1

Case Name: Producción de [Link]

2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser3
4 USA
Date/Time: Wed May 05 [Link] 2021
5
6
7 Conversion Reactor: CRV-100
8
9
10
CONNECTIONS
11
12
Inlet Stream Connections
13 Stream Name From Unit Operation
14 FEED 1 Mixer MIX-100
15
16
Outlet Stream Connections
17 Stream Name To Unit Operation
18 PRODUCTO Distillation: T-101
19 RESIDUO
20
21
Energy Stream Connections
22 Stream Name From Unit Operation
23 Q-CALOR
24
25
PARAMETERS
26 Physical Parameters Optional Heat Transfer
27 Delta P Vessel Volume Duty Energy Stream
28 48.26 kPa * --- -1.277e+006 kJ/h Q-CALOR
29
30
REACTION DETAILS
31 Reaction: Rxn-1
32 Component Mole Weight Stoichiometric Coeff.
33 Ethylene 28.05 -2.000 *
34 i-Butane 58.12 -1.000 *
35 n-Octane 114.2 1.000 *
36
37 Reaction: Rxn-2
38 Component Mole Weight Stoichiometric Coeff.
39 Ethylene 28.05 -2.000 *
40 n-Butane 58.12 -1.000 *
41 n-Octane 114.2 1.000 *
42
43
44
REACTION RESULTS FOR : Set-1
45
46
Extents
47 Name Rank Specified Use Default Actual Base Reaction Extent
48 % Conversion % Conversion Component
49 Rxn-1 0* 80.00 Yes 81.95 Ethylene 2.351e-003
50 Rxn-2 0* 10.00 Yes 14.63 Ethylene 4.197e-004
51
52
Balance
53 Components Total Inflow Total Reaction Total Outflow
54
55 Nitrogen 2.737e-004 0.0000 2.737e-004
56 Ethylene 5.737e-003 -5.541e-003 1.958e-004
57 n-Butane 9.913e-003 -4.197e-004 9.494e-003
58 i-Butane 6.557e-003 -2.351e-003 4.206e-003
59 n-Octane 5.914e-004 2.771e-003 3.362e-003
60
61
RATING
62
63
Sizing
64 Cylinder Vertical Reactor has a Boot: No
65 Volume --- Diameter --- Height ---
66
67
Nozzles
68 Base Elevation Relative to Ground Level 0.0000 m * Diameter --- Height ---
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6
7 Conversion Reactor: CRV-100 (continued)
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9 FEED 1 PRODUCTO RESIDUO
10 Diameter (m) 5.000e-002 5.000e-002 5.000e-002
11 Elevation (Base) (m) 0.0000 0.0000 0.0000
12 Elevation (Ground) (m) 0.0000 0.0000 0.0000
13 Elevation (% of Height) (%) --- --- ---
14
15
CONDITIONS
16 Name FEED 1 RESIDUO PRODUCTO Q-CALOR
17 Vapour 0.9883 0.0000 1.0000 ---
18 Temperature (C) 32.6535 93.0000 93.0000 * ---
19 Pressure (psia) 19.2748 12.2748 12.2748 ---
20 Molar Flow (kgmole/h) 83.0622 0.0000 63.1128 ---
21 Mass Flow (kg/h) 4296.6224 0.0000 4296.6258 ---
22 Std Ideal Liq Vol Flow (m3/h) 7.8892 0.0000 7.0182 ---
23 Molar Enthalpy (kJ/kgmole) -8.472e+004 -2.209e+005 -1.317e+005 ---
24 Molar Entropy (kJ/kgmole-C) 158.4 97.27 175.8 ---
25 Heat Flow (kJ/h) -7.0369e+06 -0.0000e-01 -8.3143e+06 -1.2774e+06
26
27
PROPERTIES
28 Name FEED 1 RESIDUO PRODUCTO
29 Molecular Weight 51.73 107.8 68.08
30 Molar Density (kgmole/m3) 5.426e-002 5.768 2.829e-002
31 Mass Density (kg/m3) 2.807 621.5 1.926
32 Act. Volume Flow (m3/h) 1531 0.0000 2231
33 Mass Enthalpy (kJ/kg) -1638 -2050 -1935
34 Mass Entropy (kJ/kg-C) 3.061 0.9027 2.583
35 Heat Capacity (kJ/kgmole-C) 89.06 268.1 135.6
36 Mass Heat Capacity (kJ/kg-C) 1.722 2.488 1.991
