110-2 G10 Chemistry(R) Weekly Test-6
Class: number: name:
Ch.14
I. Multiple Choice Questions (50%; 5% for each question)
Identify the choice that best completes the statement or answers the question
1. Which of the following equations’ equilibrium constant (Kc) expression includes [H2O]?
(A)C6H14(l) ⇌ C6H12(l) + H2(g)
(B)HF(aq) + H2O(l) ⇌ H3O+(aq) + F–(aq)
(C)NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH–(aq)
(D)2H2(g) + O2(g) ⇌ 2H2O(g)
(E)Mg(OH)2(s) + 2HF(aq) ⇌ Mg2+(aq) + 2F–(aq) + 2H2O(l)
2. The Kc for the reaction 2HCl(g) ⇌ H2(g) + Cl2(g) is 4.0×10 34. What is the Kc for the reaction 0.5H2(g) + 0.5Cl2(g) ⇌ HCl(g)?
(A) 4.0×10 34 (B) 2.0×10 34 (C) 2.0×10 17 (D) 5.0×1016 (E) 1.6×10 67
3. Which of the following factors affects equilibrium constants?
(A)temperature (B)the concentration of reactants (C)the concentration of products (D)catalysts (E)the volume of container
4. In which of the following reactions will Kc = Kp?
(A)4NH3(g) + 3O2(g) ⇌ 2N2(g) + 6H2O(g) (B)SO3(g) + NO(g) ⇌ SO2(g) + NO2(g) (C)2N2(g) + O2(g) ⇌ 2N2O(g)
(D)2SO2(g) + O2(g) ⇌ 2SO3(g) (E)NH3(g) + HCl(g) ⇌ NH4Cl(s)
5. Determine the value of Kp for the following reaction if the equilibrium pressures are as follows:
2CO(g) + O2(g) ⇌ 2CO2(g)
CO = 2.0 atm, O2 = 1.0 atm, CO2 = 4.0 atm
(A)2.0 (B)4.0 (C)8.0 (D)16.0 (E)32.0
6. Consider the following reaction and its equilibrium constant:
SO2(g) + NO2(g) ⇌ SO3(g) + NO(g) Kc = 0.33
Which of the following states will react and shift in the direction of products?
(A)[SO2] = 0.1 M, [NO2] = 0.2 M, [SO3] = 1.0 M, [NO] = 1.0 M
(B)[SO2] = 1.0 M, [NO2] = 1.0 M, [SO3] = 1.0 M, [NO] = 0.33 M
(C)[SO2] = 2.0 M, [NO2] = 0.2 M, [SO3] = 2.0 M, [NO] = 1.0 M
(D)[SO2] = 2.0 M, [NO2] = 1.0 M, [SO3] = 0.1 M, [NO] = 0.5 M
(E)[SO2] = 2.0 M, [NO2] = 2.0 M, [SO3] = 2.0 M, [NO] = 0.66 M
7. At equilibrium, the pressure of the reacting mixture is 0.105 atm at 350°C. Calculate Kp for this reaction.
CaCO3(s) ⇌ CaO(s) + CO2(g)
(A)0.105 atm (B)3.66×10 3 atm (C)2.05×10 3 atm (D)1.90×10 3 atm (E)1.00 atm
8. Consider the following equilibrium system involving SO2, Cl2, and SO2Cl2:
SO2(g) + Cl2(g) ⇌ SO2Cl2(g)
The temperature remains constant. Which of the following stresses would change equilibrium position toward the direction of
products?
(A)Adding SO2Cl2(g) under constant volume (B)Adding Cl2(g) under constant volume
(C)Doubling the container’s volume (D)Adding catalyst into the container
(E)Adding Helium (He) under constant volume
9. Consider the following equilibrium system involving NO2 and N2O4:
2NO2(g) ⇌ N2O4(g)
The temperature remains constant. Which of the following stresses would make the concentration of NO2(g) lower when new
equilibrium achieves?
(A)Adding NO2 under constant volume (B)Removing NO2 under constant volume
(C)Adding catalyst into the container (D)Reducing the volume of the container by half
(E)Increasing total pressure to the system
10. Consider the following equilibrium system involving NO2 (reddish-brown) and N2O4 (colorless):
2NO2(g) ⇌ N2O4(g)
Which of the following statements is not correct at equilibrium?
(A)The color of the gas mixture remains fixed.
(B)The partial pressure of N2O4(g) remains fixed.
(C)The concentration of NO2(g) remains fixed.
(D)The forward rate of the reaction is equal to the reverse rate of the reaction.
(E)Equilibrium is a static state. There are no reactants reacting to form products.
II. Free Response Questions (55%)
Show your work clearly and circle your final answer. Don’t forget to write down the answer’s unit.
11. Express the conc. equilibrium constant (Kc) for the following reaction. (12%; 3% for each)
(a)H2(g) + Br2(g) ⇌ 2HBr(g)
(b)2NH3(g) ⇌ N2(g) + 3H2(g)
(c)CaCO3(s) ⇌ CaO(s) + CO2(g)
(d)2CrO42 (aq) + 2H+(aq) ⇌ Cr2O72 (aq) + H2O(l)
12. Consider the following reaction:
CO(g) + Cl2(g) ⇌ COCl2(g)
A reaction mixture initially contains 0.5 M CO and 0.5 M Cl2. Determine the equilibrium concentration of CO if Kc for the
reaction at this temperature is 5×109.(6%)
13. Consider the following reaction:
CO(g) + H2O(g) ⇌ CO2(g) + H2(g)
A reaction mixture initially contains 1.0 mol CO(g), 1.0 mol H2O(g), 2.0 mol CO2(g) and 2.0 mol H2(g) in a 2.0 L vessel. The Kc for the
reaction at this temperature is 16.
(a)What is the initial concentration (molarity) of the four gases? (4%; 1% for each)
(b)What is the equilibrium concentration (molarity) of the four gases? (12%; 3% for each)
14. Equilibrium constant Kc for the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g) is 20 at 227°C. In one experiment 2.00 mol SO2 and 2.00 mol O2
were initially present in a flask.
(a)Which one is limiting reagent? SO2 or O2? (2%)
(b)How many moles of SO3 produced if the percent yield is 80.0%? (3%)
(c)What is the volume of the flask? (5%)
(d)What is the concentration (molarity) of O2 at equilibrium? (3%)
(e)What is the partial pressure of O2 at equilibrium? (3%)