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Answer ALL questions.
Do NOT spend more than 30 minutes on Question 1.
1. (a) A student is provided with two solutions, X andY. X is aqueous sulphuric acid containing
4.9 g drn-3 •
Y is an aqueous sodium hydroxide solution which was prepared by dissolving 5.0 g of
impure sodium hydroxide in 1 dm3 of solution.
The student titrates X against 25.0 cm3 of Yin order to determine the purity of the sodium
hydroxide.
Figure 1 below shows the readings on the burette before and after each titration against
25 cm3 of solution Y.
.. ·.
·.· .·
Start End Start End Start End
Titration 1 Titration 2 Titration 3
Figure 1. Readings on the burette
(i) In the space below construct Table 1 to record the titration results. You should
include the initial and final burette volumes and the volume of solution X used.
TABLE 1
(7 marks)
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01212020/JANUARY/F 2006
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(ii) What is the volume of X to be used for calculation?
(1 mark )
(iii) Calculate the concentration of sulphuric acid in solution X in mol dm-3 .
(Relative atomic mass: H = 1; S = 32; 0 = 16)
(1 mark)
(iv) Calculate the number of moles of sulphuric acid used in the titration.
(1 mark )
(v) Write a balanced equation for the reaction between the sulphuric acid and sodium
hydroxide solutions.
(2 marks)
(vi) Determine the number of moles of sodium hydroxide in the 25 cm3 of solution
used .
(1 mark)
(vii) Calculate the concentration of NaOH in g dm·3 •
(Relative atomic mass: Na = 23; 0 = 16; H = 1)
(2 marks)
GO ON TO THE NEXT PAGE
01212020/JANUA RY/F 2006