37 LHV Molar Basis (Std) (kJ/kgmole) 2.357e+006 4.835e+006 3.073e+006
38 HHV Molar Basis (Std) (kJ/kgmole) 2.533e+006 5.185e+006 3.305e+006
39 HHV Mass Basis (Std) (kJ/kg) 4.897e+004 4.811e+004 4.855e+004
40 CO2 Loading --- --- ---
41 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
42 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
43 LHV Mass Basis (Std) (kJ/kg) 4.556e+004 4.486e+004 4.514e+004
44 Phase Fraction [Vol. Basis] 0.9822 --- 1.000
45 Phase Fraction [Mass Basis] 0.9778 0.0000 1.000
46 Phase Fraction [Act. Vol. Basis] 0.9999 --- 1.000
47 Mass Exergy (kJ/kg) 12.71 15.91 19.07
48 Partial Pressure of CO2 (psia) 0.0000 0.0000 0.0000
49 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
50 Act. Gas Flow (ACT_m3/h) 1531 --- 2231
51 Avg. Liq. Density (kgmole/m3) 10.53 --- 8.993
52 Specific Heat (kJ/kgmole-C) 89.06 268.1 135.6
53 Std. Gas Flow (STD_m3/h) 1964 0.0000 1492
54 Std. Ideal Liq. Mass Density (kg/m3) 544.6 695.8 612.2
55 Act. Liq. Flow (m3/s) 3.957e-005 0.0000 ---
56 Z Factor --- --- ---
57 Watson K 14.00 12.70 13.20
58 User Property --- --- ---
59 Partial Pressure of H2S (psia) 0.0000 0.0000 0.0000
60 Cp/(Cp - R) 1.103 1.032 1.065
61 Cp/Cv 1.112 1.032 1.070
62 Ideal Gas Cp/Cv 1.105 1.041 1.066
63 Ideal Gas Cp (kJ/kgmole-C) 87.63 213.3 134.9
64 Mass Ideal Gas Cp (kJ/kg-C) 1.694 1.979 1.982
65 Heat of Vap. (kJ/kgmole) 3.707e+004 4.840e+004 5.367e+004
66 Kinematic Viscosity (cSt) --- 0.3816 4.502
67 Liq. Mass Density (Std. Cond) (kg/m3) 553.4 700.5 617.4
68 Liq. Vol. Flow (Std. Cond) (m3/h) 7.764 0.0000 6.960
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Date/Time: Wed May 05 [Link] 2021
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7 Conversion Reactor: CRV-100 (continued)
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9
10
PROPERTIES
11 Name FEED 1 RESIDUO PRODUCTO
12 Liquid Fraction 1.173e-002 1.000 0.0000
13 Molar Volume (m3/kgmole) 18.43 0.1734 35.34
14 Mass Heat of Vap. (kJ/kg) 716.5 449.1 788.4
15 Phase Fraction [Molar Basis] 0.9883 0.0000 1.0000
16 Surface Tension (dyne/cm) 17.53 13.63 ---
17 Thermal Conductivity (W/m-K) --- 0.1031 2.108e-002
18 Bubble Point Pressure (psia) 364.9 26.01 288.5
19 Viscosity (cP) --- 0.2372 8.671e-003
20 Cv (Semi-Ideal) (kJ/kgmole-C) 80.75 259.8 127.3
21 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.561 2.411 1.869
22 Cv (kJ/kgmole-C) 80.08 259.8 126.7
23 Mass Cv (kJ/kg-C) 1.548 2.411 1.861
24 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
25 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
26 Cp/Cv (Ent. Method) --- --- ---
27 Reid VP at 37.8 C (psia) 208.4 6.449 62.64
28 True VP at 37.8 C (psia) 385.3 7.451 183.2
29 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 7.771 0.0000 6.960
30 Viscosity Index -35.55 -15.19 -40.37
31
Fluid Package: Basis-1
32 Material Stream: FEED Property Package: Peng-Robinson
33
34
35
CONDITIONS
36 Overall Vapour Phase
37 Vapour / Phase Fraction 1.0000 1.0000
38 Temperature: (C) 93.00 * 93.00
39 Pressure: (psia) 20.00 * 20.00
40 Molar Flow (kgmole/h) 35.10 * 35.10
