Practice Problems: Redox Reactions
1. Determine the oxidation number of the elements in each of the following
compounds:
a. H2CO3
b. N2
c. Zn(OH)42-
d. NO2-
e. LiH
f. Fe3O4
Hint: Review rules for assigning oxidation numbers.
2. Identify the species being oxidized and reduced in each of the following
reactions:
a. Cr+ + Sn4+ Cr3+ + Sn2+
b. 3 Hg2+ + 2 Fe (s) 3 Hg2 + 2 Fe3+
c. 2 As (s) + 3 Cl2 (g) 2 AsCl3
Hint: Look at oxidation numbers.
3. Would you use an oxidizing agent or reducing agent in order for the
following reactions to occur?
a. ClO3- ClO2
b. SO42- S2-
c. Mn2+ MnO2
d. Zn ZnCl2
Hint: Look at oxidation numbers. Remember an oxidizing agent (or oxidant) is one
that causes oxidation. It is reduced in the reaction. A reducing agent (reductant) is one
that causes the reduction in the redox reaction. It is oxidized in the reaction
4. Write balance equations for the following redox reactions:
a. NaBr + Cl2 NaCl + Br2
b. Fe2O3 + CO Fe + CO2 in acidic solution
c. CO + I2O5 CO2 + I2 in basic solution
Hint: Again start by looking at the oxidation numbers. Then work out the half
reactions. Balance these equations and combine.
5. Write balanced equations for the following reactions:
Hint: Determine the oxidation numbers first. Then get the half reactions.
a. Cr(OH)3 + Br2 CrO42- + Br- in basic solution
b. O2 + Sb H2O2 + SbO2- in basic solution
Hint: Remember that in peroxide, the oxidation number of oxygen is an
exception.
c. HCOOH + MnO4- CO2 + Mn2+ in acidic solution
d. ClO2- ClO2 + Cl- in acidic solution
Hint: In this problem ClO2- is both oxidized and reduced. Include it in both half
reactions.
6. Write the balanced half reactions of the following reactions:
a. NiO2 + 2 H2O + Fe Ni(OH)2 + Fe(OH)2 in basic solution
b. CO2 + 2 NH2OH CO + N2 + 3 H2O in basic solution
c. 2 H+ + H2O2 + 2 Fe2+ 2 Fe3+ + 2 H2O in acidic solution
d. H+ + 2 H2O + 2 MnO4- + 5 SO2 2 Mn2+ + 5 HSO4- in acidic solution
Hint: Look at only those elements involved in the actual reduction and oxidation.
Ignore H2O, OH-, and H+ as well as the coefficients. Then write the skeleton half
reactions that you can balance.