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Geochemical Analysis of Brofoyedru Soils

The document discusses the geochemistry of soils in the Brofoyedu area, focusing on minor and trace elements through various statistical techniques such as correlation analysis, principal components analysis, factor analysis, and cluster analysis. It outlines the methods for analyzing relationships between variables, reducing data dimensions, and visualizing spatial distributions of geochemical data. The report includes figures that illustrate positive and negative correlations, as well as spatial distribution plots related to environmental phenomena.

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Adu Gilbert
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0% found this document useful (0 votes)
17 views10 pages

Geochemical Analysis of Brofoyedru Soils

The document discusses the geochemistry of soils in the Brofoyedu area, focusing on minor and trace elements through various statistical techniques such as correlation analysis, principal components analysis, factor analysis, and cluster analysis. It outlines the methods for analyzing relationships between variables, reducing data dimensions, and visualizing spatial distributions of geochemical data. The report includes figures that illustrate positive and negative correlations, as well as spatial distribution plots related to environmental phenomena.

Uploaded by

Adu Gilbert
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

KWAME NKRUMAH UNIVERSITY OF SCIENCE AND

TECHNOLOGY, KNUST; KUMASI. 

 GEOLOGICAL ENGINEERING DEPARTMENT 

TOPIC: MINOR AND TRACE ELEMENTS GEOCHEMISTRY OF SOILS


IN BROFOYEDU AREA, ASHANTI REGION.

SUPERVISOR: Dr. O.B. Nuamah

MEMBERS: Acheampong Solomon, Baku Aremiyaw and Owusu-Bempong


Theophilus

Assignment 2: Multivariate Techniques

DATE: 16th March, 2022.


Table of Contents
Table of Contents.............................................................................................................................1

Table of figures................................................................................................................................1

CORRELATION ANALYSIS........................................................................................................2

Positive correlation......................................................................................................................3

Negative Correlation....................................................................................................................3

No Correlation..............................................................................................................................4

Principal Components Analysis.......................................................................................................5

Factor Analysis................................................................................................................................5

Differences between the Principal Component Analysis and the Factor Analysis.........................6

CLUSTER ANALYSIS...................................................................................................................6

SPATIAL DISTRIBUTION PLOTS...............................................................................................7

Table of figures.

Figure 1. Positive correlation..........................................................................................................3


Figure 2. Negative correlation.........................................................................................................3
Figure 3. No Correlation..................................................................................................................4
Figure 4. The spatial distribution of earthquake stress rotations following large subduction zone
earthquakes......................................................................................................................................7
Figure 5. Spatial distribution of heavy metal concentrations surrounding a cement factory and its
effect on Astragalus gossypinus and wheat in Kurdistan Province, Iran........................................8
Figure 6. Spatial distribution of neighborhood-level housing prices and its association with all-
cause mortality in Seoul, Korea (2013–2018): A spatial panel data analysis.................................8

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CORRELATION ANALYSIS

Correlation Analysis is a statistical method that is used to discover if there is a relationship


between two variables/datasets, and how strong that relationship may be. They are used to
analyse qualitative and quantitative geochemical data gathered from exploration methods to
identify whether there is any significant connections, patterns or trends between the two.

Essentially, correlation analysis is used for spotting patterns with datasets. A positive correlation
result means that both variables increase in relation to each other, while a negative correlation
means that as one variable decreases, the other increases.

Two basic methods ae used whether the parameters associated with the data gathered. The two
terms to watch out for are:

 Parametric:(Pearson’s coefficient) where the data must be handled in relation to the


parameters of population or probability distributions. Typically used with quantitative
data already set out within said parameters.

 Non-Parametric:(Spearman’s coefficient) where no assumptions can be made about


the probability distribution. Typically used with qualitative data, but can be used with
quantitative data if spearman’s rank proves inadequate.

In cases when both are applicable, statisticians recommend using the parametric methods
such as Pearson’s coefficient, because they tend to be more precise. But that doesn’t mean
discount the non-parametric methods if there isn’t enough data or a more specified accurate
result.

Interpreting results

Typically, the best way to gain a generalized but more immediate interpretation of the results
of a set of data, is to visualize it on a scatter graph such as these.