41 Mass Flow (kg/h) 1436 1436
42 Std Ideal Liq Vol Flow (m3/h) 3.000 3.000
43 Molar Enthalpy (kJ/kgmole) -2.168e+004 -2.168e+004
44 Molar Entropy (kJ/kgmole-C) 185.1 185.1
45 Heat Flow (kJ/h) -7.609e+005 -7.609e+005
46 Liq Vol Flow @Std Cond (m3/h) 2.982 * 2.982
47
48
PROPERTIES
49 Overall Vapour Phase
50 Molecular Weight 40.90 40.90
51 Molar Density (kgmole/m3) 4.575e-002 4.575e-002
52 Mass Density (kg/m3) 1.871 1.871
53 Act. Volume Flow (m3/h) 767.2 767.2
54 Mass Enthalpy (kJ/kg) -529.9 -529.9
55 Mass Entropy (kJ/kg-C) 4.526 4.526
56 Heat Capacity (kJ/kgmole-C) 78.13 78.13
57 Mass Heat Capacity (kJ/kg-C) 1.910 1.910
58 LHV Molar Basis (Std) (kJ/kgmole) 1.889e+006 1.889e+006
59 HHV Molar Basis (Std) (kJ/kgmole) 2.023e+006 2.023e+006
60 HHV Mass Basis (Std) (kJ/kg) 4.946e+004 4.946e+004
61 CO2 Loading --- ---
62 CO2 App ML Con (kgmole/m3) --- ---
63 CO2 App WT Con (kgmol/kg) --- ---
64 LHV Mass Basis (Std) (kJ/kg) 4.618e+004 4.618e+004
65 Phase Fraction [Vol. Basis] 1.000 1.000
66 Phase Fraction [Mass Basis] 1.000 1.000
67 Phase Fraction [Act. Vol. Basis] 1.000 1.000
68 Mass Exergy (kJ/kg) 30.67 ---
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Fluid Package: Basis-1
7 Material Stream: FEED (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Vapour Phase
12 Partial Pressure of CO2 (psia) 0.0000 ---
13 Cost Based on Flow (Cost/s) 0.0000 0.0000
14 Act. Gas Flow (ACT_m3/h) 767.2 767.2
15 Avg. Liq. Density (kgmole/m3) 11.70 11.70
16 Specific Heat (kJ/kgmole-C) 78.13 78.13
17 Std. Gas Flow (STD_m3/h) 829.9 829.9
18 Std. Ideal Liq. Mass Density (kg/m3) 478.6 478.6
19 Act. Liq. Flow (m3/s) --- ---
20 Z Factor 0.9901 0.9901
21 Watson K 15.13 15.13
22 User Property --- ---
23 Partial Pressure of H2S (psia) 0.0000 ---
24 Cp/(Cp - R) 1.119 1.119
25 Cp/Cv 1.124 1.124
26 Ideal Gas Cp/Cv 1.120 1.120
27 Ideal Gas Cp (kJ/kgmole-C) 77.74 77.74
28 Mass Ideal Gas Cp (kJ/kg-C) 1.901 1.901
29 Heat of Vap. (kJ/kgmole) 2.252e+004 ---
30 Kinematic Viscosity (cSt) 5.962 5.962
31 Liq. Mass Density (Std. Cond) (kg/m3) 481.5 481.5
32 Liq. Vol. Flow (Std. Cond) (m3/h) 2.982 2.982
33 Liquid Fraction 0.0000 0.0000
34 Molar Volume (m3/kgmole) 21.86 21.86
35 Mass Heat of Vap. (kJ/kg) 550.6 ---
36 Phase Fraction [Molar Basis] 1.0000 1.0000
37 Surface Tension (dyne/cm) --- ---
38 Thermal Conductivity (W/m-K) 2.567e-002 2.567e-002
39 Bubble Point Pressure (psia) --- ---
40 Viscosity (cP) 1.116e-002 1.116e-002
41 Cv (Semi-Ideal) (kJ/kgmole-C) 69.81 69.81
42 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.707 1.707
43 Cv (kJ/kgmole-C) 69.48 69.48
44 Mass Cv (kJ/kg-C) 1.699 1.699
45 Cv (Ent. Method) (kJ/kgmole-C) --- ---
46 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
47 Cp/Cv (Ent. Method) --- ---
48 Reid VP at 37.8 C (psia) 440.8 440.8
49 True VP at 37.8 C (psia) 600.7 600.7
50 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2.982 2.982
51 Viscosity Index -3.001 ---
52
53
COMPOSITION
54
55
Overall Phase Vapour Fraction 1.0000

56 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
