Chemistry Q1 Module Overview and Labs
Chemistry Q1 Module Overview and Labs
Contents
Instructions: This credit recovery module integrates both textbook and software resources. It is
recommended that a student do the vocabulary for each chapter first, to prepare for reading the
chapter. Watching the Khan Academy chemistry clips will reinforce the reading and give some
examples. The Guided Reading Worksheets will help students focus as they read each of the
assigned chapters. At the conclusion of the Guided Reading will be a virtual lab. These labs
will need to be completed in the Learning Center where the software has been provided. Each
lab has a Record Sheet that should be completed as the student does the lab.
Vocabulary Review
Column A Column B
d. electrons
_____3. a vertical column of elements
in the periodic table e. atomic number
_____4. subatomic particles with no f. atomic mass
charge
g. group
_____6. the smallest particle of an
element that retains its identity in a h. nucleus
chemical reaction
i. periodic table
_____7.the number of protons in the
j. proton
nucleus of an element
This section describes early atomic theories of matter and provides ways to understand the tiny
size of individual atoms.
1. Democritus, who lived in Greece during the fourth century B.C., suggested that matter is
made up of tiny particles that cannot be divided. He called these particles
__________________.
2. List two reasons why the ideas of Democritus were not useful in a scientific sense.
____________________________________________________________________________
____________________________________________________________________________
____________________________________________________
3. The modern process of discovery about atoms began with the theories of an English
schoolteacher named ________________________.
4. Circle the letter of each sentence that is true about Dalton’s atomic theory.
5. Skip to number 6
6. Suppose you could grind a sample of the element copper into smaller and smaller particles.
The smallest particle that could no longer be divided, yet still has the chemical properties of
copper, is ________________________________________________________________
7. About how many atoms of copper when placed side by side would form a line 1 cm long?
____________________________________________________________
Match each term from the experiments of J.J. Thomson with the correct description.
7. The diagram shows electrons moving from left to right in a cathode-ray tube. Draw an arrow
showing how the path of the electrons will be affected by the placement of the negatively and
positively charged plates.
8. Thomson observed that the production of cathode rays did not depend on the kind of gas in
the tube or the type of metal used for the electrodes. What conclusion did he draw from these
observations?__________________________________________________________
_____________________________________________________________________
9. What two properties of an electron did Robert Millikan determine from his
experiments?___________________________________________________________
10. Circle the letter of each sentence that is true about atoms, matter, and electric charge.
12. The positively charged subatomic particle that remains when a hydrogen atom loses an
electron is called ______________________________________.
16. Explain why in 1911 Rutherford and his coworkers were surprised when they shot a narrow beam of alpha
particles through a thin sheet of gold foil.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
17. Circle the letter of each sentence that is true about the nuclear theory of atoms suggested
by Rutherford’s experimental results.
b. All the positive charge of an atom is concentrated in a small central region called the nucleus.
This section explains how atomic number identifies an element; how to use atomic number and mass
number to find the number of protons, neutrons, and electrons in an atom, how isotopes differ; and how to
calculate average atomic mass.
1. Circle the letter of the term that correctly completes the sentence. Elements are different
because their atoms contain different numbers of _______________.
a. electrons
b. protons
c. neutrons
d. nuclei
2. Complete the table showing the number of protons and electrons in atoms of six elements.
4. What is the mass number of a helium atom that has two protons and two neutrons? _______
5. How many neutrons does a beryllium atom with four protons and a mass number of nine
have? ________________
6. Place the labels chemical symbol, atomic number, and mass number in the shorthand
notation below.
Ne ←
→
7.
Designate
the
atom
shown
in
Question
6
in
the
form
“name
of
element”
–
“mass
number.”
_______________
8. How
many
protons,
neutrons,
and
electrons
are
in
the
atom
discussed
in
questions
6
and
7?
Protons:
_____
Neutrons:
_____
Electrons:
_____
_____________________________________________________________________________
_____________________________________________________________________________
11. Is the following sentence true or false? Isotopes are chemically alike because they have identical
numbers of protons and electrons. ________________________________________________
Match the designation of each hydrogen isotope with its commonly used name.
