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Phase Change Answer Key & Energy Values

This document contains the answer key for exercises related to thermochemistry. It provides the answers to multiple choice and numerical value questions on topics like standard enthalpy of formation, heat of reaction, heat of combustion, bond energies, and thermochemical calculations. The exercises cover basic concepts in thermochemistry and calculating thermodynamic quantities like energy, temperature, heat, and entropy from thermochemical data.

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Amudala Hemashvini
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33 views1 page

Phase Change Answer Key & Energy Values

This document contains the answer key for exercises related to thermochemistry. It provides the answers to multiple choice and numerical value questions on topics like standard enthalpy of formation, heat of reaction, heat of combustion, bond energies, and thermochemical calculations. The exercises cover basic concepts in thermochemistry and calculating thermodynamic quantities like energy, temperature, heat, and entropy from thermochemical data.

Uploaded by

Amudala Hemashvini
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Page # 28 THERMOCHEMISTRY

Answer-Key

Exercise-I

1. D 2. D 3. D 4. A 5. C 6. C 7. B 8. A
9. A 10.C 11. A 12. D 13. D 14. C
15. (i) B (ii) A (iii) A (iv) C 16. A  (P,R), B  (Q,S), C  (Q,S), D  (Q,S)
17. A  (P,S), B  (Q), C  (R) 18. A 19. B 20. B 21. A 22. A
23. A 24. D 25. B 26. A 27. B 28. B 29. A

Exercise-II

1. C,D 2. A,B,C 3. C,D 4. A,B,C 5. B,C,D 6. A,Ca 7. C,D 8. B,C,D


9. A,B,C 10. A,C 11. A,C,D 12. A,B,C,D 13. A,C,D

Exercise-III

1. –324.8 kJ/mol 2. –34.5 kJ/mol 3. –26.8 kJ/mol 4. 35.973 MJ


5. 18.95% 6. 25.66 days 7. E = 27.91 KJ mol–1, t = 514 sec.
8. 27.43 g O2 9. –22.123 k cal 10. 2.95 kcal 11. –1410 cal 12. –18.7 kcal
13. 11.2 Kcal 14. –75.14 kJ/mol 15. (i) –885 kJ/mol (ii) –889.980 kJ/mol
16. 10.0 mol% CH4 17. –726.6 kJ/mol 18. 208 kJ/mol 19. –120.08 J/ml
20. B.E. (C – C) = 82 kcal/mole; fH [C2H6(g)] = – 20.1 kcal/mole 21. –72 kJmol–1
22. (i) 343.08 ; (ii) 891.2 23. EC  C = 160.86 k cal 24. –192.3 kJ mol–1 25. 277.5 kJ/mol
26. –23.68 KJ/mol 27. –669.7 kJ mol 28. –352 kJ mol–1 29. –618.7 kJ mol–1 30. –90.75 kcal mol–1

Exercise-IV

1. –85 kJ/mole 2. (a) 92.435 g (b) 93.72 g 3. 404 K


4. mole % O2(g) = 37.5, H2O (g) = 62.5
b
5. (a) (i) aT (ii) aT + (T 2 – T12) (b) 1000cal, 1012cal, 1.1858% error
2 2
6. 0.9346 k cal g–1, 3.94 kcal cm–3 7. 9.822 MJ/day evolved
8. 1 : 3 9. –666.81 k cal mol–1, 15.55 Mcal
10. C – C = 97.81 kJ, C – H = 454.64 kJ, C = O = 804.26 kJ, C = C = 434.3 kJ, C = C = 733.48 kJ
11. +20.6 kcal 12. –266 kJ mol–1 13. 292 kcal/mol
14. for Cl – 384 kJ mol , for I – 307 kJ mol–1
– –1 –
15. advantage = 5393 kJ mol–1
16. –718 kJ/mol 17. –30.06 kJ/mol 18. 22 kcal mol–1
19. 2.80 : 1

Exercise-V

1. B 2. B 3. A 4. C 5. B 6. –2035 kJ mol–1 7. 309.6 kJ/mol

8. 9 9. D

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 [Link], email-info@[Link]

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