57 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
58 Nitrogen 0.1000 * 0.0028 * 2.8013 * 0.0020 * 0.0035 * 0.0012 *
59 Ethylene 20.0000 * 0.5698 * 561.0760 * 0.3908 * 1.4641 * 0.4880 *
60 n-Butane 5.0000 * 0.1425 * 290.6200 * 0.2024 * 0.4983 * 0.1661 *
61 i-Butane 10.0000 * 0.2849 * 581.2400 * 0.4048 * 1.0343 * 0.3447 *
62 n-Octane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
63 Total 35.1000 1.0000 1435.7373 1.0000 3.0002 1.0000
64
65
Vapour Phase Phase Fraction 1.000

66 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
67 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
68 Nitrogen 0.1000 0.0028 2.8013 0.0020 0.0035 0.0012
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Fluid Package: Basis-1
7 Material Stream: FEED (continued) Property Package: Peng-Robinson
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COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 20.0000 0.5698 561.0760 0.3908 1.4641 0.4880
16 n-Butane 5.0000 0.1425 290.6200 0.2024 0.4983 0.1661
17 i-Butane 10.0000 0.2849 581.2400 0.4048 1.0343 0.3447
18 n-Octane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 35.1000 1.0000 1435.7373 1.0000 3.0002 1.0000
20
Fluid Package: Basis-1
21 Material Stream: FONDO Property Package: Peng-Robinson
22
23
24
CONDITIONS
25 Overall Liquid Phase
26 Vapour / Phase Fraction 0.0000 1.0000
27 Temperature: (C) 118.5 118.5
28 Pressure: (psia) 12.00 12.00
29 Molar Flow (kgmole/h) 9.734 9.734
30 Mass Flow (kg/h) 1112 1112
31 Std Ideal Liq Vol Flow (m3/h) 1.576 1.576
32 Molar Enthalpy (kJ/kgmole) -2.242e+005 -2.242e+005
33 Molar Entropy (kJ/kgmole-C) 114.0 114.0
34 Heat Flow (kJ/h) -2.182e+006 -2.182e+006
35 Liq Vol Flow @Std Cond (m3/h) 1.570 * 1.570
36
37
PROPERTIES
38 Overall Liquid Phase
39 Molecular Weight 114.2 114.2
40 Molar Density (kgmole/m3) 5.404 5.404
41 Mass Density (kg/m3) 617.4 617.4
42 Act. Volume Flow (m3/h) 1.801 1.801
43 Mass Enthalpy (kJ/kg) -1962 -1962
44 Mass Entropy (kJ/kg-C) 0.9981 0.9981
45 Heat Capacity (kJ/kgmole-C) 297.5 297.5
46 Mass Heat Capacity (kJ/kg-C) 2.604 2.604
47 LHV Molar Basis (Std) (kJ/kgmole) 5.118e+006 5.118e+006
48 HHV Molar Basis (Std) (kJ/kgmole) 5.488e+006 5.488e+006
49 HHV Mass Basis (Std) (kJ/kg) 4.804e+004 4.804e+004
50 CO2 Loading --- ---
51 CO2 App ML Con (kgmole/m3) --- ---
52 CO2 App WT Con (kgmol/kg) --- ---
53 LHV Mass Basis (Std) (kJ/kg) 4.481e+004 4.481e+004
54 Phase Fraction [Vol. Basis] 0.0000 1.000
55 Phase Fraction [Mass Basis] 0.0000 1.000
56 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
57 Mass Exergy (kJ/kg) 29.59 ---
58 Partial Pressure of CO2 (psia) 0.0000 ---
59 Cost Based on Flow (Cost/s) 0.0000 0.0000
60 Act. Gas Flow (ACT_m3/h) --- ---
61 Avg. Liq. Density (kgmole/m3) 6.175 6.175
62 Specific Heat (kJ/kgmole-C) 297.5 297.5
63 Std. Gas Flow (STD_m3/h) 230.2 230.2
64 Std. Ideal Liq. Mass Density (kg/m3) 705.4 705.4
65 Act. Liq. Flow (m3/s) 5.003e-004 5.003e-004
66 Z Factor 4.701e-003 4.701e-003
67 Watson K 12.67 12.67
68 User Property --- ---
