SAFETY DATA SHEET

Date of issue/Date of revision 18 June 2020

Version 13

Section 1. Identification
Product name : AQUAPON Zinc Rich Epoxy Primer Kit
Product code : 00338242
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Industries, Inc.

One PPG Place
Pittsburgh, PA 15272
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)

Technical Phone Number : 888-977-4762

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 79.2%
(Oral), 80.8% (Dermal), 5.2% (Inhalation)
GHS label elements
Hazard pictograms :

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Section 2. Hazards identification

Signal word : Danger
Hazard statements : Flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Precautionary statements
Prevention : Obtain special instructions before use. Wear protective gloves. Wear protective
clothing. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Use explosion-proof electrical,
ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static
discharges. Avoid breathing vapor. Wash thoroughly after handling.
Response : Immediately call a POISON CENTER or doctor. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Sanding and grinding dusts may be harmful if inhaled. Repeated exposure to high vapor
elements concentrations may cause irritation of the respiratory system and permanent brain and
nervous system damage. Inhalation of vapor/aerosol concentrations above the
recommended exposure limits causes headaches, drowsiness and nausea and may
lead to unconsciousness or death. Avoid contact with skin and clothing. Wash
thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : AQUAPON Zinc Rich Epoxy Primer Kit

Ingredient name % CAS number

xylene ≥1.0 - ≤5.0 1330-20-7
Epoxy resin (700<MW<1100) ≥1.0 - ≤5.0 25068-38-6
butan-1-ol ≥1.0 - ≤4.7 71-36-3
zinc oxide ≥1.0 - ≤3.8 1314-13-2
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil ≥1.0 - ≤5.0 68082-29-1
fatty acids and triethylenetetramine
diiron trioxide ≥1.0 - ≤5.0 1309-37-1
Isopropyl alcohol ≥1.0 - ≤5.0 67-63-0
ethylbenzene <1.0 100-41-4
toluene <1.0 108-88-3
4-methylpentan-2-one <1.0 108-10-1

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

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Section 3. Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Section 4. First aid measures

Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

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Section 7. Handling and storage

Conditions for safe storage, : Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance
including any with local regulations. Store in a segregated and approved area. Store in original
incompatibilities container protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see Section 10) and food and drink. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
xylene ACGIH TLV (United States, 3/2019).
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Epoxy resin (700<MW<1100) None.
butan-1-ol ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 300 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
zinc oxide OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2019).
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall- None.
oil fatty acids and triethylenetetramine
diiron trioxide ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 5/2018).
TWA: 10 mg/m³ 8 hours.
Isopropyl alcohol ACGIH TLV (United States, 3/2019).
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 980 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 3/2019).

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Section 8. Exposure controls/personal protection

TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
toluene OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
4-methylpentan-2-one ACGIH TLV (United States, 3/2019).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles and face shield.

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Section 8. Exposure controls/personal protection

Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 40°C (104°F)
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 3.15
Density ( lbs / gal ) : 26.29
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water

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Section 9. Physical and chemical properties

Viscosity : Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
Volatility : 48% (v/v), 12.908% (w/w)
% Solid. (w/w) : 87.092

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
Epoxy resin (700<MW<1100) LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LC50 Inhalation Vapor Rat 8000 ppm 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
zinc oxide LC50 Inhalation Dusts and mists Rat >5700 mg/m³ 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
diiron trioxide LC50 Inhalation Dusts and mists Rat >5 mg/l 4 hours
LD50 Oral Rat 10 g/kg -
Isopropyl alcohol LC50 Inhalation Vapor Rat 72600 mg/m³ 4 hours
LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5045 mg/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Dermal Rabbit 8.39 g/kg -

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Section 11. Toxicological information

LD50 Oral Rat 5580 mg/kg -
4-methylpentan-2-one LC50 Inhalation Vapor Rat 12.3 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 2.08 g/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Fatty acids, C18-unsatd., Skin - Irritant Human - - -
dimers, oligomeric reaction
products with tall-oil fatty
acids and
triethylenetetramine
Eyes - Severe irritant Rabbit - - -
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Product/ingredient name Route of Species Result
exposure
Fatty acids, C18-unsatd., skin Mouse Sensitizing
dimers, oligomeric reaction
products with tall-oil fatty
acids and
triethylenetetramine
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Classification
Product/ingredient name OSHA IARC NTP
xylene - 3 -
diiron trioxide - 3 -
Isopropyl alcohol - 3 -
ethylbenzene - 2B -
toluene - 3 -
4-methylpentan-2-one - 2B -
Carcinogen Classification code:

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Section 11. Toxicological information

IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -

Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
xylene Category 3 - Respiratory tract
irritation
butan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Isopropyl alcohol Category 3 - Narcotic effects
toluene Category 3 - Narcotic effects
4-methylpentan-2-one Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Target organs : Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the nervous system, liver, spleen, upper respiratory tract, skin, central nervous
system (CNS), ears, eye, lens or cornea.

Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms

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Section 11. Toxicological information

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.

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Section 11. Toxicological information

Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
AQUAPON Zinc Rich Epoxy Primer Kit 3296.4 3176.8 N/A 226.3 30.9
xylene 4300 1700 N/A 11 1.5
Epoxy resin (700<MW<1100) 2500 2500 N/A N/A N/A
butan-1-ol 790 3400 N/A 24 N/A
zinc oxide N/A 2500 N/A N/A N/A
diiron trioxide 10000 N/A N/A N/A N/A
Isopropyl alcohol 5045 12800 N/A 72.6 N/A
ethylbenzene 3500 17800 N/A 17.8 1.5
toluene 5580 8390 N/A 49 N/A
4-methylpentan-2-one 2080 N/A N/A 12.3 1.5

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
butan-1-ol Acute LC50 1376 mg/l Fish 96 hours
zinc oxide Acute EC50 0.17 mg/l Algae 72 hours
Acute EC50 0.481 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Chronic NOEC 0.017 mg/l Fresh water Algae 72 hours
Fatty acids, C18-unsatd., EC10 1.78 mg/l Algae 72 hours
dimers, oligomeric reaction
products with tall-oil fatty
acids and
triethylenetetramine
diiron trioxide Acute EC50 >100 mg/l Daphnia 48 hours
Isopropyl alcohol Acute EC50 10100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
ethylbenzene Acute LC50 150 to 200 mg/l Fresh water Fish 96 hours
4-methylpentan-2-one Acute LC50 >179 mg/l Fish 96 hours

Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
4-methylpentan-2-one OECD 301F 83 % - Readily - 28 days - -

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Section 12. Ecological information

Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
Fatty acids, C18-unsatd., - - Not readily
dimers, oligomeric reaction
products with tall-oil fatty
acids and
triethylenetetramine
ethylbenzene - - Readily
toluene - - Readily
4-methylpentan-2-one - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
xylene 3.16 7.4 to 18.5 low
butan-1-ol 0.88 - low
Isopropyl alcohol 0.05 - low
ethylbenzene 3.15 79.43 low
toluene 2.73 8.32 low
4-methylpentan-2-one 1.31 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

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14. Transport information

DOT IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper shipping PAINT PAINT PAINT
name
Transport hazard class 3 3 3
(es)
Packing group III III III
Environmental hazards No. Yes. Yes. The environmentally
hazardous substance mark is
not required.
Marine pollutant Not applicable. (Zinc powder - zinc dust Not applicable.
substances (stabilized), zinc oxide)
Product RQ (lbs) 1291.5 Not applicable. Not applicable.
RQ substances (Zinc powder - zinc dust Not applicable. Not applicable.
(stabilized), xylene)

Additional information
DOT : This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft.
Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as
hazardous materials in package sizes less than the product reportable quantity.
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IATA : The environmentally hazardous substance mark may appear if required by other transportation
regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : Not determined.
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312

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Section 15. Regulatory information

Classification : FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
HNOC - Defatting irritant
Composition/information on ingredients
Name % Classification
xylene ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
Epoxy resin (700<MW<1100) ≥1.0 - ≤5.0 SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1B
butan-1-ol ≥1.0 - ≤4.7 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Fatty acids, C18-unsatd., dimers, ≥1.0 - ≤5.0 SKIN IRRITATION - Category 2
oligomeric reaction products SERIOUS EYE DAMAGE - Category 1
with tall-oil fatty acids and SKIN SENSITIZATION - Category 1A
triethylenetetramine
Isopropyl alcohol ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ethylbenzene <1.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
toluene <1.0 FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2

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Section 15. Regulatory information

ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
4-methylpentan-2-one <1.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
SARA 313
Chemical name CAS number Concentration
Supplier notification : Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100
xylene 1330-20-7 1-5
butan-1-ol 71-36-3 1-5
zinc oxide 1314-13-2 1-5
ethylbenzene 100-41-4 0.1 - 1
4-methylpentan-2-one 108-10-1 0.1 - 1
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.

California Prop. 65
WARNING: Cancer and Reproductive Harm - [Link].

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 3 * Flammability : 2 Physical hazards : 1
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 3 Flammability : 2 Instability : 1
Date of previous issue : 2/27/2020
Organization that prepared : EHS
the MSDS
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient

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Section 16. Other information

MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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