15. Why is the atomic mass unit (amu), rather than the gram, usually used to express whole
mass? _________________________________________________________
____________________________________________________________________
16. Skip to 18
17. Skip to 18
18. Circle the letter of each statement that is true about the average atomic mass of an element
and the relative abundance of its isotopes.
19. Circle the letter of the correct answer. When chlorine occurs in nature, there are three
atoms of chlorine-35 for every one atom of chlorine-37. Which atomic mass number is closer to
the average atomic mass of chlorine?
a. 35 amu b. 37 amu
20. In the periodic table, the elements are organized into groups based on
___________________________________________________________________________________.
21. What are the horizontal rows in the periodic table called?
_________________________________________________________________________________
Fill in the write-on lines and boxes provided as you work through the guided practice problems.
18. Use Table 4.2 to express the compositions of carbon-12, fluorine-19, and beryllium-9 in shorthand
notation.
Analyze
Carbon-12
Calculate
Step 2. The number of protons plus the number of neutrons in an atom is called its _________________
number. For carbon-12, this number is ____________.
Mass number →
Atomic number →
Evaluate
Step 4
Except for hydrogen-1, the mass number of an isotope is always greater than its atomic number. Is the
mass number reasonable? _________________
Solve
Flourine-19
Solve
Beryllium-9
____________________________________________________________________________
____________________________________________________________________________
24. Calculate the atomic mass of rubidium. The two isotopes of rubidium have atomic masses
and relative abundancies of 84.91 amu (72.16%) and 86.91 amu (27.84%)._______________
3. Point the cursor arrow at the base of the metal sample stand (in the center) and squeeze the
mouse. What metal foil is used?
4. Point the cursor arrow to the detector (on the right). What detector is used in this
experiment?
5. Turn on the detector by clicking on the red/green light switch. What does the signal in the
middle of the screen represent?
Click on the Persist button (the dotted arrow) on the phosphor detector screen. According
to the plum pudding model, what is causing the deflection of the alpha particles?
Make an observation of the number of alpha particles hitting the phosphor detection screen.
6. Now, you will make observations at different angles of deflection. Click on the gray lab
table window to bring it to the front. Grab the phosphor detection screen by its base and
move it to the spotlight in the top right corner. The Persist button should still be on.
Describe the number of hits in this spotlight position as compared to the first detector
position.
7. Move the detector to the top center spotlight position at a 90-degree angle to the foil
stand. Describe the number of hits in this spotlight position as compared to the first detector
position.
8. Move the detector to the top left spotlight position. Describe the number of hits in this
spotlight position as compared to the first detector position.
How do these results disprove the plum pudding model? Keep in mind that there are
1,000,000 alpha particles passing through the gold foil at any given second.
Further Investigation
Students often ask, “Why did Rutherford use gold foil?” The most common response is that
gold is soft and malleable and can be made into very thin sheets of foil. There is another
reason, which you can discover for yourself.
1. Turn off the phosphor detection screen. Double-click the base of the metal foil sample
holder. It will move the holder to the stockroom window. Click on the Stockroom to enter.
Click on the metal sample box on the top shelf. Click on Na to select sodium. Return to
Lab.
2. Move the metal foil sample holder from the stockroom window back to the center
spotlight. Turn on the phosphor detection screen. Click Persist. Observe the number of
hits with sodium compared to the number of hits with a gold sample. Why would
Rutherford choose gold foil instead of sodium foil? Explain.
This section summarizes the development of atomic theory. It also explains the significance of quantized energies of
electrons as they relate to the quantum mechanical model of the atom.
1. Complete the table about atomic models and the scientists who developed them.
Thomson
Rutherford
Bohr
2. Is the following sentence true or false? The electrons in an atom can exist between energy
levels. ____________________
____________________________________________________________________________
4. Circle the letter of the term that completes the sentence correctly. A quantum of energy is the
amount of energy required to
a. move an electron from its present energy level to the next lower one.
c. move an electron from its present energy level to the next higher one
5. In general, the higher the electron is on the energy ladder, the __________________ it is
from the nucleus.
