starr (vms562) – Homework 9 – sutcliffe – (50985) 1

This print-out should have 22 questions.

Multiple-choice questions may continue on 1. −800 kJ
the next column or page – find all choices
before answering. 2. −50 kJ
What’s the chemical formula of water?
HIJKLMNO (a little geek humor for you) 3. −550 kJ
NOTE: Read the questions carefully. If it
asks for a CHANGE (Delta) in a quantity or 4. +450 kJ
the VALUE of that quantity, then you must
be sure to include the correct sign. Remem- 5. −950 kJ
ber that the quantities are for the SYSTEM,
unless stated differently, and sometimes we 004 10.0 points
switch our viewpoint of what the system is Calculate the energy required to heat 282 g
once we have finished a calculation. This cov- of mercury from 37 ◦ C to 42 ◦ C. The specific
ers Ch. 9. The rest will be on HW 10, the last heat capacity of Hg(ℓ) is 0.138 J/g ·◦ C.
HW. Answer in units of cal.

001 10.0 points 005 10.0 points

When a hydrocarbon is burned in the pres- How much energy would be required to melt
ence of oxygen, the amount of energy in the 48 g of HCl at its melting point of −110.8◦ C?
universe ∆Hfus for HCl is 14.2 cal/g and ∆Hvap for
HCl is 98.7 cal/g.
1. increases. Answer in units of cal.

2. decreases. 006 10.0 points

How many grams of water at 36.0◦ C must be
3. stays the same. added to 10.0 grams of ice at −20◦ C to result
in ONLY liquid water at 0◦ C?
002 10.0 points
A sample of an ideal gas having a volume of 1. 12.5 g
0.542 L at 298 K and 10.0 atm pressure is al-
lowed to expand against a constant opposing 2. 68.8 g
pressure of 0.793 atm until it has a volume of
1.000 L at 200 K and the pressure equals the 3. 21.2 g
opposing pressure. What is the work for the
system? 4. 22.4 g
Answer in units of J.
5. 11.2 g
003 10.0 points
A CD player and its battery together do 500 6. 74.0 g
kJ of work, and the battery also releases 250
kJ of energy as heat and the CD player re- 7. 109.2 g
leases 50 kJ as heat due to friction from spin-
ning. What is the change in internal energy 8. 24.9 g
of the system, with the system regarded as
the CD player alone? Assume that the bat- 9. 56.6 g
tery does 500 kJ of work on the CD player,
which then does the same amount of work on 10. 1.25 g
the surroundings.
 starr (vms562) – Homework 9 – sutcliffe – (50985) 2
007 10.0 points 3. ∆H = +590 kJ
Note: The heat capacity of BF3 is 3R
J/mol/k. Be sure to use the right value of 4. ∆U = −590 kJ
R!!
Calculate the final temperature when 2.50 5. ∆U = +11.8 kJ
kJ of energy is transferred as heat to 1.50 mol
BF3 at 298 K and 1 atm at constant volume. 6. ∆H = −590 kJ