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Positive correlation
Any score of +0.5 to +1 indicates a very strong positive correlation, which means that they
both increase at the same time. The line of best fit is placed best represent the data on the
graph. In this case, it is following the data upwards to indicate the positive correlation.

Figure 1. Positive correlation

Negative Correlation
Any score from -0.5 to -1 indicate a strong negative correlation, which means that as one
variable increases, the other decreases proportionally. The line of best fit can be seen here to
indicate the negative [Link] these cases is will slope downwards from the point of origin.

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Figure 2. Negative correlation.

No Correlation
Very simply, a score of zero indicates that there is no correlation, or relationship between two variables.
The larger the sample, the more accurate the result. No matter which formula is used, this fact will stand
true for all. The more data there is in putted into the formula, the more accurate the end result will be.

Figure 3. No Correlation
The cause of any relationship that may be discovered through the correlation analysis, is for the
researcher to determine through other means of statistical analysis, such as the coefficient of
determination analysis. However, this is a great amount of value that correlation analysis can
provide for egs the value dependency or the variables can be estimated.

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Principal Components Analysis

Principal components analysis is a geochemical technique that removes dependency or


redundancy in the data by dropping those features that contain the same information as given by
other [Link] the derived components of each other. In much sense, a component is a
derived new dimension (or variable) so that the derived variables are linearly independent of
each other

The approach of PCA is to reduce the unnecessary features, which are present in the data, this is
by creating or deriving new dimensions (or also referred to as components). These components
are a linear combination of the original variables.

Factor Analysis

Factor analysis is another multivariate technique whereby a factor is a common or underlying


element which several other variables are correlated. This is used to understand the underlying
cause which these factors capture much of the information of a set of variables in the dataset
data. The primary aspect of factor analysis is to unravel the latent (also known as the factors) that
store a variable’s spread (or the information).

Factor analysis is performed to decrease the large number of attributes into a smaller set of
factors. When analyzing data with many predictors, some of the features may have a common
theme amongst themselves. The features that have similar meaning underneath could be

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influencing the target variable by sharing this causation, and hence such features are combined
into one factor. Thus, a factor is a common element which several other variables are correlated.

Differences between the Principal Component Analysis and the Factor Analysis

 In principal components analysis, the goal is to explain as much of the total variance in
the variables as possible whereas in factor analysis, the original variables are defined as
linear combinations of the factors. The goal of factor analysis is to explain the
covariances or correlations between the variables.

 In principal components analysis, the components are calculated as linear combinations


of the original variables. In factor analysis, the original variables are defined as linear
combinations of the factors.

 Principal component analysis is used reduce the data into smaller number of components
but factor analysis is used to understand what constructs underlie the data.

CLUSTER ANALYSIS

Another interdependence technique, cluster analysis is used to group similar items within
a geochemical dataset into clusters, when grouping data into clusters, the aim is for the

5|Page
variables in one cluster to be more similar to each other than they are to variables in other
clusters. This measured in measured in terms of intracluster and intercluster distance.

Intracluster distance looks at the distance between data points within one cluster. This
should be small.

Intercluster distance looks at the distance between data points in different clusters. This
should be large or the intercluster distances are maximized. Cluster analysis helps you to
understand how data in your sample is distributed and to find patterns.

SPATIAL DISTRIBUTION PLOTS

A spatial distribution in statistics is a distribution or set of geographic observations representing


the values of behavior of a particular phenomenon or characteristic across many locations on the
surface of the Earth. A graphical display of a spatial distribution may summarize raw data
directly or may reflect the outcome of a more sophisticated data analysis. This graphical display
of the spatial distribution of raw data directly is called a Spatial Distribution Plot. Many
different aspects of a phenomenon can be shown in a single graphical display by using a suitable
choice of different colors to represent differences.

One example of such a display could be observations made to describe the geographic patterns of
features, both physical and human across the earth. The information included could be where
units of something are, how many units of the thing there are per units of area, and how sparsely
or densely packed they are from each other.

An example is shown in (Fig. 4, Fig. 5 and Fig. 7) below.

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Figure 4. The spatial distribution of earthquake stress rotations following large subduction zone
earthquakes.

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Figure 5. Spatial distribution of heavy metal concentrations surrounding a cement factory and
its effect on Astragalus gossypinus and wheat in Kurdistan Province, Iran.