6. What is the difference between the previous models of the atom and the modern quantum mechanical
model?
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
Prepare by reading the chapter and watching the 3 Khan Academy videos:
1. [Link]
2. [Link]
3. [Link]
This section shows you how to apply the aufbau principle, the Pauli exclusion principle, and Hund’s rule to help you
write the electron configurations of elements. It also explains why the electron configurations for some elements
differ from those assigned using the aufbau principle.
> Electron Configurations (pages 133-135)
1. The ways in which electrons are arranged around the nuclei of atoms are called
___________________________.
Match the name of the rule used to find the electron configurations of atoms with the rule itself.
_______ 2. aufbau principle a. When electrons occupy orbitals of equal energy,
one electron enters each orbital until all the
orbitals contain one electron with parallel spins.
_______ 3. Pauli exclusion principle b. Electrons enter orbitals of lowest energy first.
6. Fill in the electron configurations for the elements given in the table. Use the orbital filling
diagrams to complete the table.
SECTION 5.3 PHYSICS AND THE QUANTUM MECHANICAL MODEL (pages 138-146)
This section explains how to calculate the wavelength, frequency, or energy of light, given two of these values. It also
explains the origin of the atomic emission spectrum of an element.
2. The units of frequency are usually cycles per second. The SI unit of cycles per second is
called a(n)__________________.
3. Label the parts of a wave in this drawing. Label the wavelength, the amplitude, the crest,
and the origin.
9. Look at Figure 5.10 on page 139. The electromagnetic spectrum consists of radiation over a
broad band of wavelengths. What type of radiation has the lowest frequency? The highest
frequency? _________________________________________________
_____________________________________________________________________
11. Passing the light emitted by an element through a prism gives the
_____________________________ of the element.
12. Is the following sentence true or false? The emission spectrum of an element can be the
same as the emission spectrum of another element. _________________________
15. What did Albert Einstein call the quanta of energy that is light? ____________________
16. What did de Broglie’s equation predict about the behavior of particles?______________
______________________________________________________________________
17. Is the following sentence true or false? The new method of describing the motions of
subatomic particles, atoms, and molecules is called quantum mechanics. ______________
18. Is the following sentence true or false? De Broglie’s conclusions were supported by
experimental evidence. ___________________
19. Does the Heisenberg uncertainty principle apply to cars and airplanes?
_____________________________________________________________________
Does this radiation have a longer or shorter wavelength than red light? ______________
Analyze
Step 1. What is the equation for the relationship between frequency and wavelength?
Solve
Step 4. Solve the equation for the unknown. λ= ____ / _____
Step 5. Substitute the known quantities into the equation and solve.
(3.00 x 108 m/s) / _____________ = _______________
Step 6. Compare the answer with the wavelength of red light. Does the given radiation
have a wavelength longer or shorter than that of red light?
Evaluate
Step 7. Explain why you think your result makes sense?
Step 8. Are the units in your answer correct? How do you know?
2. What is the purpose of using the cobalt glass in the identification of sodium and
potassium?
2. Click on the Visible/Full switch to magnify only the visible spectrum. You will see four
peaks in the spectrum. If you drag your cursor over a peak, it will identify the wavelength (in
nm) in the x-coordinate field in the bottom right corner of the window. Record the wavelength
in the table below for the four peaks in the hydrogen spectrum. (Round to whole numbers.)
3. Each wavelength corresponds to another property of light called its frequency. Use the
wavelength value of each of the lines to calculate its frequency given that
v=c/λ
where
c
–
2.988 1017 nm/s (2.998 108 m/s). The energy (E) of a quantum of light an atom emits is
related to its frequency
(v)
by
E
=
hv. Use the frequency value for each line and
h
=
6.63
X
10-‐
34
J
s
to calculate its corresponding energy.