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Date/Time: Wed May 05 [Link] 2021
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Fluid Package: Basis-1
7 Material Stream: FONDO (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Liquid Phase
12 Partial Pressure of H2S (psia) 0.0000 ---
13 Cp/(Cp - R) 1.029 1.029
14 Cp/Cv 1.246 1.246
15 Ideal Gas Cp/Cv 1.036 1.036
16 Ideal Gas Cp (kJ/kgmole-C) 239.0 239.0
17 Mass Ideal Gas Cp (kJ/kg-C) 2.093 2.093
18 Heat of Vap. (kJ/kgmole) 3.524e+004 ---
19 Kinematic Viscosity (cSt) 0.3383 0.3383
20 Liq. Mass Density (Std. Cond) (kg/m3) 708.3 708.3
21 Liq. Vol. Flow (Std. Cond) (m3/h) 1.570 1.570
22 Liquid Fraction 1.000 1.000
23 Molar Volume (m3/kgmole) 0.1850 0.1850
24 Mass Heat of Vap. (kJ/kg) 308.5 ---
25 Phase Fraction [Molar Basis] 0.0000 1.0000
26 Surface Tension (dyne/cm) 12.60 12.60
27 Thermal Conductivity (W/m-K) 0.1024 0.1024
28 Bubble Point Pressure (psia) 12.00 ---
29 Viscosity (cP) 0.2089 0.2089
30 Cv (Semi-Ideal) (kJ/kgmole-C) 289.2 289.2
31 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.532 2.532
32 Cv (kJ/kgmole-C) 238.7 238.7
33 Mass Cv (kJ/kg-C) 2.090 2.090
34 Cv (Ent. Method) (kJ/kgmole-C) --- ---
35 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
36 Cp/Cv (Ent. Method) --- ---
37 Reid VP at 37.8 C (psia) 0.5533 0.5533
38 True VP at 37.8 C (psia) 0.5533 0.5533
39 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 1.570 1.570
40 Viscosity Index -18.73 ---
41
42
COMPOSITION
43
44
Overall Phase Vapour Fraction 0.0000

45 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
46 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
47 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 i-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 n-Octane 9.7343 1.0000 1111.9686 1.0000 1.5764 1.0000
52 Total 9.7343 1.0000 1111.9686 1.0000 1.5764 1.0000
53
54
Liquid Phase Phase Fraction 1.000

55 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
56 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
57 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 n-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 i-Butane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 n-Octane 9.7343 1.0000 1111.9686 1.0000 1.5764 1.0000
62 Total 9.7343 1.0000 1111.9686 1.0000 1.5764 1.0000
63
64
K VALUE
65 COMPONENTS MIXED LIGHT HEAVY
66 Nitrogen 0.0000 0.0000 ---
67 Ethylene 0.0000 0.0000 ---
68 n-Butane 0.0000 0.0000 ---
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K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 i-Butane 0.0000 0.0000 ---
13 n-Octane 0.0000 0.0000 ---
14
15 Mixer: MIX-100
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CONNECTIONS
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Inlet Stream
21 STREAM NAME FROM UNIT OPERATION
22 FEED
23 STREAM RECYCLE Recycle RCY-1
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Outlet Stream
26 STREAM NAME TO UNIT OPERATION
27 FEED 1 Conversion Reactor CRV-100
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