Chem 101 YA1 Assignment 2
Names: Date: Score:
I. Tell whether a precipitation reaction takes place using the given pair of aqueous solutions. If it does, give
the formula of the precipitate. Identify the spectator ions and write the chemical equations asked for.
Will
Formula of the
Reactants precipitation Spectator Ion(s)
Precipitate
take place?
1.) AgNO3(aq) and KI(aq)
Balanced molecular equation
Complete ionic equation
Net ionic equation
2.) Ca(CH3COO)2 and Pb(ClO4)2
Balanced molecular equation
Complete ionic equation
Net ionic equation
3.) (NH4)2S and NaBr
Balanced molecular equation
Complete ionic equation
Net ionic equation
II. Complete and write the overall balanced chemical equation, the complete ionic equation, and the net ionic
equation for the reactions below.
Chemical Reactions Complete Ionic Equation Net Ionic Equation
1.) H3PO4(aq) + NaOH(aq)
_____________ + ____________
2.) CH3COOH(aq) + NaOH(aq)
_____________ + ____________
3.) HClO4(aq) + NH3(aq)
____________ + ___________
III. For each of the following redox reactions, identify the substance oxidized, the substance reduced, the
oxidizing agent, and the reducing agent.
Substance Substance Oxidizing Reducing
Chemical Reactions
Oxidized Reduced Agent Agent
1.) Mg + CuCl2 MgCl2 + Cu
2.) WO3 + 3H2 W + 3H2O
3.) Cl2 + 2NaBr 2NaCl + Br2
IV. Balance the following redox equations using the indicated method.
1.) Pb + PbO2 + H + + SO4 2- PbSO4 + H2O (oxidation number method)
2.) H2O + P4 + HOCl H3PO4 + Cl - + H + (half reaction method in acidic medium)
3.) H+ + Cr2O72 - + H2S Cr 3 + + S + H2O (half reaction method in basic medium)
V. Solve the following problems and express your final answer with the correct unit and in the proper
number of significant figures. Enclose final answer in a box.
1.) How much ethanol, C2H5OH (density = 0.789 g/mL), in liters, must be dissolved in water to produce
500.0 L of 0.655 M C2H5OH?
2.) Determine the mass percent, molality, ppm and mole fraction of the solution formed from1.66 g of
C12H22O11 dissolved in 200. mL of water.
3.) What volume of water should be added to 19.5mL of 1.25M LiCl solution to make a 1.04M solution of it?
4. A 17.6mL of 1.33M Ca(OH)2 solution is titrated with 0.667M HBr. How many mL of HBr is required for
neutralization?
5. In a titration, 15.02mL of 0.100M NaOH was required to titrate 0.1011g of an unknown acid, HX. What is
the molar mass of the acid?
6.) A 20.00 g sample of vinegar, which contains acetic acid, HC 2H3O2, is placed in a flask together with few
drops of phenolphthalein solution (to serve as an indicator). The phenolphtahalein is colorless in acidic
medium. A 0.4500 M solution of NaOH is added from a buret, and the reaction is:
NaOH (aq) + CH3COOH (aq) → CH3COONa (aq) + H2O (l).
When 35.50 mL of the 0.4500M NaOH solution has been added, the phenolphthalein changes to a pink
color, which indicates the endpoint. What is the mass percentage of acetic acid in the sample of vinegar?