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Soda Lime Decarboxylation Mechanisms

1) The document discusses decarboxylation reactions, including the relative rates of decarboxylation for compounds P, Q, and R. P undergoes decarboxylation most rapidly, followed by Q, then R. 2) Intermediates in decarboxylation reactions and products of reactions involving malonic acid, alcohol Q, and other compounds are identified. 3) Multiple choice questions are presented regarding the identities of compounds involved in decarboxylation reactions, rates of decarboxylation, and reaction intermediates and products.

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Rajdeep Biswas
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143 views4 pages

Soda Lime Decarboxylation Mechanisms

1) The document discusses decarboxylation reactions, including the relative rates of decarboxylation for compounds P, Q, and R. P undergoes decarboxylation most rapidly, followed by Q, then R. 2) Intermediates in decarboxylation reactions and products of reactions involving malonic acid, alcohol Q, and other compounds are identified. 3) Multiple choice questions are presented regarding the identities of compounds involved in decarboxylation reactions, rates of decarboxylation, and reaction intermediates and products.

Uploaded by

Rajdeep Biswas
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

LOCUS ACADEMY DECARBOXYLATION

chemistry for iit jee & neet

01.
04.
intermediate in the above reaction is :

(1) (2) Order of rate of decarboxylation is:


(1) P > Q > R
(3) (4)
(2) R > Q > P
(3) Q > R > P

02. (4) Q > P > R

05.

which one is incorrect:


‘C’ is:

(1) (2) (1) ‘P’ is

(2) ‘Q’ is
(3) (4)

(3) (P) is more reactive than benzoic acid towards


03. soda lime
(4) (P) is less reactive than towards
soda lime

(C) and (B) are respectively:


06.
(1)

rate of decarboxylation is:


(2) CH3-CH3 , (1) 1 > 2 > 3
(2) 3 > 2 > 1
(3) 2 > 3 > 1
(3) CH3-CH3 ,
(4) 2 > 1 > 3

(4) CH3-CH3 , CH3-CH2-COOH


07. (2)

(P), (Q) and (R) are respectively:


(3)
(1) , CH3-COOH , CH3-CH2-CH2-COOH

(2) , CH3-COOH , CH3-CH2-COOH (4)

(3) , CH3-CH2-COOH , CH3-CH2-CH2-COOH


11.
(4)

(1)
08.

(2)
rate of decarboxylation is:
(1) 1 > 3 > 2 (2) 1 > 2 > 3
(3) 3 > 2 > 1 (4) 3 > 1 > 2 (3)
09. Most stable carbanion is:

(1) (4)

(2) 12.

(3) (1)

(4)
(2)
10. Which of the following will loose its
molecular mass most easily :

(1) (3)
(4) 15.

13. (P) and (R) respectively:

(1)

(Q) = alcohol.
(Q) + Conc.H2SO4 (R)

(2)

(Q) and (S) are respectively:

(1) , , CH3-CH2-CH2-CH2-CH2-COOH (3)

(2) , CH3-CH2-CH2-CH2-CH2-COOH (4)

(3) , CH3-CH2-CH2-CH2-CH2-CH2-COOH 16.

(4) ,,
(B) is:

14. (1)

(2)

(C) and (D) are respectively:


(1) CH3-CH2-CH2-NH2 ,
(3)

(2) CH3-CH2-CH2-NH-CH3 ,

(3) CH3-CH2-CH2-NH-CH3 , (4)

(4) CH3-CH2-CH2-NH2 ,
17. Malonic acid Δ (A) + gas (x) 20.
(A) LiAlH4 (B)
𝐍𝐚𝐎𝐂𝐥 (A) and (B) are respectively:
(B) (C)
𝑯𝟑 𝑶+

(A) , (B) and (C) are respectively:


(1)
(1) CH3-COOH, CH3-CH2OH, HCOOH
(2) CH3-CH2-COOH, , CH3COOH

(2)
(3) CH3-COOH , , CH3-COOH

(4) CH3-CH2-COOH , CH3-CH2-OH , HCOOH.

(3)

18.

(4)
rate of decarboxylation is:
(1) I > II > III
(2) I > III > II
(3) II > I > III
(4) II > III > I

19.

(B) is:

(1)

(2)

(3)

(4)

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