5. To exchange gas samples, turn off the Spectrometer with the On/Off switch in the top
right corner. Double-click on the Electric Field to place it on the stockroom shelf. Double-
click on the Gas (H2) sample tube to place it on the stockroom shelf.
9. Determine the wavelength (in nm), the frequency (in 1/s) and the energy (kn J) for the
peak on the far right.
Wavelength (nm) Frequency (1/s) Energy (J)
Line (far right)
Purpose
To understand the origins of Quantum Theory by using a spectrometer to observe the emission
spectrum of several gases.
Background
The classical picture of atoms would allow electrons to be at any energy level. According to this
classical model, when electrons are excited and then fall back down to the ground state, they
emit light at all wavelengths and the emission spectrum would be continuous.
In the 1800s scientists found that when a sample of gas is excited by an alternating
electric current, it emits light only at certain discrete wavelengths. This allowed for the
development of spectroscopy, which is used in the identification and analysis of elements and
compounds. Even though scientists found spectroscopy very useful, they could not explain why
the spectrum was not continuous. The explanation of this was left to Niels Bohr, a Danish
physicist. Bohr proposed that energy levels of electrons are not continuous but quantized. The
electrons only exist in specific energy levels. Because of this quantization of energy, excited
electrons can only fall to discrete energy levels.
This assignment illustrates the measurements that helped Bohr develop his quantum
model, now known as Quantum Theory. It also illustrates some practical uses for this science.
Mercury vapor is used in fluorescent lights and sodium vapor in street lighting.
You can separate the lines in the full region of an emission spectrum by using an optical
prism or a diffraction grating. A spectrometer is an instrument designed to separate the emitted
light into its component wavelengths and plots the intensity of the light as a function of
wavelength.
Procedure
1. Start Virtual ChemLab and select Electronic State Energy Levels from the list of
assignments. The lab will open in the Quantum laboratory.
2. The lab table will be set up with four items. What is the detector on the right?
______________________________________________________________
______________________________________________________________
A heat source is used to heat the metal sample to high temperatures. What is the
temperature of the heat source?
______________________________________________________________
4. Turn the Spectrometer off with the On/Off switch. Click on the Stockroom. Click on the
clipboard on the right. Click on the preset lab #9 Photoemission – H2 and return to the lab
by clicking on the Return to Lab arrow. Click on the Visible/Full switch to change the view to
the visible spectrum. Record this spectrum in the Lab Book. Click just after the spectra file
name and type hydrogen gas. What observations can you make about the emission
spectrum for hydrogen gas?
5. To exchange gas samples, turn off the Spectrometer. Double-click on the Electric Field
to place it on the stockroom shelf. Double-click on the Gas (H2) sample tube to place it on
the stockroom shelf.
6. Click in the Stockroom. Click on the Gases sample on the top shelf. Click on the
cylinder labeled Ne to select neon as the gas and it will fill the gas sample tube. If you point
to the gas sample tube it should read Ne.
7. Return to Lab. Drag the gas sample tube off the stockroom shelf. When you select it, a
white spotlight will appear indicating where you can place the gas sample tube – place it
there. Drag the Electric Field and place it on the gas sample tube. Carefully click on the
button just above the far left zero on the volt meter and change the voltage to 300 V. Turn
on the Spectrometer. Click the Visible/Full switch to convert to only the visible spectrum.
Record this spectrum in the lab book and identify this link with the name of the element
typed after the blue link.
8. Continue with this same process until you have completed the following gas samples: H2,
He, Ne, Na, and Hg. You should have five spectra saved in the lab book in addition to
tungsten metal. Record your observations for each element. You can return to the lab book
and click on any of the spectra to view them again. Include in your observations a
comparison for each element to the spectrum for heated tungsten metal.
9. How do your observations of these gas emission spectra help confirm Quantum Theory?
2. Load the spectrum for mercury from the lab book into the spectrometer. Examine the
visible spectrum. Click the switch to change to full spectrum. What differences do you see
when changing between visible and full spectrum for mercury?
