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Thermal Equilibrium Diagrams for Alloys

Thermal equilibrium diagrams contain information about phase changes that occur in alloys as their temperature changes. Key features include the liquidus line, which marks the boundary between the fully liquid and partially solid states, and the solidus line, which marks the boundary between partial and full solidification. Between these lines lies the pasty region where the alloy is partially liquid and partially solid simultaneously. Phase diagrams graphically represent the different phases that can exist in an alloy at varying temperatures and compositions, and describe the conditions required for phases to coexist in equilibrium.

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187 views3 pages

Thermal Equilibrium Diagrams for Alloys

Thermal equilibrium diagrams contain information about phase changes that occur in alloys as their temperature changes. Key features include the liquidus line, which marks the boundary between the fully liquid and partially solid states, and the solidus line, which marks the boundary between partial and full solidification. Between these lines lies the pasty region where the alloy is partially liquid and partially solid simultaneously. Phase diagrams graphically represent the different phases that can exist in an alloy at varying temperatures and compositions, and describe the conditions required for phases to coexist in equilibrium.

Uploaded by

Misbah Tehseen
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© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Task 4:

Thermal equilibrium diagram


Thermal equilibrium diagrams are special diagrams which contain
information about changes that take place in alloys. The temperature at
which a particular alloy changes from liquid to solid is an example of
the type of thermal information contained in a thermal equilibrium
diagram.

Liquidus line: for the alloy system this line represents the boundary
between the fully liquid state and the beginning of solidification.

Solidus line: the boundary line that determines the end of


solidification. Below this line, the alloy is completely solid.

Liquid region: the two metals are soluble in a liquid state.


Solid region: the two metals are soluble in a solid state.

Pasty region: between the liquidus and solidus lines, the alloy system is
in a partly liquid and a partly solid state.

Temperature time graph:

Temperature time graph including Quenching Lamelarizing and


tempring

Phase diagram:
Alloy metals can exist in different phases. Phases are physically homogeneous
states of an alloy. A phase has a precise chemical composition – a certain
arrangement and bonding between the atoms.
This structure of atoms imparts different properties to different phases. We can
choose the phase we want and use it in our applications.
Only some special alloys can exist in multiple phases. Heating the metal to specific
temperatures using heat treatment procedures results in different phases. Some
special alloys can exist in more than one phase at the same temperature.
Phase diagrams are graphical representations of the phases present in an alloy at
different conditions of temperature, pressure, or chemical composition.
The diagram describes the suitable conditions for two or more phases to exist in
equilibrium. For example, the water phase diagram describes a point (triple point)
where water can coexist in three different phases at the same time. This happens
at just above the freezing temperature (0.01°C) and 0.006 atm.
The iron-carbon phase diagram is widely used to understand the different phases
of steel and cast iron. Both steel and cast iron are a mix of iron and carbon. Also,
both alloys contain a small amount of trace elements.
The graph is quite complex but since we are limiting our exploration to Fe3C, we
will only be focusing up to 6.67 weight percent of carbon.
This iron carbon phase diagram is plotted with the carbon concentrations by
weight on the X-axis and the temperature scale on the Y-axis.

Refrences:
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