1. 80◦ C 7. ∆H = +11.8 kJ

2. 67◦ C 8. ∆U = −11.8 kJ

3. 92◦ C 010 10.0 points

When 26 g of a metal at 86 ◦ C is added to
4. 125◦ C 47 g of water at 24◦ C, the temperature of the
water rises to 31.1 ◦C. What is the specific
5. 100◦ C heat capacity of the metal? Assume no heat
ws lost to the surroundings.
008 10.0 points J
Answer in units of .
Calculate the enthalpy change that occurs g ·◦ C
when 1 lb (454 g) of mercury freezes at its
011 10.0 points
freezing point (234.3 K). The standard en-
A sample of 2.01 grams of compound Y is
thalpy of fusion of mercury is 2.29 kJ · mol−1 .
burned completely in a bomb calorimeter
which contains 2500 g of water. The temper-
1. +2.29 kJ
ature rises from 25.347◦ C to 25.728◦ C. What
is ∆Urxn for the combustion of compound Y?
2. −5.18 kJ
The hardware component of the calorimeter
has a heat capacity of 3.66 kJ/◦ C. The spe-
3. +5.18 kJ
cific heat of water is 4.184 J/g ·◦C, and the
MW of Y is 101 g/mol.
4. −2.29 kJ
Answer in units of kJ/mol of Y.
5. −1.04 × 103 kJ
012 (part 1 of 2) 10.0 points
Suppose that coal of density 1.5 g/cm3 is pure
009 10.0 points
carbon. (It is, in fact, much more compli-
A 50 gram sample of delicious pork rinds is
cated, but this is a reasonable first approxima-
placed in an open, constant pressure calorime-
tion.) The combustion of carbon is described
ter that contains 3000 grams of water. The
by the equation
temperature of the water increases by 47◦ C
C(s) + O2 (g) −→ CO2 (g) ∆H ◦ = −394 kJ
when the pork rinds are combusted. The heat
What is the value of q (heat) when a lump
capacity of water is 4.184 J/g ◦ C. Assume the
of coal of size 8.5 cm×8 cm×7.5 cm is burned?
heat lost to the calorimeter itself or to the air
Answer in units of kJ.
is negligible. Which of the following is correct
for the SYSTEM?
013 (part 2 of 2) 10.0 points
What mass of water can be heated from 37◦ C
1. ∆U = +590 kJ
to 100◦ C by burning this piece of coal?
Answer in units of g.
2. ∆H = −11.8 kJ
 starr (vms562) – Homework 9 – sutcliffe – (50985) 3
014 10.0 points 3. an endothermic chemical change.
For the methanol combustion reaction
4. an endothermic phase change.
2 CH3OH(ℓ) + 3 O2 (g) −→
2 CO2 (g) + 4 H2 O(g) 5. an exothermic chemical change.
estimate the amount of P ∆V work done and
tell whether the work was done on or by the 017 10.0 points
system. Assume a temperature of 27◦ C. Calculate the reaction enthalpy for the com-
bustion of ethanol
1. 7.5 kJ, work done on the system
CH3 CH2 OH + 3 O2 → 2 CO2 + 3 H2O
2. 7.5 kJ, work done by the system given the data
5
3. No work is done in this reaction. C2 H2 + O2 → 2 CO2 + H2 O
2
∆Hrxn
◦
= −1300 kJ/mol
◦
4. 2.5 kJ, work done by the system C2 H2 + H2 → C2 H4 ∆Hrxn = −175 kJ/mol
C2 H4 + H2 O → CH3 CH2 OH
5. 2.5 kJ, work done on the system ∆Hrxn ◦
= −44 kJ/mol
1
H2 + O2 → H2 O ∆Hrxn◦
= −286 kJ/mol
015 10.0 points 2
HINT: You have been given the Enthalpy 1. −1717 kJ/mol
Change. You are looking for the Internal
Energy Change. You will need to write a 2. −1800 kJ/mol
chemical reaction - make sure you do it as
written below. 3. −1761 kJ/mol
The combustion of one mole of ethanol
(C2 H5 OH(ℓ)) to produce carbon dioxide and 4. None of these is correct.
gaseous water has ∆Hr = −1235 kJ · mol−1
at 298 K. What is the change in internal en- 5. −1367 kJ/mol
ergy for this reaction?
018 10.0 points
1. −1230 kJ · mol−1
For which reactions
I) O2 (g) + H2 (g) → H2 O2 (ℓ)
2. −1237 kJ · mol−1
II) C(s, diamond) + O2 (g) → CO2 (g)
III) N2 (ℓ) + 3 F2 (g) → 2 NF3 (ℓ)
3. −1240 kJ · mol−1 3
IV) C(s, graphite) + O2 (g) + H2 (g) →
2
4. −1247 kJ · mol−1 CO2 (g) + H2 O(g)
3
5. −1223 kJ · mol−1 V) 2 Fe(s) + O2 (g) → Fe2 O3 (s)
2
would ∆Hr◦ = ∆Hf◦ ?
016 10.0 points
A liquid freezes. 1. IV and V only
This process is
2. I and V only
1. an exothermic phase change.
3. I, III, IV and V only
2. neither endothermic nor exothermic.
4. II, III and IV only
 starr (vms562) – Homework 9 – sutcliffe – (50985) 4

5. I, II, III, IV and V 1. +312 kJ · mol−1

6. II and IV only 2. −472 kJ · mol−1

7. I, III and V only 3. +175 kJ · mol−1

8. I and II only 4. −124 kJ · mol−1

019 10.0 points 5. −36 kJ · mol−1

Calculate the standard reaction enthalpy
for the final stage in the production of nitric 021 10.0 points
acid, when nitrogen dioxide dissolves in and The energy change ∆H associated with the
reacts with water: reaction

3 NO2 (g) + H2 O(ℓ) → 2 HNO3 (aq) + NO(g) .

NBr3 (g) + 3 H2 O(g) → 3 HOBr(g) + NH3 (g)
The standard enthalpy of formation
for HNO3 is −207.36 kJ/mol, for NO is +81 kJ. NBr3 is arranged with all of the
90.25 kJ/mol, for NO2 33.18 kJ/mol, and bromines attached to the nitrogen and HOBr
for H2 O −285.83 kJ/mol. is arranged as H O Br. The strength of
the N Br bond is
1. −170.12 kJ/mol
1. 465 kJ/mol
2. −80.52 kJ/mol
2. 66 kJ/mol
3. −2000.2 kJ/mol
3. 128 kJ/mol
4. −138.18 kJ/mol
4. 280 kJ/mol
5. −160.32 kJ/mol
5. 155 kJ/mol
6. −150.23 kJ/mol
6. 248 kJ/mol
020 10.0 points
Calculate the standard enthalpy of formation 7. 4 kJ/mol
of bicyclo[1.1.0]butane
H 022 10.0 points
Consider the reaction
C
CH4 (g) + X2 (g) → CH3 X(g) + HX(g) ,
H2 C CH2
C where X is a halogen-like atom (Group 7A).
Calculate ∆H for this reaction if bond en-
H ergy tables give the following values:
given the standard enthalpies of formation of C H : 416 kJ/mol X X : 225 kJ/mol
717 kJ · mol−1 for C(g) and 218 kJ · mol−1 for
H X : 347 kJ/mol C X : 278 kJ/mol
H(g) and the average bond enthalpies of 412 Answer in units of kJ/mol.
kJ · mol−1 for C H and 348 kJ · mol−1 for
C C.