FeO + 2 HCl = FeCl2 + H2O
(T) (T,g) (T) (T)
___ _ ______ _ _____ _ ___
T(K) Delta_H�(J) Delta_G�(J) Delta_Vol(litre) Delta_S�(J/K)
Delta_Cp(J/K) Keq T
_____________ ______________ ___________ ________________ _____________
_____________ __________ _
------ FeO(s) HCl(g) FeCl2(s) H2O(l) ------
300.00 -177125.0 -103652.4 -4.9235E+01 -244.908 4.4152E+01
1.1144E+18
373.50 -173926.4 -86014.4 -6.1298E+01 -235.371 4.3775E+01
1.0687E+12
------ FeO(s) HCl(g) FeCl2(s) H2O(g) ------
H2O(1 mol): DH� = 40855.8 DG� = 0 ------ DS� = 109.385
373.50 -133070.6 -86014.4 -3.0649E+01 -125.986 1.8252E+00
1.0687E+12
400.00 -133018.2 -82678.1 -3.2823E+01 -125.850 2.1563E+00
6.2571E+10
500.00 -132713.4 -70124.4 -4.1029E+01 -125.178 3.9984E+00
2.1167E+07
600.00 -132224.4 -57649.7 -4.9235E+01 -124.291 5.7089E+00
1.0441E+05
700.00 -131588.8 -45269.2 -5.7440E+01 -123.314 6.9151E+00
2.3875E+03
800.00 -130857.8 -32986.8 -6.5646E+01 -122.339 7.6294E+00
1.4248E+02
900.00 -130076.4 -20799.5 -7.3852E+01 -121.419 7.9409E+00
1.6112E+01
950.00 -129678.2 -14739.5 -7.7955E+01 -120.988 7.9751E+00
6.4627E+00
------ FeO(s) HCl(g) FeCl2(l) H2O(g) ------
FeCl2(1 mol): DH� = 43012.0 DG� = 0 ------ DS� = 45.276
950.00 -86666.2 -14739.5 -7.7955E+01 -75.712 2.3184E+01
6.4627E+00
1000.00 -85519.1 -10983.6 -8.2058E+01 -74.535 2.2690E+01
3.7472E+00
1100.00 -83304.6 -3638.2 -9.0264E+01 -72.424 2.1573E+01
1.4885E+00
1200.00 -81212.2 3510.8 -9.8469E+01 -70.603 2.0255E+01
7.0337E-01
1300.00 -79257.8 10490.8 -1.0668E+02 -69.037 1.8811E+01
3.7886E-01
1315.58 -78966.7 11564.5 -1.0795E+02 -68.815 1.8575E+01
3.4741E-01
------ FeO(s) HCl(g) FeCl2(g) H2O(g) ------
FeCl2(1 mol): DH� = 128955.9 DG� = 0 ------ DS� = 98.022
1315.58 49989.2 11564.5 0.0000E+00 29.207 -2.0074E+01
3.4741E-01
1400.00 48253.3 9152.8 0.0000E+00 27.929 -2.1062E+01
4.5553E-01
1500.00 46084.7 6434.8 0.0000E+00 26.433 -2.2327E+01
5.9693E-01
1600.00 43784.9 3865.7 0.0000E+00 24.950 -2.3681E+01
7.4783E-01
1644.15 42725.8 2778.6 0.0000E+00 24.297 -2.4124E+01
8.1607E-01
------ FeO(l) HCl(g) FeCl2(g) H2O(g) ------
FeO(1 mol): DH� = 31189.1 DG� = 0 ------ DS� = 18.970
1644.15 11536.7 2778.6 0.0000E+00 5.327 -2.4124E+01
8.1607E-01
1700.00 10199.2 2503.6 0.0000E+00 4.527 -2.3771E+01
8.3767E-01
1800.00 7846.9 2119.0 0.0000E+00 3.182 -2.3275E+01
8.6798E-01
1900.00 5543.6 1863.9 0.0000E+00 1.937 -2.2795E+01
8.8871E-01
2000.00 3287.1 1728.8 0.0000E+00 0.779 -2.2340E+01
9.0126E-01
2100.00 1074.5 1705.4 0.0000E+00 -0.300 -2.1919E+01
9.0694E-01 T
2200.00 -1097.9 1786.6 0.0000E+00 -1.311 -2.1535E+01
9.0695E-01 T
2300.00 -3233.8 1965.6 0.0000E+00 -2.261 -2.1190E+01
9.0232E-01 T
2400.00 -5337.2 2236.9 0.0000E+00 -3.156 -2.0886E+01
8.9396E-01 T
2500.00 -7412.4 2595.2 0.0000E+00 -4.003 -2.0623E+01
8.8263E-01 T
2600.00 -9463.2 3036.1 0.0000E+00 -4.807 -2.0400E+01
8.6897E-01 T
2700.00 -11493.7 3555.4 0.0000E+00 -5.574 -2.0217E+01
8.5353E-01 T
2800.00 -13507.8 4149.7 0.0000E+00 -6.306 -2.0071E+01
8.3674E-01 T
2900.00 -15507.7 4815.7 0.0000E+00 -7.008 -1.9933E+01
8.1896E-01 T
3000.00 -17495.5 5550.4 0.0000E+00 -7.682 -1.9828E+01
8.0050E-01 T
3100.00 -19474.3 6351.2 0.0000E+00 -8.331 -1.9752E+01
7.8160E-01 T
3200.00 -21446.7 7215.8 0.0000E+00 -8.957 -1.9699E+01
7.6246E-01 T
3300.00 -23414.9 8141.9 0.0000E+00 -9.563 -1.9668E+01
7.4324E-01 T
3400.00 -25380.8 9127.7 0.0000E+00 -10.150 -1.9654E+01
7.2406E-01 T
3500.00 -27346.2 10171.3 0.0000E+00 -10.719 -1.9655E+01
7.0503E-01 T
3600.00 -29312.4 11271.0 0.0000E+00 -11.273 -1.9670E+01
6.8622E-01 T
3700.00 -31280.6 12425.4 0.0000E+00 -11.812 -1.9696E+01
6.6771E-01 T
3800.00 -33252.0 13633.1 0.0000E+00 -12.338 -1.9732E+01
6.4954E-01 T
3831.13 -33866.4 14019.7 0.0000E+00 -12.499 -1.9745E+01
6.4396E-01 T
------ FeO(g) HCl(g) FeCl2(g) H2O(g) ------
FeO(1 mol): DH� = 392509.2 DG� = 0 ------ DS� = 102.453
3831.13 -426375.6 14019.7 -3.1437E+02 -114.952 7.0188E+00
6.4396E-01
3900.00 -425897.5 21932.0 -3.2003E+02 -114.828 6.8647E+00
5.0846E-01
4000.00 -425222.0 33406.2 -3.2823E+02 -114.657 6.6463E+00
3.6624E-01
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