Mercury vapor is used in the fluorescent light tubes that you see at school and home. The
emitted light is not very bright for just the mercury vapor, but when scientists examined the
full spectrum for mercury they saw what you observed and recorded. There is an enormous
emission in the ultraviolet range (UV). This light Is sometimes called black light. You may
have seen it with glow-in-the dark displays.
Scientists coat the inside of the glass tube of fluorescent light tubes with a compounded that
will absorb UC and emit the energy as visible light with all the colors of the rainbow. All
colors together create white light which is why fluorescent light tubes emit very white light.
3. Load the spectrum for sodium. What distinct feature do you see in the sodium spectrum?
Astronomers are excited about cities changing from normal street lights to sodium vapor
street lights because astronomers can easily filter out the peak at 589 nm and minimize light
pollution.
Chapter 6-The Periodic Table Vocabulary. Match the item in Column B with Column A
Column A
1.
The
highest
occupied
s
and
p
sublevels
Column B
are
partially
filled.
a.
representative
elements
2.
The
highest
occupied
s
sublevel
and
a
nearby
d
sublevel
contain
electrons.
b.
electronegativity
3.
metals
having
only
2
electrons
in
the
highest
occupied
energy
level
c.
atomic
radius
4.
one
half
the
distance
between
the
nuclei
of
two
atoms
of
the
same
element
when
the
atoms
are
joined
d.
metals
5.
decreases
for
cations
and
anions
from
left
to
right
across
a
period
e.
ionization
energy
6.
measures
the
ability
of
an
atom
to
attract
electrons
when
the
atom
is
in
a
compound
f.
cation
7.
an
atom
or
group
of
atoms
that
has
a
positive
or
negative
charge
g.
noble
gases
8.
elements
in
which
the
highest
occupied
s
and
p
sublevels
are
filled
h.
alkali
metals
9.
nonmetals
of
Group
7A
i.
inner
transition
metals
10.
The
highest
occupied
s
sublevel
and
a
nearby
f
sublevel
contain
electrons.
j.
nonmetals
11.
energy
required
to
remove
an
electron
from
an
atom
k.
ionic
radius
12.
positively
charged
ion
l.
ion
13.
Group
1A
elements
m.
Group
2A
14.
good
conductors
of
heat
and
electric
current
n.
transition
metal
15.
negatively
charged
ion
o.
halogens
16.
poor
conductors
of
heat
and
electric
p.
anion
current
This section describes the development of the periodic table and explains the periodic law. It
also describes the classification of elements into metals, nonmetals and metalloids.
9. Explain the color coding of the squares in the periodic table in Figure 6.5.
_________________________________________________________
11. Is the following statement true or false? The variation in properties among metals is
greater than the variation in properties among nonmetals. _______
5. Classify each of the following elements as a (an) alkali metal, alkaline earth metal, halogen,
or noble gas.
a. sodium _____________ e. xenon ________________
b. chlorine ____________ f. potassium _____________
c. calcium ____________
d. fluorine ____________
6. For elements in each of the following groups, how many electrons are in the higher occupied
energy level?
a. Group 3A _______________
b. Group 1A _______________
c. Group 8A _______________
7. Complete the table about classifying elements according to the electron configuration of their
highest occupied energy level.
Prepare by reading the chapter and watching this Khan Academy Video:
[Link] 15 minutes
This section explains how to interpret group trends and periodic trends in atomic size, ionization
energy, ionic size, and electronegativity.
3. What is the general trend in atomic size within a group? Within a period?
____________________________________________________________
____________________________________________________________
4. What are the two variables that affect atomic size within a group?
a.____________________________________________________
b. ____________________________________________________
5. For each pair of elements pick the element with the largest atom.
Vocabulary Review
Select
the
term
from
the
following
list
that
best
matches
each
description.
mole
percent
composition
Avogadro’s
number
empirical
formula
molar
mass
standard
temperature
and
pressure
(0°
C,
1
atm)
22.4
L
1. a description of the relative amounts of each element in a compound
7. the temperature and pressure at which one mole of gas occupies a volume of 22.4 L
Prepare by reading the chapter and watching the Khan Academy video:
[Link] 10 minutes
This section defines and explains how the mole is used to measure matter. It also teaches you how to
calculate the mass of a mole of any substance.