Figure 6. Spatial distribution of neighborhood-level housing prices and its association with all-
cause mortality in Seoul, Korea (2013–2018): A spatial panel data analysis.

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Common questions

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Correlation analysis in geochemical studies is used to identify relationships between two variables or datasets and assess the strength of these relationships . It helps in spotting patterns within datasets, which is crucial for interpreting geochemical data from exploration methods . In positive correlation, scores range from +0.5 to +1, indicating that both variables increase together . Conversely, negative correlation scores range from -0.5 to -1, showing that as one variable increases, the other decreases .

The fundamental difference between PCA and Factor Analysis is their objectives and methodologies. PCA aims to explain as much of the total variance in the variables as possible by reducing data into fewer components that are linear combinations of the original variables . In contrast, Factor Analysis seeks to explain the covariances or correlations between variables by uncovering latent variables or 'factors,' which are used to express the original variables . These factors are presumed to underlie the variables and are defined as linear combinations of the factors themselves .

Principal Component Analysis (PCA) contributes to reducing dimensionality in geochemical datasets by transforming the original variables into a set of new, uncorrelated variables called principal components . These components are linear combinations of the original variables and capture the maximum variance within the data using fewer dimensions, thereby simplifying the dataset while retaining its essential information . This reduction process helps in eliminating redundancy and focusing on variables that contribute the most information .

The coefficient of determination, often denoted as R², plays a crucial role in correlation analysis by quantifying the proportion of variance in one variable that is predictable from another variable through their linear relationship . It helps in assessing the strength and significance of the relationship between variables, providing insight into how well the model explains the observed data . By understanding R², researchers can determine how effective a statistical model is in predicting outcomes, making it essential for evaluating the robustness of correlations identified .

Cluster analysis helps understand data distribution in geochemical datasets by grouping similar items into clusters, ensuring that data within a cluster is more similar compared to data in different clusters . The key concepts include intracluster distance, which measures how close or similar the data points within a single cluster are, and should be minimized for effective clustering. Intercluster distance measures the separation between clusters and should be maximized to ensure the clusters are distinct from each other .

Utilizing multivariate techniques such as PCA and Factor Analysis is important in geochemical research because these techniques allow researchers to handle complex datasets with multiple variables efficiently . PCA helps in dimensionality reduction by eliminating redundancy and focusing on key variables, while Factor Analysis identifies underlying factors or constructs that can explain observed correlations . These methods enable the simplification of data interpretation and help uncover patterns or relationships that might not be evident through univariate analysis, thereby improving the accuracy and depth of geochemical studies .

Spatial distribution plots are utilized in geochemical studies to visually display how a particular phenomenon or characteristic disperses across different geographical locations . These plots can summarize raw data or represent outcomes from sophisticated analyses, using color differentiation to show various aspects of the phenomenon . Examples include representing earthquake stress rotations following large subduction zone earthquakes, the spatial distribution of heavy metal concentrations around a cement factory, and neighborhood-level housing prices in relation to mortality rates in urban areas like Seoul, Korea .

A researcher might choose a non-parametric method like Spearman's coefficient over a parametric method like Pearson's when the data does not assume a parametric distribution, such as when dealing with qualitative data or when the assumptions required for parametric tests (like normality) are not met . Spearman's coefficient does not require assumptions about the data's distribution, making it preferable when handling data that may not fit the strict parameters needed for parametric testing .

Pearson's coefficient is suitable for quantitative data that adheres to parametric assumptions, such as normal distribution and linear relationships between variables . In contrast, Spearman's coefficient applies to both quantitative and qualitative data that do not necessarily meet parametric assumptions, analyzing ranked data and non-linear relationships . Pearson's is preferred when applicable because it tends to be more precise for normally distributed data, providing more reliable and accurate correlation coefficients due to leveraging parametric assumptions .

Spatial distribution plots enhance the interpretation of geochemical phenomena by providing a visual representation that is often more intuitive and easier to understand compared to traditional tabular data methods . These plots allow for the quick identification of patterns, trends, and anomalies over geographic regions, helping to contextualize and understand the spatial relationships between various elements or concentrations . Visualizations make data more accessible and interpretable, enabling researchers to make informed decisions and hypotheses about underlying geological processes .

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