 108-88-3 95.0 - 99.0 % A
Key:
(A) Substance
(C) Impurity
General advice : Take proper precautions to ensure your own health and safety
before attempting rescue and providing first aid.
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In case of skin contact : Take off contaminated clothing and shoes immediately.
In case of contact, immediately flush skin with soap and plenty
of water.
Wash off immediately with plenty of water for at least 15
minutes.
Seek medical attention if ill effect or irritation develops.
In case of eye contact : In case of eye contact, remove contact lens and rinse
immediately with plenty of water, also under the eyelids, for at
least 15 minutes.
If eye irritation persists, consult a specialist.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
DO NOT induce vomiting. If vomiting does occur, have victim
lean forward to reduce risk of aspiration. Get medical attention
immediately.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Notes to physician
Symptoms : Signs of eye, throat, and respiratory tract irritation (cough and
difficulty breathing), CNS depression (fatigue, dizziness,
headache, collapse, coma and death) and possible cardiac
sensitization may occur after exposure to high vapor
concentrations.
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5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : SMALL FIRE: Use dry chemical, CO2, water spray or regular
foam. LARGE FIRE: Use water spray, water fog or regular
foam. Do not use straight streams.
Specific hazards during fire : Flammable vapors may be heavier than air.
fighting Extremely flammable vapors may be generated by material
(flash point < freezing point) below normal ambient
temperatures.
Fine sprays/mists may be combustible at temperatures below
normal flash point.
Vapors may travel long distances along the ground before
reaching a source of ignition and flashing back.
Fight fire from maximum distance or use unmanned hose
holders or monitor nozzles.
Apply water spray/fog for cooling.
Do not use solid water stream - may spread fire.
Move containers from fire area if it can be done without risk.
Blanket with firefighting foam.
Withdraw immediately in case of rising sound from venting
safety devices or discoloration of tank.
Heat may build enough pressure to rupture closed
containers/spreading fire/increasing risk of burns/injuries.
Always stay away from tanks engulfed in fire.
For massive fire, use unmanned hose holders or monitor
nozzles; if this is impossible, withdraw from area and let fire
burn.
This material releases flammable vapors at well below ambient
temperatures and may form flammable mixtures with air.
When mixed with air in certain proportions and exposed to an
ignition source, these vapors can burn in the open or be
explosive in confined spaces. Being heavier than air, these
vapors may travel long distances along the ground before
reaching a point of ignition and flashing back.
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Control parameters
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Remarks: 10 minutes
Remarks: 10 minutes
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Exposure controls
Engineering measures
Both local exhaust and good general room ventilation must be provided not only to control
exposure but also to prevent formation of flammable mixtures.
Special attention should be given to low areas/pits where flammable vapors can accumulate.
Eye and face protection : Eye protection such as chemical splash goggles and/or face
shield must be worn when possibility exists for eye contact
due to splashing or spraying liquid, airborne particles, or
vapor.
Skin and body protection : Protective clothing including gloves, apron, sleeves, boots,
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Appearance : liquid
Color : Colorless.
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Conditions to avoid : Avoid contact with strong oxidizers, excessive heat, sparks or
open flame.
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Acute toxicity
: Respiratory sensitization
Not classified
No study available.
Chronic toxicity
Carcinogenicity : Classified
May cause cancer.
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Reproductive toxicity
Effects on fertility / : Classified
Effects on or via lactation May cause harm to breast-fed children.
Ecotoxicology Assessment
Short-term (acute) aquatic : Classified, Toxic to aquatic life.
hazard
Long-term (chronic) : Classified, Harmful to aquatic life with long lasting effects.
aquatic hazard
Toxicity to fish : Toxic to fish (acute exposure).
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SAFETY DATA SHEET
: NOEC: 10 mg/l
Exposure time: 96 HOURS
Species: Pseudokirchneriella subcapitata (green algae)
(growth rate)
: Biodegradation: 80 %
(After 20 days in a ready biodegradability test)
Stability in water
benzene : Not expected to hydrolyze readily.
Stability in soil
toluene : Low potential for soil adsorption expected
Bioaccumulative potential
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SAFETY DATA SHEET
Mobility in soil
CFR_ROAD
UN number : 1294
Description of the goods : TOLUENE
Class : 3
Packing group : II
Labels : 3
Marine pollutant : no
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SAFETY DATA SHEET
CFR_RAIL
UN number : 1294
Description of the goods : TOLUENE
Class : 3
Packing group : II
Labels : 3
Marine pollutant : no
TSCA 12b
SARA 302/304
SARA 311/312
Based upon available information, this material is classified as the following health and/or physical
hazards according to Section 311 & 312:
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SAFETY DATA SHEET
Aspiration hazard
SARA 313
This product contains the following chemicals subject to the reporting requirements of SARA Title III,
Section 313 and 40 CFR 372:
State Reporting
This material contains the following chemical substance which is regulated under California
Proposition 65. However, it is the responsibility of the California business owner to develop his or her
own regulatory compliance plan. Contact Product Safety for further information at
[Link]@[Link].
This product contains the following chemicals regulated by New Jersey's Worker and Community
Right to Know Act:
108-88-3 Toluene
71-43-2 Benzene
100-41-4 Ethyl Benzene
This product contains the following chemicals regulated by Massachusetts' Right to Know Law:
108-88-3 Toluene
71-43-2 Benzene
This product contains the following chemicals regulated by Pennsylvania's Right to Know Act:
108-88-3 Toluene
71-43-2 Benzene
100-41-4 Ethyl Benzene
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REACh status
If the product has been purchased from any company of the LyondellBasell group of companies
registered in the European Union, we confirm that the chemical substance in this product has been
registered under REACh, in accordance with the deadlines set forth in REACh. (Regulation (EU) No.
1907/2006)
Revised Section(s): 15 16
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SAFETY DATA SHEET
Further information
Disclaimer
Information in this document is accurate to the best of our knowledge at the date of publication.
The document is designed to provide users general information for safe handling, use,
processing, storage, transportation, disposal and release and does not c onstitute any warranty
or quality specification, either express or implied, including any warranty of merchantability or
fitness for any particular purpose. Users shall determine whether the product is suitable for
their use and can be used safely and legally.
In addition to any prohibitions of use specifically noted in this document, LyondellBasell may
further prohibit or restrict the sale of its products into certain applications. For further
information, please contact a LyondellBasell representative or visit the LyondellBasell website
at: [Link]
The Trade Name referenced in section 1 is a trademark owned or used by the LyondellBasell
family of companies.
Language Translations
The information presented in this document has been translated from English by a vendor
LyondellBasell believes to be reliable. LyondellBasell and its vendor have made a good -faith
effort to verify the accuracy of the translation, but assume no liability or other responsibility for
any errors that may have occurred. Please refer to our web site ([Link]) for
the original document written in English.
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