1. What do the questions “how much” and “how many” have in common?
____________________________________________________________________________
______________________________________________________________
5. Circle the letter of the term that is NOT a representative particle of a substance.
a. molecule b. atom c. grain d. formula unit
6. List the representative particle for each of the following types of substances.
a. Molecular compounds _______________________________
b. Ionic compounds ________________________________
c. Elements ________________________________
7. Skip
8. How can you determine the number of atoms in a mole of a molecular compound?
________________________________________________________________________
________________________________________________________________________
Sodium ion
Sodium chloride
15. Is the following sentence true or false? Molar masses can be calculated directly from
atomic masses expressed in grams. ______________________
4. Circle the letter of each term that can complete this sentence correctly. The volume of a gas
varies with a change in
a. Temperature c. pressure
b. The size of the container d. the amount of light in the container
6. Is the following sentence true or false? Standard pressure is 101.3 kPa or 1 atmosphere
(atm). ______________________________
7. What is the molar volume of a gas at standard temperature and pressure (STP)?
____________________________________________________________________
8. What units do you normally use to describe the density of a gas?
____________________________________________________________________
10. Look at Figure 10.9 on page 300 to help you answer this question. Why is Avogadro’s
hypothesis reasonable? __________________________________________________
____________________________________________________________________________
____________________________________________________________________________
11. How many gas particles occupy a volume of 22.4L at a standard temperature and
pressure?___________________________________________________________
a. _______________________ c. _________________________
b. _______________________ d. _________________________
Step 2. Multiply the atoms of silicon 2.80 x 1024 atoms Si x (1 mol / £atoms Si )
by a mol/atoms conversion factor
Analyze
Knowns_____________________________________________________________________
____________________________________________________________________________
Unknown____________________________________________________________________
____________________________________________________________________________
Calculate
The first conversion factor is 6.02 x 1023 molecules of water / 1 mol water
= __________________
Evaluate
Purpose
Determine the mass of several samples of chemical elements and compounds and use the data
to count atoms.
Procedure
Start Virtual ChemLab and select Counting by measuring Mass from the list of assignments.
The lab will open in the Calorimetry laboratory.
2. Drag the Petri dish to the spotlight near the balance. Click on the Balance area to zoom
in. Drag the gold sample to the balance pan and record the mass in Table 1.
3. Click on the red disposal bucket to clear the lab after each sample. Repeat for lead (Pb),
uranium (U), sodium (Na) and a metal of your choosing.
gold (Au) lead (Pb) uranium (U) sodium (Na) Your Choice
Mass
(grams)
Molar Mass
(g/mol)
Moles of
each
element
Atoms of
each
element
Analyze
1. Calculate the moles of Au contained in the sample and enter into Table 1.
2. Calculate the atoms of Au contained in the sample and enter into Table 1.
3. Repeat steps 1 and 3 for the other metals and fill in the table. Clear the laboratory when
you are finished by clicking on the disposal bucket.
3. Pick up the Scoop and scoop out some sample; as you drag your cursor and the scoop
down the face of the bottle it picks up more. Select the largest sample possible and drag
the scoop to the weigh paper until it snaps in place which will place the sample on the
paper. Record the mass of the sample in Table 2.
4. Repeat steps 1-3 for table sugar (sucrose, C12H22O11), NH4Cl, C6H5OH (phenol), and a
compound of your choice. Record the mass of each sample in table 2.
Analyze
1. Calculate the moles of C12H22O11 contained in the sample and record your results in Table 2
2. Calculate the moles of each element in C12H22O11 and record your results in Table 2.
3. Calculate the atoms of each element in C12H22O11 and record your results in Table 2.
4. Repeat steps 1-3 for the other compounds and record your results in table 2.